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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Comparison of flash-memory elements using materials based on graphene

Charge capture on flash-memory test structures with floating gates made of graphene (few-layer graphene) and its compounds (graphene oxide and partially fluorinated graphene) is investigated. A comparison of the memory window for different structures has shown the potential of using reduced graphene oxide, graphene with only a few layers, and fluorographene. For the first time, partially fluorinated graphene has been employed as a floating gate in flash-memory structures. Graphene-based materials are promising for 2D printing technologies and flexible electronics.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2013

Final Report - DE-EE0000260

In this program, we are developing next-generation SOFC materials and architectures for use with biomass-derived fuel streams, with a focus on addressing the technical challenges and the required operating windows associated with carbon-deposit formation. We are developing fuel-processing strategies for processing landfill- and anaerobic-digester-derived biomass streams for use in SOFCs. Similarly, we are examining processing of biomass-derived liquid fuels for use in solid-oxide fuel cell systems. We conduct extensive computational modeling work to support the materials-development and fuel-processing tasks. Modeling is conducted across a broad range of length scales, from the microscopic level to examine the fundamental underpinnings of cell operation, to the mesoscopic level to examine and optimize fuel-reformer design, and to the system level to craft optimal integration and dynamic-control solutions.

03 NATURAL GAS↗
DOE OSTI2013

Tailored ion energy distributions on plasma electrodes

As microelectronic device features continue to shrink approaching atomic dimensions, control of the ion energy distribution on the substrate during plasma etching and deposition becomes increasingly critical. The ion energy should be high enough to drive ion-assisted etching, but not too high to cause substrate damage or loss of selectivity. In many cases, a nearly monoenergetic ion energy distribution (IED) is desired to achieve highly selective etching. In this work, the author briefly reviews: (1) the fundamentals of development of the ion energy distribution in the sheath and (2) methods to control the IED on plasma electrodes. Such methods include the application of “tailored” voltage waveforms on an electrode in continuous wave plasmas, or the application of synchronous bias on a “boundary electrode” during a specified time window in the afterglow of pulsed plasmas.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Theoretical simulations of protective thin film Fabry-Pérot filters for integrated optical elements of diode pumped alkali lasers (DPAL)

The lifetime of Diode-Pumped Alkali Lasers (DPALs) is limited by damage initiated by reaction of the glass envelope of its gain medium with rubidium vapor. Rubidium is absorbed into the glass and the rubidium cations diffuse through the glass structure, breaking bridging Si-O bonds. A damage-resistant thin film was developed enhancing high-optical transmission at natural rubidium resonance input and output laser beam wavelengths of 780 nm and 795 nm, while protecting the optical windows of the gain cell in a DPAL. The methodology developed here can be readily modified for simulation of expected transmission performance at input pump and output laser wavelengths using different combination of thin film materials in a DPAL. High coupling efficiency of the light through the gas cell was accomplished by matching the air-glass and glass-gas interfaces at the appropriate wavelengths using a dielectric stack of high and low index of refraction materials selected to work at the laser energies and protected from the alkali metal vapor in the gain cell. Thin films as oxides of aluminum, zirconium, tantalum, and silicon were selected allowing the creation of Fabry-Perot optical filters on the optical windows achieving close to 100% laser transmission in a solid optic combination of window and highly reflective mirror. This approach allows for the development of a new whole solid optic laser.

36 MATERIALS SCIENCE↗
DOE OSTI2013

Low Cost Electrochromic Film on Plastic for Net-Zero Energy Buildings

Over 4 Quads of energy are lost through windows annually. Passive coatings reduce wasted energy, but energy lost through windows would remain over 2 Quads with complete replacement of Low-E glass. Active control of transmitted light and solar heating with electrochromic (EC) windows can transform the efficiency of energy use within buildings, thereby reducing energy footprints and corresponding greenhouse emissions. High production, integration, and distribution cost limits adoption of current EC products. ITN aimed to utilize its proven heritage of efficiently transitioning technologies from rigid to flexible substrates employing roll-to-roll manufacturing to capture the emerging EC window market opportunity. The project focused on three main efforts (1) Transition Small Scale Prototypes To Limited 0.5 Meter Wide, Web Coater Production, (2) Satisfy Market Driven EC Performance Metrics on Plastic Substrates, and (3) Product Development and Commercialization. The overall goal was to substantially reduce investor risk to motivate private investment in a production facility to further transition and scale this promising technology. A 0.5 meter roll-to-roll web coater was designed, constructed, and commissioned at ITN to support EC development effort. With this tool, we were able to establish the feasibility of roll-to-roll production of EC devices. Individually layers were continuously produced at lengths up to 3 meters with good uniformity, both down web and cross web. Solid state devices were produced, and device performance was being enhanced through hardware modifications underway at the close of the project. When deployed in composite device structures, we were able to verify that individual layers were able to achieve a transmission range of 3-70% transmission average over the visible portion of the spectrum. Initial development of intelligent process controls led to verification of a 2-state controller employed during deposition of the electrochromic layer. The project also successfully increased device performance in line with market needs. Improved device materials provided increased transmission range to a 5-65% transmission over the visible spectrum and faster switching times for both small area batch parts and large area composite materials. We were able to demonstrate durable cycling over 10,000-20,000 cycles in a variety of architectures including suspended films in an IGU and films laminated to glass tested in open air representative of retrofit applications. Robust packaging techniques were identified and samples proved durable even in 40C and 100% relative humidity outside the IGU environment.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Birefringent Glass‐Engraved Tilted Pillar Metasurfaces for High Power Laser Applications

Abstract Birefringent materials—which are highly needed in high power laser systems—may be limited in usage due to the laser‐induced damage threshold of traditional birefringent materials. This work reports here on all‐glass metasurfaces, fabricated by angled etching through sacrificial metal nanoparticle (NP) etching masks, for generation of effective birefringence in the formed layer. As a result, a fused silica metasurface, monolithic to the underlying substrate, is demonstrated to exhibit a birefringence of 6.57° under 375 nm illumination. Full‐wave analysis shows a good agreement with the measurement and presents potential paths forward to increasing the effective metasurface birefringence. This is the first demonstration, to the best of knowledge, of an etching technique to obtain the resulting tilted pillar‐like nanofeatures. The anisotropy of the metasurface nanoelements along the two window in‐plane major axes presents different effective paths for the two polarizations and thus generates birefringence in a nonbirefringent material. Additionally, the imparted anisotropy lends itself to manipulation of physical properties of the surface as well, with metasurface feature orientation suppressing water flow along one principal axis and giving rise to water flow steering capabilities.

36 MATERIALS SCIENCE↗
NASA NTRS2005

Deployable Wide-Aperture Array Antennas

Inexpensive, lightweight array antennas on flexible substrates are under development to satisfy a need for large-aperture antennas that can be stored compactly during transport and deployed to full size in the field. Conceived for use aboard spacecraft, antennas of this type also have potential terrestrial uses . most likely, as means to extend the ranges of cellular telephones in rural settings. Several simple deployment mechanisms are envisioned. One example is shown in the figure, where the deployment mechanism, a springlike material contained in a sleeve around the perimeter of a flexible membrane, is based on a common automobile window shade. The array can be formed of antenna elements that are printed on small sections of semi-flexible laminates, or preferably, elements that are constructed of conducting fabric. Likewise, a distribution network connecting the elements can be created from conventional technologies such as lightweight, flexible coaxial cable and a surface mount power divider, or preferably, from elements formed from conductive fabrics. Conventional technologies may be stitched onto a supporting flexible membrane or contained within pockets that are stitched onto a flexible membrane. Components created from conductive fabrics may be attached by stitching conductive strips to a nonconductive membrane, embroidering conductive threads into a nonconductive membrane, or weaving predetermined patterns directly into the membrane. The deployable antenna may comprise multiple types of antenna elements. For example, thin profile antenna elements above a ground plane, both attached to the supporting flexible membrane, can be used to create a unidirectional boresight radiation pattern. Or, antenna elements without a ground plane, such as bow-tie dipoles, can be attached to the membrane to create a bidirectional array such as that shown in the figure. For either type of antenna element, the dual configuration, i.e., elements formed of slots in a conductive membrane, can also be used. Finally, wide bandwidth antennas or arrays can be formed in which the principal direction of radiation is in the plane of the membrane. For this embodiment, the set of elements on the membrane is arranged to form one or more traveling wave antennas. In this case, a nonconductive form of the perimeter springlike material is required to provide the deploying force.

Fink, Patrick W.↗
DOE OSTI2017

Considerations for Use of Am-241 for Heat Source Material for Radioisotope Power Systems.

There have been several efforts made over the last 60 years to examine the entire periodic table of the elements to determine the best isotope/element for use as a heat source for radioisotope power systems (RPS). Am-241 is typically not in the final group being considered due to its 432-year half-life. The window of isotopes considered has usually been kept to 15-100 year half-life. The criteria in down selecting an isotope for use as a heat source material have been: 1) radiation characteristics (easy to shield), 2) specific power (higher is better), 3) fuel form considerations (chemically compatible with cladding, chemically inert with respect to the environment, robust mechanically, high melting point), and 4) available at a reasonable cost and suitable quantities. There have been a few efforts examining Am-241 for use in RPS during the past 2 decades. None of these has advanced beyond comparison of known chemical or material properties. No heat sources have been made and none have been placed into RPS for testing. No tests have been conducted of the various americium oxides (AmO, Am 2 O 3 , AmO 2 nor nonstoichiometric phases between these oxides) for their behavior with the environment to confirm inert behavior or compatibility with cladding materials. From a crystallographic point of view americium and oxygen can form crystal phases that exhibit face-centered cubic, monoclinic, cubic or tetragonal characteristics. A simple point to make here is that the chemistry of americium and oxygen is complicated and not well understood at this point compared to plutonium and oxygen.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2018

Multistate and On-Demand Smart Windows

Composite films consisting of wrinkles on top of the elastomeric poly(dimethylsiloxane) film and a thin layer of silica particles embedded at the bottom is prepared as on-demand mechanoresponsive smart windows. By carefully varying the wrinkle geometry, silica particle size, and stretching strain, different initial optical states and a large degree of optical transmittance change in the visible to near infrared range with a relatively small strain (as small as 10%) is achieved. The 10% pre-strain sample has shallow wrinkles with a low amplitude and shows moderate transmittance (60.5%) initially and the highest transmittance of 86.4% at 550 nm when stretched at the pre-strain level. Stretching beyond the pre-strain level leads to a drastic decrease of the transmittance at 550 nm, 39.7% and 70.8% with an additional 10% and 30% strain, respectively. The large drop of optical transmittance is the result of combined effects from the formation of secondary wrinkles and nanovoids generated around the particles. The 20% pre-strain sample has wrinkles with a moderate amplitude, showing 36.9% transmittance in the initial state, and the highest transmittance of 71.5% at 550 nm when stretched to the pre-strain level. Lastly, further stretching leads to increased opacity similar to that seen from the 10% pre-strain sample.

36 MATERIALS SCIENCE↗
DOE OSTI2015

SU-E-E-11: Novel Matching Module for Respiration-Gated Motion Tumor of Cone-Beam Computed Tomography (CBCT) to 4DCT

Purpose: Four dimensional computed tomography (4DCT) scans reliably record whole respiratory phase and generate internal target volumes (ITV) for radiotherapy planning. However, image guiding with cone-beam computed tomography (CBCT) cannot acquire all or specific respiratory phases. This study was designed to investigate the correlation between average CT and Maximum Intensity Projection (MIP) from 4DCT and CBCT. Methods: Retrospective respiratory gating were performed by GE Discovery CT590 RT. 4DCT and CBCT data from CRIS Dynamic Thorax Phantom with simulated breathing mode were analyzed. The lung tissue equivalent material encompassed 3 cm sphere tissue equivalent material. Simulated breathing cycle period was set as 4 seconds, 5 seconds and 6 seconds for representing variation of patient breathing cycle time, and the sphere material moved toward inferior and superior direction with 1 cm amplitude simulating lung tumor motion during respiration. Results: Under lung window, the volume ratio of CBCT scans to ITVs derived from 10 phases average scans was 1.00 ± 0.02, and 1.03 ± 0.03 for ratio of CBCT scans to MIP scans. Under abdomen window, the ratio of CBCT scans to ITVs derived from 10 phases average scans was 0.39 ± 0.06, and 0.06 ± 0.00 for ratio of CBCT scans to MIP scans. There was a significant difference between lung window Result and abdomen window Result. For reducing image guiding uncertainty, CBCT window was set with width 500 and level-250. The ratio of CBCT scans to ITVs derived from 4 phases average scans with abdomen window was 1.19 ± 0.02, and 1.06 ± 0.01 for ratio of CBCT to MIP scans. Conclusion: CBCT images with suitable window width and level can efficiently reduce image guiding uncertainty for patient with mobile tumor. By our setting, we can match motion tumor to gating tumor location on planning CT more accurately neglecting other motion artifacts during CBCT scans.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2018

Ionic liquids and derived materials for lithium and sodium batteries

The ever-growing demand for advanced energy storage devices in portable electronics, electric vehicles and large scale power grids has triggered intensive research efforts over the past decade on lithium and sodium batteries. The key to improve their electrochemical performance and enhance the service safety lies in the development of advanced electrode, electrolyte, and auxiliary materials. Ionic liquids (ILs) are liquids consisting entirely of ions near room temperature, and are characterized by many unique properties such as ultralow volatility, high ionic conductivity, good thermal stability, low flammability, a wide electrochemical window, and tunable polarity and basicity/acidity. These properties create the possibilities of designing batteries with excellent safety, high energy/power density and long-term stability, and also provide better ways to synthesize known materials. IL-derived materials, such as poly(ionic liquids), ionogels and IL-tethered nanoparticles, retain most of the characteristics of ILs while being endowed with other favourable features, and thus they have received a great deal of attention as well. This paper provides a comprehensive review of the various applications of ILs and derived materials in lithium and sodium batteries including Li/Na-ion, dual-ion, Li/Na–S and Li/Na–air (O 2 ) batteries, with a particular emphasis on recent advances in the literature. Their unique characteristics enable them to serve as advanced resources, medium, or ingredient for almost all the components of batteries, including electrodes, liquid electrolytes, solid electrolytes, artificial solid–electrolyte interphases, and current collectors. Finally, some thoughts on the emerging challenges and opportunities are also presented in this review for further development.

25 ENERGY STORAGE↗
DOE OSTI2023

Revealing Variable Dependences in Hexagonal Boron Nitride Synthesis via Machine Learning

Wafer-scale monolayer two-dimensional (2D) materials have been realized by epitaxial chemical vapor deposition (CVD) in recent years. To scale up the synthesis of 2D materials, a systematic analysis of how the growth dynamics depend on the growth parameters is essential to unravel its mechanisms. However, the studies of CVD-grown 2D materials mostly adopted the control variate method and considered each parameter as an independent variable, which is not comprehensive for 2D materials growth optimization. Herein, we synthesized a representative 2D material, monolayer hexagonal boron nitride (hBN), on single-crystalline Cu (111) by epitaxial chemical vapor deposition and varied the growth parameters to regulate the hBN domain sizes. Furthermore, we explored the correlation between two growth parameters and provided the growth windows for large flake sizes by the Gaussian process. Here, this new analysis approach based on machine learning provides a more comprehensive understanding of the growth mechanism for 2D materials.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Interface Coating Design for Dynamic Voltage Stability of Solid‐State Batteries

Abstract Intrinsic or interface thermodynamic voltage windows of solid electrolytes are often narrower than the operational voltage range needed by a full battery, thus various interface decomposition reactions can happen in a practical solid‐state battery. Experimentally, it is found that a proper battery design utilizing the reactions can lead to a dynamic evolution from interface instability to stability, giving the so‐called dynamic voltage stability for advanced battery performance. Here, first the state‐of‐the‐art understanding is articulated about how the dynamic voltage stability should be interpreted in physical picture and treated in computation, emphasizing the potential importance of nonequilibrium reaction pathways. The constrained ensemble computational approach is further applied across most types of solid‐state electrolytes to systematically evaluate and compare their dynamic stability voltage windows in response to the mechanical constriction effect. High‐throughput calculations are used to search for coating materials for different interfaces between sulfide, halide, and oxide electrolytes and typical cathode materials with enhanced dynamic voltage stability. A comparison with experiment is given to highlight the value of these computational predictions.

Wang, Yichao↗
DOE OSTI2017

Dynamical centrosymmetry breaking — A novel mechanism for second harmonic generation in graphene

We discover an unusual phenomenon that occurs when a graphene monolayer is illuminated by a short and intense pulse at normal incidence. Due to the pulse-induced oscillations of the Dirac cones, a dynamical breaking of the layer’s centrosymmetry takes place, leading to the generation of second harmonic waves. We prove that this result can only be found by using the full Dirac equation and show that the widely used semiconductor Bloch equations fail to reproduce this and some other important physics of graphene. Our results open new windows in the understanding of nonlinear light-matter interactions in a wide variety of new 2D materials with a gapped or ungapped Dirac-like dispersion.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1984

Theoretical design of acoustic treatment for cabin noise control of a light aircraft

An analytical procedure has been used to design an acoustic treatment for cabin noise control of a light aircraft. Using this approach acoustic add-on treatments capable of reducing the average noise levels in the cabin by about 17 dB from the untreated condition are developed. The added weight of the noise control package is about 2 percent of the total gross take-off weight of the aircraft. The analytical model uses modal solutions wherein the structural modes of the sidewall and the acoustic modes of the receiving space are accounted for. The additional noise losses due to add-on treatments are calculated by the impedance transfer method. The input noise spectral levels are selected utilizing experimental flight data. The add-on treatments considered for cabin noise control include aluminum honeycomb panels, constrained layer damping tape, porous acoustic materials, noise barriers and limp trim panels. To reduce the noise transmitted through the double wall aircraft windows to acceptable levels, changes in the design of the aircraft window are recommended.

Vaicaitis, R.↗
NASA NTRS1994

Real-time thickness measurement of MCC ablator material

One of the most favorable characteristics of the Space Shuttle Program is the reusability of two of its primary components: the orbiter itself and the Solid Rocket Boosters (SRB). The SRB's provide the primary source of propulsion for the Space Shuttle during take-off after which they are recovered for refurbishment and reuse. During refurbishment, the SRB's are stripped of all remaining ablative (heat resistant) coating. A new layer is applied to the appropriate sections (nose cone, frustum, forward skirt, and aft skirt). It is the process of applying the ablative coating which provided the impetus for this project. The thickness of this protective layer is considered to be of primary importance to the level of thermal protection provided. The objectives of this effort are to investigate possible techniques for measuring the thickness of MCC, and if possible to test the specific capabilities of those considered good candidates for implementation. The system would be able to take measurements in real-time as close to the spray gun as possible. This will allow the information to be used in the control of the process without an inordinate time delay between a measurement and its appropriate response. The thickness of the deposited material is to be measured with less than 0.100 in if uncertainty. This is the defined tolerance window for the ablator thickness. Finally, it must operate within the confines of the chamber which encloses the turntable, robot, and spray system, and therefore is required to be insensitive to, or at least maintainable in, that environment.

Greenway, R. Bryan, Jr.↗
NASA NTRSDate not supplied

Lessons for Future In-Space Telerobotic Servicing from Robotic Refueling Mission

The Robotic Refueling Mission (RRM) was a multi-phased technology development effort by the National Aeronautics & Space Administration (NASA) and the Canadian Space Agency (CSA). The program leveraged the existing robotic systems and expertise of the International Space Station (ISS) program and the tool design and satellite servicing expertise of NASA’s Exploration & In-space Services (NExIS) Projects Division at Goddard Space Flight Center (GSFC) to evaluate new hardware and techniques for on-orbit telerobotic servicing. Between 2011 and 2021, two external ISS payloads housed over a dozen robotic tools and adapters designed to service a variety of existing and novel satellite interfaces. Robot operators at NASA’s Johnson Space Center (JSC) and CSA used the Special Purpose Dexterous Manipulator (SPDM) to retrieve and operate these tools for tasks such as cutting wires or multi-layer insulation blanketing, removing valve caps, mating electrical connectors, transferring fluids, and performing visual inspections inside a vehicle. Each phase of RRM involved years of preparation. Tool and interface designs were prototyped and evaluated using both NASA and Canadian ground robotic systems. Procedures were developed by GSFC engineers and vetted in partnership with JSC and CSA robot operators. GSFC engineers were trained to provide real-time support during on-orbit operations. These preparatory efforts and the successful on-orbit evaluations yielded an array of lessons for future in-space telerobotic missions. Designing robotic tools for the space environment requires special consideration of materials, indicators, and differences between ground and flight use cases and environments. When there is a limited window for on-orbit operations, devoting time and high-fidelity hardware to ground testing can be critical. Needs during potential troubleshooting are more essential to camera view quality, frame rate, and position requirements more than nominal operations. Detailed hardware manuals, nominal and contingency procedures, along with clearly defined operations team roles and protocols are vital for efficiency. RRM also demonstrated how the ISS can be utilized to increase the technology readiness levels required for future missions and led to additional technology partnerships between NExIS and the ISS program. The lessons from RRM are currently being applied to designs, operations concepts, and ground test methodology for missions such as On-orbit Servicing, Assembly, and Manufacturing1(OSAM-1)and Mars Sample Return.

Zakiya Tomlinson↗
DOE OSTI2019

Solution target for cyclotron production of radiometals

Methods of producing and isolating 68Ga, 89Zr, 64Cu, 63Zn, 86Y, 61Cu, 99mTc, 45Ti, 13N, 52Mn, or 44Sc and solution targets for use in the methods are disclosed. The methods of producing 68Ga, 89Zr, 64Cu, 63Zn, 86Y, 61Cu, 99mTc, 45Ti, 13N, 52Mn, or 44Sc include irradiating a closed target system with a proton beam. The closed target system can include a solution target. The methods of producing isolated 68Ga, 89Zr, 64Cu, 63Zn, 86Y, 61Cu, 99mTc, 45Ti, 52Mn, or 44Sc further include isolating 68Ga, 89Zr, 64Cu, 63Zn, 86Y, 61Cu, 99mTc, 45Ti, 52Mn, or 44Sc by ion exchange chromatography. An example solution target includes a target body including a target cavity for receiving the target material; a housing defining a passageway for directing a particle beam at the target cavity; a target window for covering an opening of the target cavity; and a coolant gas flow path disposed in the passageway upstream of the target window.

Degrado, Timothy R.↗