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At least 649 records · Page 36

Matrix effects for reflectivity spectra of dispersed nanophase (superparamagnetic) hematite with application to Martian spectral data

The effect of the matrix on the reflectivity spectra of nanophase (superparamagnetic) hematite (np-Hm) dispersed within the matrix was investigated in four series of powder samples containing np-Hm dispersed within discrete powder particles (of two size ranges) of silica gel and activated alumina. The spectral data show that matrix effects are large. Samples with the same Fe2O3 content can have np-Hm absorption edges characterized by very different positions and curvature and slope indices, while samples with equivalent absorption edges can have very different Fe2O3 concentrations. Thus, quantitative relationships between the positions of ferric absorption edges and Fe2O3 concentrations are unreliable without knowledge of matrix properties of the system. It is shown that it was possible to match the Fe2O3 concentration, magnetic properties, and spectral data for Martian surface material with a laboratory mixture whose only ferric-bearing phase was hematite.

Morris, Richard V.↗

Yarkovsky Drift Detections for 247 Near-Earth Asteroids

The Yarkovsky effect is a thermal process acting upon the orbits of small celestial bodies, which can cause these orbits to slowly expand or contract with time. The effect is subtle (〈da/dt〉∼10{sup −4} au My{sup −1} for a 1 km diameter object) and is thus generally difficult to measure. We analyzed both optical and radar astrometry for 600 Near-Earth Asteroids (NEAs) for the purpose of detecting and quantifying the Yarkovsky effect. We present 247 NEAs with measured drift rates, which is the largest published set of Yarkovsky detections. This large sample size provides an opportunity to examine the Yarkovsky effect in a statistical manner. In particular, we describe two independent population-based tests that verify the measurement of Yarkovsky orbital drift. First, we provide observational confirmation for the Yarkovsky effect’s theoretical size dependence of 1/D, where D is diameter. Second, we find that the observed ratio of negative to positive drift rates in our sample is 2.34, which, accounting for bias and sampling uncertainty, implies an actual ratio of 2.7{sub −0.7}{sup +0.3}. This ratio has a vanishingly small probability of occurring due to chance or statistical noise. The observed ratio of retrograde to prograde rotators is two times lower than the ratio expected from numerical predictions from NEA population studies and traditional assumptions about the sense of rotation of NEAs originating from various main belt escape routes. We also examine the efficiency with which solar energy is converted into orbital energy and find a median efficiency in our sample of 12%. We interpret this efficiency in terms of NEA spin and thermal properties.

79 ASTRONOMY AND ASTROPHYSICS↗

Shortgrass prairie spectral measurements

The spectral methods of vegetation analysis not only measure herbage biomass on a nondestructive basis but also can be adapted to aircraft and satellite devices to map the spatial distribution over an area in an efficient and economical fashion. This study reviews the ground-based in situ field spectrometry in the 0.350-0.800 micron region of the spectrum. A statistical analysis of in situ spectroreflectance data from sample plots of the shortgrass prairie shows that green biomass, chlorophyll concentration, and leaf water content are directly interrelated to that composite property of the plot which is called functioning green biomass. Spectrocorrelation data indicate the spectral regions of optimum sensitivity for a remote estimation of the green biomass, chlorophyll, and leaf water content. The near-infrared region of the spectrum shows a high positive spectrocorrelation to these three sample parameters, regardless of the amount of standing dead vegetation.

Tucker, C. J.↗

TOWARD PRECISE AGES FOR SINGLE STARS IN THE FIELD. GYROCHRONOLOGY CONSTRAINTS AT SEVERAL Gyr USING WIDE BINARIES. I. AGES FOR INITIAL SAMPLE

We present a program designed to obtain age-rotation measurements of solar-type dwarfs to be used in the calibration of gyrochronology relations at ages of several Gyr. This is a region of parameter space crucial for the large-scale study of the Milky Way, and where the only constraint available today is that provided by the Sun. Our program takes advantage of a set of wide binaries selected so that one component is an evolved star and the other is a main-sequence star of FGK type. In this way, we obtain the age of the system from the evolved star, while the rotational properties of the main-sequence component provide the information relevant for gyrochronology regarding the spin-down of solar-type stars. By mining currently available catalogs of wide binaries, we assemble a sample of 37 pairs well positioned for our purposes: 19 with turnoff or subgiant primaries and 18 with white dwarf components. Using high-resolution optical spectroscopy, we measure precise stellar parameters for a subset of 15 of the pairs with turnoff/subgiant components and use these to derive isochronal ages for the corresponding systems. Ages for 16 of the 18 pairs with white dwarf components are taken from the literature. The ages of this initial sample of 31 wide binaries range from 1 to 9 Gyr, with precisions better than {approx}20% for almost half of these systems. When combined with measurements of the rotation period of their main-sequence components, these wide binary systems would potentially provide a similar number of points useful for the calibration of gyrochronology relations at very old ages.

79 ASTRONOMY AND ASTROPHYSICS↗

Sampling synchronization through GPS signals

A method uses a distributed data acquisition system with multiple, physically unconnected, data acquisition units, that can be in wireless communication with a remote host, to timestamp measurement data with sub-microsecond time base accuracy of sampling clock relative to an absolute timeframe. A current absolute time is derived from messages received from a satellite radio beacon positioning system (GPS). Measurement data is sampled by each unit at a specified sampling rate. Using hardware logic, batches of sampled data are associated with corresponding timestamps representing the absolute time at which the data was sampled. Data and timestamps may be transmitted to the host. A time offset bias is compensated by comparing timestamps against a nominal time based on start time and nominal sampling rate. The sampling clock rate may be disciplined using time pulses from the GPS receiver. An initial start of data sampling by all units can also be synchronized.

Zhuge, James Q.↗

Supersonic and subsonic measurements of mesospheric ionization.

An Arcas rocket-parachute system was used at night to compare supersonic and subsonic ionization measurements below 75 km. A hemispherical nose-tip probe was used on ascent and a parachute-borne blunt probe on descent to measure polar conductivities, which were due entirely to positive and negative ions. The velocity of the supersonic probe was Mach 2.5 at 50 km and 1.75 at 70 km; the blunt probe was subsonic below 71 km. Between 65 and 75 km the ratio of negative to positive conductivities (and thus of mobilities) determined by the blunt probe was about 1.2, and it approached 1 below this altitude range. The ratio obtained by the nose-tip probe varied from 1.5 at 75 km to .6 at 65 km, thus indicating a rapid variation of the effects of the shock wave on the sampled ions. The absolute values of positive conductivity measured subsonically and supersonically were essentially identical from 60 to 75 km, indicating that the sampled ions were unchanged by the shock. However, below 60 km the shock apparently 'broke up' the positive ions, as indicated by higher measured conductivities.

Hale, L. C.↗

UNVEILING THE NATURE OF THE UNIDENTIFIED GAMMA-RAY SOURCES. IV. THE SWIFT CATALOG OF POTENTIAL X-RAY COUNTERPARTS

A significant fraction (∼30%) of the high-energy γ-ray sources listed in the second Fermi Large Area Telescope (LAT) catalog are still of unknown origin, having not yet been associated with counterparts at lower energies. To investigate the nature of these enigmatic sources, we present an extensive search of X-ray sources lying in the positional uncertainty region of a selected sample of these unidentified gamma-ray sources (UGSs) that makes use of all available observations performed by the Swift X-ray Telescope before 2013 March 31, available for 205 UGSs. To detect the fainter sources, we merged all the observations covering the Fermi LAT positional uncertainty region at a 95% level of confidence of each UGS. This yields a catalog of 357 X-ray sources, finding candidate X-ray counterparts for ∼70% of the selected sample. In particular, 25% of the UGSs feature a single X-ray source within their positional uncertainty region, while 45% have multiple X-ray sources. For each X-ray source, we also looked in the corresponding Swift UVOT merged images for optical and ultraviolet counterparts, also performing source photometry. We found ultraviolet-optical correspondences for ∼70% of the X-ray sources. We searched several major radio, infrared, optical, and ultraviolet surveys for possible counterparts within the positional error of the sources in the X-ray catalog to obtain additional information on their nature. Applying the kernel density estimation technique to infrared colors of Wide-Field Infrared Survey Explorer counterparts of our X-ray sources we select six γ-ray blazar candidates. In addition, comparing our results with previous analyses, we select 11 additional γ-ray blazar candidates.

79 ASTRONOMY AND ASTROPHYSICS↗

Genomic aberrations in normal tissue adjacent to HER2-amplified breast cancers: field cancerization or contaminating tumor cells?

Field cancerization effects as well as isolated tumor cell foci extending well beyond the invasive tumor margin have been described previously to account for local recurrence rates following breast conserving surgery despite adequate surgical margins and breast radiotherapy. To look for evidence of possible tumor cell contamination or field cancerization by genetic effects, a pilot study (Study 1: 12 sample pairs) followed by a verification study (Study 2: 20 sample pairs) were performed on DNA extracted from HER2-positive breast tumors and matching normal adjacent mammary tissue samples excised 1–3 cm beyond the invasive tumor margin. High-resolution molecular inversion probe (MIP) arrays were used to compare genomic copy number variations, including increased HER2 gene copies, between the paired samples; as well, a detailed histologic and immunohistochemical (IHC) re-evaluation of all Study 2 samples was performed blinded to the genomic results to characterize the adjacent normal tissue composition bracketing the DNA-extracted samples. Overall, 14/32 (44 %) sample pairs from both studies produced genome-wide evidence of genetic aberrations including HER2 copy number gains within the adjacent normal tissue samples. The observed singleparental origin of monoallelic HER2 amplicon haplotypes shared by informative tumor–normal pairs, as well as commonly gained loci elsewhere on 17q, suggested the presence of contaminating tumor cells in the genomically aberrant normal samples. Histologic and IHC analyses identified occult 25–200 lm tumor cell clusters overexpressing HER2 scattered in more than half, but not all, of the genomically aberrant normal samples re-evaluated, but in none of the genomically normal samples. These genomic and microscopic findings support the conclusion that tumor cell contamination rather than genetic field cancerization represents the likeliest cause of local clinical recurrence rates following breast conserving surgery, and mandate caution in assuming the genomic normalcy of histologically benign appearing peritumor breast tissue.

59 BASIC BIOLOGICAL SCIENCES↗

Phase changes in fluoropolymer binders

Motivation: Understanding fluoropolymer binder structure and aging response continues to be an important goal for the prediction and assessment of polymer bonded explosive compositions within the stockpile. As part of ongoing efforts within NNM, we are developing new methods to quantify crystallization and chemical degradation within aged Fluoropolymer materials. Significance: Time, temperature and radiation are known to alter the mechanical properties of fluoropolymers as crystalline domains nucleate and grow within the material. However, current methods do not accurately quantify and assess the degree or rapidity of these physical aging processes. For this reason, we are developing methods that directly measure crystalline domain, composition, size and shape and cross-correlating them with traditional techniques. Progress: Most recently, we thermally aged fluoropolymer binder, FK800, for various durations up to 23 days at several temperatures including: 25C (red), 35C (green), and 60C (blue). We used wide angle X-ray scattering (WAXS) to observe when crystalline peaks emerged, signaling a phase transition from amorphous to partially crystalline. Some of these data are summarized in Figure 1. As expected, samples held at 25C (red), which is below the glass transition temperature at 28C, remain amorphous – the WAXS data (Figure 1b) lacks sharp peaks indicative of crystallinity and the ultra-small angle X-ray scattering (USAXS) also has a smooth background without peaks indicative of structure (Figure 1a). By contrast, samples held at 35C and 60C have new peaks in both the USAXS and WAXS data. The structure is clearer after subtracting off the amorphous background from the WAXS data (Figure 1c). These data show that samples aged at 60C are more crystalline as determined by the more defined peaks and also have a larger lattice constant as seen by the shift in peak position as compared to the 35C samples. The corresponding USAXS data (Figure 1a) indicate that the size of the crystals was larger at 60C than at 35C as seen by the shift in the knee position to lower q-values. Interestingly, the shape of the scatter curve also changed, which indicates a change in morphology. Atomic force microscopy (AFM) was used to image the fluoropolymer (Figure 1c-e). At 35C, ~50nm long stacked crystal plates are observed. High resolution imaging shows that the stacks consist of 2-6 lamellae that are spaced approximately 3nm apart. At 60C, the individual lamella appear both thicker and longer and are intertwined to fill the surface. Morphological data such as these images help to interpret & model volume averaging techniques like X-ray scattering and NMR. We also expect the shift from isolated islands to intertwined clusters to impact mechanical properties.

36 MATERIALS SCIENCE↗

Structural, thermal, magnetic, and electronic transport properties of the LaNi₂(Ge 1-x P x )₂ system

Polycrystalline samples of LaNi₂(Ge 1-x P x )₂ (x=0,0.25,0.50,0.75,1) were synthesized and their properties investigated by x-ray diffraction (XRD) measurements at room temperature and by heat capacity C p , magnetic susceptibility χ, and electrical resistivity ρ measurements versus temperature T from 1.8 to 350 K. Rietveld refinements of powder XRD patterns confirm that these compounds crystallize in the body-centered-tetragonal ThCr₂Si₂-type structure (space group I4/mmm) with composition-dependent lattice parameters that slightly deviate from Vegard's law. The ρ(T) measurements showed a positive temperature coefficient for all samples from 1.8 to 300 K, indicating that all compositions in this system are metallic. The low-T C p measurements yield a rather large Sommerfeld electronic specific heat coefficient γ=12.4(2) mJ/mol K² for x=0, reflecting a large density of states at the Fermi energy that is comparable with the largest values found for the AFe₂As₂ class of materials with the same crystal structure. The γ decreases approximately linearly with x to 7.4(1) mJ/mol K² for x=1. The χ measurements show nearly temperature-independent paramagnetic behavior across the entire range of compositions except for LaNi₂Ge₂, where a broad peak is observed at ≈300 K from χ(T) measurements up to 1000 K that may arise from short-range antiferromagnetic correlations in a quasi-two-dimensional magnetic system. High-accuracy Padé approximants representing the Debye lattice heat capacity and Bloch-Grüneisen electron-phonon resistivity functions versus T are presented and are used to analyze our experimental C p (T) and ρ(T) data, respectively, for 1.8K≤T≤300 K. The T dependences of ρ for all samples are well-described over this T range by the Bloch-Grüneisen model, although the observed ρ(300 K) values are larger than calculated from this model. A significant T dependence of the Debye temperature determined from the C p (T) data was observed for each composition. No clear evidence for bulk superconductivity or any other long-range phase transition was found for any of the LaNi₂(Ge 1-x P x )₂ compositions studied.

Goetsch, R. J.↗

Pulling Results Out of Thin Air: Four Years of Ozone and Greenhouse Gas Measurements by the Alpha Jet Atmospheric Experiment (AJAX)

The Alpha Jet Atmospheric eXperiment (AJAX) has been measuring atmospheric ozone, carbon dioxide, methane and meteorological parameters from near the surface to 8000 m since January 2011. The main goals are to study photochemical ozone production and the impacts of extreme events on western US air quality, provide data to support satellite observations and aid in the quantification of emission sources e.g. wildfires, urban outflow, diary and oil and gas. The aircraft is based at Moffett Field and flies multiple times a month to sample vertical profiles at selected sites in California and Nevada, providing long-term data records at these sites. AJAX is also uniquely positioned to launch with short notice sampling flights in rapid response to extreme events e.g. the 2013 Yosemite Rim fire. This talk will focus on the impacts of vertical transport on surface air quality, and investigation of emission sources from diaries and wildfires.

AJAX↗

Rolling-Tooth Core Breakoff and Retention Mechanism

Sampling cores requires the controlled breakoff of the core at a known location with respect to the drill end. An additional problem is designing a mechanism that can be implemented at a small scale that is robust and versatile enough to be used for a variety of core samples. This design consists of a set of tubes (a drill tube and an inner tube) and a rolling element (rolling tooth). An additional tube can be used as a sample tube. The drill tube and the inner tube have longitudinal holes with the axes offset from the axis of each tube. The two eccentricities are equal. The inner tube fits inside the drill tube, and the sample tube fits inside the inner tube. While drilling, the two tubes are positioned relative to each other such that the sample tube is aligned with the drill tube axis and core. The drill tube includes teeth and flutes for cuttings removal. The inner tube includes, at the base, the rolling element implemented as a wheel on a shaft in an eccentric slot. An additional slot in the inner tube and a pin in the drill tube limit the relative motion of the two tubes. While drilling, the drill assembly rotates relative to the core and forces the rolling tooth to stay hidden in the slot along the inner tube wall. When the drilling depth has been reached, the drill bit assembly is rotated in the opposite direction, and the rolling tooth is engaged and penetrates into the core. Depending on the strength of the created core, the rolling tooth can score, lock the inner tube relative to the core, start the eccentric motion of the inner tube, and break the core. The tooth and the relative position of the two tubes can act as a core catcher or core-retention mechanism as well. The design was made to fit the core and hole parameters produced by an existing bit; the parts were fabricated and a series of demonstration tests were performed. This invention is potentially applicable to sample return and in situ missions to planets such as Mars and Venus, to moons such as Titan and Europa, and to comets. It is also applicable to terrestrial applications like forensic sampling and geological sampling in the field.

Badescu, Mircea↗

Large fluxes and rapid turnover of mineral-associated carbon across topographic gradients in a humid tropical forest: insights from paired 14 C analysis

It has been proposed that the large soil carbon (C) stocks of humid tropical forests result predominantly from C stabilization by reactive minerals, whereas oxygen (O 2 ) limitation of decomposition has received much less attention. We examined the importance of these factors in explaining patterns of C stocks and turnover in the Luquillo Experimental Forest, Puerto Rico, using radiocarbon ( 14 C) measurements of contemporary and archived samples. Samples from ridge, slope, and valley positions spanned three soil orders (Ultisol, Oxisol, Inceptisol) representative of humid tropical forests, and differed in texture, reactive metal content, O 2 availability, and root biomass. Mineral-associated C comprised the large majority (87 ± 2%, n = 30) of total soil C. Turnover of most mineral-associated C (66 ± 2%) was rapid (11 to 26 years; mean and SE: 18 ± 3 years) in 25 of 30 soil samples across surface horizons (0–10 and 10–20 cm depths) and all topographic positions, independent of variation in reactive metal concentrations and clay content. Passive C with centennial–millennial turnover was typically much less abundant (34 ± 3%), even at 10–20 cm depths. Carbon turnover times and concentrations significantly increased with concentrations of reduced iron (Fe(II)) across all samples, suggesting that O 2 availability may have limited the decomposition of mineral-associated C over decadal scales. Steady-state inputs of mineral-associated C were statistically similar among the three topographic positions, and could represent 10–25% of annual litter production. Observed trends in mineral-associated Δ 14 C over time could not be fit using the single-pool model used in many other studies, which generated contradictory relationships between turnover and Δ 14 C as compared with a more realistic two-pool model. The large C fluxes in surface and near-surface soils documented here are supported by findings from paired 14 C studies in other types of ecosystems, and suggest that most mineral-associated C cycles relatively rapidly (decadal scales) across ecosystems that span a broad range of state factors.

Hall, S. J.↗

Spectroscopic and dielectric response of zinc bismuth phosphate glasses as a function of chromium content

Graphical abstract: 20ZnF{sub 2}–(20 − x)Bi{sub 2}O{sub 3}–60P{sub 2}O{sub 5}:xCr{sub 2}O{sub 3} (0 ≤ x ≤2 mol%) glasses are prepared by melt quenching technique. The optical absorption spectra of present glasses are analyzed as a function of chromium content. The absorption bands are assigned to {sup 4}A{sub 2g}(F) ⟶ {sup 4}T{sub 1g}(F), {sup 4}A{sub 2g}(F) ⟶ {sup 4}T{sub 2g}(F), {sup 4}A{sub 2g}(F) ⟶ {sup 2}T{sub 1g}(G) and {sup 4}A{sub 2g}(F) ⟶ {sup 2}E{sub g}(G) transitions of Cr{sup 3+} ions. - Highlights: • ZnF{sub 2}–Bi{sub 2}O{sub 3}–P{sub 2}O{sub 5}:Cr{sub 2}O{sub 3} glasses were prepared by melt quenching and annealing. • Spectroscopic and dielectric properties of chromium ions were investigated. • ESR and optical absorption spectra indicate the co-existence of Cr{sup 6+} ions with Cr{sup 5+} ions and Cr{sup 3+} ions. • Cr{sup 3+} ions act as modifiers and influence the semiconducting nature of the glass system. - Abstract: 20ZnF{sub 2}–(20 − x)Bi{sub 2}O{sub 3}–60P{sub 2}O{sub 5}:xCr{sub 2}O{sub 3} (0 ≤ x ≤2 mol%) glasses are prepared by melt quenching technique. Amorphous nature of these samples is confirmed by X-ray diffraction (XRD) analysis. FTIR study reveals bands due to CrO{sub 6}(o{sub d}) and CrO{sub 4}{sup 2−}(T{sub d}) units along with conventional phosphate groups. The optical absorption and ESR studies of present glasses are analyzed as a function of chromium content. The absorption bands are assigned to {sup 4}A{sub 2g}(F) ⟶ {sup 4}T{sub 1g}(F), {sup 4}A{sub 2g}(F) ⟶ {sup 4}T{sub 2g}(F), {sup 4}A{sub 2g}(F) ⟶ {sup 2}T{sub 1g}(G) and {sup 4}A{sub 2g}(F) ⟶ {sup 2}E{sub g}(G) transitions of Cr{sup 3+} ions. The highest concentration of Cr{sup 3+} ions (in octahedral sites, with network modifying positions) is found in the sample with 2.0 mol% of Cr{sub 2}O{sub 3}. The analysis of dielectric properties indicates a gradual increase in semiconducting character with increase in the concentration of Cr{sub 2}O{sub 3} from 0.2 to 2.0 mol%. The studies on dielectric breakdown strength identify the highest insulating strength for lowest mol% of Cr{sub 2}O{sub 3} in the present samples.

36 MATERIALS SCIENCE↗

Concentrations of Staphylococcus species in indoor air as associated with other bacteria, season, relative humidity, air change rate, and S. aureus-positive occupants

The aim of this study was to obtain knowledge about concentrations of Staphylococcus aureus, MRSA (methicillin-resistant S. aureus), and other Staphylococcus species in indoor air in Greater Copenhagen and about factors affecting the concentrations. The effects of season, temperature, relative humidity, air change rate (ACR), other bacterial genera, area per occupant, and presence of S. aureus-positive occupants were studied. In samples from 67 living rooms, S. hominis, S. warneri, S. epidermidis, and S. capitis were found in 13–25%; S. saprophyticus, S. cohnii, and S. pasteuri in 5–10%; and S. lugdunensis, S. haemolyticus, S. caprae, S. equorum, S. kloosii, S. pettenkoferi, S. simulans, and S. xylosus in less than 3%. Staphylococcus aureus were found in two of 67 living rooms: spa type t034 (an MRSA) was recovered from a farmhouse, while spa type t509 was found in an urban home. Two species, S. equorum and S. kloosii, were found only in the farmhouse. Staphylococcus was significantly associated with season with lowest concentration and richness in winter. Genera composition was associated with ACR with smaller fractions of Staphylococcus at higher ACR, while richness was significantly and negatively associated with area per occupant. Concentration of Staphylococcus correlated positively with the total concentration of bacteria, but negatively with the total concentration of other bacteria. The concentration of Staphylococcus was not significantly associated with concentrations of the other abundant genera Bacillus, Kocuria, and Micrococcus. In offices with S. aureus-positive occupants, airborne S. aureus was not found. In conclusion, Staphylococcus species constitute a considerable proportion of the airborne bacteria in the studied homes and offices. However, both S. aureus and MRSA had very low prevalence during all seasons. Thus, transmission of S. aureus and MRSA through the air in living rooms in Copenhagen is expected to be limited. The negative associations between ACR and the fraction Staphylococcus constituted out of total bacteria, and between area per occupant and Staphylococcus richness indicate that it might be possible to affect the presence of airborne Staphylococcus in homes.

54 ENVIRONMENTAL SCIENCES↗

197 candidates and 104 validated planets in K2's first five fields

We present 197 planet candidates discovered using data from the first year of the NASA K2 mission (Campaigns 0–4), along with the results of an intensive program of photometric analyses, stellar spectroscopy, high-resolution imaging, and statistical validation. We distill these candidates into sets of 104 validated planets (57 in multi-planet systems), 30 false positives, and 63 remaining candidates. Our validated systems span a range of properties, with median values of R {sub P} = 2.3 R{sub ⊕}, P = 8.6 days, T{sub eff} = 5300 K, and Kp = 12.7 mag. Stellar spectroscopy provides precise stellar and planetary parameters for most of these systems. We show that K2 has increased by 30% the number of small planets known to orbit moderately bright stars (1–4 R {sub ⊕}, Kp = 9–13 mag). Of particular interest are 76 planets smaller than 2 R {sub ⊕}, 15 orbiting stars brighter than Kp = 11.5 mag, 5 receiving Earth-like irradiation levels, and several multi-planet systems—including 4 planets orbiting the M dwarf K2–72 near mean-motion resonances. By quantifying the likelihood that each candidate is a planet we demonstrate that our candidate sample has an overall false positive rate of 15%–30%, with rates substantially lower for small candidates (<2R{sub ⊕}) and larger for candidates with radii >8R{sub ⊕} and/or with P<3 days. Extrapolation of the current planetary yield suggests that K2 will discover between 500 and 1000 planets in its planned four-year mission, assuming sufficient follow-up resources are available. Efficient observing and analysis, together with an organized and coherent follow-up strategy, are essential for maximizing the efficacy of planet-validation efforts for K2, TESS, and future large-scale surveys.

79 ASTRONOMY AND ASTROPHYSICS↗

Evidence for Evolved Stellar Binary Mergers in Observed B-type Blue Supergiants

Blue supergiants are the brightest stars in their host galaxies, and yet their evolutionary status has been a long-standing problem in stellar astrophysics. In this pioneering work, we present a large sample of 59 early B-type supergiants in the Large Magellanic Cloud with newly derived stellar parameters and identify the signatures of stars born from binary mergers among them. We simulate novel 1D merger models of binaries consisting of post main-sequence giants with helium-rich cores (primaries) and main-sequence companions (secondaries), and consider the effects of interaction of the secondary with the core of the primary along with the mixing induced by the merger in the envelope. Thereafter, the evolution of the newborn 17–43 M ⊙ stars is followed until core-carbon depletion, close to their final pre-explosion stage. Unlike stars born alone with comparable masses, stars born from mergers of evolved binaries are blue throughout their core helium-burning phase and replicate the surface gravities and Hertzsprung–Russell diagram positions of most of our sample, thus indicating that B-type supergiants structurally resemble stars born from such mergers. Moreover, the large nitrogen-to-carbon and nitrogen-to-oxygen number ratios, coupled with helium enhancements exhibited by at least half our data sample, is uniquely reproduced by our merger models. Collectively, these findings provide compelling evidence toward the important role of binary mergers in producing the currently observed population of blue supergiants in our Universe.

79 ASTRONOMY AND ASTROPHYSICS↗

RAPID UNSEPARATED RARE EARTH ELEMENT ANALYSES BY ISOTOPE DILUTION MULTICOLLECTOR INDUCTIVELY COUPLED MASS SPECTROMETRY (ID-MC-ICP-MS)

We present a method for analyzing rare earth elements (REEs) by isotope dilution without separation of individual elements. Utilizing a Nu Plasma 2 multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS) equipped with an Aridus II desolvation nebulizer, sample introduction tuning parameters (torch position, gas flows) were investigated and used to minimize oxide formation (e.g., NdO/Nd <0.05%) and remove the need to analyze the REEs as separated “cuts.” Ratios for spike/sample isotopes in mixed synthetic standards containing varying amounts of Ce, Nd, Sm, Eu, Gd, Dy, Er, and Yb were measured accurately within 1% of IUPAC values. La and Lu in the standards were more than 2% off from expected values due to more demanding interference corrections. A USGS BCR-2 rock standard was also processed with flux fusion, iron coprecipitation and a single column pass bulk separation followed by analysis. The concentrations for Ce, Nd, Sm, Eu, Dy, Er, and Yb fell within 2% of consensus values. A United States Geological Survey (USGS) BIR-1A rock standard was also processed in triplicate by hydrofluoric and nitric acid digestion, yielding rare earth concentrations within 3% of consensus values with 0.3% relative standard deviation (n=3). This demonstrates the ability to produce high quality REE patterns of comparable quality to traditional methods involving labor and time intensive REE separation, with sample preparation and analytical times that are comparable to analyses against isotope dilution by single-collector ICP-MS.

Shen, Steve D.↗