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At least 649 records · Page 36

Interfacial electroneutrality controls transport of asymmetric salts through charge-patterned mosaic membranes

Membranes that selectively enhance target solute permeation while rejecting competing species are essential for precision separations. This study introduces charge-patterned mosaic membranes (CMMs) that selectively transport divalent asymmetric salts by leveraging a net-neutral membrane–solution interface. This mechanism, dictated by the charge ratio of positive and negative domains on the membrane surface and the balance of cations and anions in the salt, is supported by analytical, numerical, and experimental results. Analytical solutions identified cationic domain coverages (f + ) of 33%, 50%, and 66% as optimal for the selective transport of +2:−1 salts, +1:−1 salts, and +1:−2 salts, respectively, under conditions where the pattern size (L) is significantly larger than the Debye length. Numerical simulations and experiments using CMMs with alternating charged-stripes inkjet-printed onto nanostructure copolymer substrates confirmed these findings. By varying stripe widths to control f + , pressure-driven filtration experiments demonstrated selective enrichment of MgCl 2 and K 2 SO 4 at the predicted f + values, with deviations from these values leading to salt rejection. These results highlight the pivotal role of a net-neutral interface in enabling asymmetric salt enrichment. This study positions CMMs as a versatile platform for tuning ion selectivity, addressing challenges in resource recovery, water treatment, and precision separations.

additive manufacturing↗

River systems under peaked stress

The change in the global energy production mix towards variable renewable energy sources requires efficient utilization of regulated rivers to optimise hydropower operations meet the needs of a changing energy market. However, the flexible operation of hydropower plants causes non-natural, sub-daily fluctuating flows in the receiving water bodies, often referred to as ‘hydropeaking’. Drastic changes in sub-daily flow regimes undermine attempts to improve river system health. Environmental decision makers, including permitting authorities and river basin managers facing the intense and increasing pressure on river environments, should consider ecosystem services and biodiversity issues more thoroughly. The need for research innovations in hydropeaking operation design to fulfil both the water and energy security responsibilities of hydropower is highlighted. Our paper outlines optimized hydropeaking design as a future research direction to help researchers, managers, and decision-makers prioritize actions that could enable better integration of river science and energy system planning. The goal of this is to find a balanced hydropower operation strategy.

54 ENVIRONMENTAL SCIENCES↗

Measuring impacts of California agri-environmental programs using field-scale satellite data

In the past decade, California has invested over $\$$200 million in direct grants to growers to support the adoption of agricultural practices that save water and/or improve soil health while also reducing greenhouse gas emissions. Ex-post evaluation of agri-environmental outcomes of these grant programs, however, is limited. We use satellite data to monitor changes in field-level consumptive water use and greenness (i.e. normalized difference vegetation index), a proxy for agricultural productivity, for the most frequently funded crop-types (almonds, grapes, and walnuts) in two California Department of Food and Agriculture programs. Nearly 600 fields receiving funding during the 2014–2022 period were analyzed using two causal inference methods. Fields that received grants to both upgrade irrigation systems and install irrigation water management sensors showed reduced consumptive water use and greenness by an average of 3.5% and 4.2%, respectively (significant at the 10% level). In contrast, we find that the adoption of only irrigation water management sensors, which are designed to inform irrigation scheduling and management, resulted in an average increase of 4.1% and 4.8% in consumptive water use and greenness respectively (significant at the 5% level). We find negligible effects for either consumptive water use or greenness when both pump efficiency upgrades and sensors were implemented. We further find that grants for compost addition and cover cropping led to small greenness increases of 1.7% and 2.8% respectively (significant at the 10% level) and had insignificant effects on consumptive water use. Our analysis of five agri-environmental program interventions reveals that several practice outcomes may be at odds with stated program goals of reducing water use while maintaining or improving agricultural productivity.

agriculture↗

Impacts of Sea‐Level Rise on Hypoxia and Phytoplankton Production in Chesapeake Bay: Model Prediction and Assessment

In this study, the influence of sea-level rise (SLR) on seasonal hypoxia and phytoplankton production in Chesapeake Bay is investigated using a 3D unstructured grid model. Three SLR scenarios (0.17, 0.5, and 1.0 m) were conducted from 1991 to 1995. Results show that the summer hypoxic volume (HV) increases about 2%, 8%, and 16%, respectively, for these three scenarios, compared with Base Scenario. The contributions of physical and biological processes on the increase in the HV were analyzed. With the projected SLR, enhanced gravitational circulation transports more oxygen-rich water in the bottom layer from the mouth. However, the pycnocline moves upwards along with increasing water depth, which largely prolongs the time for dissolved oxygen (DO) to be transported to the bottom. The altered physical processes contribute greatly to a larger HV bay-wide. Besides, SLR increases the whole Bay phytoplankton production, with a larger increase in shallow areas (e.g., 53% in areas with depth <1 m under SLR of 0.5 m). Enhanced light availability is suggested to be the major driver of blooming phytoplankton under SLR in shallow areas. While increased DO production over the euphotic zone is mostly released to the atmosphere and transported downstream, the increase in settled organic matter greatly promotes DO consumption in the water column. The increased respiration is another major cause of the HV increase besides the physical contributions.

54 ENVIRONMENTAL SCIENCES↗

Climate Extremes and Variability Surrounding Chesapeake Bay: Past, Present, and Future

Measures of extreme climate variability around Chesapeake Bay have changed over the past century (1895–2014), resulting in the need to establish new baselines for understanding future change. Here, observed climate variability is compared with Coupled Model Intercomparison Project fifth assessment climate models to evaluate ensemble model skill in this region. Observed trends include annual and seasonal declines in the percentage of cold days. Similarly, increases in the annual and seasonal percentages of warm days occurred in all seasons of the North Chesapeake (>38.2°N) but were only significant in spring and summer in the South (<38.2°N) demonstrating regional differences even at local scales. Precipitation intensity increased over the past century. Models using emissions scenarios RCP4.5 and 8.5 project these trends will continue, though they have little skill in precipitation extremes. Pacific and Atlantic climate modes are generally more correlated with climate extremes than mean temperature and precipitation suggesting potential predictability in the synoptic patterns underlying the extremes. However, they also drive the need for time series at least 60-years long for establishing climate trends. This local analysis differs from regional, state level, and local 2.5° × 3.75° grid analyses, highlighting the importance of local climate assessments that consider topographic and regional weather patterns.

54 ENVIRONMENTAL SCIENCES↗

Using a Multi‐Institutional Ensemble of Watershed Models to Assess Agricultural Conservation Effectiveness in a Future Climate

This study investigates the combined impacts of climate change and agricultural conservation on the magnitude and uncertainty of nutrient loadings in the Maumee River Watershed, the second-largest watershed of the Laurentian Great Lakes. Two scenarios — baseline agricultural management and increased agricultural conservation — were assessed using an ensemble of five Soil and Water Assessment Tools driven by six climate models. The increased conservation scenario included raising conservation adoption rates from a baseline of existing conservation practices to feasible rates in the near future based on farmer surveys. This increased adoption of winter cover crops on 6%–10% to 60% of cultivated cropland; subsurface placement of phosphorus fertilizers on 35%–60% to 68% of cultivated cropland; and buffer strips intercepting runoff from 29%–34% to 50% of cultivated cropland. Increased conservation resulted in statistically significant (p ≤ 0.05) reductions in annual loads of total phosphorus (41%), dissolved reactive phosphorus (18%), and total nitrogen (14%) under the highest emission climate scenario (RCP 8.5). While nutrient loads decreased with increased conservation relative to baseline management for all watershed models, different conclusions on the true effectiveness of conservation under climate change may be drawn if only one watershed model was used.

54 ENVIRONMENTAL SCIENCES↗

Community‐Level Metabolic Shifts Following Land Use Change in the Amazon Rainforest Identified by a Supervised Machine Leaning Approach

ABSTRACT The Amazon rainforest has been subjected to high rates of deforestation, mostly for pasturelands, over the last few decades. This change in plant cover is known to alter the soil microbiome and the functions it mediates, but the genomic changes underlying this response are still unresolved. In this study, we used a combination of deep shotgun metagenomics complemented by a supervised machine learning approach to compare the metabolic strategies of tropical soil microbial communities in pristine forests and long‐term established pastures in the Amazon. Machine learning‐derived metagenome analysis indicated that microbial community structures (bacteria, archaea and viruses) and the composition of protein‐coding genes were distinct in each plant cover type environment. Forest and pasture soils had different genomic diversities for the above three taxonomic groups, characterised by their protein‐coding genes. These differences in metagenome profiles in soils under forests and pastures suggest that metabolic strategies related to carbohydrate and energy metabolisms were altered at community level. Changes were also consistent with known modifications to the C and N cycles caused by long‐term shifts in aboveground vegetation and were also associated with several soil physicochemical properties known to change with land use, such as the C/N ratio, soil temperature and exchangeable acidity. In addition, our analysis reveals that these alterations in land use can also result in changes to the composition and diversity of the soil DNA virome. Collectively, our study indicates that soil microbial communities shift their overall metabolic strategies, driven by genomic alterations observed in pristine forests and long‐term established pastures with implications for the C and N cycles.

carbon and nitrogen cycles↗

Geostatistical Mapping of Salinity Conditioned on Borehole Logs, Montebello Oil Field, California

We present a geostatistics-based stochastic salinity estimation framework for the Montebello Oil Field that capitalizes on available total dissolved solids (TDS) data from groundwater samples as well as electrical resistivity (ER) data from borehole logging. Data from TDS samples (n = 4924) was coded into an indicator framework based on falling below four selected thresholds (500, 1000, 3000, and 10,000 mg/L). Collocated TDS-ER data from the surrounding groundwater basin were then employed to produce a kernel density estimator to establish conditional probabilities for ER data (n = 8 boreholes) falling below the selected TDS thresholds within the Montebello Oil Field area. Directional variograms were estimated from these indicator coded data, and 500 TDS realizations from conditional indicator simulation were generated for the subsurface region above the Montebello Oil Field reservoir. Simulations were summarized as 3D maps of median TDS, most likely salinity class, and probability for exceeding each of the specified TDS thresholds. Results suggested TDS was below 500 mg/L in most of the study area, with a trend toward higher values (500 to 1000 mg/L) to the southwest; consistent with the average regional groundwater flow direction. Discrete localized zones of TDS greater than 1000 mg/L were observed, with one of these zones in the greater than 10,000 mg/L range; however, these areas were not prevalent. The probabilistic approach used here is adaptable and is readily modified to include additional data and types and can be employed in time-lapse salinity modeling through Bayesian updating.

54 ENVIRONMENTAL SCIENCES↗

Estimation of the Water Table Position in Unconfined Aquifers with MODFLOW 6

Abstract The numerical estimation of the position of the water table in unconfined aquifers is important for many practical applications. Its determination through observations or analytical methods is restricted to a few cases. Therefore, it is often estimated through numerical simulations, which may be affected by numerical artifacts and/or poor stability. We use MODFLOW to estimate the position of the water table for a seemingly simple example problem and demonstrate difficulties that can be faced when performing this kind of numerical simulation. We explain the causes for the numerical challenges that originate from the properties of the mathematical equations that must be solved. Based on the results of more than 600 steady‐state simulations, we show how the stability of the numerical solution can be affected by the values of physical parameters that define the problem (e.g., recharge rate, anisotropy ratio, and other parameters that control the numerical algorithm such as settings of the linear and nonlinear solution methods). Finally, we comment on some best practices to apply numerical simulations to estimate the water table position.

Geology↗