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Guidelines on Lithium-ion Battery Use in Space Applications

This guideline discusses a standard approach for defining, determining, and addressing safety, handling, and qualification standards for lithium-ion (Li-Ion) batteries to help the implementation of the technology in aerospace applications. Information from a variety of other sources relating to Li-ion batteries and their aerospace uses has been collected and included in this document. The sources used are listed in the reference section at the end of this document. The Li-Ion chemistry is highly energetic due to its inherent high specific energy and its flammable electrolyte. Due to the extreme importance of appropriate design, test, and hazard control of Li-ion batteries, it is recommended that all Government and industry users and vendors of this technology for space applications, especially involving humans, use this document for appropriate guidance prior to implementing the technology.

Mckissock, Barbara↗

Measurements of bow shock particles far upstream from the earth

Electrons and ions moving upstream frequently appear at distances up to 240 earth radii from earth at times when the direction of the interplanetary magnetic field allows their propagation from the bow shock. Strong asymmetries in the ion angular pitch angle distribution are often observed, a consequence of the sharp gradient in guiding center density and very weak scattering. The gradient is due to the restricted spatial region over which these particles are accelerated. The solar wind electric field acts on these particles and produces striking effects in both the ion angular distributions and the ion energy spectra. The frequent occurrence of these effects implies that the source region of the diffuse ions at the bow shock is not more than a few tens of thousands of km.

Anderson, K. A.↗

Energy and Mass Transport of Magnetospheric Plasmas during the November 2003 Magnetic Storm

Intensive energy and mass transport from the solar wind across the magnetosphere boundary is a trigger of magnetic storms. The storm on 20-21 November 2003 was elicited by a high-speed solar wind and strong southward component of interplanetary magnetic field. This storm attained a minimum Dst of -422 nT. During the storm, some of the solar wind particles enter the magnetosphere and eventually become part of the ring current. At the same time, the fierce solar wind powers strong outflow of H+ and O+ from the ionosphere, as well as from the plasmasphere. We examine the contribution of plasmas from the solar wind, ionosphere and plasmasphere to the storm-time ring current. Our simulation shows, for this particular storm, ionospheric O+ and solar wind ions are the major sources of the ring current particles. The polar wind and plasmaspheric H+ have only minor impacts. In the storm main phase, the strong penetration of solar wind electric field pushes ions from the geosynchronous orbit to L shells of 2 and below. Ring current is greatly intensified during the earthward transport and produces a large magnetic depression in the surface field. When the convection subsides, the deep penetrating ions experience strong charge exchange loss, causing rapid decay of the ring current and fast initial storm recovery. Our simulation reproduces very well the storm development indicated by the Dst index.

Fok, Mei-Chging↗

The chemistry of metastable species in the Venusian ionosphere

Reactions of metastable species are important in determining the densities of minor ions in the Venusian ionosphere. Calculations are carried out in which the coupled continuity and momentum equations are solved for twelve ions and four neutral species in the dayside ionosphere, including O(+)(2D), O(2P), N(2D), and N(2P). Altitude profiles of these metastable species are presented. Their reactions are shown to be a significant source of several minor ions, especially N2(+), CO(+), and N(+). The discrepancies which existed between model and measured densities of these ions are resolved.

Fox, J. L.↗

Do the Satellites of Uranus Control Its Magnetosphere?

The importance of the satellites of Uranus as sources of magnetospheric plasma were investigated. It is found that neither an Io like plasma source nor a Titan like source is likely at Uranus. The likely presence of a heavy ion plasma torus maintained by charged particle sputtering of the icy satellites is examined. Sputtering of Saturn's icy satellites is considered an important source of heavy ion (oxygen) plasma in Saturn's inner magnetosphere. A major unresolved question is whether this sputtering process does depend on the preexistence of magnetospheric heavy ions derived from another source, Titian.

Cheng, A. F.↗

Plasma observations near Neptune - Initial results from Voyager 2

The plasma science experiment on Voyager 2 made observations of the plasma environment in Neptune's magnetosphere and in the surrounding solar wind. Because of the large tilt of the magnetic dipole and fortuitous timing, Voyager entered Neptune's magnetosphere through the cusp region, the first cusp observations at an outer planet. Thus the transition from the magnetosheath to the magnetosphere observed by Voyager 2 was not sharp but rather appeared as a gradual decrease in plasma density and temperature. The maximum plasma density observed in the magnetosphere is inferred to be 1.4 per cubic centimeter (the exact value depends on the composition), the smallest observed by Voyager in any magnetosphere. The plasma has at least two components; light ions (mass, 1 to 5) and heavy ions (mass, 10 to 40), but more precise species identification is not yet available. Most of the plasma is concentrated in a plasma sheet or plasma torus and near closest approach to the planet. A likely source of the heavy ions is Triton's atmosphere or ionosphere, whereas the light ions probably escape from Neptune. The large tilt of Neptune's magnetic dipole produces a dynamic magnetosphere that changes configuration every 16 hours as the planet rotates.

Belcher, J. W.↗

A survey of upwelling ion event characteristics

Quasi-static electric field data collected by the DE-1 spacecraft were used to study ionospheric ion upwelling events observed in the vicinity of the dayside cleft. Bulk plasma parameters such as ion-species density and field-aligned bulk velocity and flux were derived at points within several upwelling ion events for the H(+), He(+), O(+), and O(2+), and the ion-species bulk parameters near the source altitude were compared. It was found that O(+) ions comprise about 90 percent of the upwelling particle density, followed by H(+) at less than 10 percent; He(+) and O(2+) contribute about 1 percent each. The upwelling O(+) flux is also dominant, followed by upward H(+) flux, which is relatively more significant than the fractional H(+) density, due to its high upward flow velocity.

Pollock, C. J.↗

Hopkins Ultraviolet Telescope determination of the Io torus electron temperature

Sulfur ion emissions from the Io plasma torus observed by the Hopkins Ultraviolet Telescope (HUT) in 1990 December have been analyzed to determine the effective temperature of the exciting electrons. Spectra were obtained with a long slit that extended from 3.1 to 8.7 Jupiter radii R(sub J) on both dawn and dusk torus ansae. The average temperature of electrons exciting S(2+) emissions from the dawn ansa is (4800 +/- 2400) K lower than on the dusk ansa, a dawn-dusk asymmetry comparable in both sign and magnitude to that measured by the Voyager Ultraviolet Spectrograph (UVS) experiment. Emissions from S(2+) ions are generated in a source region with electron temperatures in the range 32,000-56,000 K; S(3+) ion emissions are excited by electrons that average 20,000-40,000 K hotter. This distinct difference suggests that the S(3+) emission source region is spatially separate from the S(2+) source region. Estimated relative aperture filling factors suggest that the S(3+) emissions originate from a region more extended out of the centrifugal plane than the S(2+) emissions.

Hall, D. T.↗

Quasi-linear velocity space diffusion of heavy cometary pickup ions on bispherical diffusion characteristics

We consider an ion transport equation describing the source, convection, adiabatic acceleration, and quasi-linear velocity diffusion of cometary pickup ions. The equation is solved numerically along solar wind plasma flow lines for the environment of Comet Halley, to obtain distributions at positions on the Giotto spacecraft trajectory which may be compared with observations. We obtain full two-dimensional (pitch angle and velocity) numerical distributions which show pitch angle scattering about the wave scattering centers at +/- V(A), where V(A) is the Alfven wave speed in the solar wind frame. Peak ion phase-space densities approximately follow the bispherical shell geometry. The energy distributions F(v) agree well with Giotto observations at lower v, but in the high-energy tail there is evidence possibly for the first-order Fermi acceleration mechanism taking place in the Comet Halley foreshock region.

Huddleston, D. E.↗

The Transport of Density Fluctuations Throughout the Heliosphere

The solar wind is recognized as a turbulent magnetofluid, for which the properties of the turbulent velocity and magnetic field fluctuations are often described by the equations of incompressible magnetohydrodynamics (MHD). However, low-frequency density turbulence is also ubiquitous. On the basis of a nearly incompressible formulation of MHD in the expanding inhomogeneous solar wind, we derive the transport equation for the variance of the density fluctuations (Rho(exp 2)). The transport equation shows that density fluctuations behave as a passive scalar in the supersonic solar wind. In the absence of sources of density turbulence, such as within 1AU, the variance (Rho(exp 2)) approximates r(exp -4). In the outer heliosphere beyond 1 AU, the shear between fast and slow streams, the propagation of shocks, and the creation of interstellar pickup ions all act as sources of density turbulence. The model density fluctuation variance evolves with heliocentric distance within approximately 300 AU as (Rho(exp 2)) approximates r(exp -3.3) after which it flattens and then slowly increases. This is precisely the radial profile for the density fluctuation variance observed by Voyager 2. Using a different analysis technique, we confirm the radial profile for Rho(exp 2) of Bellamy, Cairns, & Smith using Voyager 2 data. We conclude that a passive scalar description for density fluctuations in the supersonic solar wind can explain the density fluctuation variance observed in both the inner and the outer heliosphere.

Zank, G. P.↗

Survey of Warm Pancake-Shaped Ion Distributions at Geosynchronous Orbit

It has been proposed that the electromagnetic proton cyclotron instability is the strongest source of heating for the anisotropic warm ions observed at geosynchronous orbit. We present here the results of a statistical study of warm pancake-shaped ion distributions observed with the Los Alamos magnetospheric plasma analyzer (MPA) on geosynchronous satellites. We examined the ion distributions to determine the correlation between the observed warm ion distributions and various magnetospheric parameters, and their location relative to the plasma trough, plasmasphere, plasma sheet, and local time. We find that the warm pancake-shaped ion distributions occur more frequently near noon, and during low magnetospheric activity. The implications of our observations for the proton cyclotron instability, as the source of energy for the warm ions, will be discussed.

Ober, Daniel M.↗

Energetic ion anisotropies in the geomagnetic tail. I - A statistical survey. II - Magnetic field and substorm characteristics

A comprehensive data set from the ISEE 2 spacecraft is used here to perform a statistical study of events in the earth's central magnetotail that are characterized by high anisotropies of energetic ions. In about 75 percent of the cases the anisotropy vector deviates no more than 45 deg from the tidal axis. High-anisotropy samples within 45 deg of the tidal axis are dominated by the earthward fraction. High ion anisotropies are observed continuously for longer than 1 min only in a few cases. The probability of observing high ion anisotropies is significantly enhanced beyond about 16 R(E) downtail distance within a few earth radii of the neutral sheet and on the duskside of the magnetotail. The analysis is extended with respect to the local magnetic field and to the relationship between energetic ion anisotropies and substorm phases. It is found that the events can be well organized in terms of substorm expansion phase and substorm recovery. These relations and the magnetic field characteristics during the events support the notion that the near-earth source of tailward streaming ions is identical with a substorm neutral line.

Kettmann, Georg↗

The Use of Laser-Induced Fluorescence to Characterize Discharge Cathode Erosion in a 30 cm Ring-Cusp Ion Thruster

Relative erosion rates and impingement ion production mechanisms have been identified for the discharge cathode of a 30 cm ion engine using laser-induced fluorescence (LIF). Mo and W erosion products as well as neutral and singly ionized xenon were interrogated. The erosion increased with both discharge current and voltage and spatially resolved measurements agreed with observed erosion patters. Ion velocity mapping identified back-flowing ions near the regions of erosion with energies potentially sufficient to generate the level of observed erosion. Ion production regions downstream of the cathode were indicated and were suggested as possible sources of the erosion causing ions.

Sovey, James S.↗

Impact of Substorm Time O+ Outflow on Ring Current Enhancement

Energetic O+ ions (tens of keV) rapidly increase in the inner magnetosphere and contribute significantly to the ring current during substorms. Previously, two source regions of the energetic O+ ions have been proposed. The first one is the dayside polar region. Ions from the dayside polar region are transported to the lobe; then they are injected to the nightside plasma sheet during substorm expansion phase. The second one is the nightside aurora region. After the substorm onset, energetic O+ ions are extracted from the ionosphere with the auroral acceleration processes, and the O+ ions are directly supplied to the nightside plasma sheet. We investigated the relative importance of these two regions on supplying the energetic O+ ions in the inner magnetosphere. We performed a test particle simulation in global MHD electromagnetic fields. We obtained the following results. (1) During the substorm growth phase, O+ ions at tens of eV are extracted from the dayside polar region, resulting in the enhancement of the warm O+ ions (hundreds of eV) in the lobe. After the substorm onset, the warm O+ ions are nonadiabatically accelerated to tens of keV and injected to the inner magnetosphere. These O+ ions contribute to most of the O+ ring current. (2) O+ ions at less than a few keVs are supplied from the nightside aurora region to the plasma sheet. However, their contribution to the O+ ring current remains small. From the results, we concluded that the main source of the energetic O+ ions is the dayside polar region.

outflow↗

A laboratory study on the dissociative recombination of vibrationally excited O2/+/ions

The dissociative recombination of vibrationally excited O2(+) ions is studied in light of the possible importance of this reaction in upper atmospheric chemistry. A plasma spectroscopy experiment was performed in a microwave cavity filled by an argon-oxygen mixture, with O(1S) production monitored by measurements of the 5577-A afterglow, the O2(+) density and the electron concentration. Plasma and optical data reveal the predominant afterglow ions to be Ar2(+) and O2(+), with an effective O(1S) dissociative recombination coefficient of 2.1 x 10 to the -8th cu cm/sec, corresponding to a quantum yield of 10%. Experiments with an argon-krypton-oxygen mixture reveal that vibrationally excited O2(+) ions are the chief source of the O(1S) atoms, with a specific recombination coefficient for the dissociation of O2(+)(2 pi g) into O(1S) and O(1D) of 4.2 x 10 to the -9th cu cm/sec. A comparison of the laboratory results with Atmospheric Explorer data on the 5577-A airglow implies that O2(+) ions in the sunlit ionosphere are vibrationally excited to the same degree as in the laboratory, with the vibrational relaxation of these ions much slower than dissociative recombination. Results also predict a dawn-twilight asymmetry in the effective O(1S) yield due to the normal variation of electron content.

Zipf, E. C.↗

Laboratory measurements of the O+/2D/ + N2 and O+/2D/ + O2 reaction rate coefficients and their ionospheric implications

Rate coefficients which have been measured at thermal energies for the charge transfer reactions of metastable O+/2D/ ions with N2 and O2 are reported. It is found that at an effective temperature of about 550 K, k(n2) = (8 + or - 2) x 10 to the -10 cu cm/sec and k(O2) = (7 + or - 2) x 10 to the -10 cu cm/sec. Drift tube-mass spectrometer measurements employ the reaction He(+) + O2 as the source of metastable O+ ions, showing that the ions produced in this manner are in the 2D state rather than the 2P state, a possible alternative identification. Finally, consideration is given to the ionospheric implications of the laboratory measurements.

Johnsen, R.↗

Compositional Impact of Io Volcanic Emissions on Jupiter's Magnetosphere and the Icy Galilean Moons

The magnetospheric ion population of Jupiter is dominated by the 1000 kg/s of iogenic material constantly ejected by IO volcanism as neutral gas (approx. 1 kg/s goes out as high speed dust grains), subsequent atmospheric losses to the IO torus, and radial transport of torus ions throughout the magnetosphere. As that magnetosphere is greatly distended in radial size by the iogenic plasma loading, so are surfaces of the other Galilean moons also significantly, and perhaps even dominantly, affected by iogenic plasma bombardment, e.g. at the level up to 0.2 kg/s heavy ions (mostly O and S) onto Europa as per local plasma ion measurements. In comparison, cometary impacts onto IO deliver about 0.02 kg/s of impact ejecta to Europa via ballistic transfer through the Jupiter system. The magnetosphere of this system operates as a powerful engine to produce and transport ions from the IO source to the surfaces of these other moons, and any future orbiter missions to these moons must account for surface distributions of the iogenic material and its chemical effects before real assessments can be made of sensible chemical materials otherwise arising from primordial formation and subsequent evolution of these moons. This is a fundamental problem of space weathering that must be addressed for all planetary bodies with thin atmospheres and direct surface exposure to their space plasma environments. Long-standing debates from Galileo Orbiter measurements about the origins of hydrate sulfates at Europa present examples of this problem, as to whether the sulfates arise from oceanic minerals or from iogenic sulfur chemistry. Any orbiter or landed mission to Europa for astrobiological investigations would further need to separate the potential chemical biosignatures of life or its precursors from the highly abundant background of iogenic material. Although no single ion carries a tag identifying it as of iogenic or other origin, the elemental abundance distributions of ions to be measured throughout the jovian magnetosphere and in the local moon environments can act as tracers if we know from direct measurements and models the distributions at the mostly likely sources, i.e. at IO. However, our knowledge of these abundances are very limited from earlier in-situ and remote measurements, mainly confined to major (S, O) and some minor (Na, K, Cl) species with abundances at or above a few percent relative to O. Future in-situ plasma measurements by the planned Jupiter Europa Orbiter and Jupiter Ganymede Orbiter missions should extend the abundance coverage to minor and even trace elemental species. For Europa astrobiological investigations it is also important to specify iogenic inputs and surface processing of isotopic species. We discuss the range of abundance distributions arising from models for IO hot volcanic emissions, and from the subsequent dynamics of ion injection, magnetospheric transport, and icy moon surface bombardment.

Cooper, John↗

Facility produced charge-exchange ions

These facility produced ions are created by charge-exchange collisions between neutral atoms and energetic thruster beam ions. The result of the electron transfer is an energetic neutral atom and an ion of only thermal energy. There are true charge-exchange ions produced by collisions with neutrals escaping from the ion thruster and being charge-exchange ionized before the neutral intercepts the tank wall. The facility produced charge-exchange ions will not exist in space and therefore, represent a source of error where measurements involving ion thruster plasmas and their density are involved. The quantity of facility produced ions in a test chamber with a 30 cm mercury ion thruster was determined.

Carruth, M. R., Jr.↗