Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “morphological features”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Key Features of Polyimide‐Derived Carbon Molecular Sieves

Abstract Carbon molecular sieve (CMS) membranes have impressive separation properties; however, both chemical and morphology structures need to be understood better. Here we characterize CMS with the simplest polyimide (PI) PMDA/pPDA (PMDA=pyromellitic dianhydride, pPDA= p ‐phenylenediamine), using FTIR, solid‐state 15 N‐NMR and 13 C‐NMR, XPS, XRD, and Raman spectra to study chemical structure. We also compare gas separation properties for this CMS to a CMS derived from a more conventional PI precursor. The detailed characterization shows the presence of aromatic pyridinic, pyrrolic rings as well as graphitic, pyridonic components and a few other groups in both CMS types derived from the very different precursors. The CMS morphologies, while related to precursor and pyrolysis temperature details, show similarities consistent with a physical picture comprising distributed molecular sieving plate‐like structures. These results assist in understanding diverse CMS membrane separation performance.

Qiu, Wulin↗
DOE OSTI2021

Key Features of Polyimide-Derived Carbon Molecular Sieves

Carbon molecular sieve (CMS) membranes have impressive separation properties; however, both chemical and morphology structures need to be understood better. Here we characterize CMS with the simplest polyimide (PI) PMDA/pPDA (PMDA=pyromellitic dianhydride, pPDA=p-phenylenediamine), using FTIR, solid-state 15 N-NMR and 13 C-NMR, XPS, XRD, and Raman spectra to study chemical structure. Here we also compare gas separation properties for this CMS to a CMS derived from a more conventional PI precursor. The detailed characterization shows the presence of aromatic pyridinic, pyrrolic rings as well as graphitic, pyridonic components and a few other groups in both CMS types derived from the very different precursors. The CMS morphologies, while related to precursor and pyrolysis temperature details, show similarities consistent with a physical picture comprising distributed molecular sieving plate-like structures. These results assist in understanding diverse CMS membrane separation performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Dual-Responsive Macromolecular Surfaces with Binary Patterns

The development of nanopatterned interfaces incorporating multiple stimuli-responsive polymers has great potential for advancing smart sensors and molecular capture devices, yet it remains challenging due to limitations in patterning techniques and “grafting from” methods. Here, we present a binary-patterned surface featuring honeycomb-shaped photothermal polypyrrole (PPy) and thermally responsive poly(ethylene glycol methyl ether acrylate-co-poly(ethylene glycol) methyl ether acrylate) [poly(EGMEA-co-PEGMEA)] brushes within the cavities, fabricated using colloidal lithography and surface-initiated photoinduced electron transfer-reversible addition–fragmentation chain transfer (SI-PET-RAFT) polymerization. The morphology of the surface can be precisely tuned by adjusting the height of each domain. This design integrates unique topographical features with the stimuli-responsiveness of the polymer, enabling the collapse of the copolymer brushes through direct heating or photothermal conversion of PPy under near-IR light. In conclusion, this innovative system offers potential capture-release functionality, providing versatility for diverse applications and enhancing adaptability across different functional scenarios.

Copolymers↗
DOE OSTI2024

Street-level temperature estimation using graph neural networks: Performance, feature embedding and interpretability

Estimating street-level air temperature is a challenging task due to the highly heterogeneous urban surfaces, canyon-like street morphology, and the diverse physical processes in the built environment. Though pioneering studies have embarked on investigations via data-driven approaches, many questions remain to be answered. Here, in this study, we leveraged an innovative framework and redefined the street-level temperature estimation problem using Graph Neural Networks (GNN) with spatial embedding techniques. The results showed that GNN models are more capable and consistent of estimating street-level temperature among tested locations, benefiting from its unique strength in handling extensive data over unstructured graph topology. In addition, we conducted in-depth analysis of feature importance to enhance the model interpretability. Among the urban features analyzed in this study, the time-variant canopy density and meter-level land use data emerge as crucial factors. Our findings highlight GNN 's high potential in capturing the complex dynamics between urban elements and their impacts on microclimate, thus offering valuable insights for comprehensive urban data collection and urban climate modeling in general. Collectively, this study also contributes to urban planning and policy by providing avenues to enhance city resilience against climate change, thereby advancing the agenda for environmental stewardship and urban sustainability.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Detecting multi‐scale riverine topographic variability and its influence on Chinook salmon habitat selection

Abstract Quantifying geomorphic conditions that impact riverine ecosystems is critical in river management due to degraded riverine habitat, changing flow and thermal conditions, and increasing anthropogenic pressure. Geomorphic complexity at different scales directly impacts habitat heterogeneity and affects aquatic biodiversity resilience. Here we showed that the combination of continuous spatial survey at high resolution, topobathymetric light detection and ranging (LiDAR), and continuous wavelet analysis can help identify and characterize that complexity. We used a continuous wavelet analysis on 1‐m resolution topobathymetry in three rivers in the Salmon River Basin, Idaho (USA), to identify different scales of topographic variability and the potential effects of this variability on salmonid redd site selection. On each river, wavelet scales characterized the topographic variability by portraying repeating patterns in the longitudinal profile. We found three major representative spatial wavelet scales of topographic variability in each river: a small wavelet scale associated with local morphology such as pools and riffles, a mid‐wavelet scale that identified larger channel unit features, and a large wavelet scale related to valley‐scale controls. The small wavelet scale was used to identify pools and riffles along the entire lengths of each river as well as areas with differing riffle‐pool development. Areas along the rivers with high local topographic variability (high wavelet power) at all wavelet scales contained the largest features (i.e., deepest or longest pools) in the systems. By comparing the wavelet power for each wavelet scale to Chinook salmon redd locations, we found that higher small‐scale wavelet power, which is related to pool‐riffle topography, is important for redd site selection. The continuous wavelet methodology objectively identified scales of topographic variability present in these rivers, performed efficient channel‐unit identification, and provided geomorphic assessment without laborious field surveys.

Duffin, Jenna↗
DOE OSTI2025

Stemflow Hydrodynamics

Stemflow hydrodynamics is the study of water movement along the exterior surface area of plants. Its primary goal is to describe water velocity and water depth along the stem surface area. Its significance in enriching the rhizosphere with water and nutrients is not in dispute. Yet, the hydrodynamics of stemflow have been entirely overlooked. This review seeks to fill this knowledge gap by drawing from thin film theories to seek outcomes at the tree scale. The depth‐averaged conservation equations of water and solute mass are derived at a point. These equations are then supplemented with the conservation of momentum that is required to describe water velocities or relations between water velocities and water depth. Relevant forces pertinent to momentum conservation are covered and include body forces (gravitational effects), surface forces (wall friction), line forces (surface tension), and inertial effects. The inclusion of surface tension opens new vistas into the richness and complexity of stemflow hydrodynamics. Flow instabilities such as fingering, pinching of water columns into droplets, accumulation of water within fissures due to surface tension and their sudden release are prime examples that link observed spatial patterns of stemflow fronts and morphological characteristics of the bark. Aggregating these effects at the tree‐ and storm‐ scales are featured using published experiments. The review discusses outstanding challenges pertaining to stemflow hydrodynamics, the use of dynamic similarity and 3D printing to enable the interplay between field studies and controlled laboratory experiments.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

A Geomechanical Model for Gas Hydrate Bearing Sediments Incorporating High Dilatancy, Temperature, and Rate Effects

The geomechanical behavior of methane hydrate bearing sediments (MHBS) is influenced by many factors, including temperature, fluid pressure, hydrate saturation, stress level, and strain rate. The paper presents a visco-elastoplastic constitutive model for MHBS based on an elastoplastic model that incorporates the effect of hydrate saturation, stress history, and hydrate morphology on hydrate sediment response. The upgraded model is able to account for additional critical features of MHBS behavior, such as, high-dilatancy, temperature, and rate effects. The main components and the mathematical formulation of the new constitutive model are described in detail. The upgraded model is validated using published triaxial tests involving MHBS. The model agrees overly well with the experimental observations and is able to capture the main features associated with the behavior of MHBS.

15 GEOTHERMAL ENERGY↗
DOE OSTI2021

Direct Recycling R&D at the ReCell Center

The expected rapid growth in electric vehicle deployment will inevitably be followed by a corresponding rise in the supply of end-of-life vehicles and their lithium-ion batteries (LIBs). The batteries may be reused, but will eventually be spent and provide a potential domestic resource that can help supply materials for future battery production. However, commercial recycling processes depend on profits from recovery of cobalt, use of which is being reduced in new cathode chemistries. The U.S. Department of Energy, therefore, established the ReCell Center in early 2019 to develop robust LIB recycling technology that would be economical even for batteries that contain no cobalt. The central feature of the technology is recovery of the cathode material with its unique crystalline cathode morphology intact in order to retain its value and functionality. Other materials are recovered as well in order to maximize revenues and minimize waste-handling costs. Analysis and modeling serve to evaluate and compare process options so that we can identify those that will be most economical while still minimizing energy use and environmental impacts. This paper provides background and describes highlights of the center’s first 2 years of operation.

Gaines, Linda (ORCID:0000000237263387)↗
NASA NTRS1973

Eolian deposits and dunes on Mars

Detailed analysis of the Mariner 9 pictures reveals that eolian activity is not only a superficial effect, but a surface process of profound importance in the geologic evolution of Mars. Moderate- and large-scale topographic features that may be attributed to wind erosion are described and latitudinal variations in crater morphology are interpreted in terms of eolian deposition and erosion in the mid-latitudes of Mars.

Cutts, J. A.↗
NASA NTRS1976

The geology and geophysics of Mars

The current state of knowledge concerning the regional geology and geophysics of Mars is summarized. Telescopic observations of the planet are reviewed, pre-Mariner models of its interior are discussed, and progress achieved with the Mariner flybys, especially that of Mariner 9, is noted. A map of the Martian geological provinces is presented to provide a summary of the surface geology and morphology. The contrast between the northern and southern hemispheres is pointed out, and the characteristic features of the surface are described in detail. The global topography of the planet is examined along with its gravitational field, gravity anomalies, and moment of inertia. The general sequence of events in Martian geological history is briefly outlined.

Saunders, R. S.↗
NASA NTRS1985

Topographic Evidence for Shield Volcanism on Io

A volcano was identified whose morphology, especially topography, supports and extends current evidence that shield volcanoes occur on Io. The feature is centered at 30 deg. S, 246 deg w and lies in a region near the terminator. The presence of shield volcanism on Io was inferred from the planimetric configuration of flaws on such features as Ra Patera. A central edifice roughly 40 to 50 km in diameter is situated on intervent plains material, and a broad, slightly elliptical base 75 to 90 km across. The size of this feature is comparable to large shield volcanoes found on Earth. In addition, the topography is similar to some terrestrial shield volcanoes that exhibit a change in slope; the steepening may be explained by shorter and/or thicker flows emplaced during late stage eruptions.

Albin, E. F.↗
NASA NTRS1986

Bilateral symmetry of circular impact structures of astroblemes

The relief of the true crater-bottom and the distribution of impactites and allogenic breccias for the Popigay and Kara astroblemes is examined. It is shown that the crater morphology and the distribution of ejecta of fragmented and melted masses has a series of features of symmetry in common with lunar analogs of large astroblemes, formed as a result of an oblique impact, as well as with impact and impact-explosive craters. This leads to the conclusion that both structures were formed as a result of oblique impact of meteoroid bodies; the trajectory projection of the body which formed the Popigay crater had an azimuth of 200 + or - 10 deg., while this azimuth for the Kara crater was 50 + or - 10 deg.

Masaytis, V. L.↗
NASA NTRS1987

Circumnuclear starbursts in Seyfert galaxies

Observational diagnostics for the recognition of circumnuclear star formation in Seyfert galaxies are described and illustrated. These methods include: (1) spatially resolved optical spectroscopy, which allows the emission lines for HII regions to be separated from those originating in gas ionized by the Seyfert nucleus; (2) radio continuum mapping, where the linear radio sources characteristic of the nuclear activity may be distinguished from the diffuse morphology of multiple supernova remnants generated in a starburst; (3) infrared spectroscopic searches for emission features of dust, which are seen in starbursts but not in Seyfert nuclei; (4) the shape of the IRAS spectrum. These various diagnostics agree well as to the presence or absence of ongoing star formation. The IRAS spectra of a significant fraction of Seyferts are dominated by emission from dust heated by stars, not the Seyfert nucleus itself. In these cases, the spectrum is curved, being steep between 25 and 60 microns and flatter between 60 and 100 microns. When the Seyfert nucleus dominates, the 25 to 100 micron spectrum is much flatter. It is suggested that the location of a Seyfert galaxy in the IRAS color-color diagram reflects primarily the relative contributions of the active nucleus and dust heated by stars to the infrared fluxes.

Wilson, Andrew S.↗
NASA NTRS1988

R Aquarii - The large-scale optical nebula and the Mira variable position

The R Aquarii symbiotic star system is surrounded by a large-scale optical nebula. Observations of the nebular forbidden O III structure are presented and its morphological significance are discussed in context with previously observed small-scale radio-continuum features, which may be related. It is suggested that a precessing accretion disk may explain the global features of both the large-scale optical emission and the small-scale radio emission. Moreover, an accurate position has been determined of the system's Mira, which suggests that a recent theoretical model, yielding an egg-shaped central H II region for symbiotic systems with certain physical parameters, may apply to R Aquarii. The optical position of the 387 d period Mira variable is consistent with previous findings in the radio, that SiO maser emission is far removed from the Mira photosphere.

Michalitsianos, A. G.↗
NASA NTRS1991

Venus volcanism - Initial analysis from Magellan data

Magellan images confirm that volcanism is widespread and has been fundamentally important in the formation and evolution of the crust of Venus. High-resolution imaging data reveal evidence for intrusion (dike formation and cryptodomes) and extrusion (a wide range of lava flows). Also observed are thousands of small shield volcanoes, larger edifices up to several hundred kilometers in diameter, massive outpourings of lavas, and local pyroclastic deposits. Although most features are consistent with basaltic compositions, a number of large pancake-like domes are morphologically similar to rhyolite-dacite domes on earth. Flows and sinuous channels with lengths of many hundreds of kilometers suggest that extremely high effusion rates or very fluid magmas (perhaps komantiites) may be present. Volcanism is evident in various tectonic settings (coronae, linear extensional and compressional zones, mountain belts, upland rises, highland plateaus, and tesserae). Volcanic resurfacing rates appear to be low (less than 2 cu km/yr) but the significance of dike formation and intrusions, and the mode of crustal formation and loss remain to be established.

Head, James W.↗
NASA NTRS1992

The large impact process inferred from the geology of lunar multiring basins

The nature of the impact process has been inferred through the study of the geology of a wide variety of impact crater types and sizes. Some of the largest craters known are the multiring basins found in ancient terrains of the terrestrial planets. Of these features, those found on the Moon possess the most extensive and diverse data coverage, including morphological, geochemical, geophysical, and sample data. The study of the geology of lunar basins over the past 10 years has given us a rudimentary understanding of how these large structures have formed and evolved. The topics covered include basin morphology, basin ejecta, basin excavation, and basin ring formation.

Spudis, Paul D.↗
NASA NTRS1995

The Spreading of Variable-Viscosity Axisymmetric Radial Gravity Currents: Applications to the Emplacement of Venusian 'Pancake' Domes

The Magellan images of Venus have revealed a number of intriguing volcanic features, including the steep-sided or 'pancake' domes. These volcanic domes or flows have morphologies that suggest formation by a single continuous emplacement of lava with a higher viscosity than that of the surrounding basaltic plains. Numerous investigators have suggested that such high viscosity is due to high silica content, leading to the conclusion that the domes are evidence of evolved magmatic products on Venus. However, viscosity depends on crystallinity as well as on silica content: high viscosity could therefore also be due to a cooler (and therefore higher crystal content) lava. Models of dome emplacement which include both cooling and composition factors are thus necessary in order to determine the ranges of crystallinity and silica content which might lead to the observed gross dome morphologies. Accordingly, in this study domes are modelled as radial viscous gravity currents with an assumed cooling-induced viscosity increase to include both effects. Analytical and numerical results indicate that pancake dome formation is feasible with compositions ranging from basaltic to rhyolitic. Therefore, observations of gross dome morphology alone are insufficient for determining composition and the domes do not necessarily represent strong evidence for evolved magmatism on Venus.

Sakimoto, S. E. H.↗
NASA NTRS2002

Science goals for a Mars Polar Cap subsurface mission : optical approaches for investiagations of inclusions in ice

The Mars Polar Caps are highly interesting features of Mars and have received much recent attention with new and exciting data on morphology, basal units, and layered outcroppings. We have examined the climatological, glaciological, and geological issues associated with a subsurface exploration of the Mars North Polar Cap and have determined that a finescale optical examination of ice in a borehole, to examine the stratigraphy, geochemistry and geochronology of the ice, is feasible. This information will enable reconstruction of the development of the cap as well as predication of the properties of its ice. We present visible imagery taken of dust inclusions in archived Greenland ice cores as well as in-situ images of accreted lithologic inclusions in West Antarctica, and we argue for use of this kind of data in Mars climate reconstruction as has been successful with Greenland and Antarctic ice core anlaysis.

dust↗