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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

Additive Manufacturing and Characterization of Polylactic Acid (PLA) Composites Containing Metal Reinforcements

Additive manufacturing of polymeric systems using 3D printing has become quite popular recently due to rapid growth and availability of low cost and open source 3D printers. Two widely used 3D printing filaments are based on polylactic acid (PLA) and acrylonitrile butadiene styrene (ABS) systems. PLA is much more environmentally friendly in comparison to ABS since it is made from renewable resources such as corn, sugarcane, and other starches as precursors. Recently, polylactic acid-based metal powder containing composite filaments have emerged which could be utilized for multifunctional applications. The composite filaments have higher density than pure PLA, and the majority of the materials volume is made up of polylactic acid. In order to utilize functionalities of composite filaments, printing behavior and properties of 3-D printed composites need to be characterized and compared with the pure PLA materials. In this study, pure PLA and composite specimens with different metallic reinforcements (Copper, Bronze, Tungsten, Iron, etc) were 3D printed at various layer heights and resulting microstructures and properties were characterized. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) behavior of filaments with different reinforcements were studied. The microscopy results show an increase in porosity between 3-D printed regular PLA and the metal composite PLA samples, which could produce weaker mechanical properties in the metal composite materials. Tensile strength and fracture toughness behavior of specimens as a function of print layer height will be presented.

brass↗
NASA NTRS2016

Exploring the Overabundance of ULXs in Metal- and Dust-Poor Local Lyman Break Analogs

We have studied high-mass X-ray binary (HMXB) populations within two low-metallicity, starburst galaxies, Haro 11 and VV 114. These galaxies serve as analogs to high-redshift (z greater than 2) Lyman break galaxies and, within the larger sample of Lyman break analogs (LBAs), they are sufficiently nearby (less than 87 Mpc) to be spatially resolved by Chandra. Previous studies of the X-ray emission in LBAs have found that the 2-10 keV luminosity per star formation rate (SFR) in these galaxies is elevated, potentially because of their low metallicities (12 + log[O/H] = 8.3-8.4). Theoretically, the progenitors of XRBs forming in lower metallicity environments lose less mass from stellar winds over their lifetimes, producing more massive compact objects (i.e., neutron stars and black holes), and thus resulting in more numerous and luminous HMXBs per SFR. In this paper, we have performed an in-depth study of the only two LBAs that have spatially resolved 2-10 keV emission with Chandra to present the bright end of the X-ray luminosity distribution of HMXBs (L(sub X) approximately greater than 10(exp 39) erg s(exp −1); ultraluminous X-ray sources, ULXs) in these low-metallicity galaxies, based on eight detected ULXs. Compared with the star-forming galaxy X-ray luminosity function (XLF) presented by Mineo et al., Haro 11 and VV 114 host approximately equal to 4 times more L(sub X) greater than 10(exp 40) erg s(exp −1) sources than expected given their SFRs. We simulate the effects of source blending from crowded lower-luminosity HMXBs using the star-forming galaxy XLF and then vary the XLF normalizations and bright-end slopes until we reproduce the observed point source luminosity distributions. We find that these LBAs have a shallower bright-end slope (gamma(sub 2) = 1.90) than the standard XLF (gamma(sub 2) 2.73). If we conservatively assume that the brightest X-ray source from each galaxy is powered by an accreting supermassive black hole rather than an HMXB and eliminate these sources from consideration, the luminosity distribution becomes poorly constrained but does appear to be consistent with a standard XLF.

galaxies: evolution aEuro" galaxies: individual↗
NASA NTRS2017

High Performance High Temperature Thermoelectric Composites with Metallic Inclusions

The present invention provides a composite thermoelectric material. The composite thermoelectric material can include a semiconductor material comprising a rare earth metal. The atomic percent of the rare earth metal in the semiconductor material can be at least about 20%. The composite thermoelectric material can further include a metal forming metallic inclusions distributed throughout the semiconductor material. The present invention also provides a method of forming this composite thermoelectric material.

Ma, James M.↗
NASA NTRS2017

The Effects of Normal Metal Stripes on TES Performance

Exploring the effects of size and geometry of normal metal features on the transition shapes and performance of transition-edge sensor microcalorimeters. The spectral resolution of transition-edge sensor (TES) microcalorimeters is very sensitive to the specific dependencies of the resistance R in the superconducting transition on the current I, magnetic field B, and temperature T. In particular, it has been shown that transitions that are very steep in (R,T) space lead to a significant noise term, in excess of conventional expectations. This so-called unexplained noise is known to be reduced by the addition of normal metal stripes across the TES perpendicular to the direction of current flow. These normal metal stripes have been shown to drastically alter the oscillatory patterns seen in measurements of the critical current as a function of magnetic field. However, there are many remaining questions about the exact impact of the stripes on current distributions within the TES, the Fraunhofer pattern and, therefore, the shape of the R(I, B, T) surface. Through measurements of the resistance under DC bias of TES devices of various sizes, with different stripe patterns and dimensions, we will discuss how these stripes can affect the R(I, B, T) surface. In addition, using measurements and analysis of the noise spectra of various devices we will present how these changes to the stripe pattern may affect the performance of the TES. In particular, we will discuss strategies to reduce the presence of localized discontinuities in the derivative of R, associated with increased noise, while maintaining the globally low levels of unexplained noise currently achieved with conventional metal stripe patterns. Implementing these strategies is a path towards producing large arrays with highly uniform transitions and high spectral resolution. These large uniform arrays will be required for future x-ray astronomy applications, such as the X-IFU on ATHENA.

TES↗
NASA NTRS2017

Systems and Methods for Implementing Bulk Metallic Glass-Based Macroscale Compliant Mechanisms

Systems and methods in accordance with embodiments of the invention implement bulk metallic glass-based macroscale compliant mechanisms. In one embodiment, a bulk metallic glass-based macroscale compliant mechanism includes: a flexible member that is strained during the normal operation of the compliant mechanism; where the flexible member has a thickness of 0.5 mm; where the flexible member comprises a bulk metallic glass-based material; and where the bulk metallic glass-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.25.

Hofmann, Douglas C.↗
NASA NTRS2015

Sulfur and Metal Fertilization of the Lower Continental Crust

Mantle-derived melts and metasomatic fluids are considered to be important in the transport and distribution of trace elements in the subcontinental lithospheric mantle. However, the mechanisms that facilitate sulfur and metal transfer from the upper mantle into the lower continental crust are poorly constrained. This study addresses this knowledge gap by examining a series of sulfide- and hydrous mineral-rich alkaline mafic-ultramafic pipes that intruded the lower continental crust of the Ivrea-Verbano Zone in the Italian Western Alps. The pipes are relatively small (<300 m diameter) and primarily composed of a matrix of subhedral to anhedral amphibole (pargasite), phlogopite and orthopyroxene that enclose sub-centimeter-sized grains of olivine. The 1 to 5 m wide rim portions of the pipes locally contain significant blebby and disseminated Fe-Ni-Cu-PGE sulfide mineralization.Stratigraphic relationships, mineral chemistry, geochemical modeling and phase equilibria suggest that the pipes represent open-ended conduits within a large magmatic plumbing system. The earliest formed pipe rocks were olivine-rich cumulates that reacted with hydrous melts to produce orthopyroxene, amphibole and phlogopite.Sulfides precipitated as immiscible liquid droplets that were retained within a matrix of silicate crystals and scavenged metals from the percolating hydrous melt. New high-precision chemical abrasion TIMS-UPb dating of zircons from one of the pipes indicates that these pipes were emplaced at 249.1+/-0.2 Ma, following partial melting of lithospheric mantle pods that were metasomatized during the Eo-Variscan oceanic to continental subduction (approx. 420-310 Ma). The thermal energy required to generate partial melting of the metasomatized mantle was most likely derived from crustal extension, lithospheric decompression and subsequent asthenospheric rise during the orogenic collapse of the Variscan belt (<300 Ma). Unlike previous models, outcomes from this study suggest a significant temporal gap between the occurrence of mantle metasomatism, subsequent partial melting and emplacement of the pipes.We argue that this multi-stage process is a very effective mechanism to fertilize the commonly dry and refractory lower continental crust in metals and volatiles. During the four-dimensional evolution of the thermo-tectonic architecture of any given terrain, metals and volatiles stored in the lower continental crust may become available as sources for subsequent ore-forming processes, thus enhancing the prospectivity of continental block margins for a wide range of mineral systems.

Marek Locmelis↗
NASA NTRS2018

Ionic Liquid Facilitated Recovery of Metals and Oxygen from Regolith

Regolith, being largely composed of metal oxides, has the potential to be an excellent in situ source of metals, such as iron, nickel and aluminum, as well as oxygen. There is, however, no current technology that is suited for the in space separation of metal oxides into their constituent elements. Terrestrial methods require large volumes/masses of hazardous reagents. Alternative methods, such as molten oxide electrolysis, have been investigated, but these processes generally require high temperatures to operate. Such a requirement imposes significant material compatibility restraints, necessitates high energy inputs, and may pose a threat to the health and safety of the crew. This paper discusses a novel process that uses ionic liquids (ILs) to recover high purity metals and oxygen from regolith and meteorite materials. ILs are organic salts that are molten at or near room temperature, and can have a number of attractive properties including wide liquidus ranges and high thermal and electrochemical stability. The structure of an IL can be readily modified to tune these properties, allowing the synthesis of task specific ILs. Together, these attributes give ILs great utility in a number of space related areas, such environmental control and life support, in space repair and manufacture, and in situ resource utilization.

Karr, Laurel J.↗
NASA NTRS2019

MycoMaterials: Metal-Fungi Hybrids

There is an interest in creating aerospace structures that regenerate, communicate and that are capable of using carbondioxide as a fuel source. Before such a vision is achieved several fundamental questions must first be answered. For example, what are the optimal conditions and laboratory settings for mycelium growth and is it possible for mycelium to digest different metals to form metal-mycelium hybrid structures? Recent research has shown that fungi and photosynthetic organisms can absorb harmful metals. Eight different species of fungi were grown such as blue oyster (Pleurotus columbinus), reishi ling chi (Ganoderma lucidum), and shaggy mane (Coprinus comatus). Species of fungi were chosen based on their potential growth rate, potential strength and non-toxicity to humans. Metal-mycelium hybrids were developed by using both the cell and mycelium life stages. In experiments involving the mycelium stage, varying amounts of sterilized sawdust (0.5-1g), zinc sulfide (0.5-1g), and small pieces of aluminum foil (0.1-1g) were applied on top of the mycelium growing on petri dishes. For experiments using the cell stage, 8-9 drops of the fungal sample were applied to zinc sulfide (0.5-1g) and aluminum foil (0.5-1g). Mycelium (blue oyster) were grown on to differing quantities of aluminum foil. Cells (shaggy mane) have been grown onto aluminum foil with and without nutrients from the petri dish. Shaggy mane cells have also grown onto 0.5 g of zinc sulfide.

Kyles-Stewart, Maiya A.↗
NASA NTRS2020

On the X-Ray Spectral Energy Distributions of Star-Forming Galaxies: The 0.3-30 keV Spectrum of the Low-Metallicity Starburst Galaxy VV 114

Binary population synthesis combined with cosmological models suggests that X-ray emission from star-forming galaxies, consisting primarily of emission from X-ray binaries(XRBs)and the hot interstellar medium(ISM),could be an important, and perhaps dominant, source of heating of the intergalactic medium prior to the epoch of reionization. However, such models rely on empirical constraints for the X-ray spectral energy distributions(SEDs)of star-forming galaxies, which are currently lacking for low-metallicity galaxies. Using a combination of Chandra, XMM-Newton, and NuSTAR observations, we present new constraints on the 0.3–30 keV SED of the low-metallicity starburst galaxy VV 114, which is known to host several ultraluminous X-ray sources(ULXs)with luminosities above 1040erg s−1. We use an archival Chandra observation of VV 114 to constrain the contributions to the X-ray SED from the major X-ray-emitting components of the galaxy and newly acquired, nearly simultaneous XMM-Newton and NuSTAR observations to extend the spectral model derived from Chandra to cover the 0.3–30 keV range. Using our best-fit galaxy-wide spectral model, we derive the 0.3–30 keV SED ofVV114, which we find is dominated by emission from the XRB population, and in particular ULXs, at energies>1.5 keV, and which we find to have an elevated galaxy-integrated X-ray luminosity per unit star formation rate relative to higher-metallicity star-forming galaxies. We discuss our results in terms of the effect of metallicity on XRB populations and the hot ISM, as well as the importance of X-ray emission from star-forming galaxies in the high-redshift universe.

Kristen Garofali↗
NASA NTRSDate not supplied

Machine Learning Applications to Metal-Silicate Equilibria and their Insights into Core Formation

An extensive number of studies have experimentally investigated how elements distribute between metal and silicate phases, to better constrain core-mantle chemical equilibrium. Here, we present a new database compiling all (to our knowledge) experimental data on liquid metal-silicate partitioning from 118 peer-reviewed publications. We applied various machine learning techniques to gain further insights into these partitioning equilibria and their dependencies. We performed a network analysis to investigate the relationship between experiments and partition coefficients, which enables visualizing gaps in the experimental dataset and biases related to varying experimental conditions and analytical setup. In addition, semi-empirical thermodynamic models are commonly used to extrapolate these chemical reactions to the wide range of pressure, temperature and compositional conditions of planetary differentiation. These models are based on linear regressions that assume continuous relationship between partition coefficients and experimental variables. Here, we considered random forest regressions, which are algorithms based on ensembles of decision trees and does not consider continuous effects of each variable. The application of this regression significantly improves the prediction of metal-silicate partitioning for several elements including Ni, Si and Cr. We will show how this new approach improves our understanding of elemental exchange between metal and silicate and their implications for the Earth’s core formation.

siderophile element↗
NASA NTRSDate not supplied

Material Compatibility Study of Coated Metals to Maintain Biocidal Silver in a Spacecraft Potable Water System

Ionic silver-based biocide remains an option of choice for microbial control in spacecraft potable water systems. However, depletion of silver ions by wetted materials readily reduces ionic silver to nonbiocidal levels. This phenomenon occurs via various transport mechanisms at the liquid-solid interfaces between the silver-containing water and adjacent surfaces. Consequently, challenges remain in the design and/or selection of materials that can be used for the wetted system components that will help ensure silver is maintained at biocidal levels. Since silver has been baselined, and/or remains, as a potable water biocide option for several future spacecraft potable water systems, a multitiered approach is being investigated, looking at heritage materials, new processes, and/or alterative materials. This study conducted the application of eleven chemically-resistant coatings onto coupons that were cut out from three types of spacecraft-grade metals (Titanium Grade 2, Inconel 718, and 316L Stainless Steel) to investigate the performance of this material strategy as a barrier against silver depletion. In this investigation, the coated metals were immersed in a static 400 parts per billion silver biocide solution at a surface-area-to-volume ratio of 2.0 cm^(-1) and left to soak for predefined time periods. The concentration of the solution in contact with the coated samples was analyzed at various points via inductively coupled plasma mass spectrometry, and the measurements were interpreted as silver retention percentages over time. This paper summarizes the coating selection process, the configuration of the test, and the performance of each coating-metal combination at diminishing silver depletion. The preliminary results demonstrate that some of the selected coatings succeeded at maintaining biocidal silver concentrations far beyond the corresponding base metal in a similar test. The knowledge acquired through this investigation supports the deploying of coatings on plumbing lines for the integration of biocidal silver in the water system architecture of a spacecraft. Nevertheless, further testing must be continued to assess the performance of these coatings on other wetted geometries and any implications of unifying this material strategy with traditional and developmental engineering design processes for spacecraft potable water systems.

water↗
NASA NTRS2023

Investigating the Impact of Metallicity on Star Formation in the Outer Galaxy. I. VLT/KMOS Survey of Young Stellar Objects in Canis Major

The effects of metallicity on the evolution of protoplanetary disks may be studied in the outer Galaxy where the metallicity is lower than in the solar neighborhood. We present the VLT/KMOS integral field spectroscopy in the near-infrared of∼120 candidate young stellar objects (YSOs) in the CMa-ℓ224 star-forming region located at a Galactocentric distance of 9.1 kpc. We characterise the YSO accretion luminosities and accretion rates using the hydrogen Brγemission and find the median accretion luminosity of log (Lacc) =−0.82+0.80−0.82L⊙.Based on the measured accretion luminosities, we investigate the hypothesis of star formation history in the CMa-ℓ224. Their median values suggest that Cluster C, where most of YSO candidates have been identified, might be the most evolved part of the region. The accretion luminosities are similar to those observed toward low-mass YSOs in the Perseus and Orion molecular clouds, and do not reveal the impact of lower metallicity. Similar studies in other outer Galaxy clouds covering a wide range of metallicities are critical to gain a complete picture of star formation in the Galaxy

Dominika Itrich↗
NASA NTRS2023

TOI-5344 b: A Saturn-like Planet Orbiting a Super-solar Metallicity M0 Dwarf

We confirm the planetary nature of TOI-5344 b as a transiting giant exoplanet around an M0-dwarf star. TOI-5344 b was discovered with the Transiting Exoplanet Survey Satellite photometry and confirmed with ground-based photometry (the Red Buttes Observatory 0.6 m telescope), radial velocity (the Habitable-zone Planet Finder), and speckle imaging (the NN-Explore Exoplanet Stellar Speckle Imager). TOI-5344 b is a Saturn-like giant planet (ρ = 0.80 +0.17 −0.15 g cm −3 ) with a planetary radius of 9.7 ± 0.5 R⊕ (0.87 ± 0.04 R Jup ) and a planetary mass of 135 +17 −18 M⊕ (0.42 +0.05 −0.06 M Jup ). It has an orbital period of 3.792622 +0.000010 −0.000010 days and an orbital eccentricity of 0.06 +0.07 −0.04 . We measure a high metallicity for TOI-5344 of [Fe/H] = 0.48 ± 0.12, where the high metallicity is consistent with expectations from formation through core accretion. We compare the metallicity of the M-dwarf hosts of giant exoplanets to that of M-dwarf hosts of nongiants (≲8 R⊕). While the two populations appear to show different metallicity distributions, quantitative tests are prohibited by various sample caveats.

Te Han↗
NASA NTRSDate not supplied

Scalable Variable Charge Molecular Dynamics Simulations of Metal-Oxide Systems

Interfaces between metals and oxides are an important feature in many technologically relevant materials, e.g., oxidation of metal surfaces, oxide-dispersion strengthened (ODS) alloys, dielectric components, and thermal barrier coatings among others. Experimental studies of such interfaces are challenging since the majority are buried within the bulk, making computational modeling an attractive alternative. Molecular dynamics (MD) simulations operate at the length scales relevant to many interface-mediated mechanisms, but the requisite interatomic potentials for metal-oxide systems require computationally expensive variable charge schemes to account for the disparate bonding types, thus often limiting their effectiveness. Here we introduce several improvements to the charge transfer interatomic potential (CTIP) model which enable greater computational efficiency for large scale MD simulations. Then, using a new CTIP parametrization for the Ni-O system, we demonstrate its capabilities to capture critical atomic scale mechanisms associated with metal-oxide interfaces. Long time scale simulations (>10 ns) are used to investigate high temperature oxidation and oxide precipitation from the melt, and large length scale simulations (> 1 million atoms) are used to study the interaction of dislocations with oxide particles. We have implemented the new CTIP model in the widely used, open-source MD code LAMMPS.

Gabriel Plummer↗
NASA NTRS2026

Hybrid Modeling Study on Grain Evolution in the Metal Welding Process and Its Potential Lunar Application

Metal is most commonly used structural material in a wide range of spacecraft, and welding is the principal method for joining metal components into functional systems. However, conducting welding experiments under extreme environments—such as microgravity or vacuum conditions in space—is prohibitively expensive and experimentally challenging. To overcome these limitations, multi-physics computational welding models provide a cost-effective and versatile alternative. In this work, the authors have developed a coupled thermal (fluid) microstructure simulation framework to model metal welding under varying gravity conditions. The framework integrates a mixed-mode heat transfer formulation (conduction, convection, and radiation) with molten pool fluid dynamics, enabling accurate prediction of temperature fields and weld-pool geometry. A grain growth model is further incorporated to capture the spatial and temporal evolution of microstructure, including grain size distribution and morphological transitions during solidification. This approach provides detailed insight into molten pool evolution and grain-level microstructure development throughout the welding process. By explicitly parameterizing environmental conditions, the model supports extrapolation to off-Earth manufacturing scenarios such as welding on the lunar surface. Tantalum—chosen in this study due to its high melting point, oxidation resistance, and mechanical stability at elevated temperatures—serves as the material system for model demonstration. Beyond Tantalum, the integrated multi-physics framework offers broad applicability for predictive welding simulations of various structural and refractory metals or alloys used in extreme terrestrial or extraterrestrial environments.

kinetic Monte Carlo (SPPARKS)↗
NASA NTRS1963

Liquid Metals for Aerospace Electric-Power Systems

Liquid metals and their properties, as applied to space electric-power systems, are discussed as possible heat-transfer and thermodynamic working fluids. Representative liquid metals—lithium, sodium, potassium, NaK-78, lead, and bismuth — tare discussed and compared. Space power requirements are listed and used as a basis for evaluating the potentialities of the liquid metals.

Heat transfer↗