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At least 649 records · Page 36

Analysis of fouling mechanism in ultrafiltration of produced water

Flux decline measurements provided insight into the fouling behavior of ultrafiltration (UF) membranes for produced water (PW) treatment. Three UF membranes were compared in terms of the rate and the intensity of fouling. The flux decline analysis showed the fouling transition from blocking mechanisms (i.e., complete and intermediate blocking as well as standard blocking) to cake formation occurs earlier for more permeable membranes. Lower trans-membrane pressure (TMP) of 0.1 bar led to particle accumulation on the membrane surface leading to cake formation as the predominant fouling mechanism. In higher TMP experiments, standard and intermediate blocking followed by cake formation were found to be apparent fouling mechanisms. Overall, for the membranes with higher permeabilities and for the filtrations with pre-filtered feed, faster transition to cake formation was observed primarily due to crowd out effect. By understanding membrane fouling and behavior, it is possible to mitigate performance losses in membrane-based technologies that could be used for the treatment of PW. Furthermore, this study provides information to identify blocking rate and intensity in various conditions for UF membranes when treating PW.

42 ENGINEERING↗

Demonstrating imaging plate detector stacks for proton radiography using exploding pusher capsules

A new detector design has been fielded on the Omega-60 laser facility using a D 3 He backlighter capsule to radiograph a magnetized experiment. D 3 He capsules produce a low flux (~ 10 8 total yield in 4π) of protons requiring detectors with close-to single-particle sensitivity to be employed. The new detector stack consisted of both imaging plate (IP) and CR-39 to detect 14.7 MeV protons where, historically, only CR-39 has been used. IP is sensitive to significant contributions in signal from both x-rays and protons so additional filtering has to be added to attenuate the x-rays. Here, the signals and features observed from a single shot are detected by both IP and CR-39, giving confirmation that it is protons creating the signatures on the IP. Measurements of PSL/pixel are used to calculate approximate on-shot proton yields and agree with commonly measured yields. A second IP is used at the rear of the stack to measure, and subsequently remove, a background signal. The spatial resolution at the IP is limited, primarily, by a range of proton energies with varying deflections being recorded at the detector, causing potential ‘blurring’ of features. We find for this setup that the blurring effect is less than the smallest identifiable features observed at the detector, and therefore of minimal impact. A large benefit to this new stack design is that IP can be scanned and processed on much faster timescales than CR-39 allowing for prompt shot feedback. Future designs and modifications to the stack design fielded on this experiment could help improve the contrast of the radiograph on IP, as well as detecting protons produced at alternative energies.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Fiscal Year 2022. Filtration of Hanford Tank 241-AP-101 Supernatant at 16 °C

Bench-scale filtration testing of ~9 liters of supernatant from Hanford waste tank 241-AP-101, chilled to 16 °C, was conducted using a backpulse dead-end filter (BDEF) filtration system equipped with a feed vessel and a Mott inline filter Model 6610 (Media Grade 5) in the hot cells of the Radiochemical Processing Laboratory at Pacific Northwest National Laboratory. This was done to assess the performance of the anticipated third feed to the Tank Side Cesium Removal (TSCR) system. The as-received samples were diluted to the target sodium concentration and transferred to 1.5-liter polyethylene bottles and held at 16 °C for approximately 1 week prior to filtration. The feed was filtered through the BDEF system at a targeted flux of 0.065 gpm/ft 2 to match the prototypic operation of the TSCR system. During filtration, the differential pressure required to effect filtration at 0.065 gpm/ft 2 increased little over the filtration campaign and never reached 2 psid (the TSCR action limit). This indicates that the TSCR filter should perform well when processing AP-101 supernatant. After completing filtration of the AP-101 feed, the filter was cleaned. Solids concentrated from the backpulse solutions displayed sodium nitrate-type phases, aluminum and silicon phases reported as cancrinite or nitrate-cancrinite, a mixed chromium-aluminum oxide, iron oxides, and Ca-bearing phases (calcite). Scanning electron microscopy analyses showed that the average particle size was 0.5 micron.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Water purification system

A method and system for water purification includes a particle accelerator configured to generate a particle beam and a conduit configured to be substantially in line with the particle beam wherein said electron beam is incident on a fluid flowing through the conduit. The electron beam can be oriented to be substantially head on to the direction of flow of the fluid in the conduit. A shielding assembly can be configured around the conduit. A cartridge filtering system and contaminant filtering system can be provided to remove additional contaminants.

Geelhoed, Michael↗

Seeing through nuclear fuel: Three-dimensional, nondestructive X-ray microscopy and volumetric analyses of neutron-irradiated TRISO-coated fuel kernels

The three-dimensional (3D) characterization of nuclear fuel with X-ray microscopy has historically proven difficult, due to uranium’s high attenuation of easily accessible X-rays, both in a laboratory setting and at a synchrotron user facility. However, this imaging modality provides nondestructive information that can be used to investigate morphological changes arising from external stimuli (e.g., neutron irradiation, high-temperature testing). Using an appropriate X-ray energy spectrum and an adequate X-ray filter, suitable transmissions through properly sized nuclear fuel specimens can be achieved. Here, in this study, we present the methods and results of using a commercially available, laboratory-based X-ray microscope (XRM) to examine the extent of 3D morphological changes of tristructural isotropic (TRISO)-coated fuel particles, specifically uranium oxide/uranium carbide fuel kernels, after high-temperature neutron irradiation.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Quantifying oil filtration effects on bearing life

Rolling-element bearing life is influenced by the number, size, and material properties of particles entering the Hertzian contact of the rolling element and raceway. In general, rolling-element bearing life increases with increasing level of oil filtration. Based upon test results, two equations are presented which allow for the adjustment of bearing L(sub 10) or catalog life based upon oil filter rating. It is recommended that where no oil filtration is used catalog life be reduced by 50 percent.

Needelman, William M.↗

Growth of organized flow coherent motions within a single-stream shear layer: 4D-PTV measurements

Abstract This study investigates the evolution of a single-stream shear layer (SSSL) originating from a wall boundary layer past a backward-facing step. Utilizing a time-resolved 3D-Particle Tracking Velocimetry (4D-PTV) technique, we track the trajectories of fluorescent particles to gain insight into the flow characteristics of the SSSL. A compact water tunnel facility ( $$\textrm{Re}_\tau =1\,240$$ Re τ = 1 240 ) is fabricated to obtain an SSSL with a perpendicular slow entrainment stream past the separation edge. A hybrid interpolation approach that combines ensemble binning and Gaussian weighting is implemented to derive minimally filtered mean and instantaneous lower- and higher-order flow field parameters. Spanwise-dominant coherent motion accompanied by finer flow scales is observed to grow due to flow entrainment through “nibbling” actions of small-scale vortices, “engulfing” by large-scale vortices, and vortex pairing events. Furthermore, the non-zero-speed stream edge grows relatively faster than the zero-speed stream edge, showing a strong asymmetry in mixing composition across a mixing layer. The SSSL reaches self-similarity at a streamwise distance of $$\approx 55\,\theta _{0}$$ ≈ 55 θ 0 , where $$\theta _0$$ θ 0 is the initial momentum thickness from the separation edge, i.e., considerably shorter than reported in previous studies. A literature comparison of growth rate parameters raises intriguing questions regarding a potential inclusive growth scaling unifying the free shear layers. A turbulent kinetic energy (TKE) budget analysis reveals a negative production region immediately downstream of the separation edge attributed to a large positive streamwise gradient of streamwise velocity. In the self-similar region, the phase-averaged flow mapping demonstrates a larger concentration of turbulence production rate around the outer edges of spanwise vortices, specifically at the intersection of braids and vortices. Furthermore, a spatial separation exists in the regions of peak production and dissipation rates within the vortex core region favoring dissipation. The braids exhibit a larger concentration of turbulence diffusion rates, indicating their function as a conduit for exchanging turbulence between neighboring coherent motions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Installation of a solid state neutral particle analyzer array on mega ampere spherical tokamak upgrade

A compact solid state neutral particle analyzer (SSNPA) diagnostic, previously installed at NSTX-U, has been moved to MAST-U and successfully operated in the first physics campaign (MU01). The SSNPA operates by detecting the flux of fast neutral particles produced by charge exchange (CX) reactions to diagnose the fast ion distribution. The diagnostic consists of three 16-channel sensors, which provide a radial view of the plasma and have a sightline intersection with the South–South neutral beam line. From this radial geometry, active CX signals from mostly trapped particles are observed. Each channel has a spatial resolution of 3–4 cm, a temporal resolution of 200 kHz, and an average pitch angle resolution of a few degrees. The three-sensor configuration allows for coarse energy resolution of the CX signals; each sensor sees similar sightlines but different filter thicknesses alter the energy cutoffs by known amounts. Experimental data show that all channels are collecting data as intended. The signal to noise ratio is typically around 15. Preliminary data analysis shows a correlation between the SSNPA signal and magnetohydrodynamic activity in the plasma as expected.

Instruments & Instrumentation↗

Pancam Multispectral and APXS Chemical Examination of Rocks and Soils in Marathon Valley and Points South Along the Rim of Endeavour Crater

The Mars Exploration Rover Opportunity has concluded its exploration of Marathon Valley, a 100-meter-wide valley in the western rim of the 22-kilometer-diameter Endeavour crater. Orbital observations from CRISM (Compact Reconnaissance Imaging Spectrometer for Mars) indicated the presence of Fe smectites in Marathon Valley. Since leaving the valley, Opportunity has been traversing along the inner rim of the crater, and currently towards the outer rim. This presentation describes the Pancam 430 to 1009 nanometer (VNIR - Visible and Near Infared) multispectral reflectance and APXS (Alpha Particle X-ray Spectrometer) chemical compositions of rock and soil units observed during the latter portions of the Marathon Valley campaign on the Knudson Ridge area and observations of those materi-als along the traverse to the south. Full Pancam spectral coverage of rock targets consists of 13 filter (13f) data collections with 11 spectrally unique channels with data processing. Data were examined using spectral parameters, decorrelation stretch composites, and spectral mixture analysis. Note that color terms used here refer to colors in various false-color renditions, not true colors. The APXS determines major and select trace element compositions of targets.

Farrand, W. H.↗

Apparatus and methods for filtering granular solid material

Apparatuses for screening granular solid particulate material include a generally planar first screen and a second screen. A plurality of apertures extends through the first screen. At least a portion of the second screen is oriented at an angle to the first screen, and apertures extend through a perforated region of the second screen. The second screen includes at least one region configured to prevent at least some particles of solid material from passing through the second screen.

Backes, Douglas J.↗

Submicron and Nanoparticulate Matter Removal by HEPA-Rated Media Filters and Packed Beds of Granular Materials

Contaminants generated aboard crewed spacecraft by diverse sources consist of both gaseous chemical contaminants and particulate matter. Both HEPA media filters and packed beds of granular material, such as activated carbon, which are both commonly employed for cabin atmosphere purification purposes have efficacy for removing nanoparticulate contaminants from the cabin atmosphere. The phenomena associated with particulate matter removal by HEPA media filters and packed beds of granular material are reviewed relative to their efficacy for removing fine (less than 2.5 micrometers) and ultrafine (less than 0.01 micrometers) sized particulate matter. Considerations are discussed for using these methods in an appropriate configuration to provide the most effective performance for a broad range of particle sizes including nanoparticulates.

Perry, J. L.↗

An integrated dynamical and geochemical approach to lunar origin modelling

The three major categories of models of lunar origin which explain the Moon's properties are complete and a more general scenario is presented. The model presented is as the Earth grew by planetesimal bombardment, a circumterrestrial cloud of particles was created from a combination of impact ejected mantle material and planetismals captured directly into orbit around the Earth. The compositional properties are explained two ways: (1) a few big late planetismals of diverse composition are captured in orbit and/or hit the Earth; and (2) the circumterrestrial swarm acts as a filter, preferentially capturing small weak silicate bodies, while passing large iron planetismals.

Greenberg, R.↗

Accuracy Studies of a Magnetometer-Only Attitude-and-Rate-Determination System

A personal computer based system was recently prototyped that uses measurements from a three axis magnetometer (TAM) to estimate the attitude and rates of a spacecraft using no a priori knowledge of the spacecraft's state. Past studies using in-flight data from the Solar, Anomalous, and Magnetospheric Particles Explorer focused on the robustness of the system and demonstrated that attitude and rate estimates could be obtained accurately to 1.5 degrees (deg) and 0.01 deg per second (deg/sec), respectively, despite limitations in the data and in the accuracies of te truth models. This paper studies the accuracy of the Kalman filter in the system using several orbits of in-flight Earth Radiation Budget Satellite (ERBS) data and attitude and rate truth models obtained from high precision sensors to demonstrate the practical capabilities. This paper shows the following: Using telemetered TAM data, attitude accuracies of 0.2 to 0.4 deg and rate accuracies of 0.002 to 0.005 deg/sec (within ERBS attitude control requirements of 1 deg and 0.0005 deg/sec) can be obtained with minimal tuning of the filter; Replacing the TAM data in the telemetry with simulated TAM data yields corresponding accuracies of 0.1 to 0.2 deg and 0.002 to 0.005 deg/sec, thus demonstrating that the filter's accuracy can be significantly enhanced by further calibrating the TAM. Factors affecting the fillter's accuracy and techniques for tuning the system's Kalman filter are also presented.

Challa, M.↗

Cloud Thickness from Diffusion of Lidar Pulses in Clouds

Measurements of the distribution of reflected light from a laser beam incident on an aqueous suspension of particles or "cloud" with known thickness and particle size distribution are reported. The distribution is referred to as the "cloud radiative Green's function", G. In the diffusion domain, G is sensitive to cloud thickness, allowing that important quantity to be retrieved. The goal of the laboratory simulation is to provide preliminary estimates of sensitivity of G to cloud thickness,for use in the optimal design of an offbeam Lidar instrument for remote sensing of cloud thickness (THOR, Thickness from Offbeam Returns). These clouds of polystyrene microspheres suspended in water are analogous to real clouds of water droplets suspended in air. The microsphere size distribution is roughly lognormal, from 0.5 microns to 25 microns, similar to real clouds. Density of suspended spheres is adjusted so mean-free-path of visible photons is about 10 cm, approximately 1000 times smaller than in real clouds. The light source is a ND:YAG laser at 530 nm. Detectors are flux and photon-counting Photomultiplier Tube (PMTS), with a glass probe for precise positioning. A Labview 5 VI controls positioning, and data acquisition, via an NI Motion Control board connected to a stepper motor driving an Edmund linear slider, and a 16-channel 16-bit NI-DAQ board. The stepper motor is accurate to 10 microns, and step size is selectable from the VI software. Far from the incident beam, the rate of exponential increase as the direction of the incident beam is approached scales as expected from diffusion theory, linearly with the cloud thickness, and inversely as the square root of the reduced optical thickness, and is independent of particle size. Near the beam the signal begins to increase faster than exponential, due to single and low-order scattering near the backward direction, and here the distribution depends on particle size. Results are being used to verify 3D Monte Carlo radiative transfer simulations, used to estimate signal-to-noise ratios for remotely sensed off beam returns, for both homogeneous and inhomogeneous clouds. Signal-to-noise estimates show that unfiltered observations are straight forward at night, while narrow band pass filters are being studied for day.

Cahalan, Robert F.↗

Experimental validation of the Finite Element-Multibody model of a cryomodule during road transportation

The present activity aims to test the Transportation Tooling (TT) designed for the Cryomodule SSR1 at Fermilab facilities. The tests consisted of road transportation trials of a cryomodule sub-assembly, suspended on a truck using the designed TT. The truck drove along a path inside Fermilab facilities. The trial was performed at an approximate speed of about 25 km/h, which is close to the transportation conditions of the complete Cryomodule. Several accelerometers were mounted on the Transportation Tooling frame and the cryomodule sub-assembly. This allowed comparing the vibration behavior of the inner frame of the TT with the solicitation coming from the truck loading bed, to assess the filtering capabilities of the tooling. Also, the acceleration of the main components could be monitored during the whole transportation, to obtain a validation of the developed numerical model.

43 PARTICLE ACCELERATORS↗

Experimental and numerical investigation of sands and Geldart A biomass co-fluidization

This study investigated the fluidization of sands and small Geldart A biomass mixtures. The mixture fluidized like Geldart A type particles with a uniform bed expansion regime before bubbling. The video recorded color distance between pure sands and sands–biomass mixtures was used to estimate the sands–biomass mixing. The coarse-grained computational fluid dynamics–discrete element method with a hybrid drag model which couples the Syamlal–O'Brien drag and a filtered drag can capture the mixing while the simulation with Gidaspow drag predicted a segregated bed. The simulations were further validated with experimental measured pressure drops. The time averaged pressure drop equals the weight of the bed material, however, its fluctuation is about three times of the bed material fluctuation.

42 ENGINEERING↗

Uncertainty quantification and propagation in lithium-ion battery electrodes using bayesian convolutional neural networks

The complex nature of manufacturing processes stipulates electrodes to possess high variability with increased heterogeneity during production. X-ray computed tomography imaging has proved to be critical in visualizing the complicated stochastic particle distribution of as-manufactured electrodes in lithium-ion batteries. However, accurate prediction of their electrochemical performance necessitates precise evaluation of kinetic and transport properties from real electrodes. Image segmentation that characterizes voxels to particle/pore phase is often meticulous and fraught with subjectivity owing to a myriad of unconstrained choices and filter algorithms. Here we utilize a Bayesian convolutional neural network to tackle segmentation subjectivity and quantify its pertinent uncertainties. Otsu inter-variance and Blind/Referenceless Imaging Spatial Quality Evaluator are used to assess the relative image quality of grayscale tomograms, thus evaluating the uncertainty in the derived microstructural attributes. We analyze how image uncertainty is correlated with the uncertainties and magnitude of kinetic and transport properties of an electrode, further identifying pathways of uncertainty propagation within microstructural attributes. The coupled effect of spatial heterogeneity and microstructural anisotropy on the uncertainty quantification of transport parameters is also understood. This work demonstrates a novel methodology to extract microstructural descriptors from real electrode images through quantification of associated uncertainties and discerning the relative strength of their propagation, thus facilitating feedback to manufacturing processes from accurate image based electrochemical simulations.

25 ENERGY STORAGE↗

Numerical quantum clock simulations for measuring tunneling times

Here, we numerically study two methods of measuring tunneling times using a quantum clock. In the conventional method using the Larmor clock, we show that the Larmor tunneling time can be shorter for higher tunneling barriers. In the second method, we study the probability of a spin-flip of a particle when it is transmitted through a potential barrier including a spatially rotating field interacting with its spin. According to the adiabatic theorem, the probability depends on the velocity of the particle inside the barrier. It is numerically observed that the probability increases for higher barriers, which is consistent with the result obtained by the Larmor clock. By comparing outcomes for different initial spin states, we suggest that one of the main causes of the apparent decrease in the tunneling time can be the filtering effect occurring at the end of the barrier.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗