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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

Constraints on the Recent Rate of Lunar Regolith Accumulation from Diviner Observations

Many large craters on the lunar nearside show radar CPR signatures consistent with the presence of blocky ejecta blankets, to distances pre dicted to be covered by continuous ejecta. However, most of these sur faces show limited enhancements in both derived rock abundance and rock-free regolith temperatures calculated from Diviner nighttime infrar ed observations. This indicates that the surface rocks are covered by a layer of thermally insulating regolith material. By matching the results of one-dimensional thermal models to Diviner nighttime temperat ures, we have constrained the thermophysical properties of the upper regolith, and the thickness of regolith overlying proximal ejecta. We find that for all of the regions surveyed (all in the nearside highla nds), the nighttime cooling curves are best fit by a density profile that varies exponentially with depth, consistent with a linear mixture of rocks and regolith fines, with increasing rock content with depth . Our results show significant spatial variations in the density e-folding depth, H, among young crater ejecta regions, indicating differen ces in the thickness of accumulated regolith. However, away from youn g craters, the average regional "equilibrium" value of H (Heq) is remarkably consistent, and is on the order of 5 cm. As expected, near-rim ejecta associated with young craters show lower values of H, indicating a high rock content in the shallow subsurface; for older craters, the average value of H approaches the regional value of Heq. Calculat ed H values for young craters show a clear correlation with published ages, providing the first observational constraint on the recent rate of lunar regolith accumulation. In addition, this result may help to resolve the apparent discrepancy between ages calculated from small crater counts on melt ponds versus counts on continuous ejecta (e.g., King crater; Ashley et al., 2011, LPSC 42, abstract 2437). This method could, in principle, be extended to other airless bodies (e.g., aste roids), which would in turn constrain the recent impactor flux.

Ghent, R. R.↗
NASA NTRS2014

Ballistic Performance Model of Crater Formation in Monolithic, Porous Thermal Protection Systems

Porous monolithic ablative systems insulate atmospheric reentry vehicles from reentry plasmas generated by atmospheric braking from orbital and exo-orbital velocities. Due to the necessity that these materials create a temperature gradient up to several thousand Kelvin over their thickness, it is important that these materials are near their pristine state prior to reentry. These materials may also be on exposed surfaces to space environment threats like orbital debris and meteoroids leaving a probability that these exposed surfaces will be below their prescribed values. Owing to the typical small size of impact craters in these materials, the local flow fields over these craters and the ablative process afford some margin in thermal protection designs for these locally reduced performance values. In this work, tests to develop ballistic performance models for thermal protection materials typical of those being used on Orion are discussed. A density profile as a function of depth of a typical monolithic ablator and substructure system is shown in Figure 1a.

Miller, J. E.↗
NASA NTRSDate not supplied

Distribution and Sources of Tropospheric Aerosols Over the Western North Atlantic During ACTIVATE (February-March 2020)

The Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment (ACTIVATE) is a five-year (2019-2023) NASA Earth-Venture Suborbital-3 (EVS-3) mission to robustly characterize aerosol-cloud-meteorology interactions during February-June, with a focus on marine boundary layer clouds. This characterization requires understanding of aerosol composition, distribution, transport pathways, and sources. Here we use the GEOS-Chem chemical transport model driven by the MERRA-2 reanalysis to simulate tropospheric carbon monoxide (CO) and aerosols over the western North Atlantic Ocean (WNAO) during the first field deployment of ACTIVATE (February-March 2020). CO is used as a tracer to diagnose transport pathways for continental pollution outflow to the WNAO. The aerosol simulation represents all major aerosols including sulfate-nitrate-ammonium (SNA), mineral dust, sea salt, black and organic carbon aerosols. Model-simulated mixing ratios of SNA and organic carbon are compared with aircraft observations. We show that intensive aerosol mass measurements in the lower troposphere over the North American outflow region during ACTIVATE provide strong constraints on model aerosol wet scavenging. Comparisons of model aerosol extinctions with the airborne High Spectral Resolution Lidar-2 (HSRL-2) measurements indicate that the model generally captures continental outflow of aerosols and enhanced extinctions associated with sea salt. Simulated aerosol optical depths (AODs) and extinction vertical profiles are also compared with satellite retrievals from MODIS/Aqua and CALIOP/CALIPSO, respectively. CALIOP sometimes observes enhanced aerosol extinction at altitudes between ~1.5km and ~2.0km south of 32°N. The model reproduces this enhancement and attributes it to coarse-mode sea salt associated with high relative humidity. The relative contributions of continental and oceanic sources to the aerosol loading, AOD, and their distributions over the study domain will also be discussed.

aerosols↗
NASA NTRS2019

Investigation of CATS Aerosol Products and Application Toward Global Diurnal Variation of Aerosols

We present a comparison of 1064 nm aerosol optical depth (AOD) and aerosol extinction profiles from the Cloud-Aerosol Transport System (CATS) level 2 aerosol product with collocated Aerosol Robotic Network (AERONET) AOD, Moderate Imaging Spectroradiometer (MODIS) Aqua and Terra Dark Target AOD and Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) AOD and extinction data for the period of March 2015–October 2017. Upon quality-assurance checks of CATS data, reasonable agreement is found between aerosol data from CATS and other sensors. Using quality-assured CATS aerosol data, for the first time, variations in AODs and aerosol extinction profiles are evaluated at 00:00, 06:00, 12:00 and 18:00 UTC (and/or 00:00, 06:00, 12:00 and 18:00 local time or LT) on both regional and global scales. This study suggests that marginal variations are found in AOD from a global mean perspective, with the minimum aerosol extinction values found at 18:00 LT near the surface layer for global oceans, for both the June–November and December–May seasons. Over land, below 500 m, the daily minimum and maximum aerosol extinction values are found at 12:00 and 00:00/06:00 LT, respectively. Strong diurnal variations are also found over north Africa, the Middle East and India for the December–May season, and over north Africa, south Africa, the Middle East and India for the June–November season.

Logan Lee↗
NASA NTRS2001

High-Frequency Focused Water-Coupled Ultrasound Used for Three-Dimensional Surface Depression Profiling

To interface with other solids, many surfaces are engineered via methods such as plating, coating, and machining to produce a functional surface ensuring successful end products. In addition, subsurface properties such as hardness, residual stress, deformation, chemical composition, and microstructure are often linked to surface characteristics. Surface topography, therefore, contains the signatures of the surface and possibly links to volumetric properties, and as a result serves as a vital link between surface design, manufacturing, and performance. Hence, surface topography can be used to diagnose, monitor, and control fabrication methods. At the NASA Glenn Research Center, the measurement of surface topography is important in developing high-temperature structural materials and for profiling the surface changes of materials during microgravity combustion experiments. A prior study demonstrated that focused air-coupled ultrasound at 1 MHz could profile surfaces with a 25-m depth resolution and a 400-m lateral resolution over a 1.4-mm depth range. In this work, we address the question of whether higher frequency focused water-coupled ultrasound can improve on these specifications. To this end, we employed 10- and 25-MHz focused ultrasonic transducers in the water-coupled mode. The surface profile results seen in this investigation for 25-MHz water-coupled ultrasound, in comparison to those for 1-MHz air-coupled ultrasound, represent an 8 times improvement in depth resolution (3 vs. 25 m seen in practice), an improvement of at least 2 times in lateral resolution (180 vs. 400 m calculated and observed in practice), and an improvement in vertical depth range of 4 times (calculated).

Roth, Don J.↗
NASA NTRS1987

Dynamic topography and gravity anomalies for fluid layers whose viscosity varies exponentially with depth

Adopting the formalism of Parsons and Daly (1983), analytical integral equations (Green's function integrals) are derived which relate gravity anomalies and dynamic boundary topography with temperature as a function of wavenumber for a fluid layer whose viscosity varies exponentially with depth. In the earth, such a viscosity profile may be found in the asthenosphere, where the large thermal gradient leads to exponential decrease of viscosity with depth, the effects of a pressure increase being small in comparison. It is shown that, when viscosity varies rapidly, topography kernels for both the surface and bottom boundaries (and hence the gravity kernel) are strongly affected at all wavelengths.

Revenaugh, Justin↗
NASA NTRS1992

Observation and interpretation of the asymmetric Stokes Q, U, and V line profiles in sunspots

We present a first approach to systematic characterization and interpretation of observed asymmetries of Stokes profiles as a function of spatial position within sunspots. Spatial maps of the full Stokes profiles of Fe I 6302.5 A gathered in large sunspots using the HAO Stokes II instrument reveal asymmetries that vary systematically across large sunspots observed during 1980. We use the inversion technique by Landolfi to extract the velocity gradients along the line of sight (LOS) which give rise to these asymmetries. The gradients derived from full Stokes profiles are in agreement with previous characterizations of the Evershed flow derived from Stokes I profiles alone (i.e., a flow increasing with depth in the atmosphere). By coupling this semiempirical gradient of velocity with a magnetic field inclination varying along the LOS, the synthesized profiles are able to mimic basic observed features of the broad-band circular polarization present in our data and observed previously by others. This characterization has magnetic field lines which become progressively more horizontal with depth in the penumbra.

Sanchez Almeida, J.↗
NASA NTRS2014

AVCOAT Density Characterization for Orion Multi-Purpose Crew Vehicle

The Orion Multi-Purpose Crew Vehicle (MPCV) will transport four crew members to and from lunar-class orbital destinations. The first orbital Exploration Flight Test (EFT-1) is scheduled for December 2014 and will provide valuable data on several systems, including the heat shield. The heat shield material is AvcoatTM, a mid-density ablator. Specifically, the heat shield contains a fiberglass-phenolic honeycomb structure filled with an ablative epoxy novolac resin. Post-flight characterization of the EFT-1 thermal protection system will be conducted in order to study the material response and measure the char front of the material. Avcoat density profiling will be conducted to study three critical material zones: char, pyrolysis, and virgin states as a function of material depth. As part of a ground test campaign, Avcoat coupons are tested at the NASA Ames Research Center Arc Jet Complex. The test campaign is set forth to study material response based on environments, perform Avcoat material density characterization, and compare the char depths from the HEAT sensor and density profiling studies. These investigations will then be compared to flight data in order to improve upon TPS material response models.

AVCOAT↗
NASA NTRS1990

The transfer of resonance-line radiation in static astrophysical media

An analytic solution is derived for the mean intensity of resonance-line radiation within an absorbing medium of large scattering optical depth but low density. The line profile, the mean number of scatterings before absorption or escape, the mean path length traveled, and the fraction of the photons which escape the medium are derived. Approximate methods are also developed which permit the treatment of media of intermediate optical depth, where scattering takes place in the Doppler core. Astrophysical applications include the absorption of H Ly-alpha radiation by stellar dust, the pumping of H2 Lyman band lines by H Ly-alpha and the Bowen fluorescence.

Neufeld, David A.↗
NASA NTRS1994

Near-surface ice on Mercury and the Moon: A topographic thermal model

A thermal model that can be easily adapted to craters of arbitrary shape is developed and applied to high-latitude impact craters on Mercury and the Moon, Chao Meng Fu crater at -87.5 deg L on Mercury, an unnamed bowl-shaped crater at 86.7 deg L on Mercury, and Peary crater at 88.6 deg L on the Moon. For an assumed input topography and grid of surface elements, the model computes for each element the irradiation from direct insolation and reflected and emitted radiation from other elements, taking into account shadowing by walls of the crater, partial obscuration of the solar disk near the poles and the diurnal, orbital, and seasonal cycles. Temperatures are computed over the surface grid as functions of depth and time from the surface to a specified depth and over the pertinent astronomical cycles, including the effects of direct and indirect surface irradiation, infrared radiation, heat conduction, and interior heating. Vapor fluxes and ice recession times are computed as functions of ice depth over the surface grid. Temperatures profiles, vapor fluxes, and ice recession times were computed for flat surfaces not associated with craters near the poles of Mercury and the Moon. It was found that water ice could have existed throughout geologic time within the maximum radar detection depth of recent observation of Mercury (J. K. Harmon and M. A. Slade, 1992, Science 258, 640-643) poleward of approximately 87 - 88 deg L on Mercury and poleward of approximately 73 deg L on the Moon. For Chao Meng Fu crater it was found that approximately 40% of the crater floor is permanently shadowed from direct solar insolation, while the remainder of the crater floor is periodically illuminated by a partially obscured Sun. Temperatures at the upper levels of the south wall can slightly exceed 550 K. Surface temperatures in the permanently shadowed region of the crater floor are under approximately 130 K, which could have allowed water ice to exist throughout geologic time within the radar detection depth of recent observation of Mercury. For small bowl-shaped crater on Mercury, it was found that most of the crater is permanently shadowed from direct solar radiation, except for a narrow semicircular band bordering the north rim. However, temperatures in the permanently shadowed region periodically reach a maximum near approximately 315 K due to efficient heating of the small crater by thermal emission and reflection from the small sunlit region, which periodically reaches temperatures exceeding 630 K. Water ice could not have existed throughout geologic time anywhere in this crater within the radar detection depth. For Peary crater on the Moon, the entire crater floor is permanently shadowed from direct solar insolation with maximum temperature under 120 K. The upper level of the north wall periodically reaches a maximum temperature near 310 K. The low temperatures on the crater floor would have allowed water ice to exist near the surface throughout geologic time, provided that the Moon's obliquity was always as low as it is at present.

Salvail, James R.↗
DOE OSTI2022

A Meteorology and Snow Data Set From Adjacent Forested and Meadow Sites at Crested Butte, CO, USA

We present meteorology and snow observation data collected at sites in the southwestern Colorado Rocky Mountains (USA) over three consecutive water years with different amounts of snow water equivalent (SWE) accumulation: A year with above average SWE (2019), a year with average SWE (2020), and a year with below average SWE (2021). This data set is distinguished by its emphasis on paired open-forest sites in a continental snow climate. Approximately once a month during February–May, we collected data from 15 to 20 snow pits and took 8 to 19 snow depth transects. Our sampling sites were in open and adjacent forested areas at 3,100 m and in a lower elevation aspen (3,035 m) and higher elevation conifer stand (3,395 m). In total, we recorded 270 individual snow pit density and temperature profiles and over 4,000 snow depth measurements. These data are complimented by continuous meteorological measurements from two weather stations: One in the open and one in the adjacent forest. Meteorology data—including incoming shortwave and longwave radiation, outgoing shortwave radiation, relative humidity, wind speed, snow depth, and air and infrared surface temperature—were quality controlled and the forcing data were gap-filled. These data are available to download from Bonner, Smyth, et al. at three levels of processing, including a level with downscaled, adjusted precipitation based on data assimilation using observed snow depth and a process-based snow model. We demonstrate the utility of these data with a modeling experiment that explores open-forest differences and identifies opportunities for improvements in model representation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Water foraging with dynamic roots in E3SM; The role of roots in terrestrial ecosystem memory on intermediate timescales (Final Technical Report)

Terrestrial ecosystems can show sustained responses to stress events that may last for years after the initial perturbation. This phenomenon is referred to as legacy or memory and it emerges from a set of ecosystem processes that are poorly captured by Earth System and Land Surface Models. Consequently, these models struggle to predict the impact that extreme climate events have on surface energy, carbon and hydrological exchange once a stressor such as drought has relaxed or in response to repeated exposure to stress. In this project, we set out to test how the addition of dynamic root profiles in land surface models impact the capacity for Earth System Models, such as the Department of Energy’s E3SM, to capture realistic legacy effects. Observations have shown that vegetation shifts their root profiles during stress events to forage for water and these altered root profiles may take years to relax back to the initial state. We hypothesized that the alteration of the belowground root structures may be a source of terrestrial ecosystem legacy that is missing from models. To test this idea we undertook three core activities. (1) We developed a global-scale analysis of the impact of dynamic roots on ecosystem legacy building from a recently developed dynamic root module. (2) We developed new root dynamics in the DOE’s Energy Land Model (ELM) that allowed not only root profiles to shift their profile but also simultaneously alter carbon allocation to fine root pools. We then tested the impact of these new dynamics with intensive sensitivity analysis at four long-term AmeriFlux sites. (3) We undertook detailed isotopic analysis of tree rings from these AmeriFlux sites to assess ecophysiological and ecohydrological legacy to stress events that can be used to benchmark the sensitivity experiments with ELM. From these core activities, we report the following key findings. Firstly, on a global scale, the addition of dynamic roots led to chronically water-stressed ecosystems recovering faster to climate stress while wetter ecosystem showed enhanced legacy. This is because across ecosystems, stress events were almost universally associated with water shortages that led to the development of deeper root profiles. These deeper root profiles proved beneficial for recovery from drought stress. While the root dynamics did not universally improve the modeled representation of legacy it showed complex transient dynamics that emerge from the addition of dynamic roots. Secondly, the sensitivity analysis illustrated long term shifts in rooting depths away from the prescribed default profile suggesting that initializing of root profiles could benefit from spin-up simulations that converge on locally optimized root profiles. In addition, by enabling dynamic allocation some of the sites predicted unrealistically low allocation to roots (and high allocation to leaves). While these changes did not dramatically alter modeled gross primary productivity, they illustrated that without more sophisticated root processes in models, there is little penalty to dramatically disinvest in roots. Thirdly, the isotopic analysis of tree rings showed highly distinct legacy responses across species and sites. For example, T. canadensis showed reduced transpiration the year after stress events illustrated by sustained elevated $\delta^{18}$O. In contrast, A saccharum displayed elevated $\delta^{13}$C associated with reduced stomatal conductance in response to the previous years’ stress event. These geochemical signatures of legacy were present despite tree growth returning to normal the year after the stress. The results show the importance of species-level dynamics in legacy that are absent in modeling that assumes common traits within plant functional types. In summary, the work here established new avenues to explore root dynamics in models while illustrating how additional root processes are needed before dynamic carbon allocation can be implemented. Lastly, this project provided mentorship to a postdoctoral fellow, training for an early career scientist and multiple undergraduate students recruited from a minority serving institution.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Aerobic respiration controls on shale weathering, Geochimica et Cosmochimica Acta, 2023: Dataset

This data package was generated in order to support the development of a deep-time weathering model and to assess the coupling between shale weathering and aerobic respiration in the paper “Aerobic respiration controls on shale weathering” by Stolze et al., Geochimica et Cosmochimica Acta (2023). The package contains two csv files providing the average CO2(g) concentration profiles [ppm] and mineral concentration profiles [wt%], respectively. The CO2(g) concentration profiles were measured in the vicinity of the monitoring well PLM2 between January 2018 and April 2019. The gas samples were collected in the unsaturated zone to a depth of 1.52 m. The mineral concentration profiles were determined by X-Ray diffraction (XRD). The XRD measurements were performed on sub-core samples collected in the monitoring well PLM3 down to a depth of 7.01 m. The dataset additionally includes a file-level metadata (flmd.csv) file that lists each file contained in the dataset with associated metadata; and a data dictionary (dd.csv) file that contains column/row headers used throughout the files along with a definition, units, and data type.Update on 2024-05-28: Revised versions of the CSV data files (CO2_data_GCA_Stolze_et_al_2023.csv and XRD_data_GCA_Stolze_et_al_2023.csv) were made to apply ESS-DIVE's CSV reporting format guidelines. Updated versions of the File Level Metadata (v2_20240528_flmd.csv) and Data Dictionary (v2_20240528_dd.csv) files were updated to reflect the changes made to the CSV files.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2011

Standardization of a Volumetric Displacement Measurement for Two-Body Abrasion Scratch Test Data Analysis

A limitation has been identified in the existing test standards used for making controlled, two-body abrasion scratch measurements based solely on the width of the resultant score on the surface of the material. A new, more robust method is proposed for analyzing a surface scratch that takes into account the full three-dimensional profile of the displaced material. To accomplish this, a set of four volume- displacement metrics was systematically defined by normalizing the overall surface profile to denote statistically the area of relevance, termed the Zone of Interaction. From this baseline, depth of the trough and height of the plowed material are factored into the overall deformation assessment. Proof-of-concept data were collected and analyzed to demonstrate the performance of this proposed methodology. This technique takes advantage of advanced imaging capabilities that allow resolution of the scratched surface to be quantified in greater detail than was previously achievable. When reviewing existing data analysis techniques for conducting two-body abrasive scratch tests, it was found that the ASTM International Standard G 171 specified a generic metric based only on visually determined scratch width as a way to compare abraded materials. A limitation to this method was identified in that the scratch width is based on optical surface measurements, manually defined by approximating the boundaries, but does not consider the three-dimensional volume of material that was displaced. With large, potentially irregular deformations occurring on softer materials, it becomes unclear where to systematically determine the scratch width. Specifically, surface scratches on different samples may look the same from a top view, resulting in an identical scratch width measurement, but may vary in actual penetration depth and/or plowing deformation. Therefore, two different scratch profiles would be measured as having identical abrasion properties, although they differ significantly.

Street, K. W. Jr.↗
NASA NTRS1989

Comparisons of satellite ozone data in the lower stratosphere for 1978/1979

Lower stratospheric zonal mean O3 distributions are compared in both hemispheres from the Nimbus 7 Solar Backscattered Ultraviolet (SBUV) and Limb Infrared Monitor of the Stratosphere (LIMS) data sets. Generally there is very good agreement with regard to individual profile shape and magnitude and with their longitudinal variability about the zonal mean. When the data are considered in terms of Umkehr layer amounts, there are subtle but significant differences in the respective meridional O3 gradients and their variations with time which are probably related to a changing O3 optical depth and constants to an assumed profile climatology in the retrieval. Stratospheric Aerosol and Gas Experiment (SAGE) satellite O3 results are presented which tend to split the differences between SBUV and LIMS. Additional comparisons with electrochemical concentration cell sonde and Mastsonde O3 profiles are presented in order to sort out the more noticeable differences.

Remsberg, Ellis E.↗
DOE OSTI2026

Depth-resolved sagebrush root metabolomics, rhizosphere microbial communities, and geochemistry at the East River Watershed

This data set consists of results from soil nutrient profile, untargeted metabolomics, mass spec imaging, and amplicon sequencing. Data for soil nutrient profile includes common cations (Ca, Mg, Na, and K etc.) extracted from 3 digesting steps – ammonia acetate (for exchangeable cations), nitric acid (for acid dissolved fraction), and hydrofluoric acid/perchloric acid (HF/HClO4) for whole soil digestion. It also includes concentration of organic carbon, inorganic nitrogen (ammonia and nitrate) and phosphorus (Bray-1 P and nitric acid extract), and total nitrogen and phosphorus. Data for untargeted metabolomics includes metabolomic profile for root exudate/tissues and soil extracts from depths at surface soil to saprolite, that were measured using gas chromatography – mass spectrometry (GC-MS), and liquid chromatography – tandem mass spectrometry (LC-MS/MS). Data for mass spec imaging includes spatial distribution of metabolites that were detected and annotated with Fourier transformation ion cyclotron resonance mass spectrometer (FTICR-MS). Data for amplicon sequencing includes the base paired 16S and ITS ribosomal RNA sequences from Miseq Illumina sequencing. All samples were collected from 2 sampling campaign October 2022 and June 2023. Collectively, these datasets enable a mechanistic evaluation of how nutrient acquisition, especially nitrogen and phosphorus, differs between shallow roots operating in soil and deep roots functioning within the fractured bedrock zone. All files are provided as comma-separated values (CSV) fies (.csv) and (GZIP) file (.gz). The compressed .gz FASTQ files can be read directly in R using the dada2 package as part of the amplicon sequence analysis workflow. This work was supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231. This research was performed on a project award 60563 (https://dx.doi.org/10.46936/expl.proj.2022.60563/60008727) from the Environmental Molecular Sciences Laboratory, a DOE Office of Science User Facility sponsored by the Biological and Environmental Research program under Contract No. DE-AC05-76RL01830.

EARTH SCIENCE > AGRICULTURE > SOILS > CARBON↗
DOE OSTI2021

Aerosol Direct Radiative Effects at the ARM SGP and TWP Sites: Clear Skies

The clear-sky aerosol direct radiative effect (DRE) was estimated at the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) and Tropical Western Pacific (TWP) sites. The NASA Langley Fu-Liou radiation model was used with observed inputs including aerosol vertical extinction profile from the Raman lidar; spectral aerosol optical depth (AOD), single-scattering albedo and asymmetry factor from Aerosol Robotic Network; temperature and water vapor profiles from radiosondes; and surface shortwave (SW) spectral albedo from radiometers. A radiative closure experiment was conducted for clear-sky conditions. The mean differences of modeled and observed surface downwelling SW total fluxes were 1 W m-2 at SGP and 2 W m -2 at TWP, which are within observational uncertainty. At SGP, the estimated annual mean clear-sky aerosol DRE is -3.00 W m -2 at the top of atmosphere (TOA) and -6.85 W m -2 at the surface. The strongest aerosol DRE of -4.81 (-10.77) W m -2 at the TOA (surface) are in the summer when AODs are largest. The weakest aerosol DRE of -.28 (-2.77) W m -2 at the TOA (surface) are in November–January when AODs and single-scattering albedos are lowest. At TWP, the annual mean clear-sky DRE is -2.82 W m-2 at the TOA and -10.34 W m -2 at the surface. The strongest aerosol DRE of -5.95 (-22.20) W m -2 at the TOA (surface) are in November (October) due to the biomass burning season’s peak. The weakest aerosol DRE of -0.96 (-4.16) W m -2 at the TOA (surface) are in March (April) when AODs are smallest.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Exploring toroidal anvil profiles for larger sample volumes above 4 Mbar

Abstract With the advent of toroidal and double-stage diamond anvil cells (DACs), pressures between 4 and 10 Mbar can be achieved under static compression, however, the ability to explore diverse sample assemblies is limited on these micron-scale anvils. Adapting the toroidal DAC to support larger sample volumes offers expanded capabilities in physics, chemistry, and planetary science: including, characterizing materials in soft pressure media to multi-megabar pressures, synthesizing novel phases, and probing planetary assemblages at the interior pressures and temperatures of super-Earths and sub-Neptunes. Here we have continued the exploration of larger toroidal DAC profiles by iteratively testing various torus and shoulder depths with central culet diameters in the 30–50 µm range. We present a 30 µm culet profile that reached a maximum pressure of 414(1) GPa based on a Pt scale. The 300 K equations of state fit to our P–V data collected on gold and rhenium are compatible with extrapolated hydrostatic equations of state within 1% up to 4 Mbar. This work validates the performance of these large-culet toroidal anvils to > 4 Mbar and provides a promising foundation to develop toroidal DACs for diverse sample loading and laser heating.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗