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At least 649 records · Page 36

Propulsion-related flowfields using the preconditioned Navier-Stokes equations

A previous time-derivative preconditioning procedure for solving the Navier-Stokes is extended to the chemical species equations. The scheme is implemented using both the implicit ADI and the explicit Runge-Kutta algorithms. A new definition for time-step is proposed to enable grid-independent convergence. Several examples of both reacting and non-reacting propulsion-related flowfields are considered. In all cases, convergence that is superior to conventional methods is demonstrated. Accuracy is verified using the example of a backward facing step. These results demonstrate that preconditioning can enhance the capability of density-based methods over a wide range of Mach and Reynolds numbers.

Venkateswaran, S.↗

Exit plane H2O concentration measurements correlated with OH PLIF near-injector mixing measurements for scramjet flows

Mixing and combusting high enthalpy flows, similar to those encountered in scramjet engines, were investigated using a shock tunnel to produce the flow in conjunction with non-intrusive optical diagnostics which monitored the performance of two injector configurations. The shock tunnel is configured to produce Mach 3 flow and stagnation enthalpies corresponding to flight equivalent Mach numbers between 7 and 11. A pulsed hydrogen injection capability and interchangeable injector blocks provide a means of examining high speed, high enthalpy reacting flows. Planar laser induced fluorescence (PLIF) of OH molecules in the near injector region produced images which show the combusting and mixing zones for the reacting flow. Line-of-sight exit plane measurement of water concentration and temperature were used to provide a unique method of monitoring exit plane products. These results demonstrated that a velocity matched axial injection system produced a fuel jet that lifted off the floor of the duct. Mixing was observed to increase for this system as a velocity mismatch was introduced. Comparison of exit plane water concentrations for a wall jet injection system and a velocity matched injection system indicated similar mixing performance but an accurate pressure measurement is necessary to further validate the result. In addition, exit plane measurements indicated an approximate steady-state condition was achieved during the 1 to 2 ms test times.

Parker, T. E.↗

Study of basic physical processes in liquid rocket engines

Inconsistencies between analytical results and measurements for liquid rocket thrust chamber performance, which escape suitable explanations, have motivated the examination of the basic phys ical modeling formulations as to their unlimited application. The publication of Prof. D. Straub's book, 'Thermofluid-dynamics of Optimized Rocket Propulsions,' further stimulated the interest of understanding the gas dynamic relationships in chemically reacting mixtures. A review of other concepts proposed by Falk-Ruppel (Gibbsian Thermodynamics), Straub (Alternative Theory, AT), Prigogine (Non-Equilibrium Thermodynamics), Boltzmann (Kinetic Theory), and Truesdell (Rational Mechanism) has been made to obtain a better understanding of the Navier-Stokes equation, which is now used extensively for chemically reacting flow treatment in combustion chambers. In addition to the study of the different concepts, two workshops were conducted to clarify some of the issues. The first workshop centered on Falk-Ruppel's new 'dynamics' concept, while the second one concentrated on Straub's AT. In this report brief summaries of the reviewed philosophies are presented and compared with the classical Navier-Stokes formulation in a tabular arrangement. Also the highlights of both workshops are addressed.

Wu, S. T.↗

Innovative techniques for the production of energetic radicals for lunar processing including cold plasma processing of local planetary ores

Hydrogen reduction of ilmenite has been studied by a number of investigators as a potential means for recovery of oxygen from lunar soil. Interest in this process has always rested with the simplicity of the flow diagram and the utilization of established technology. Effective utilization of hydrogen in the reduction process at temperatures of 1200 C and below has always been disappointing and, as such, has led other investigators to focus attention on other systems. Effective utilization of hydrogen in the reduction of ilmenite can be significantly enhanced in the presence of a non-equilibrium hydrogen plasma. Ilmenite at solid specimen temperatures of 600 C to 970 C were reacted in a hydrogen plasma. Those experiments revealed that hydrogen utilization can be significantly enhanced. At a specimen temperature of 850 C the fraction of H2 reacted was 24 percent compared to the 7 percent theoretical limit calculated with thermodynamic theory for the same temperature. An added advantage for a hydrogen plasma involves further reduction of TiO2. Reduction of the iron oxide in ilmenite yields TiO2 and metallic iron as by products. Titanium forms a number of oxides including TiO, Ti2O3, Ti3O5 and the Magneli oxides (Ti4O7 to Ti50O99). In conventional processing of ilmenite with hydrogen it is possible to reduce TiO2 to Ti7O13 within approximately an hour, but with poor utilization of hydrogen on the order of one mole of H2 per thousand. In the cold or non-equilibrium plasma TiO2 can be rapidly reduced to Ti2O3 with hydrogen utilization exceeding 10 percent. Based on design considerations of the plasma reactor greater utilization of the hydrogen in the reduction of TiO2 is possible.

Bullard, D.↗

Time accurate simulations of compressible shear flows

The objectives of this research are to employ direct numerical simulation (DNS) to study the phenomenon of mixing (or lack thereof) in compressible free shear flows and to suggest new means of enhancing mixing in such flows. The shear flow configurations under investigation are those of parallel mixing layers and planar jets under both non-reacting and reacting nonpremixed conditions. During the three-years of this research program, several important issues regarding mixing and chemical reactions in compressible shear flows were investigated.

Givi, Peyman↗

Computation of wake/exhaust mixing downstream of advanced transport aircraft

The mixing of engine exhaust with the vortical wake of high speed aircraft operating in the stratosphere can play an important role in the formation of chemical products that deplete atmospheric ozone. An accurate analysis of this type of interaction is therefore necessary as a part of the assessment of the impact of proposed High Speed Civil Transport (HSCT) designs on atmospheric chemistry. This paper describes modifications to the parabolic Navier-Stokes flow field analysis in the UNIWAKE unified aircraft wake model to accommodate the computation of wake/exhaust mixing and the simulation of reacting flow. The present implementation uses a passive chemistry model in which the reacting species are convected and diffused by the fluid dynamic solution but in which the evolution of the species does not affect the flow field. The resulting analysis, UNIWAKE/PCHEM (Passive CHEMistry) has been applied to the analysis of wake/exhaust flows downstream of representative HSCT configurations. The major elements of the flow field model are described, as are the results of sample calculations illustrating the behavior of the thermal exhaust plume and the production of species important to the modeling of condensation in the wake. Appropriate steps for further development of the UNIWAKE/PCHEM model are also outlined.

Quackenbush, Todd R.↗

CFD validation of subsonic turbulent planar shear layers

The primary objective of the present study is to assess the limitations and capabilities of RPLUS in predicting the entrainment, mixing, and burning characteristics of a high subsonic planar shear layer; these computations are performed in conjunction with an experiment being conducted at NASA Lewis Research Center. Turbulence is modeled by a two-equation k-epsilon closure modified for compressibility effects. Combustion is modeled by two different models: one in which a finite-rate laminar chemistry model is used for H2-O2 oxidation, and the other based on a composition joint pdf approach to account for the turbulence-chemistry interaction effects. Between upwind and centered differencing schemes, minimal differences are observed for the flow properties of a nonreacting shear layer case studied. In comparison with experimental data, computed growth rates are underpredicted in both reacting and nonreacting cases of a shear layer, but more severely for the reacting flows. However, the qualitative agreement between computation and experiment is reasonably good for the other observable characteristics, and indicative of potential for further improvements.

Lai, H. T.↗

Oligomerization reactions of ribonucleotides - The reaction of the 5'-phosphorimidazolide of adenosine with diadenosine pyrophosphate on montmorillonite and other minerals

The overall regiospecificity of the 3',5'-phosphodiester bond formation is shown to be increased from 64 to 83 percent when a 9:1 ratio of ImpA to A5'ppA instead of ImpA alone is reacted in the presence of Na(+)-montmorillonite. The major factor in the regiospecificity increase is the formation of 3',5'-linked A5'ppA3'pA and A5'pp-A3'pA3'pA. The results obtained show that ImpA reacts more readily with A5'ppA than it does with another ImpA molecule and that A5'ppA plays a central role in directing the formation of 3',5'-phosphodiester bonds.

Ferris, James P.↗

Polyimides Containing Pendent Ethynyl Groups

Series of novel diamines containing pendent ethynyl groups synthesized and reacted with various dianhydrides to form polyamide acids cyclodehydrated to form polyimides containing pendent ethynyl groups. Copolyimides of these diamines and other diamines also prepared. Upon heating, ethynyl groups in these polymers react with one another to form cross-linked molecular structures. As result of curing reaction, resistance to solvents, glass-transition temperature, and modulus of elasticity of polymer of this type generally increase, accompanied by corresponding decrease in tensile elongation and toughness. Cured polymers used as films, moldings, adhesives, and composite matrices.

Hergenrother, Paul M.↗

Di(hydroxyphenyl)- 1,2,4-triazole monomers

The di(hydroxyphenyl)- 1,2,4-triazole monomers were first synthesized by reacting bis (4-hydroxyphenyl) hydrazide with aniline hydrochloride at 250 C in the melt and also by reacting 1,3 or 1,4-bis- (4-hydroxyphenyl)- phenylene- dihydrazide with 2 moles of aniline hydrochloride in the melt. Purification of the di(hydroxyphenyl)- 1,2,4-triazole monomers was accomplished by recrystallization. Poly (1,2,4-triazoles) (PT) were prepared by the aromatic nucleophilic displacement reaction of di(hydroxyphenyl)- 1,2,4-triazole monomers with activated aromatic dihalides or activated aromatic dinitro compounds. The reactions were carried out in polar aprotic solvents such as sulfolane or diphenylsulfone using alkali metal bases such as potassium carbonate at elevated temperatures under nitrogen. This synthetic route has provided high molecular weight PT of new chemical structure, is economically and synthetically more favorable than other routes, and allows for facile chemical structure variation due to the availability of a large variety of activated aromatic dihalides.

Connell, John W.↗

Application of fault detection techniques to spiral bevel gear fatigue data

Results of applying a variety of gear fault detection techniques to experimental data is presented. A spiral bevel gear fatigue rig was used to initiate a naturally occurring fault and propagate the fault to a near catastrophic condition of the test gear pair. The spiral bevel gear fatigue test lasted a total of eighteen hours. At approximately five and a half hours into the test, the rig was stopped to inspect the gears for damage, at which time a small pit was identified on a tooth of the pinion. The test was then stopped an additional seven times throughout the rest of the test in order to observe and document the growth and propagation of the fault. The test was ended when a major portion of a pinion tooth broke off. A personal computer based diagnostic system was developed to obtain vibration data from the test rig, and to perform the on-line gear condition monitoring. A number of gear fault detection techniques, which use the signal average in both the time and frequency domain, were applied to the experimental data. Among the techniques investigated, two of the recently developed methods appeared to be the first to react to the start of tooth damage. These methods continued to react to the damage as the pitted area grew in size to cover approximately 75% of the face width of the pinion tooth. In addition, information gathered from one of the newer methods was found to be a good accumulative damage indicator. An unexpected result of the test showed that although the speed of the rig was held to within a band of six percent of the nominal speed, and the load within eighteen percent of nominal, the resulting speed and load variations substantially affected the performance of all of the gear fault detection techniques investigated.

Zakrajsek, James J.↗

Measurement of atmospheric OH by titration of near-IR fluorescent dyes

Recent research has shown that certain polymethine dyes can be detected at ultratrace levels (greater than or equal to 6x10(exp -14) M) in solution by fluorimetry. These detection limits are possible because of the inherent sensitivity of fluorescence techniques, because the dyes fluoresce in the near infrared region where background interference is negligible, and because powerful infrared diode lasers are now available to improve the signal to noise ratio. Other work has shown that the hydroxyl radical destroys the ability of polymethine dyes to fluoresce. These observations form the basis for a new hydroxyl radical detector that is essentially a fluorometric titrator. Theoretically, the detector should show an acceptable sensitivity and response time. Assuming that the atmospheric HO concentration is about 10(exp -11) moles m(exp -3) (i.e. 10(exp 6) molecules cm(exp -3)), then 10 L of air 'titrated' with 20 mL of 10(exp -11) M dye solution (an easily detected concentration) should result in a drop in the fluorescent signal of 50 percent - a readily detectable change. At a flow rate of 3 L min(exp -1) the sampling time would be 3 minutes. The biggest potential problem is selectivity: other oxidants may also cause the fluorescence signal to be lost. The chemistry of polymethine dyes has not been studied in detail and so no quantitative data are available. However, a survey of the literature suggests that in general HO should react up to six orders of magnitude faster than HO2 and other radicals such as RO2 and RO. It should also react much more rapidly than H2O2 and O3. Thus it may be possible to discriminate kinetically against potential interfering substances. It was shown in the laboratory that 10(exp -4) M H2O2 has little effect on the absorption spectrum of the dye IR125 over a period of hours but that the band at 780 nm is slowly lost in water over a period of days even under argon in the dark. By contrast, DMSO solutions of IR125 are stable.

Betterton, Eric A.↗

Poly(arylene ether-co-imidazole)s as toughness modifiers for epoxy resins

A toughened epoxy was prepared by reacting an epoxy resin with a poly(arylene ether-co-imidazole)s (PAEI). The epoxy resin comprises N,N,N',N'tetraglycidyl-4,4'- methylenebisbenzenamine and 4-aminophenyl sulfone. The PAEI was prepared by reacting an aromatic bisphenol, a bisphenol imidazole, and an activated aromatic dihalide or dinitro compound in the presence of potassium carbonate in a polar aprotic solvent at an elevated temperature. The epoxies which were modified with these particular PAEI's showed a significant increase in toughness with only a 10 weight percent loading of the PAEI into the epoxy. These toughened epoxies were used to prepare composites and molded parts.

Mcdaniel, Patricia D.↗

Atomic oxygen interaction at defect sights in protective coatings on polymers flown on LDEF

Although the Long Duration Exposure Facility (LDEF) has exposed materials with a fixed orientation relative to the ambient low-Earth-orbital environment, arrival of atomic oxygen is angularly distributed as a result of the atomic oxygen's high temperature Maxwellian velocity distribution and the LDEF's orbital inclination. Thus, atomic oxygen entering defects in protective coatings on polymeric surfaces can cause wider undercut cavities than the size of the defect in the protective coating. Because only a small fraction of atomic oxygen reacts upon first impact with most polymeric materials, secondary reactions with lower energy thermally accommodated atomic oxygen can occur. The secondary reactions of scattered and/or thermally accommodated atomic oxygen also contribute to widening the undercut cavity beneath the protective coating defect. As the undercut cavity enlarges, exposing more polymer, the probability of atomic oxygen reacting with underlying polymeric material increases because of multiple opportunities for reaction. Thus, the effective atomic oxygen erosion yield for atoms entering defects increases above that of the unprotected material. Based on the results of analytical modeling and computational modeling, aluminized Kapton multilayer insulation exposed to atomic oxygen on row 9 lost the entire externally exposed layer of polyimide Kapton, yet based on the results of this investigation, the bottom surface aluminum film must have remained in place, but crazed. Atomic oxygen undercutting at defect sites in protective coatings on graphite epoxy composites indicates that between 40 to 100 percent of the atomic oxygen thermally accommodates upon impact, and that the reaction probability of thermally accommodated atomic oxygen may range from 7.7 x 10(exp -6) to 2.1 x 10(exp -3), depending upon the degree of thermal accommodation upon each impact.

Banks, Bruce A.↗

Structure of a Swirl-stabilized, Combusting Spray

Measurements of the structure of a swirl-stabilized, reacting spray are presented. The configuration consisted of a research air-assist atomizer located in the center surrounded by a coflowing air stream. Both the air assist and coflow streams had swirl imparted to them in the same direction with 45 degree angle swirlers. The fuel and air entered the combustor at ambient temperature and the combustor was operated in an unconfined environment. The gas phase was seeded with aluminum oxide particles in order to obtain velocity measurements. Velocity measurements for the gas phase are reported for both an isothermal, single-phase case without drops and a reacting spray case at axial distances from 2.5 to 350 mm downstream of the nozzle. Both mean and fluctuating values are reported. Heptane fuel was used for all the experiments. Drop size and velocity, and drop number flux are also reported for five axial distances downstream. Both mean and fluctuating values are reported for the drops. The measurements were performed using a two-component phase/Doppler particle analyzer. Profiles across the entire flowfield where velocities were significant are presented. Mean gas phase temperatures were also measured intrusively using a single pt/pt-13 percent rh thermocouple and are reported at axial distances from 2.5 to 200 mm downstream of the nozzle.

Bulzan, Daniel L.↗

Diamines and polyimides containing pendent ethynyl groups

Diamines containing pendent ethynyl and substituted ethynyl groups are synthesized. These diamines are reacted with dianhydrides to form polyamide acids, which are chemically or thermally cyclodehydrated to form polyimides and copolyimides with pendent ethynyl groups. Upon heating, the pendent ethynyl groups react to form crosslinked resins that are useful as adhesives, composite matrices, coatings, moldings, and films.

Hergenrother, Paul M.↗

Low dielectric polyimide fibers

A high temperature resistant polyimide fiber that has a dielectric constant of less than 3 is presented. The fiber was prepared by first reacting 2,2-bis (4-(4aminophenoxy)phenyl) hexafluoropropane with 2,2-bis (3,4-dicarboxyphenyl) hexafluoropropane dianhydride in an aprotic solvent to form a polyamic acid resin solution. The polyamic acid resin solution is then extruded into a coagulation medium to form polyamic acid fibers. The fibers are thermally cured to their polyimide form. Alternatively, 2,2-bis(4-(4-aminophenoxy)phenyl) hexafluoropropane is reacted with 2,2-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride to form a polyamic acid, and the polyamic acid is chemically converted to its polyimide form. The polyimide is then dissolved in a solvent to form a polyimide resin solution, and the polyimide resin is extruded into a coagulation medium to form a polyimide wet gel filament. In order to obtain polyimide fibers of increased tensile properties, the polyimide wet gel filaments are stretched at elevated temperatures. The tensile properties of the fibers were measured and found to be in the range of standard textile fibers. Polyimide fibers obtained by either method will have a dielectric constant similar to that of the corresponding polymer, viz., less than 3 at 10 GHz.

Dorogy, William E., Jr.↗

Towards a generalized computational fluid dynamics technique for all Mach numbers

Currently there exists no single unified approach for efficiently and accurately solving computational fluid dynamics (CFD) problems across the Mach number regime, from truly low speed incompressible flows to hypersonic speeds. There are several CFD codes that have evolved into sophisticated prediction tools with a wide variety of features including multiblock capabilities, generalized chemistry and thermodynamics models among other features. However, as these codes evolve, the demand placed on the end user also increases simply because of the myriad of features that are incorporated into these codes. In order for a user to be able to solve a wide range of problems, several codes may be needed requiring the user to be familiar with the intricacies of each code and their rather complicated input files. Moreover, the cost of training users and maintaining several codes becomes prohibitive. The objective of the current work is to extend the compressible, characteristic-based, thermochemical nonequilibrium Navier-Stokes code GASP to very low speed flows and simultaneously improve convergence at all speeds. Before this work began, the practical speed range of GASP was Mach numbers on the order of 0.1 and higher. In addition, a number of new techniques have been developed for more accurate physical and numerical modeling. The primary focus has been on the development of optimal preconditioning techniques for the Euler and the Navier-Stokes equations with general finite-rate chemistry models and both equilibrium and nonequilibrium thermodynamics models. We began with the work of Van Leer, Lee, and Roe for inviscid, one-dimensional perfect gases and extended their approach to include three-dimensional reacting flows. The basic steps required to accomplish this task were a transformation to stream-aligned coordinates, the formulation of the preconditioning matrix, incorporation into both explicit and implicit temporal integration schemes, and modification of the numerical flux formulae. In addition, we improved the convergence rate of the implicit time integration schemes in GASP through the use of inner iteration strategies and the use of the GMRES (General Minimized Resisual) which belongs to the class of algorithms referred to as Krylov subspace iteration. Finally, we significantly improved the practical utility of GASP through the addition of mesh sequencing, a technique in which computations begin on a coarse grid and get interpolated onto successively finer grids. The fluid dynamic problems of interest to the propulsion community involve complex flow physics spanning different velocity regimes and possibly involving chemical reactions. This class of problems results in widely disparate time scales causing numerical stiffness. Even in the absence of chemical reactions, eigenvalue stiffness manifests itself at transonic and very low speed flows which can be quantified by the large condition number of the system and evidenced by slow convergence rates. This results in the need for thorough numerical analysis and subsequent implementation of sophisticated numerical techniques for these difficult yet practical problems. As a result of this work, we have been able to extend the range of applicability of compressible codes to very low speed inviscid flows (M = .001) and reacting flows.

Walters, R. W.↗