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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Reaction cycle and thermodynamics in bacteriorhodopsin

Light causes the all-trans to 13-cis isomerization of the retinal in bacteriorhodopsin; the thermal relaxation leading back to the initial state drives proton transport first via proton transfer between the retinal Schiff base and D85 and then between the Schiff base and D96. The reaction sequence and thermodynamics of this photocycle are described by measuring time-resolved absorption changes with a gated multichannel analyzer between 100 ns and 100 ms, at six temperatures between 5 degrees C and 30 degrees C. Analysis of the energetics of the chromophore reaction sequence is on the basis of a recently proposed model (Varo & Lanyi, Biochemistry 30, 5016-5022, 1991) which consists of a single cycle and many reversible reactions: BR -hv-->K<==>L<==>M1-->M2<==>N<==>O-->BR. The existence of the M1-->M2 reaction, which functions as the switch in the proton transfer, is confirmed by spectroscopic evidence. The calculated thermodynamic parameters indicate that the exchange of free energy between the protein and the protons is at the switch step. Further, a large entropy decrease at this reaction suggests a protein conformation change which will conserve delta G for driving the completion of the reaction cycle. The results provide insights to mechanism and energy coupling in this system, with possible relevance to the general question of how ion pumps function.

Review↗
NASA NTRS2003

Sensitivity analysis of radiative transfer for atmospheric remote sensing in thermal IR: atmospheric weighting functions and surface partials

In this presentation, we apply the adjoint sensitivity analysis of radiative transfer in thermal IR to the general case of the analytic evaluation of the weighting functions of atmospheric parameters together with the partial derivatives for the surface parameters. Applications to remote sensing of atmospheres of Mars and Venus are discussed.

sensitivity analysis remote sensing↗
NASA NTRS2019

Life's Requirements

Life on Earth is molecular in nature, with its lifelike attributes- e.g., information processing and catalysis- emerging as a result of both the specific properties of those molecules and the interactions among them. If this is a general model for life, then life must require (i) a source of energy, with which to build and sustain molecular complexity and information processing; (ii) elemental raw materials, from which to construct molecules having specific properties and reactivity; (iii)a solvent that supports the synthesis of the full range of molecules required by life and properly mediates the full range of necessary interactions among those molecules; and (iv) physicochemical conditions in which life's molecules can be synthesized, are appropriately stable, and can interact as needed for lifelike function. For life on Earth, these general requirements, respectively, take the specific form: (i) light energy in visible-to-near-infrared wavelengths or chemical energy as provided by oxidation–reduction disequilibrium, (ii) the "biogenic "elements (carbon, hydrogen, oxygen, nitrogen, phosphorus, and sulfur) (iii)liquid water, and (iv) specific ranges in temperature, pH, salinity, pressure, and other environmental factors. Our knowledge of these factors relates to cellula rlife as we observe it now or can infer from the fossil or molecular records. Life's origin may be constrained by a more stringent set of requirements that are, as yet,not fully understood.

Habitability↗
NASA NTRS1976

On Schmidt's Vm estimator and other estimators of luminosity functions

Schmidt's (1968) estimator, sometimes used to calculate the luminosity function from a complete sample of observed objects, can be generalized naively to the case in which the maximum distance for detection is a function of the direction. Though unbiased, this estimator then does not have minimum variance and, in some cases, is inferior to the classical estimator. The classical estimator, however, is biased when the magnitude boxes are not infinitesimal. A generalization of Schmidt's estimator is proposed which is unbiased and usually superior to both Schmidt's and the classical estimator. Variance formulas and numerical examples are given. The results can be used in combining several catalogs.

Felten, J. E.↗
NASA NTRS1985

Atmospheric Effect on Remote Sensing of the Earth's Surface

Radiative transfer theory (RT) for an atmosphere with a nonuniform surface is the basis for understanding and correcting for the atmospheric effect on remote sensing of surface properties. In the present work the theory is generalized and tested successfully against laboratory and field measurements. There is still a need to generalize the RT approximation for off-nadir directions and to take into account anisotropic reflectance at the surface. The reflectance at the surface. The adjacency effect results in a significant modification of spectral signatures of the surface, and therefore results in modification of classifications, of separability of field classes, and of spatial resolution. For example, the 30 m resolution of the Thematic Mapper is reduced to 100 m by a hazy atmosphere. The adjacency effect depends on several optical parameters of aerosols: optical thickness, depth of aerosol layer, scattering phase function, and absorption. Remote sensing in general depends on these parameter, not just adjacency effects, but they are not known well enough for making accurate atmospheric corrections. It is important to establish methods for estimating these parameters in order to develop correction methods for atmospheric effects. Such estimations can be based on climatological data, which are not available yet, correlations between the optical parameters and meteorological data, and the same satellite measurements of radiances that are used for estimating surface properties. Knowledge about the atmospheric parameters important for remote sensing is being enlarged with current measurements of them.

Fraser, R. S.↗
NASA NTRS1994

Composite-Plate-Buckling Analysis Program

Composite-Plate-Buckling Analysis Program (COMPPAP) helps engineers determine buckling loads of orthotropic or isotropic irregularly shaped plates without need to perform manual calculations and extensive finite-element mathematical modeling. One-element finite-element program utilizing high-order displacement functions to perform plane-stress analysis of general plate followed by buckling calculation based on stresses found in plane-stress solution. High order of displacement functions enables user to obtain results more accurately. Written in ANSI FORTRAN 77. Two machine versions available: (MSC-22428) for computers of IBM PC 386 and higher series and for compatible computers; and UNIX (MSC-22286).

Smith, James P.↗
NASA NTRS1979

Maximum likelihood estimation for life distributions with competing failure modes

The general model for the competing failure modes assuming that location parameters for each mode are expressible as linear functions of the stress variables and the failure modes act independently is presented. The general form of the likelihood function and the likelihood equations are derived for the extreme value distributions, and solving these equations using nonlinear least squares techniques provides an estimate of the asymptotic covariance matrix of the estimators. Monte-Carlo results indicate that, under appropriate conditions, the location parameters are nearly unbiased, the scale parameter is slightly biased, and the asymptotic covariances are rapidly approached.

Sidik, S. M.↗
NASA NTRS1996

First-Order System Least Squares for the Stokes Equations, with Application to Linear Elasticity

Following our earlier work on general second-order scalar equations, here we develop a least-squares functional for the two- and three-dimensional Stokes equations, generalized slightly by allowing a pressure term in the continuity equation. By introducing a velocity flux variable and associated curl and trace equations, we are able to establish ellipticity in an H(exp 1) product norm appropriately weighted by the Reynolds number. This immediately yields optimal discretization error estimates for finite element spaces in this norm and optimal algebraic convergence estimates for multiplicative and additive multigrid methods applied to the resulting discrete systems. Both estimates are uniform in the Reynolds number. Moreover, our pressure-perturbed form of the generalized Stokes equations allows us to develop an analogous result for the Dirichlet problem for linear elasticity with estimates that are uniform in the Lame constants.

Cai, Z.↗
NASA NTRS1993

LVQ and backpropagation neural networks applied to NASA SSME data

Feedfoward neural networks with backpropagation learning have been used as function approximators for modeling the space shuttle main engine (SSME) sensor signals. The modeling of these sensor signals is aimed at the development of a sensor fault detection system that can be used during ground test firings. The generalization capability of a neural network based function approximator depends on the training vectors which in this application may be derived from a number of SSME ground test-firings. This yields a large number of training vectors. Large training sets can cause the time required to train the network to be very large. Also, the network may not be able to generalize for large training sets. To reduce the size of the training sets, the SSME test-firing data is reduced using the learning vector quantization (LVQ) based technique. Different compression ratios were used to obtain compressed data in training the neural network model. The performance of the neural model trained using reduced sets of training patterns is presented and compared with the performance of the model trained using complete data. The LVQ can also be used as a function approximator. The performance of the LVQ as a function approximator using reduced training sets is presented and compared with the performance of the backpropagation network.

Doniere, Timothy F.↗
NASA NTRS2008

Software Simulates Sight: Flat Panel Mura Detection

In the increasingly sophisticated world of high-definition flat screen monitors and television screens, image clarity and the elimination of distortion are paramount concerns. As the devices that reproduce images become more and more sophisticated, so do the technologies that verify their accuracy. By simulating the manner in which a human eye perceives and interprets a visual stimulus, NASA scientists have found ways to automatically and accurately test new monitors and displays. The Spatial Standard Observer (SSO) software metric, developed by Dr. Andrew B. Watson at Ames Research Center, measures visibility and defects in screens, displays, and interfaces. In the design of such a software tool, a central challenge is determining which aspects of visual function to include while accuracy and generality are important, relative simplicity of the software module is also a key virtue. Based on data collected in ModelFest, a large cooperative multi-lab project hosted by the Optical Society of America, the SSO simulates a simplified model of human spatial vision, operating on a pair of images that are viewed at a specific viewing distance with pixels having a known relation to luminance. The SSO measures the visibility of foveal spatial patterns, or the discriminability of two patterns, by incorporating only a few essential components of vision. These components include local contrast transformation, a contrast sensitivity function, local masking, and local pooling. By this construction, the SSO provides output in units of "just noticeable differences" (JND) a unit of measure based on the assumed smallest difference of sensory input detectable by a human being. Herein is the truly amazing ability of the SSO, while conventional methods can manipulate images, the SSO models human perception. This set of equations actually defines a mathematical way of working with an image that accurately reflects the way in which the human eye and mind behold a stimulus. The SSO is intended for a wide variety of applications, such as evaluating vision from unmanned aerial vehicles, measuring visibility of damage to aircraft and to the space shuttles, predicting outcomes of corrective laser eye surgery, inspecting displays during the manufacturing process, estimating the quality of compressed digital video, evaluating legibility of text, and predicting discriminability of icons or symbols in a graphical user interface.

Source record↗
NASA NTRS1971

Generalized invariance principles and the theory of stability.

Description of some recent extensions of the invariance principle to more generalized dynamical systems where the state space is not locally compact and the flow is unique only in the forward direction of time. A sufficient condition for asymptotic stability of an invariant set is obtained which does not require that the Liapunov function be positive-definite. A recently developed generalized invariance principle is described which is applicable to functional differential equations, partial differential equations, and, in particular, to certain stability problems arising in thermoelasticity, viscoelasticity, and distributed nonlinear networks.

Lasalle, J. P.↗
NASA NTRS1994

NLTE model stellar atmospheres with line blanketing near the series limits

In this paper we study the influence of line-merging regions at the intermediate long-wavelength side of a continuum threshold on the computed model atmosphere structure and predicted spectrum. In order to model these regions sufficiently accurately, we have developed two concepts. First, we have extended the occupation probability formalism of Hummer and Mihalas to non-local thermodynamic equilibrium (non-LTE) plasmas. Second, in order to treat the very complicated opacity in the line merging region, we have generalized the concept of opacity distribution functions to treat non-LTE situations. All Rydberg states are consistently included within this framework, so that no arbitrary cutoff of high (LTE) levels is made. We have calculated several pure hydrogen models atmospheres for two effective temperatures, T(sub eff) = 20000 and 35000 K, and discussed the differences between models calculated with various treatments of the line merging. In particular, we have shown that the error in the predicted profiles of Balmer lines resulting from the neglect of line merging is typically of the order of 3-4%, while the errors in the far-UV portion of the Balmer continuum reaches 15-35%. The errors generally decrease with increasing effective temperature. At the same time, the internal accuracy of the models is shown to be about or below 0.5% for all predicted spectral features. We conclude that for interpreting current high-accuracy spectrophotometric observations models including the line merging are necessary, and that the formalism developed in this paper is capable of providing a sufficiently accurate and robust modeling technique.

Hubeny, I.↗
NASA NTRS1973

A new approach to the design of time-varying control systems with application to the Space Shuttle Boost

A general approach to the analysis and design of closed-loop control for slowly time-varying linear systems is presented. The approach uses the method of generalized multiple scales in which slow and fast dynamics are systematically separated by employing different 'clocks' which measure time at varying rates. The clocks, which are necessarily nonlinear functions of time, are chosen in such a manner that the system dynamics are asymptotically invariant with respect to the new time scale. A transfer function relating the output to the input for general linear slowly time-varying systems is developed and represents the actual system under certain conditions. The clock function is shown to satisfy an algebraic characteristic equation and can be determined in terms of the coefficients. The approach can be viewed as an extension of time-invariant linear feedback control theory.

Ramanth, R. V.↗
NASA NTRS1994

Spatial autocorrelation of radiation measured by the Earth Radiation Budget Experiment: Scene inhomogeneity and reciprocity violation

The spatial autocorrelation functions of broad-band longwave and shortwave radiances measured by the Earth Radiation Budget Experiment (ERBE) are analyzed as a function of view angle in an investigation of the general effects of scene inhomogeneity on radiation. For nadir views, the correlation distance of the autocorrelation function is about 900 km for longwave radiance and about 500 km for shortwave radiance, consistent with higher degrees of freedom in shortwave reflection. Both functions rise monotonically with view angle, but there is a substantial difference in the relative angular dependence of the shortwave and longwave functions, especially for view angles less than 50 deg. In this range, the increase with angle of the longwave functions is found to depend only on the expansion of pixel area with angle, whereas the shortwave functions show an additional dependence on angle that is attributed to the occlusion of inhomogeneities by cloud height variations. Beyond a view angle of about 50 deg, both longwave and shortwave functions appear to be affected by cloud sides. The shortwave autocorrelation functions do not satisfy the principle of directional reciprocity, thereby proving that the average scene is horizontally inhomogeneous over the scale of an ERBE pixel (1500 sq km). Coarse stratification of the measurements by cloud amount, however, indicates that the average cloud-free scene does satisfy directional reciprocity on this scale.

Davies, Roger↗
NASA NTRS1959

Heat Transfer in a Liquid Metal Flowing Turbulently through a Channel with a Step Function Boundary Temperature

An analytical heat transfer solution is derived and evaluated for the general case of a turbulently flowing liquid metal which suddenly encounters a step-function boundary temperature in a channel system. Local Nusselt moduli, dimensionless mixed-mean fluid temperatures, and arithmetic-mean Nusselt moduli are given as functions of Reynolds and Prandtl moduli and a dimensionless axial-distance modulus. These solutions are compared with known solutions of more specific systems as well as with a set of experimental liquid-metal heat transfer data for a thermal entrance region.

Poppendiek, H. F.↗
NASA NTRS1984

Functional integration of vertical flight path and speed control using energy principles

A generalized automatic flight control system was developed which integrates all longitudinal flight path and speed control functions previously provided by a pitch autopilot and autothrottle. In this design, a net thrust command is computed based on total energy demand arising from both flight path and speed targets. The elevator command is computed based on the energy distribution error between flight path and speed. The engine control is configured to produce the commanded net thrust. The design incorporates control strategies and hierarchy to deal systematically and effectively with all aircraft operational requirements, control nonlinearities, and performance limits. Consistent decoupled maneuver control is achieved for all modes and flight conditions without outer loop gain schedules, control law submodes, or control function duplication.

Lambregts, A. A.↗
NASA NTRS1974

A direct approach to the design of linear multivariable systems

Design of multivariable systems is considered and design procedures are formulated in the light of the most recent work on model matching. The word model matching is used exclusively to mean matching the input-output behavior of two systems. The term is used in the frequency domain to indicate the comparison of two transfer matrices containing transfer functions as elements. Design methods where non-interaction is not used as a criteria were studied. Two design methods are considered. The first method of design is based solely upon the specification of generalized error coefficients for each individual transfer function of the overall system transfer matrix. The second design method is called the pole fixing method because all the system poles are fixed at preassigned positions. The zeros of terms either above or below the diagonal are partially fixed via steady state error coefficients. The advantages and disadvantages of each method are discussed and an example is worked to demonstrate their uses. The special cases of triangular decoupling and minimum constraints are discussed.

Agrawal, B. L.↗