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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Flowback verses first-flush: new information on the geochemistry of produced water from mandatory reporting

Unconventional oil and gas development uses the subsurface injection of large amounts of a variety of industrial chemicals, and there are concerns about the return of these chemical to the surface with water produced with oil and gas from stimulated wells. Produced water, including any flowback of injected fluids, must be managed so as to protect human health and the environment, and understanding the chemistry of produced water from stimulated wells is necessary to ensure the safe management of produced water. In 2014, California instituted mandatory reporting for all well stimulations, including sampling produced water two times and comprehensive chemical characterization of fluids injected and fluids recovered from stimulated wells. In this study, we analyzed data from mandatory reporting with the objective of closing previously identified data gaps concerning oil-field chemical practices and the nature of flowback and produced water from stimulated wells. It was found that the plug-flow conceptual model of flowback developed in shale formations, where salinity increases over time as produced water is extracted, was not appropriate for characterizing produced water from unconventional wells in these oil reservoirs, which are predominately diatomite and sandstones. In these formations stimulation caused a "first-flush" phenomena, where salts and metals were initially high and then decreased in concentration over time, as more produced water was extracted. Although widely applied to meet regulatory requirements, total carbohydrate measurement was not found to be a good chemical indicator of hydraulic fracturing flowback. In conclusion, mandatory reporting closed data-gaps concerning chemical use, provided new information on acid treatments, and allowed more detailed analysis of hydraulic fracturing practices, including comparison of water use by geological formation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

AnisONet: A deep neural operator-based anisotropic permeability upscaler from pore to Darcy scale

Directional permeability variations, which govern directional fluid flow in porous media with anisotropy, are important to accurately predict flow behavior, reactive transport, and fluid–solid interactions for various processes such as enhanced geothermal systems, energy storage devices, and biological systems. However, the intricate architecture of porous media makes it difficult to predict directional permeabilities. In this work, we present a novel machine learning (ML) framework, AnisONet, built upon an integration of a convolutional neural network, Swin transformer, and the deep operator network architecture, designed to predict anisotropic permeability and upscale predictions to larger spatial domains. First, AnisONet was evaluated with three classes of two-dimensional (2D) porous media, including synthetic circular and elliptical grains and natural sandstone grains from micro-computed tomography images. A lattice Boltzmann model (LBM) was used to calculate directional permeabilities at every 10° angle, producing 19 data points per image of porous media. AnisONet is then trained to predict permeability as a function of rotation angle. AnisONet showed strong predictive capability of directional permeability. Second, we tested our model for five upscaling cases with a large image size in the finite-element method (FEM) for 2D Darcy flow with various permeability tensor construction methods. Overall, upscaled permeability tensors in FEM simulations produce a reasonably good match with LBM results, highlighting the importance of selecting appropriate tensor formation strategies for accurate permeability upscaling. AnisONet, as a directional permeability estimator, could be further developed for more complex geometries, with the potential to develop a foundational ML model for various applications in porous media.

42 ENGINEERING↗
DOE OSTI2015

Uranium isotopes fingerprint biotic reduction

Knowledge of paleo-redox conditions in the Earth’s history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U), i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earth’s crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. In addition, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium.

58 GEOSCIENCES↗
DOE OSTI2019

Radiokrypton unveils dual moisture sources of a deep desert aquifer

We report that in arid regions, groundwater is a vital resource that can also provide a long-term record of the regional water cycle. However, the use of groundwater as a paleoclimate proxy has been limited by the complex hydrology and the lack of appropriate chronometers to determine the recharge time without complication. Applying 81 Kr, a long-lived radioisotope tracer, we investigate the paleohydroclimate and subsurface water storage properties of the Nubian Sandstone Aquifer in the Negev Desert, Israel. Based on the spatial distributions of stable isotopes and the abundance of 81 Kr, we resolve subsurface mixing and identify two distinct moisture sources of the recharge: one recent (<38 ky ago) from the Mediterranean and the other 361 ± 30 ky ago from the tropical Atlantic, both of which occurred under conditions of low orbital eccentricity comparable to that of the present. The recent recharge provided by the moisture from Mediterranean cyclones can be attributed to the southward shift of the storm track during the Last Glacial Maximum, and the earlier recharge can be attributed to moisture from the Atlantic delivered as tropical plumes under a climate colder than the present. Furthermore, the residence time of the latter reveals that tectonically active terrain can store groundwater for an unexpectedly long period, likely due to strongly attenuated groundwater flow across the fault zones. Lastly with this tracer, groundwater can now serve as a direct record of paleoprecipitation over land and of subsurface water storage from the mid-Pleistocene and onward.

58 GEOSCIENCES↗
DOE OSTI2016

Tepidibacillus decaturensis sp. nov., a microaerophilic, moderately thermophilic iron-reducing bacterium isolated from 1.7 km depth groundwater

Here, a Gram-stain-negative, microaerophilic rod-shaped organism designated as strain Z9 T was isolated from groundwater of 1.7 km depth from the Mt. Simon Sandstone of the Illinois Basin, Illinois, USA. Cells of strain Z9 T were rod shaped with dimensions of 0.3×(1–10) µm and stained Gram-negative. Strain Z9 T grew within the temperature range 20–60 °C (optimum at 30–40 °C), between pH 5 and 8 (optimum 5.2–5.8) and under salt concentrations of 1–5 % (w/v) NaCl (optimum 2.5 % NaCl). In addition to growth by fermentation and nitrate reduction, this strain was able to reduce Fe(III), Mn(IV), Co(III) and Cr(VI) when H 2 or organic carbon was available as the electron donor, but did not actively reduce oxidized sulfur compounds (e.g. sulfate, thiosulfate or S 0 ). The G+C content of the DNA from strain Z9 T was 36.1 mol%. Phylogenetic analysis of the 16S rRNA gene from strain Z9 T showed that it belongs to the class Bacilli and shares 97 % sequence similarity with the only currently characterized member of the genus Tepidibacillus , T. fermentans . Based on the physiological distinctness and phylogenetic information, strain Z9 T represents a novel species within the genus Tepidibacillus , for which the name Tepidibacillus decaturensis sp. nov. is proposed. The type strain is Z9 T (=ATCC BAA-2644 T =DSM 103037 T ).

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Slow dynamic elasticity at short times

It has been reported that slow dynamic nonlinear elastic relaxations, widely thought to proceed universally in proportion to the logarithm of time after cessation of mechanical conditioning, actually recover with a smaller slope at early times, with a time of transition that varies with the grain size of the material. Furthermore, this would constitute a heretofore unreported failure of the claimed universality, while suggesting application to nondestructive evaluation and structural health monitoring. Here we present new observations at short times, in the single bead system, in cement paste, mortar, concrete, sandstone and granite. Within the limits imposed by finite duration ring-down such that the effective instant of conditioning cessation is imprecise, and the corresponding ambiguity as to the time at which relaxation begins, we find no reliable sign of such a transition, even in samples of large grain size mortar and concrete similar to those described elsewhere as having clear and late cutoffs.

58 GEOSCIENCES↗
DOE OSTI2014

The first X-ray diffraction measurements on Mars

The Mars Science Laboratory landed in Gale crater on Mars in August 2012, and the Curiosity rover then began field studies on its drive toward Mount Sharp, a central peak made of ancient sediments. CheMin is one of ten instruments on or inside the rover, all designed to provide detailed information on the rocks, soils and atmosphere in this region. CheMin is a miniaturized X-ray diffraction/X-ray fluorescence (XRD/XRF) instrument that uses transmission geometry with an energy-discriminating CCD detector. CheMin uses onboard standards for XRD and XRF calibration, and beryl:quartz mixtures constitute the primary XRD standards. Four samples have been analysed by CheMin, namely a soil sample, two samples drilled from mudstones and a sample drilled from a sandstone. Rietveld and full-pattern analysis of the XRD data reveal a complex mineralogy, with contributions from parent igneous rocks, amorphous components and several minerals relating to aqueous alteration. In particular, the mudstone samples all contain one or more phyllosilicates consistent with alteration in liquid water. In addition to quantitative mineralogy, Rietveld refinements also provide unit-cell parameters for the major phases, which can be used to infer the chemical compositions of individual minerals and, by difference, the composition of the amorphous component.

Chemistry↗
DOE OSTI2016

Case History : Using time-lapse vertical seismic profiling data to constrain velocity-saturation relations: the Frio brine pilot CO 2 injection: Time-lapse VSP to constrain VSRs

CO 2 sequestration projects benefit from quantitative assessment of saturation distribution and plume extent for field development and leakage prevention. In this work, we carry out quantitative analysis of time-lapse seismic by using rock physics and seismic modelling tools. We investigate the suitability of Gassmann's equation for a CO 2 sequestration project with 1600 tons of CO 2 injected into high-porosity, brine-saturated sandstone. We analyze the observed time delays and amplitude changes in a time-lapse vertical seismic profile dataset. Both reflected and transmitted waves are analyzed qualitatively and quantitatively. To interpret the changes obtained from the vertical seismic profile, we perform a 2.5D elastic, finite-difference modelling study. The results show a P-wave velocity reduction of 750 m/s in the proximity of the injection well evident by the first arrivals (travel-time delays and amplitude change) and reflected wave amplitude changes. These results do not match with our rock physics model using Gassmann's equation predictions even when taking uncertainty in CO 2 saturation and grain properties into account. We find that time-lapse vertical seismic profile data integrated with other information (e.g., core and well log) can be used to constrain the velocity–saturation relation and verify the applicability of theoretical models such as Gassmann's equation with considerable certainty. The study shows that possible nonelastic factors are in play after CO 2 injection (e.g., CO 2 –brine–rock interaction and pressure effect) as Gassmann's equation underestimated the velocity reduction in comparison with field data for all three sets of time-lapse vertical seismic profile attributes. Here, our work shows the importance of data integration to validate the applicability of theoretical models such as Gassmann's equation for quantitative analysis of time-lapse seismic data.

58 GEOSCIENCES↗
DOE OSTI2016

Changes in geophysical properties caused by fluid injection into porous rocks: analytical models: Geophysical changes in porous rocks

Analytical models are provided that describe how the elastic compliance, electrical conductivity, and fluid-flow permeability of rocks depend on stress and fluid pressure. In order to explain published laboratory data on how seismic velocities and electrical conductivity vary in sandstones and granites, the models require a population of cracks to be present in a possibly porous host phase. The central objective is to obtain a consistent mean-field analytical model that shows how each modeled rock property depends on the nature of the crack population. We describe the crack populations by a crack density, a probability distribution for the crack apertures and radii, and the averaged orientation of the cracks. The possibly anisotropic nature of the elasticity, conductivity, and permeability tensors is allowed for; however, only the isotropic limit is used when comparing to laboratory data. For the transport properties of conductivity and permeability, the percolation effect of the crack population linking up to form a connected path across a sample is modeled. But, this effect is important only in crystalline rock where the host phase has very small conductivity and permeability. In general, the importance of the crack population to the transport properties increases as the host phase becomes less conductive and less permeable.

58 GEOSCIENCES↗
DOE OSTI2019

The Late Ordovician (Sandbian) Glasford structure: A marine-target impact crater with a possible connection to the Ordovician meteorite event

The Glasford structure in Illinois (USA) was recognized as a buried impact crater in the early 1960s but has never been reassessed in light of recent advances in planetary science. In this work, we document shatter cones and previously unknown quartz microdeformation features that support an impact origin for the Glasford structure. We identify the 4 km wide structure as a complex buried impact crater and describe syn- and postimpact deposits from its annular trough. We have informally designated these deposits as the Kingston Mines unit (KM). The fossils and sedimentology of the KM indicate a marine depositional setting. The various intervals within the KM constitute a succession of breccia, carbonate, sandstone, and shale similar to marine sedimentary successions preserved in other craters. Graptolite specimens retrieved from the KM place the time of deposition at approximately 455 ± 2 Ma (Late Ordovician, Sandbian). This age determination suggests a possible link between the Glasford impact and the Ordovician meteorite shower, an increase in the rate of terrestrial meteorite impacts attributed to the breakup of the L-chondrite parent body in the main asteroid belt.

58 GEOSCIENCES↗
DOE OSTI2020

A Study of Temperature Distribution and Thermal Stresses in a Hot Rock Due to Rapid Cooling

Thermal stresses may be induced in a hot dry rock when a cold fluid is injected in the well. To study this problem, we look at the thermoelastic response of a hot rock that is suddenly cooled. The cooling is assumed to be either at a constant temperature or at a constant heat flux per unit depth. Our approach is to nondimensionalize the equations and perform a parametric study and look at the temperature distribution and the induced-thermal stresses. The results indicate that depending on the extent of cooling and the cooling time, thermal stresses can be induced. Numerical simulations on sandstone, with an initial uniform temperature of 473 K, are also carried out. The results show that if the cooling is due to the surface temperature maintained at 463 K (10 °C lower than the initial temperature of the hot rock), thermal stresses that are larger than the rock tensile strength could be induced. When the cooling is due to a constant surface heat flux, this temperature can be reached after about 777 days of cooling with a minimum value of a heat flux of -20 W/m.

Tran, Phuoc↗
DOE OSTI2025

Wave ripples formed in ancient, ice-free lakes in Gale crater, Mars

Symmetrical wave ripples identified with NASA’s Curiosity rover in ancient lake deposits at Gale crater provide a key paleoclimate constraint for early Mars: At the time of ripple formation, climate conditions must have supported ice-free liquid water on the surface of Mars. These features are the most definitive examples of wave ripples on another planet. The ripples occur in two stratigraphic intervals within the orbitally defined Layered Sulfate Unit: a thin but laterally extensive unit at the base of the Amapari member of the Mirador formation, and a sandstone lens within the Contigo member of the Mirador formation. In both locations, the ripples have an average wavelength of ~4.5 centimeters. Internal laminae and ripple morphology show an architecture common in wave-influenced environments where wind-generated surface gravity waves mobilize bottom sediment in oscillatory flows. Their presence suggests formation in a shallow-water (<2 meters) setting that was open to the atmosphere, which requires atmospheric conditions that allow stable surface water.

Science & Technology - Other Topics↗
DOE OSTI2013

Effect of Particle Shape on Mechanical Behaviors of Rocks: A Numerical Study Using Clumped Particle Model

Since rocks are aggregates of mineral particles, the effect of mineral microstructure on macroscopic mechanical behaviors of rocks is inneglectable. Rock samples of four different particle shapes are established in this study based on clumped particle model, and a sphericity index is used to quantify particle shape. Model parameters for simulation in PFC are obtained by triaxial compression test of quartz sandstone, and simulation of triaxial compression test is then conducted on four rock samples with different particle shapes. It is seen from the results that stress thresholds of rock samples such as crack initiation stress, crack damage stress, and peak stress decrease with the increasing of the sphericity index. The increase of sphericity leads to a drop of elastic modulus and a rise in Poisson ratio, while the decreasing sphericity usually results in the increase of cohesion and internal friction angle. Based on volume change of rock samples during simulation of triaxial compression test, variation of dilation angle with plastic strain is also studied.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Numerical Simulations of Carbon Dioxide Storage Efficiency in Heterogeneous Reservoir Models

The U.S. Department of Energy’s National Energy Technology Laboratory (DOE-NETL) has been developing methods and tools (the online Carbon Dioxide Storage prospeCtive Resource Estimation Excel aNalysis (CO2-SCREEN) tool) to estimate carbon dioxide (CO2) storage potential in subsurface reservoirs. The CO2 storage efficiency terms are input in the tool to calculate storage potential in targeted reservoirs. In this effort, two CO2 storage efficiency terms were evaluated: volumetric displacement ( E V ) and microscopic displacement ( E d ). The first term deals with efficiency of CO2 propagation into an accessible reservoir volume, while the second term evaluates effectiveness of native fluid displacement with CO2. The interpreted well logs and core sample measurements were applied to create the heterogeneous reservoir models including geostatistical realizations of porosity and intrinsic permeability fields. Supercritical CO2 was injected over the course of 30 years into brine-saturated reservoir models for clastics, limestone, and dolomite lithologies and deltaic fluvial, aeolian, shallow marine, and reef depositional environments by means of varying reservoir parameters and injection scenarios. The reservoir models providing vertically heterogeneous petrophysical properties and designated as “layered reservoir models” (with homogeneous parameters along each layer of the model) were not determined to be a transition between the homogeneous and heterogeneous models in respect to storage efficiency. Another finding shows that high-efficiency factors do not necessarily mean increased CO2 storage; they rather indicate that the available volume and pore space are more fully utilized. The CO2 storage efficiency factors were evaluated dynamically at the select time points using P 10 ‐ P 50 ‐ P 90 percentiles. The results of this study show that the P 10 ‐ P 90 distribution for volumetric efficiency is wider when compared to the microscopic efficiency. It was found that where dominant buoyancy forces drive the plume to the top of a target formation, the volumetric efficiency is low. Tighter sandstone and carbonate formations show prevalence of capillary forces and better utilization of reservoir volume.

Myshakin, Evgeniy M.↗
DOE OSTI2017

In situ measurement of velocity-stress sensitivity using crosswell continuous active-source seismic monitoring

The ability to characterize time-varying reservoir properties, such as the state of stress, has fundamental implications in subsurface engineering, relevant to geologic sequestration of CO 2 . Stress variation, here in the form of changes in pore fluid pressure, is one factor known to affect seismic velocity. Induced variations in velocity have been used in seismic studies to determine and monitor changes in the stress state. Previous studies conducted to determine velocity-stress sensitivity at reservoir conditions rely primarily on laboratory measurements of core samples or theoretical relationships. In this paper, we have developed a novel field-scale experiment designed to study the in situ relationship between pore-fluid pressure and seismic velocity using a crosswell continuous active-source seismic monitoring (CASSM) system. At the Cranfield, Mississippi, CO 2 sequestration field site, we actively monitored seismic response for five days with a temporal resolution of 5 min; the target was a 26 m thick injection zone at approximately 3.2 km depth in a fluvial sandstone formation (lower Tuscaloosa Formation). The variation of pore fluid pressure was obtained during discrete events of fluid withdrawal from one of the two wells and monitored with downhole pressure sensors. The results indicate a correlation between decreasing CASSM time delay (i.e., velocity change for a raypath in the reservoir) and periods of reduced fluid pore pressure. The correlation is interpreted as the velocity-stress sensitivity measured in the reservoir. This observation is consistent with published laboratory studies documenting a velocity ( V ) increase with an effective stress increase. A traveltime change ( d t ) of 0.036 ms is measured as the consequence of a change in pressure of approximately 2.55 MPa ( d P e ). For T = 13 ms total traveltime, the velocity-stress sensitivity is d V / V / d P e = d t / T / d P e = 10.9 × 10 - 4 / MPa . Finally, the overall results suggest that CASSM measurements represent a valid technique for in situ determination of velocity-stress sensitivity in field-scale monitoring studies.

58 GEOSCIENCES↗
DOE OSTI2023

Machine learning-based inversion for acoustic impedance with large synthetic training data: Workflow and data characterization

Where wells are sparse or training data are difficult to label with high-quality wireline-derived impedance logs, machine learning (ML)-based inversion of acoustic impedance typically depends on small training data sets, leading to biased prediction. We have advanced a novel workflow that applies large synthetic seismic training data to reduce facies-related bias. Using a geologically realistic model as the truth model, we randomly select sparse seed wells to perform sequential Gaussian simulation (SGS) for impedance models of the same geometry and simulate facies variability. We implement random forest regression on 30 features extracted from the synthetic volume. We observe that more seed wells tend to reduce facies-induced bias by sampling more types of facies, resulting in a better prediction. We then focus on the responses of SGS models to facies changes, the number of seed wells necessary for a useful synthetic model, and how much a synthetic model can help ML-based inversion. Here, we observe that the SGS synthetic training model outperforms well-direct training in general. For modeled clastic shore-zone systems in Miocene Gulf of Mexico, two or more seed wells are necessary for a significant reduction of root-mean-square error and outliners, and improvement of facies imaging. In a field-data test, we apply a similar workflow to quantitatively predict acoustic impedance, which is then converted to a sand-volume map at a high-frequency sequence (10–100 m), revealing detailed facies and sandstone patterns. Such results are valuable in many geologic and engineering applications, such as hydrocarbon and CO 2 reservoir prospecting, reserve estimation, simulation, etc.

3D seismic↗
DOE OSTI2019

Geophysical Monitoring with Seismic Metamaterial Contrast Agents

Acoustic impedance tube and forced-oscillation seismic core test measurements were conducted to examine the low-frequency properties of acoustic metamaterial contrast agents. Water-stable suspensions of metal-organic framework (MOF) nanoparticles increased sound transmission loss (100-1250 Hz) and seismic attenuation (10-70 Hz), and reduced Young’s modulus of nanofluid-saturated Berea Sandstone cores. Preliminary measurements were used to parameterize a seismic wave velocity model. These results indicate that injectable MOF nanofluid contrast agents have potential to enhance seismic delineation of subsurface fluids and structures.

Miller, Quin RS↗