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NASA NTRS2004

Certification of CFD heat transfer software for turbine blade analysis

Accurate modeling of heat transfer effects is a critical component of the Turbine Branch of the Turbomachinery and Propulsion Systems Division. Being able to adequately predict and model heat flux, coolant flows, and peak temperatures are necessary for the analysis of high pressure turbine blades. To that end, the primary goal of my internship this summer will be to certify the reliability of the CFD program GlennHT for the purpose of turbine blade heat transfer analysis. GlennHT is currently in use by the engineers in the Turbine Branch who use the FORTRAN 77 version of the code for analysis. The program, however, has been updated to a FORTRAN 90 version which is more robust than the older code. In order for the new code to be distributed for use, its reliability must first be certified. Over the course of my internship I will create and run test cases using the FORTRAN 90 version of GlennHT and compare the results to older cases which are known to be accurate, If the results of the new code match those of the sample cases then the newer version will be one step closer to certification for distribution. In order to complete these it will first be necessary to become familiar with operating a number of other programs. Among them are GridPro, which is used to create a grid mesh around a blade geometry, and FieldView, whose purpose is to graphically display the results from the GlennHT program. Once enough familiarity is established with these programs to render them useful, then the work of creating and running test scenarios will begin. The work is additionally complicated by a transition in computer hardware. Most of the working computers in the Turbine Branch are Silicon Graphics machines, which will soon be replaced by LINUX PC's. My project is one of the first to make use the new PC's. The change in system architecture however, has created several software related issues which have greatly increased the time and effort investments required by the project.Although complications with the project continue to arise, it is expected that the goal of my internship can still be achieved within the remaining time period. Critical steps have been achieved and test scenarios can now be designed and run. At the completion of my internship, the FORTRAN 90 version of GlennHT should be well on its way to certification.

Jordan, William A.↗
NASA NTRS2005

Continued Astrometric Follow-up Of Near-Earth Objects

As the grant periods overlapped, some of this information below will also be present on the previous final report. During the period May 1 2004 to April 30 2005, approximately 100 NEOs fainter than V = 20 were observed on separate nights from the 1.2-m telescope at Mt. Hopkins. Additionally, a few comets were targeted, including astrometric support of the Deep Impact mission by observing comet P/Tempel 1. Kyle Smalley was again employed as an independent contractor, and he was trained in use of the telescope, performed several remote observing runs on his own, and has now begun critical software support of the observing program. Code to automatically operate the telescope, given a target list, is approximately 90% done. During the first observing run scheduled in late September or early October, this code will be tested at on the telescope. It is probable that the 1.2m telescope will be run automatically all night without any interruption from the observer for anything during this time. Additional work on selecting which NEO targets to observe is progressing, with a beta-release of a simple target selection web page. Additionally, two-night objects with the potential of being NEOs have been extracted on a routine basis during this last grant cycle. These will also be added to a web page to facilitate additional astrometric follow-up.

Spahr, Timothy↗
NASA NTRS2003

Oxidation of Carbon Fibers in a Cracked Ceramic Matrix Composite Modeled as a Function of Temperature

The oxidation model simulates the oxidation of the reinforcing carbon fibers within a ceramic matrix composite material containing as-fabricated microcracks. The physics-based oxidation model uses theoretically and experimentally determined variables as input for the model. The model simulates the ingress of oxygen through microcracks into a two-dimensional plane within the composite material. Model input includes temperature, oxygen concentration, the reaction rate constant, the diffusion coefficient, and the crack opening width as a function of the mechanical and thermal loads. The model is run in an iterative process for a two-dimensional grid system in which oxygen diffuses through the porous and cracked regions of the material and reacts with carbon in short time steps. The model allows the local oxygen concentrations and carbon volumes from the edge to the interior of the composite to be determined over time. Oxidation damage predicted by the model was compared with that observed from microstructural analysis of experimentally tested composite material to validate the model for two temperatures of interest. When the model is run for low-temperature conditions, the kinetics are reaction controlled. Carbon and oxygen reactions occur relatively slowly. Therefore, oxygen can bypass the carbon near the outer edge and diffuse into the interior so that it saturates the entire composite at relatively high concentrations. The kinetics are limited by the reaction rate between carbon and oxygen. This results in an interior that has high local concentrations of oxygen and a similar amount of consumed carbon throughout the cross section. When the model is run for high-temperature conditions, the kinetics are diffusion controlled. Carbon and oxygen reactions occur very quickly. The carbon consumes oxygen as soon as it is supplied. The kinetics are limited by the relatively slow rate at which oxygen is supplied in comparison to the relatively fast rate at which carbon and oxygen reactions occur. This results in a sharp gradient in oxygen concentration from the edge where it is supplied to the nearest source of carbon, which is where the oxygen is quickly consumed. A moving reaction front is seen in which the outlaying carbon is consumed before the next inner layer of carbon begins to react.

Halbig, Michael C.↗
NASA NTRS2004

"Smart" Magnetic Fluids Experiment Operated on the International Space Station

InSPACE is a microgravity fluid physics experiment that was operated on the International Space Station (ISS) in the Microgravity Science Glovebox from late March 2003 through early July 2003. (InSPACE is an acronym for Investigating the Structure of Paramagnetic Aggregates From Colloidal Emulsions.) The purpose of the experiment is to obtain fundamental data of the complex properties of an exciting class of smart materials termed magnetorheological (MR) fluids. MR fluids are suspensions, or colloids, comprised of small (micrometer-sized) superparamagnetic particles in a nonmagnetic medium. Colloids are suspensions of very small particles suspended in a liquid. (Examples of other colloids are blood, milk, and paint.) These controllable fluids can quickly transition into a nearly solid state when exposed to a magnetic field and return to their original liquid state when the magnetic field is removed. Controlling the strength of the magnetic field can control the relative stiffness of these fluids. MR fluids can be used to improve or develop new seat suspensions, robotics, clutches, airplane landing gear, and vibration damping systems. The principal investigator for InSPACE is Professor Alice P. Gast of the Massachusetts Institute of Technology (MIT). The InSPACE hardware was developed at the NASA Glenn Research Center. The InSPACE samples were delivered to the ISS in November 2002, on the Space Shuttle Endeavour, on Space Station Utilization Flight UF-2/STS113. Operations began on March 31, 2003, with the processing of three different particle size samples at multiple test parameters. This investigation focused on determining the structural organization of MR colloidal aggregates when exposed to a pulsing magnetic field. On Earth, the aggregates take the shape of footballs with spiky tips. This characteristic shape may be influenced by the pull of gravity, which causes most particles initially suspended in the fluid to sediment, (i.e., settle and collect at the bottom of the cell). In the absence of sedimentation effects on the ISS, the behavior and shape of these MR aggregate structures are dominated exclusively by magnetic and surface tension forces. The microscopic detail of these structures was imaged under two orthogonal camera views. The video was downlinked to the InSPACE team at Glenn's Telescience Support Center and to MIT and also recorded onboard the ISS on videotapes that will be brought back to the ground by the space shuttles. The study examined the effect on the structure formation by varying the magnetic field strength and pulse frequency, and particle size. Fundamental data that characterized the structure formation were obtained. InSPACE completed its last planned test run on July 2, 2003. Operations occurred on 21 days over approximately a 3-month period. Forty-one test points were completed during 26 test runs. During the initial testing, the procedures followed by the crew were modified to maximize the observation of some unexpected and interesting aggregate behavior. As a result Dr. Gast has reported on the formation of aggregate shapes that are more extended and diverse than those observed on the ground. Sheets of magnetic material folded over in a labyrinth pattern and large columnar aggregates with complex interfaces with the surrounding fluid are examples of the interesting structures that have been observed on the ISS. In light of these early findings, the understanding of the fundamental properties of MR fluids on the basis of ground-based observations may need to be reconsidered.The experiments on the ISS have provided a vast amount of video data for analysis. While this analysis is ongoing, plans are being made for additional experimental runs. For this purpose, additional hardware and cells containing samples of different magnetic particles and sizes are being fabricated for a future launch to the ISS. The InSPACE hardware will remain on orbit until this testing is completed.

Agui, Juan H.↗
NASA NTRS2005

Thermal Analysis Methods for Aerobraking Heating

As NASA begins exploration of other planets, a method of non-propulsively slowing vehicles at the planet, aerobraking, may become a valuable technique for managing vehicle design mass and propellant. An example of this is Mars Reconnaissance Orbiter (MRO), which will launch in late 2005 and reach Mars in March of 2006. In order to save propellant, MRO will use aerobraking to modify the initial orbit at Mars. The spacecraft will dip into the atmosphere briefly on each orbit, and during the drag pass, the atmospheric drag on the spacecraft will slow it, thus lowering the orbit apoapsis. The largest area on the spacecraft, and that most affected by the heat generated during the aerobraking process, is the solar arrays. A thermal analysis of the solar arrays was conducted at NASA Langley, to simulate their performance throughout the entire roughly 6-month period of aerobraking. Several interesting methods were used to make this analysis more rapid and robust. Two separate models were built for this analysis, one in Thermal Desktop for radiation and orbital heating analysis, and one in MSC.Patran for thermal analysis. The results from the radiation model were mapped in an automated fashion to the Patran thermal model that was used to analyze the thermal behavior during the drag pass. A high degree of automation in file manipulation as well as other methods for reducing run time were employed, since toward the end of the aerobraking period the orbit period is short, and in order to support flight operations the runs must be computed rapidly. All heating within the Patran Thermal model was combined in one section of logic, such that data mapped from the radiation model and aeroheating model, as well as skin temperature effects on the aeroheating and surface radiation, could be incorporated easily. This approach calculates the aeroheating at any given node, based on its position and temperature as well as the density and velocity at that trajectory point. Run times on several different processors, computer hard drives, and operating systems (Windows versus Linux) were evaluated.

Amundsen, Ruth M.↗
NASA NTRS2005

Uncertainty Evaluation of Computational Model Used to Support the Integrated Powerhead Demonstration Project

NASA and the U.S. Air Force are working on a joint project to develop a new hydrogen-fueled, full-flow, staged combustion rocket engine. The initial testing and modeling work for the Integrated Powerhead Demonstrator (IPD) project is being performed by NASA Marshall and Stennis Space Centers. A key factor in the testing of this engine is the ability to predict and measure the transient fluid flow during engine start and shutdown phases of operation. A model built by NASA Marshall in the ROCket Engine Transient Simulation (ROCETS) program is used to predict transient engine fluid flows. The model is initially calibrated to data from previous tests on the Stennis E1 test stand. The model is then used to predict the next run. Data from this run can then be used to recalibrate the model providing a tool to guide the test program in incremental steps to reduce the risk to the prototype engine. In this paper, they define this type of model as a calibrated model. This paper proposes a method to estimate the uncertainty of a model calibrated to a set of experimental test data. The method is similar to that used in the calibration of experiment instrumentation. For the IPD example used in this paper, the model uncertainty is determined for both LOX and LH flow rates using previous data. The successful use of this model is then demonstrated to predict another similar test run within the uncertainty bounds. The paper summarizes the uncertainty methodology when a model is continually recalibrated with new test data. The methodology is general and can be applied to other calibrated models.

Steele, W. G.↗
NASA NTRS2006

A Three-Dimensional Unsteady CFD Model of Compressor Stability

A three-dimensional unsteady CFD code called CSTALL has been developed and used to investigate compressor stability. The code solved the Euler equations through the entire annulus and all blade rows. Blade row turning, losses, and deviation were modeled using body force terms which required input data at stations between blade rows. The input data was calculated using a separate Navier-Stokes turbomachinery analysis code run at one operating point near stall, and was scaled to other operating points using overall characteristic maps. No information about the stalled characteristic was used. CSTALL was run in a 2-D throughflow mode for very fast calculations of operating maps and estimation of stall points. Calculated pressure ratio characteristics for NASA stage 35 agreed well with experimental data, and results with inlet radial distortion showed the expected loss of range. CSTALL was also run in a 3-D mode to investigate inlet circumferential distortion. Calculated operating maps for stage 35 with 120 degree distortion screens showed a loss in range and pressure rise. Unsteady calculations showed rotating stall with two part-span stall cells. The paper describes the body force formulation in detail, examines the computed results, and concludes with observations about the code.

Chima, Rodrick V.↗
NASA NTRS2006

Simulations of Hurricane Katrina (2005) with the 0.125 degree finite-volume General Circulation Model on the NASA Columbia Supercomputer

Hurricane Katrina was the sixth most intense hurricane in the Atlantic. Katrina's forecast poses major challenges, the most important of which is its rapid intensification. Hurricane intensity forecast with General Circulation Models (GCMs) is difficult because of their coarse resolution. In this article, six 5-day simulations with the ultra-high resolution finite-volume GCM are conducted on the NASA Columbia supercomputer to show the effects of increased resolution on the intensity predictions of Katrina. It is found that the 0.125 degree runs give comparable tracks to the 0.25 degree, but provide better intensity forecasts, bringing the center pressure much closer to observations with differences of only plus or minus 12 hPa. In the runs initialized at 1200 UTC 25 AUG, the 0.125 degree simulates a more realistic intensification rate and better near-eye wind distributions. Moreover, the first global 0.125 degree simulation without convection parameterization (CP) produces even better intensity evolution and near-eye winds than the control run with CP.

Shen, B.-W.↗
NASA NTRS2005

Assume-Guarantee Testing

Verification techniques for component-based systems should ideally be able to predict properties of the assembled system through analysis of individual components before assembly. This work introduces such a modular technique in the context of testing. Assume-guarantee testing relies on the (automated) decomposition of key system-level requirements into local component requirements at design time. Developers can verify the local requirements by checking components in isolation; failed checks may indicate violations of system requirements, while valid traces from different components compose via the assume-guarantee proof rule to potentially provide system coverage. These local requirements also form the foundation of a technique for efficient predictive testing of assembled systems: given a correct system run, this technique can predict violations by alternative system runs without constructing those runs. We discuss the application of our approach to testing a multi-threaded NASA application, where we treat threads as components.

Blundell, Colin↗
NASA NTRS2006

Can High-resolution WRF Simulations Be Used for Short-term Forecasting of Lightning?

A number of research teams have begun to make quasi-operational forecast simulations at high resolution with models such as the Weather Research and Forecast (WRF) model. These model runs have used horizontal meshes of 2-4 km grid spacing, and thus resolved convective storms explicitly. In the light of recent global satellite-based observational studies that reveal robust relationships between total lightning flash rates and integrated amounts of precipitation-size ice hydrometeors in storms, it is natural to inquire about the capabilities of these convection-resolving models in representing the ice hydrometeor fields faithfully. If they do, this might make operational short-term forecasts of lightning activity feasible. We examine high-resolution WRF simulations from several Southeastern cases for which either NLDN or LMA lightning data were available. All the WRF runs use a standard microphysics package that depicts only three ice species, cloud ice, snow and graupel. The realism of the WRF simulations is examined by comparisons with both lightning and radar observations and with additional even higher-resolution cloud-resolving model runs. Preliminary findings are encouraging in that they suggest that WRF often makes convective storms of the proper size in approximately the right location, but they also indicate that higher resolution and better hydrometeor microphysics would be helpful in improving the realism of the updraft strengths, reflectivity and ice hydrometeor fields.

Goodman, S. J.↗
NASA NTRS1994

Remote Objects Message Exchange (ROME)

The performance of a single program running on a single processor is limited by the character of the processor. Moreover, the cost and difficulty of developing and sustaining programs tend to increase as their size and complexity increase. Clearly there ought to be some advantage in partitioning powerful application software in relatively small and simple components that can run in parallel on multiple processors; the software should run faster and it should be cheaper and easier to deploy. Remote Objects Message Exchange (ROME) is an attempt to provide a single relatively simple, universally available abstraction for data communication among C++ objects. It aims to enable the C++ application developer to specify objects' interactions with other objects wholly in terms of the application domain, without concern for details of interprocess communication. Every ROME-compliant object is conceptually a network peer of every other, as if each one were (for example) a separate UNIX process.

processors application software data communication↗
NASA NTRS2004

IBM powerPC 405 SEU mitigation using processor voting techniques in Xilinx Virtex-I1 pro FPGA

Not until recently, Xilinx has developed a new field programmable gate array (FPGA) device family, Virtex-I1 Pro. In this single device, not only dies it have density logic cells (3K to125K), gigabit connectivity, on chip memory, digital clock management, but also it can have up to four IBM PowerPC 405 Processor hard cores, running up to 400MHz and 633 Mbps. To utilize this cutting edge device in space applications, a few Single Event Upset (SEU) mitigation techniques need to be implemented to a design for the device. At Jet Propulsion Laboratory (JPL), we have successfully demonstrated the feasibility of running multiple processors running in a lock step fashion to accomplish SEU mitigation and fault tolerance.

single event upset (SEU)↗
NASA NTRS2006

Development and Validation of a Pressurization System Model for a Crossfeed Subscale Water Test Article

A pressurization system model was developed for a crossfeed subscale water test article using the EASY5 modeling software. The model consisted of an integrated tank pressurization and pressurization line model. The tank model was developed using the general purpose library, while the line model was assembled from the gas dynamic library. The pressurization system model was correlated to water test data obtained from nine test runs conducted on the crossfeed subscale test article. The model was first correlated to a representative test run and frozen. The correlated model was then used to predict the tank pressures and compared with the test data for eight other runs. The model prediction showed excellent agreement with the test data, allowing it to be used in a later study to analyze the pressurization system performance of a full-scale bimese vehicle with cryogenic propellants.

Nguyen, Han↗
NASA NTRS2006

Terrestrial Planet Growth in Circumbinary Disks

We examine the accu~ulation of terrestrial from circumbinary disks surrounding pairs of stars with masses of either 0.5 solar masses each or 0.8 and 0.2 solar masses and orbital separations of 0.05 AU to 0.4 AU by performing numerical simulations of the late stages of planetary growth. Initial disks contain about 2.6 Earth masses of lunar to Mars-sized bodies orbiting within 2 AU of the center of mass of the system, plus giant planets with masses and orbits analogous to those of Jupiter and Saturn. We also performed simulations using analogous disks orbiting single 1 solar mass stars. The dynamics of planetary growth is quite chaotic because the gravitational perturbations resulting from close approaches greatly amplify differences in orbits. Thus, several simulations of each configuration were run with very slightly different initial conditions to enable us to distinguish systematic effects resulting from differences in the binary orbit (or differences of the initial orbits of the bodies within the disk) from pseudo-random variability in outcomes resulting from chaos. Most runs simulated 200 million years of evolution. At least one terrestrial planet remained at the end of each run; one simulation produced 6 terrestrial planets in a configuration that appears to be quite stable. The systems that formed around stars with binary apastron separations of less than 0.2 AU contained on average slightly more planets than those that formed around single stars, with the outermost planet typically orbiting at a greater distance from the system barycenter. Greater stellar separations tended to result in fewer planets, with the inner planet orbiting farther from the stars. More eccentric binaries have a more pronounced effect for the same apastron distance. The statistical distribution of final systems is not sensitive to moderate differences in the initial eccentricities of the bodies in the disk.

Lissauer, J. J.↗
NASA NTRS2007

Risk Reduction and Measures of Injury for EVA Associated Upper Extremity Medical Issues: Extended Vent Tube Study

During Neutral Buoyancy Lab (NBL) training sessions, a large amount of moisture accumulates in the EVA gloves. The glove design restricts the extension of the EVA suit s ventilation/cooling system to the hand. Subungual redness and fingernail pain develops for many astronauts following their NBL training sessions with subsequent oncholysis occurring over succeeding weeks. Various attempts have been made to reduce or avoid this problem. The causal role of moisture has yet to be defined. Methods: To determine the contribution that moisture plays in the injury to the fingers and fingernails during EVA training operations in NBL, the current Extravehicular Mobility Unit (EMU), with a Portable Life Support System (PLSS) was configured with a ventilation tube that extended down a single arm of the crewmember during the test and compared with the unventilated contralateral arm; with the ventilated hand serving as the experimental condition (E) and the opposite arm as the control (C). A cross-over design was used with opposite handedness for the vent tube on a subsequent NBL training run. Moisture content measures were conducted at six points on each hand with three types of moisture meters. A questionnaire was administered to determine subjective thermal hand discomfort, skin moisture perception, and hand and nail discomfort. Photographs and video were recorded. Measures were applied to six astronauts pre- and post-run in the NBL. Results: The consistent trends in relative hydration ratios at the dorsum, from 3.34 for C to 2.11 for E, and first ring finger joint locations, from 2.46 for C to 1.96 for E, indicated the extended vent tube promoted skin drying. The experimental treatment appeared to be more effective on the left hand versus the right hand, implying an interaction with hand anthropometry and glove fit. Video analyses differentiated fine and gross motor training tasks during runs and will be discussed. Conclusions: This potential countermeasure was effective in reducing the risks of hand and nail discomfort symptoms from moderate to low in two of six subjects. Improved design in the ventilation pattern of such a countermeasure is expected to improve the countermeasure s efficiency.

Jones, Jeffrey A.↗
NASA NTRS2007

Community Coordinated Modeling Center Support of Operations: Real-Time Simulations and V & V.

In support of Operations Community Coordinated Modeling Center (CCMC) performing validation and verification of space weather models. To identify suitable metrics the CCMC focus on parameters most useful to operations that CCMC resident models can provide. The real time simulations carried out at CCMC are an essential tool to test model performance and stability by using input conditions that may occur in nature at any time. Since 2001, the magnetospheric MHD model BATSRUS has been run in real time using ACE real time data. CCMC staff developed an experimental real-time system that controls uploading of the real-time ACE data, monitors continuous model execution, initiates automatic recovery procedure in case of data gaps or hardware failures, synchronizes BATSRUS and FRC runs, and periodically runs IDL based visualization software.

Kuznetsova, M.↗
NASA NTRS2007

Determination of Turboprop Reduction Gearbox System Fatigue Life and Reliability

Two computational models to determine the fatigue life and reliability of a commercial turboprop gearbox are compared with each other and with field data. These models are (1) Monte Carlo simulation of randomly selected lives of individual bearings and gears comprising the system and (2) two-parameter Weibull distribution function for bearings and gears comprising the system using strict-series system reliability to combine the calculated individual component lives in the gearbox. The Monte Carlo simulation included the virtual testing of 744,450 gearboxes. Two sets of field data were obtained from 64 gearboxes that were first-run to removal for cause, were refurbished and placed back in service, and then were second-run until removal for cause. A series of equations were empirically developed from the Monte Carlo simulation to determine the statistical variation in predicted life and Weibull slope as a function of the number of gearboxes failed. The resultant L(sub 10) life from the field data was 5,627 hr. From strict-series system reliability, the predicted L(sub 10) life was 774 hr. From the Monte Carlo simulation, the median value for the L(sub 10) gearbox lives equaled 757 hr. Half of the gearbox L(sub 10) lives will be less than this value and the other half more. The resultant L(sub 10) life of the second-run (refurbished) gearboxes was 1,334 hr. The apparent load-life exponent p for the roller bearings is 5.2. Were the bearing lives to be recalculated with a load-life exponent p equal to 5.2, the predicted L(sub 10) life of the gearbox would be equal to the actual life obtained in the field. The component failure distribution of the gearbox from the Monte Carlo simulation was nearly identical to that using the strict-series system reliability analysis, proving the compatibility of these methods.

Zaretsky, Erwin V.↗
NASA NTRS2006

Processes Influencing Ozone Levels in Alaskan Forest Fires Plumes during Long-Range Transport over the North Atlantic

A case of long-range transport of a biomass burning plume from Alaska to Europe is analyzed using a Lagrangian approach. This plume was sampled several times in the free troposphere over North America, the North Atlantic and Europe by 3 different aircraft during the IGAC Lagrangian 2K4 experiment which was part of the ICARTT/ITOP measurement intensive in summer 2004. Measurements in the plume showed enhanced values of CO, VOCs and NOy, mainly in form of PAN. Observed O3 levels increased by 17 ppbv over 5 days. A photochemical trajectory model, CiTTyCAT, is used to examine processes responsible for the chemical evolution of the plume. The model was initialized with upwind data, and compared with downwind measurements. The influence of high aerosol loading on photolysis rates in the plume is investigated using in-situ aerosol measurements in the plume and lidar retrievals of optical depth as input into a photolysis code (Fast-J), run in the model. Significant impacts on photochemistry are found with a decrease of 18 percent in O3 production and 24 percent in O3 destruction over 5 days when including aerosols. The plume is found to be chemically active with large O3 increases attributed primarily to PAN decomposition during descent of the plume towards Europe. The predicted O3 changes are very dependent on temperature changes during transport, and also, on water vapor levels in the lower troposphere which can lead to O3 destruction. Simulation of mixing/dilution was necessary to reproduce observed pollutants level in the plume. Mixing was simulated using background concentrations from measurements in air masses in close proximity to the plume, and mixing timescales (averaging 6.25 days) were derived from CO changes. Observed and simulated O3/CO correlations in the plume are also compared in order to evaluate the photochemistry in the model. Observed slopes changed from negative to positive over 5 days. This change, which can be attributed largely to photochemistry, is well reproduced by multiple model runs even if slope values are slightly underestimated suggesting small underestimation of photochemical processes. The possible impact of this biomass burning plume on O3 levels in the Europe boundary layer is also examined by running the model for a further 5 days, and comparing with data collected at surface sites, such as Jungfraujoch, which showed small O3 increases and elevated CO levels. The model predicts significant changes in O3 over this 10 days due to photochemistry but the signal is largely lost due to the effects of dilution. However, measurement in several others BB plumes over Europe show that O3 impact of Alaskan fires can be punctually significant over Europe.

Real, E.↗