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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Southern Hemisphere tropospheric aerosol microphysics

Aerosol particle-size distribution data have been obtained in the Southern Hemisphere from approximately 4-deg S to 44-deg S and between ground level and 5 km, in the vicinity of eastern Australia. The relative shape of the free-tropospheric size distribution for particles with radii larger than approximately 0.04 micron was found to be remarkably stable with time, altitude, and location for the autumn-winter periods considered. This was despite some large concentration changes, which were found to be typical of the southeastern Australian coastal region. The majority of free-troposphere large particles were found to have sulfuric acid or lightly ammoniated sulfate morphology. Large particles in the boundary layer almost exclusively had a sea-salt morphology.

Gras, John L.↗
NASA NTRS1990

Differential absorption lidar detection of ozone in the troposphere and lower stratosphere

The DIAL technique for deriving O3 profiles from lidar measurements is discussed. Examples of a variety of O3 and aerosol measurements are presented from studies of (1) photochemically produced O3 in the summertime over the eastern United States and in biomass burning plumes during the dry season over the Amazon Basin of Brazil; (2) vertical O3 transport from the mixed layer into the free troposphere via cloud dynamics and from the stratosphere into the troposphere via tropopause fold events; and (3) O3 depletion in the O3 hole over Antarctica. The NASA airborne DIAL system is considered to be an advanced field system.

Browell, E. V.↗
NASA NTRS1991

Raman shifting of KrF laser radiation for tropospheric ozone measurements

The differential absorption lidar (DIAL) measurement of tropospheric ozone requires use of high average power UV lasers operating at two appropriate DIAL wavelengths. Laboratory experiments have demonstrated that a KrF excimer laser can be used to generate several wavelengths with good energy conversion efficiencies by stimulated Raman shifting using hydrogen (H2) and deuterium (D2). Computer simulations for an airborne lidar have shown that these laser emissions can be used for the less than 5 percent random error, high resolution measuremment of ozone across the troposphere using the DIAL technique. In the region of strong ozone absorption, laser wavelengths of 277.0 and 291.7 nm were generated using H2 and D2, respectively. In addition, a laser wavelength at 302.0 nm was generated using two cells in series, with the first containing D2 and the second containing H2. The energy conversion efficiency for each wavelength was between 14 and 27 percent.

Grant, William B.↗
NASA NTRS1991

A two-dimensional study of ethane and propane oxidation in the troposphere

The chemistry of ethane and propane is studied using a global two-dimensional 'zonally averaged' height- and latitude-dependent tropospheric model. The purpose of the study is to derive theoretical estimates of the seasonal and latitudinal distributions of a variety of intermediate organic compounds formed by the photochemical oxidation of C2H6 and C3H8. It is shown that C2H6 and C3H8 emitted at rates of 16 Tg C2H6/a and 23 Tg C3H8/a do not affect the overall photochemistry of the troposphere significantly. Major global effects on O3 and OH concentrations are suggested to be coming from the formation of peroxyacetyl nitrate by the interactions of NOx with other hydrocarbons with strong and spatially correlated anthropogenic or natural sources at the earth's surface. It is pointed out that attention should be given to organic nitrates produced by the oxidation of NMHC other than C2H6 and C3H8.

Kanakidou, M.↗
NASA NTRS1991

The global consequences of increasing tropospheric ozone concentrations

Recent analyses of long-term records of tropospheric ozone measurements in the Northern Hemisphere suggest that it is increasing at a rate of 1 to 2 percent per year. Because of this, it is argued that the amount of atmospheric warming due to increasing tropospheric ozone is comparable to, or possibly even greater than, the amount of warming due to the increase of carbon dioxide. Unlike all other climatically important trace gases, ozone is toxic, and increases in its concentration will result in serious environmental damage, as well as impairment of human health.

Fishman, Jack↗
NASA NTRS1991

Air mass origins and troposphere-to-stratosphere exchange associated with mid-latitude cyclogenesis and tropopause folding inferred from Be-7 measurements

The 1984 extratropical mission of NASA's Stratosphere-Troposphere Exchange Project (STEP) studied cross-jet transport in regions of cyclogenesis and tropopause folding. Correlations of Be-7, ozone, water vapor, and potential vorticity measured on a NASA U-2 research aircraft flying in high shear regions above the jet core are indicative of mixing between the cyclonic and the anticyclonic sides of the jet and are consistent with the hypothesis that small-scale entrainments of upper tropospheric air into the lower stratosphere during cyclogenesis are important in maintaining the vertical gradients of Be-7, ozone, water vapor and other trace constituents in the lower few kilometers of the midlatitude stratosphere. Correlations between Be-7, and ozone suggest a lower tropical stratospheric origin for the ozone-poor lamina observed above the jet core.

Kritz, Mark A.↗
NASA NTRS1990

Analysis of troposphere-stratosphere exchange

The overall goal is to improve our understanding of stratosphere-troposphere exchange processes in the tropics and midlatitudes. Specifically, modeling and analysis are performed using aircraft, radiosonde, and satellite data from the 1980 and 1987 NASA tropical field experiments in Panama and Australia, respectively, and the 1986 NASA jet stream field experiment in California. The objectives are to: (1) examine the structure of ozone, temperature, horizontal winds, tropospheric tracers, water and ice particles, and water vapor within, around, and above cumulus anvils in the tropics and jet streams in midlatitudes; (2) establish the presence, during each of the experimental periods, of various potential mechanisms of exchange, such as direct injection by cumulus, gravity wave fluxes, turbulent fluxes, and radiative heating; and (3) evaluate quantitatively, if possible, the mass of air transferred by these mechanisms during specific transport events.

Pfister, Leonhard↗
NASA NTRS1992

First Results from TROLIX 1991: an Intercomparison of Tropospheric Ozone Lidars

Within the framework of the European environmental research programme EUROTRAC, lidar systems for routine measurements of vertical ozone profiles throughout the planetary boundary layer and the free troposphere are currently under development. Several of these systems are now operational and an intercomparison experiment was undertaken in the period from June 10 to June 28, 1991 in Bilthoven, the Netherlands. The main scientific objectives defined for the campaign are: (1) compare the lidar measurements to in situ measurements of the ozone concentration; (2) determine how many and which wavelengths are needed for a sufficiently accurate ozone retrieval in the lower troposphere under realistic conditions; (3) assess the accuracy that can be achieved under realistic conditions; and (4) compare the performance of the participating systems.

Apituley, A.↗
NASA NTRS1992

Rotational Raman Lidar for Lower Tropospheric Temperature Profiling

Accurate sensing of the tropospheric temperature profile is basically needed in meteorology and 3D mapping of the boundary layer atmospheric temperature over urban and industrial areas. Several temperature lidar techniques were investigated, including Differential Absorption Lidar (DIAL), rotational and vibrational Raman, Rayleigh and high resolution Rayleigh schemes. For the tropospheric applications, the rotational Raman scheme looks potentially advantageous, but several stringent technical problems still remain to be solved. Reported here are the continuing efforts of the system development of the rotational Raman lidar.

Kobayashi, Takao↗
NASA NTRS1992

Tropospheric and stratospheric wind profiling with a direct detection Doppler lidar

The Space Physics Research Laboratory at the University of Michigan has been operating a direct detection, high resolution Doppler Lidar (HRDL) to measure winds in the boundary layer, free troposphere and lower stratosphere. A direct detection Doppler lidar measures the Doppler shift of the aerosol or Rayleigh backscattered signal, from which the wind velocity vector can be retrieved (Benedetti-Michelangeli et al, 1972, 1974; Chanin et al., 1989; Abreu et al., 1992). The system components are shown. The transmitting system is a Continuum NY-60 Nd:YAG laser frequency doubled to a wavelength of 532 nm. The laser is injection seeded for single line mode operation yielding a linewidth of 0.0045 cm(exp -1) (135 MHz) with excellent shot-to-shot frequency stability. The laser produces 60 mJ pulses and operates at a 50 Hz repetition rate for an effective output power of 3.0 W. A description of the University of Michigan's Doppler lidar is given with examples of wind profiles for the boundary layer, free troposphere, and for the lower stratosphere. The system provides a reliable method of remotely measuring the wind. The wind error is smallest in regions of high aerosols. The system also produces aerosol extinction profiles versus altitude which can be determined by the shape of the spectra. The system has been installed in a trailor so that measurements can be made for field campaigns. Winds and aerosol data are available immediately at the site for use in forecasting.

Abreu, Vincent J.↗
NASA NTRS1991

Collisional effects in laser detection of tropospheric OH

The use of laser-induced fluorescence to measure OH in the troposphere is discussed. It is noted that quantitative laser detection of OH requires knowledge of collisional processes affecting the measurements and interference effects due to OH generated by laser photolytic processes. Collisions induce quenching of the excited A-state, as well as vibrational and rotational energy transfer in the excited and ground states. It is noted that the state-specific nature of these processes is important, especially the rotational level dependence of quenching and vibrational transfer in excited OH. Also important is the temperature dependence according to which quenching cross sections sharply increase with decreasing temperature. Laboratory experiments studying these collisional processes are described, and their implications for laser detection of tropospheric OH are examined.

Crosley, David R.↗
NASA NTRS1992

Soluble species in the Arctic summer troposphere - Acidic gases, aerosols, and precipitation

The large-scale spatial distribution from 0.15-to 6 km altitude in the North American Arctic troposphere of several soluble acidic gases and major aerosol species during the summertime is reported. The distribution is found to be compositionally consistent on a large spatial scale. The summertime troposphere is an acidic environment, with HCOOH and CH3COOH the principal acidic gases while acidic sulfate aerosols dominate the particulate phase. There appears to be a surface source of NH3 over the pack ice which may originate from decay of dead marine organisms on the ice surface, evolution from surface ocean waters in open ice leads, or release from rotting sea ice. At low altitude over the pack ice this NH34 appears to partially neutralize aerosol acidity. Over sub-Arctic tundra in southeastern Alaska, inputs of marine biogenic sulfur from the Bering Sea appear to be an important source of boundary layer aerosol SO4(2-). The rainwater acidity over the tundra is typical of remote regions.

Talbot, R. W.↗
NASA NTRS1992

Numerical sensitivity analysis of passive EHF and SMMW channels to tropospheric water vapor, clouds, and precipitation

Potential uses of specific extremely High Frequency (EHF) and Sub-Millimeter-Wave (SMMW) channels at 90, 166, 183, 220, 325, 340, and 410 GHz for passive spaceborne remote sensing of the troposphere and lower stratosphere are investigated using an iterative numerical radiative transfer model. Collectively, these channels offer potential for high spatial resolution imaging using diffraction-limited apertures of practical size, along with the ability to profile water vapor, map precipitation beneath optically opaque cloud cover, and to measure nonprecipitating cloud (e.g., cirrus) parameters. A widely-spaced set of EHF and SMMW channels can yield observable degrees of freedom related to clouds and precipitation not available by exclusively using the more thoroughly studied microwave channels below 183 GHz. A new passive airborne imaging instrument for tropospheric meteorological sensing is described.

Gasiewski, A. J.↗
NASA NTRS1993

In situ evidence of rapid, vertical, irreversible transport of lower tropospheric air into the lower tropical stratosphere by convective cloud turrets and by larger-scale upwelling in tropical cyclones

The STEP tropical objectives were successfully met during the flight experiments conducted from Darwin, Australia, January 16 to February 16, 1987. Necessary and sufficient measurements were made in, above, and downwind from very cold cirrus clouds, produced by three convective cloud types, to demonstrate irreversible mass transports into and dehydration in the lower tropical stratosphere. The three types are defined and described in terms of the physical processes that produce them and illustrated by examples derived from in situ and remote measurements. Intense solar heating is shown to produce, in addition to the usual vertical, sea breeze circulations normal to the coastline, an unusual pair of continental spanning, horizontal circulations. An upper tropospheric-lower stratospheric anticyclonic circulation, inclined upward toward the tropics, contributes to the dehydration of dissipating cirrus anvils and intensifies the upper level, tropical easterlies. The lower tropospheric cyclonic circulation with tropical westerlies and extratropical easterlies is in direct conflict with the normal tropical easterlies and extratropical westerlies. Impulsive switches between these two opposing lower-level wind systems create conditions favorable for each of these cloud types and explain the summer season's aperiodic variability.

Danielsen, Edwin F.↗
NASA NTRS1992

Global distributions of upper tropospheric relative humidity derived from SAGE II observations

The global distributions of upper tropospheric relative humidity derived from the archived SAGE II water vapor data set are presented. For both summer and winter months, vertical profiles of zonal mean relative humidity are derived for each of the six 20-deg latitude bands covering 60 deg N - 60 deg S. Some examples of global maps of upper tropospheric relative humidity are shown to illustrate the relationship between moist areas and convective activity.

Chiou, E. W.↗
NASA NTRS1993

An aircraft instrument design for in situ tropospheric OH measurements by laser induced fluorescence at low pressures

The hydroxyl radical (OH) is important for many processes involved in tropospheric chemistry. For instance, it initiates the photochemical degradation of gases that cause global climate change, such as methane and the chlorofluorocarbon substitutes (HCFCs). Because of its reactivity, its abundances are less than 0.1 pptv. Thus, OH has been very difficult to measure accurately, despite its importance. Techniques have evolved, however, so that good measurements of tropospheric OH abundances are now possible. One of these techniques that is adaptable to aircraft measurements is the laser induced fluorescence detection of the OH radical in a detection chamber at low pressures. The current ground-based instrument, which can be readily adapted to aircraft, can detect OH abundances of 1.4 x 10 exp 5 OH molecules/cu cm with S/N = 2 in 30 sec, and 5 x 10 exp 4/cu cm in 5 min.

Brune, William H.↗
NASA NTRS1993

Remote sounding of tropospheric minor constituents

The etalon interferometer, or Fabry-Perot interferometer (FPI), with its high throughput and high spectral resolution was widely used in the remote-sensing measurements of the earth's atmospheric composition, winds, and temperatures. The most recent satellite instruments include the Fabry-Perot interferometer flown on the Dynamics Explorer-2 (DE-2) and the High Resolution Doppler Imager (HRDI) to be flown on the Upper Atmosphere Research Satellite (UARS). These instruments measure the Doppler line profiles of the emission and absorption of certain atmospheric species (such as atomic oxygen) in the visible spectral region. The successful space flight of DE-FPI and the test and delivery of UARS-HRDI demonstrated the extremely high spectral resolution and ruggedness of the etalon system for the remote sensing of earth and planetary atmospheres. Recently, an innovative FPI focal plane detection technique called the Circle-to-Line Interferometer Optical (CLIO) system was invented at the Space Physics Research Laboratory (SPRL). The CLIO simplifies the FPI focal plane detection process by converting the circular rings or fringes into a linear pattern similar to that produced by a conventional spectrometer, while retaining the throughput advantage of the etalon interferometer. CLIO makes the use of linear array detectors more practical and efficient with FPI, the combination of FPI and CLIO represents a very promising new technique for the remote sensing of the lower atmospheres of Earth, Mars, Venus, Neptune, and other planets. The Multiorder Etalon Spectrometer (MOES), as a combination of the rugged etalon and the CLIO, compares very favorably to other spaceborne optical instruments in terms of performance versus complexity. The feasibility of an advanced etalon spectrometer for the remote sensing of tropospheric trace species, particularly carbon monoxide (CO), nitrous oxide (N2O), and methane (CH4) was discussed. The etalon atmospheric spectroscopy techniques are described, instrument design and related technical issues are discussed. The primary objective is to establish the concept of atmospheric spectroscopy with the CLIO and etalon system and its applications for the measurements of tropospheric trace species analyze system requirements and performance, determine the feasibility of components and subsystem implementation with available technology, and develop inversion algorithm for retrieval simulation and data analysis.

Drayson, S. Roland↗
NASA NTRS1994

Near-IR diode laser absorption for measurement of tropospheric HO2

The possibility of using tunable lead salt diode lasers in the infrared for measurement of tropospheric HO2 has been frequently considered. Although the sensitivity of diode laser absorption has been improved through the use of high frequency detection techniques, nature has been unkind in that the HO2 absorption cross sections are weak. Even using the most optimistic assumptions about attainable path length and detectable absorbance, measurement of tropospheric HO2 by diode laser absorption in the mid-IR appears marginal. A possible alternative method for measuring HO2 is by absorption at near-infrared wavelengths. Several absorption bands of HO2 occur in the wavelength region between 1.2 and 1.6 micron due to electronic transitions and overtones of the fundamental vibrational modes. InGaAsP diode lasers operate in this wavelength region and can be used for high resolution spectroscopy in a manner analogous to the lead salt lasers. A diode laser system in the near-IR offers some advantages.

Stanton, Alan C.↗