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At least 649 records · Page 36

All sources NASA NTRS DOE OSTI

NASA NTRS2004

Lunar and Planetary Science XXXV: Mars: Hydrology, Drainage, and Valley Systems

The titles in this section include: 1) Analysis of Orientation Dependence of Martian Gullies; 2) A Preliminary Relationship between the Depth of Martian Gullies and the Abundance of Hydrogen on Near-Surface Mars; 3) Water Indicators in Sirenum Terra and around the Argyre Impact Basin, Mars; 4) The Distribution of Gullies and Tounge-shaped Ridges and Their Role in the Degradation of Martian Craters; 5) A Critical Evaluation of Crater Lake Systems in Memnonia Quadrangle, Mars; 6) Impact-generated Hydrothermal Activity at Gusev Crater: Implications for the Spirit Mission; 7) Characterization of the Distributary Fan in Holden NE Crater using Stereo Analysis; 8) Computational Analysis of Drainage Basins on Mars: Appraising the Drainage Density; 9) Hypsometric Analyses of Martian Basins: A Comparison to Terrestrial, Lunar, and Venusian Hypsometry; 10) Morphologic Development of Harmakhis Vallis, Mars; 11) Mangala Valles, Mars: Investigations of the source of Flood Water and Early Stages of Flooding; 12) The Formation of Aromatum Chaos and the Water Discharge Rate at Ravi Vallis; 13) Inferring Hydraulics from Geomorphology for Athabasca Valles, Mars; 14) The Origin and Evolution of Dao Vallis: Formation and Modification of Martian Channels by Structural Collapse and Glaciation; 15) Snowmelt and the Formation of Valley Networks on Martian Volcanoes; 16) Extent of Floating Ice in an Ancient Echus Chasma/Kasei Valley System, Mars.

Source record↗

NASA NTRS2012

SCaN Network Ground Station Receiver Performance for Future Service Support

Objectives: Examine the impact of providing the newly standardized CCSDS Low Density Parity Check (LDPC) codes to the SCaN return data service on the SCaN SN and DSN ground stations receivers: SN Current Receiver: Integrated Receiver (IR). DSN Current Receiver: Downlink Telemetry and Tracking (DTT) Receiver. Early Commercial-Off-The-Shelf (COTS) prototype of the SN User Service Subsystem Component Replacement (USS CR) Narrow Band Receiver. Motivate discussion of general issues of ground station hardware design to enable simple and cheap modifications for support of future services.

Deep Space Network (DSN)↗

NASA NTRSDate not supplied

xEMU Suit Integrated Audio Communications System: Ambient and EVA Pressure Testing System Performance

Testing across several airlock and EVA thermal and pressure scenarios has demonstrated that the Integrated Audio System of NASA’s Exploration Extravehicular Mobility Unit (xEMU) spacesuits transmits and receives intelligible audio communications without the use of a commcap or similar worn device. The xEMU audio system consists of internal loudspeakers and digital microphones (Integrated Communications System –ICS) combined with an adaptive Acoustic Echo Canceller (AEC), outbound voice operated transmission (VOX), and automatic gain control (AGC). Transducers are mounted in an “exploded commcap” configuration with helmet-attached speakers near the ears and three microphones positioned at the collar. The AGC removes inbound audio signals (e.g.,suit, Mission Control, Lander, C&W tones) from the outbound comms stream, reducing echo and feedback (squeal) in low-noise suit environments. The reduction of worn communication equipment increases crewmember comfort, range of movement, and situational awareness. However, test results also highlight the need for proper fan, duct, pump, and gas flow integration with suit acoustics and audio. Ductwork may serve as waveguides for various component and structure-borne noise. Sharply angled ducts can generate turbulent-flow noise. Gas flow from inlets above the crewmember’s head can generate noise when cascading over the faceplate and collar (or commcap) microphones. Sufficient acoustic noise levels (1) require increased gain to boost inbound audio, and (2) may distort signals resulting in AEC disruption or artifacts. Suit-noise levels decline with reduced pressure (density), but then elevated speech and audio effort/power become necessary. Whether the Integrated Audio System, commcap, or other device is used, suit acoustic noise can mask speech in outbound comms. This reduces intelligibility and requires other AECs/devices to suppress comms noise. Yet, adjusting a few components may yield significant improvement. We discuss xEMU audio functionality, demonstrate how acoustical treatment combined with inbound signal conditioning improved clarity during tests, and discuss future modifications.

xEMU↗

NASA NTRSDate not supplied

xEMU Suit Integrated Audio Communications System: Ambient and EVA Pressure Testing System Performance

xEMU↗

DOE OSTI2025

High Throughput Solvent-free Manufacturing of Battery Electrodes

The project goal is to develop and demonstrate an advanced solvent-free lithium-ion battery electrode process through proposed Advanced Dry Electrode Process (ADEP) equipment, which is expected to exhibit a better binder fibrillization and high throughput and suitable for high performance electrode manufacturing, and commonize the anode and cathode dry processing equipment, supply chain and operation for lithium-ion battery OEMs for replacing the solvent-based slurry casting. Our proposed approach will facilitate low-cost battery production by addressing the following gaps in present dry electrode processing: • Extend the dry electrode fabrication process to lithium-ion battery anode manufacturing • Increase the active material content for anodes and cathodes • Intensify the process through improved mixing, powder rheology and surface modifications • Enable processing of next-generation electrode materials that are not stable to solvent or ambient air exposure. The project objectives include the development of anode-compatible binder and binder fibrillization promoter for low irreversible capacity loss, low electrode binder content yet higher film mechanical strength, and the optimization of solvent-free anode and cathode process for low cost (>60% electrode cost reduction), high performance (10% increase in energy density without sacrificing cycle life) and high throughput to enable next generation lithium-ion battery electrode production. Solvent-free electrode manufacturing will also enable next-generation cell designs based on prelithiated anodes or solid-state electrolytes.

25 ENERGY STORAGE↗

NASA NTRS1979

High Efficiency Cell Development

The specific activity was to improve the tandem junction Cell (TJC) as a high efficiency solar cell. The TJC development was to be consistent with module assembly and should contribute to the overall goals of the Low-Cost Solar Array Project. During 1978, TJC efficiency improved from approximately 11 percent to approximately 16 percent (AMI). Photogenerated current densities in excess of 42 mA/sq cm were observed at AMO. Open circuit voltages as high as 0.615 V were measured at AMO. Fill factor was only 0.68 - 0.75 due to a nonoptimum metal contact design. A device model was conceived in which the solar cell is modelled as a transitor. There are virtually no interconnect or packaging factor systems and the TJC is compatible with all conventional module fabrication systems. A modification of the TJC, the Front Surface Field (FSF) cell, was also explored.

Carbajal, B. G.↗

NASA NTRS1983

Moire deflectometry with deferred analysis

A simplified version of moire deflectometry for flow visualization is presented. The modification comprises replacement of the second grating, the ground glass screen, and the camera with a plate film holder to obtain a shadow picture. Postanalysis proceeds by placing a grid transparency of the same periodicity of the remaining glass grating on the negative for projection viewing. The rotational angle between the grating and the plate alters the moire fringe periodicity. Use of the method in studying flows is predicted to reveal weak density gradient areas and shocks.

Rhodes, D. B.↗

DOE OSTI2021

Electronic Structure Modification of Rectangular Phosphorene Quantum Dots Via Edge Passivation

Phosphorene is an elemental two-dimensional material that shows great promise as a metal-free photocatalyst owing to its high carrier mobility and direct band gap. Doping and edge functionalization of phosphorene can be exploited to tune its band gap and alter other properties. Herein, the electronic properties of a series of edge-passivated monolayer phosphorene quantum dots are investigated using an array of functional groups (OH, SH, NH 2 , SCH 3 , OCN, CN, and Cl) that are known to have electron-donating or electron-withdrawing capabilities. By employing density functional theory calculations, we demonstrate that edge functionalization can perturbatively shift the HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital) energy levels while simultaneously preserving the geometric structure and other favorable properties of pristine phosphorene. We use the average overall electrostatic potential of these systems to successfully predict the relative positioning of the HOMO and LUMO energy levels while presenting qualitative explanations on potential jumps introduced by the dipole layers formed due to edge functionalization. Furthermore, our results suggest that selective functionalization permits considerable control over the band edge positions, which could be utilized for applications in energy and optoelectronic devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1977

Crater modification by gravity - A mechanical analysis of slumping

An analysis of the stability of a crater from a mechanical point of view indicates that the observed slumping of lunar craters requires a perfectly plastic constitutive relation for the lunar surface rock. The angle of internal friction of this material must be less than a few degrees. The evidence for a perfectly plastic constitutive relation is described, and a simplified model of a crater in a perfectly plastic medium is used to investigate the nature of its collapse. Crater stability is found to depend principally upon a dimensionless parameter equal to the product of the density, acceleration of gravity, and depth divided by the yield strength. Criteria for stability, 'slope failures', and 'floor failures' are reported.

Melosh, H. J.↗

DOE OSTI2022

Strain-Induced asymmetry and on-site dynamics of silicon defects in graphene

In the last decade, the atomically-focused electron beams utilized in scanning transmission electron microscopes (STEMs) have been shown to induce a broad set of local structural transformations in materials, opening pathways for directing material synthesis and modification atom-by-atom. The mechanisms underlying these transformations remain largely unknown, due to the intractability of modeling the myriad of reaction pathways that can be accessed through high-energy electron scattering. The information on materials’ structure and dynamics that can be extracted from STEM images is similarly left underexplored. Here, we report the observation of anomalous on-site dynamics of individual silicon impurity atoms in graphene during STEM imaging. Density functional theory-based structural optimizations of anisotropically-strained molecular nanographenes reveal two distinct (but nearly degenerate) stable structures for four-fold coordinated silicon impurities, where interconversion between the two structures manifests slight changes of the silicon position within the lattice site. Implications for defect-based strain engineering in graphene are discussed.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Enhancing Dihydrogen Interaction of a Zirconium Metal–Organic Framework by Metal Doping

Advancing efficient hydrogen storage technologies is essential for enabling a sustainable energy future, especially in onboard applications. While hydrogen offers high gravimetric energy density and zero-emission combustion, its low volumetric energy density presents significant storage challenges. Metal-organic frameworks (MOFs), well known for their tunable porosity and high surface areas, have emerged as promising candidates for adsorption-based hydrogen storage. This study investigated a chemically robust zirconium-based MOF, MOF-808, as a representative platform for hydrogen storage enhancement through metal ion doping. Various divalent metal ions were introduced into MOF-808 via one-pot synthesis or post-synthetic modification (PSM) to evaluate their effects on metal doping efficiency, framework stability, and hydrogen adsorption performance. Our findings demonstrate that metal doping enhanced the hydrogen binding affinity of MOF-808 while preserving its structural integrity and excellent stability. A Mg-doped MOF, MOF-808@Mg 2:1, showed a 59% increase in hydrogen uptake, and a Cu-doped MOF, MOF-808-ZrCu, exhibited a 33% increase in isosteric heat of adsorption for H 2 compared to the pristine MOF-808 activated at the same temperature. This work highlights the potential of metal-functionalized stable MOFs for practical hydrogen storage applications. Furthermore, these materials are also being studied for their potential to enhance CO 2 adsorption.

Adsorption↗

DOE OSTI2026

Pressure-Stabilized MnSb2 with Complex Incommensurate Magnetic Order

Marcasite-type compounds have been proposed as promising hosts of exotic magnetic quantum states, yet experimental realizations in stoichiometric, disorder-free systems remain limited. Here, we report the high-pressure stabilization and magnetic characterization of MnSb2, a marcasite-type compound that is thermodynamically metastable under ambient pressure. Single crystals were synthesized using a cubic multianvil press at 3.3 GPa and 490 °C for 24 h, and powder and single-crystal X-ray diffraction confirm the orthorhombic Pnnm structure. These crystals are stable at ambient pressure for a long time up to between 450 and 500 K. Heat-capacity measurements reveal phase transitions at approximately T0 ∼ 118 K and T1 ∼ 220 K. Neutron diffraction uncovers an unconventional magnetic state below T1 ∼ 220 K. Magnetic powder neutron diffraction refinements reveal possible multiple magnetic configurations that provide comparably acceptable fits to the experimental data. While most solutions are consistent with a spin-density-wave (SDW) description, helical models systematically yield inferior agreement factors. Across a broad range of models, the Mn ordered moment reaches a maximum value of approximately 2 μB and remains predominantly collinear, with minimal canting along the c-axis. At 200 K, the magnetic propagation vector is q = (0, 0.3975, 0.3783); upon cooling, the b component increases toward 0.5, reflecting a temperature-dependent evolution of the modulation. The need for modification of the magnetic model between high and low temperatures further highlights the complex and strongly temperature-dependent nature of the magnetic order in this system. These results establish MnSb2 as a pressure-stabilized marcasite magnet with a tunable, complex magnetic state and a compelling stoichiometric platform for exploring unconventional magnetic behavior, including potential altermagnetism.

Xu, Mingyu [Michigan State University , , , ,; Iow↗

DOE OSTI2020

Point and extended defects in heteroepitaxial 𝛽−G⁡a 2 ⁢O 3 films

G⁡a 2 ⁢O 3 is emerging as an excellent potential semiconductor for high power and optoelectronic devices. However, the successful development of G⁡a 2⁢ O 3 in a wide range of applications requires a full understanding of the role and nature of its point and extended defects. Here, in this work, high quality epitaxial G⁡a 2 ⁢O 3 films were grown on sapphire substrates by metal-organic chemical vapor deposition and fully characterized in terms of structural, optical, and electrical properties. Then defects in the films were investigated by a combination of depth-resolved Doppler broadening and lifetime of positron annihilation spectroscopies and thermally stimulated emission (TSE). Positron annihilation techniques can provide information about the nature and concentration of defects in the films, while TSE reveals the energy level of defects in the bandgap. Despite very good structural properties, the films exhibit short positron diffusion length, which is an indication of high defect density and long positron lifetime, a sign for the formation of Ga vacancy related defects and large vacancy clusters. These defects act as deep and shallow traps for charge carriers as revealed from TSE, which explains the reason behind the difficulty of developing conductive G⁡a 2 ⁢O 3 films on non-native substrates. Positron lifetime measurements also show nonuniform distribution of vacancy clusters throughout the film depth. Further, the work investigates the modification of defect nature and properties through thermal treatment in various environments. It demonstrates the sensitivity of G⁡a 2 ⁢O 3 microstructures to the growth and thermal treatment environments and the significant effect of modifying defect structure on the bandgap and optical and electrical properties of G⁡a 2 ⁢O 3 .

defects↗

NASA NTRS1983

An experimental study of transonic flow about a supercritical airfoil

A series of experiments was conducted on flow fields about two airfoil models whose sections are slight modifications of the original Whitcomb supercritical airfoil section. Data obtained include surface static-pressure distributions, far-wake surveys, oil-flow photographs, pitot-pressure surveys in the viscous regions, and holographic interferograms. These data were obtained for different combinations of lift coefficient and free-stream Mach number, which included both subcritical cases and flows with upper-surface shock waves. The availability of both pitot-pressure data and density data from interferograms allowed determination of flow-field properties in the vicinity of the trailing edge and in the wake without recourse to any assumptions about the local static pressure. The data show that significant static-pressure gradients normal to viscous layers exist in this region, and that they persist to approximately 10% chord downstream of the trailing edge. Comparisons are made between measured boundary-layer properties and results from boundary-layer computations that employed measured static-pressure distributions, as well as comparisons between data and results of airfoil flow-field computations.

Spaid, F. W.↗

NASA NTRS1988

Cosmic-ray-modified stellar winds. III - A numerical iterative approach

A numerical iterative method is used to determine the modification of a stellar wind flow with a termination shock by the galactic cosmic rays. A two-fluid model consisting of cosmic rays and thermal stellar wind gas is used in which the cosmic rays are coupled to the background flow via scattering with magnetohydrodynamic waves or irregularities. A polytropic model is used to describe the thermal stellar wind gas, and the cosmic-rays are modeled as a hot, low-density gas with negligible mass flux. The positive galactic cosmic-ray pressure gradient serves to brake the outflowing stellar wind gas, and the cosmic rays modify the location of the critical point of the wind, the location of the shock, the wind fluid velocity profile, and the thermal gas entropy constants on both sides of the shock. The transfer of energy to the cosmic rays results in an outward radial flux of cosmic-ray energy.

Ko, C. M.↗

NASA NTRS2004

Magnetohydrodynamic Instabilities in a Simple Gasdynamic Mirror Propulsion System

The gasdynamic mirror has been proposed as a concept which could form the basis of a highly efficient fusion rocket engine. Gasdynamic mirrors differ from most other mirror type plasma confinement schemes in that they have much larger aspect ratios and operate at somewhat higher plasma densities. To evaluate whether a gasdynamic mirror could indeed confine plasmas in a stable manner for long periods of time, a small scale experimental gasdynamic mirror was built and tested. The objective of this experiment was to determine ranges of mirror ratios and plasma densities over which gasdynamic mirror could maintain stable plasmas. Theoretical analyses indicated that plasma magnetohydrodynamic instabilities were likely to occur during subsonic to supersonic flow transitions in the mirror throat region of the gasdynamic mirror. The experimental evidence based upon data derived from the Langmuir probe measurements seems to confirm this analysis. The assumption that a gasdynamic mirror using a simple mirror geometry could be used as a propulsion system, therefore, appears questionable. Modifications to the simple mirror concept are presented which could mitigate these MHD instabilities.

Emrich, William J., Jr.↗

DOE OSTI2023

High-throughput and high-performance lithium-ion batteries via dry processing

A scalable powder-to-electrode dry processing strategy mainly based on powder dry mixing and rolling/calendering is rationally designed. The dry processed electrodes show lower tortuosity compared to that of conventional slurry-based electrodes. The dry-processed high-loading graphite anodes (6.6 mAh cm -2 ) and LiNi 0.6 Mn 0.2 Co 0.2 O 2 cathodes (6.0 mAh cm -2 ) exhibit promising electrochemical performance in half-cells and full-cells. The full-cells with both electrodes from dry processing demonstrates superb rate performance to their counterpart with conventional slurry-based electrodes and delivers of capacity retentions of 74.1 % and 63.6 % over 400 and 800 cycles, respectively. Notably, the initial Coulombic efficiency of the dry processed graphite anodes is low ascribed to polytetrafluoroethylene binder. Finally, the results suggest that dry processing is promising for future lithium-ion battery manufacturing and also pinpoint the needs of modification for the polytetrafluoroethylene binder in the graphite anodes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2020

High-Resolution Three-Dimensional Sculpting of Two-Dimensional Graphene Oxide by E-Beam Direct Write

On demand switchable additive/subtractive patterning of 2D nanomaterials is an essential capability for developing new concepts of functional nanomaterials and their device realizations. Traditionally, this is performed via a multi-step process using photoresist coating and patterning by conventional photo or electron beam lithography, which is followed by bulk dry/wet etch or deposition. This limits the range of functionalities and structural topologies that can be achieved, as well as increases the complexity, cost, and possibility of contamination which are significant barriers to device fabrication from highly sensitive 2D materials. Focused electron beam induced processing (FEBIP) enables a material chemistry/site-specific, high-resolution multi-mode atomic scale processing and provides unprecedented opportunities for direct-write, single-step surface patterning of 2D nanomaterials with an in-situ imaging capability. It allows for realizing a rapid multi-scale/multi-mode approach, ranging from an atomic scale manipulation (e.g., via targeted defect introduction as an active site) to a large-area surface modification on nano and micro scales, including patterned doping and material removal/deposition with 2D (in-plane)/3D (out-of-plane) control. In this work, we report on a new capability of FEBIP for nanoscale patterning of graphene oxide via removal of oxygenated carbon moieties with no use of reactive gas required for etching complemented by carbon atom deposition using focused electron beam. The mechanism of experimentally observed phenomena is explored using the density functional theory (DFT) calculations, revealing that interactions of e-beam liberated reactive oxygen radicals with carbon atoms on graphene basal plane lead to creation of atomic vacancies in the material. The reaction by-products are volatile carbon di-oxides, which are dissociated and volatilized from the graphene oxide surface functional groups by interactions with an energetic focused electron beam. Along with selective “subtractive” patterning of graphene oxide, the same electron beam with increased irradiation doses can deposit out-of-plane 3D carbon nanostructures on top of or around the 2D etched pattern, thus forming a hybrid 2D/3D nanocomposite with feature control down to a few nanometers. Furthermore, this in-operando dual nanofabrication capability of FEBIP is unmatched by any other nanopatterning techniques and opens a new design window for forming 2D/3D complex nanostructures and functional nanodevices.

36 MATERIALS SCIENCE↗