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COMPARISON OF RESULTS FOR QUARTER 4 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUELS SERVICES SITE, ERWIN, TN

Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on June 12, 2013. Representatives from the U.S. Nuclear Regulatory Commission (NRC) and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and Table 1 presents the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER ≤ 3 indicates at a 99% confidence interval that split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report specifies 95% confidence level of reported uncertainties (NFS 2013). Therefore, standard two sigma reporting values were divided by 1.96. In conclusion, most DER values were less than 3 and results are consistent with low (e.g., background) concentrations. The gross beta result for sample 5198W0014 was the exception. The ORAU gross beta result of 6.30 &plusmn 0.65 pCi/L from location NRD is well above NFS's non-detected result of 1.56 &plusmn 0.59 pCi/L. NFS's data package includes no detected result for any radionuclide at location NRD. At NRC's request, ORAU performed gamma spectroscopic analysis of sample 5198W0014 to identify analytes contributing to the relatively elevated gross beta results. This analysis identified detected amounts of naturally-occurring constituents, most notably Ac-228 from the thorium decay series, and does not suggest the presence of site-related contamination.

54 ENVIRONMENTAL SCIENCES↗

COMPARISON OF RESULTS FOR QUARTER 3 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE, ERWIN, TENNESSEE

Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on March 20, 2013. Representatives from the U.S. Nuclear Regulatory Commission and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and Table 1 presents the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER {<=} 3 indicates that at a 99% confidence interval, split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report does not specify the confidence level of reported uncertainties (NFS 2013). Therefore, standard two sigma reporting is assumed and uncertainty values were divided by 1.96. In conclusion, most DER values were less than 3 and results are consistent with low (e.g., background) concentrations. The gross beta result for sample 5198W0012 was the exception. The ORAU result of 9.23 &plusmn 0.73 pCi/L from location MCD is well above NFS's result of -0.567 &plusmn 0.63 pCi/L (non-detected). NFS's data package included a detected result for U-233/234, but no other uranium or plutonium detection, and nothing that would suggest the presence of beta-emitting radionuclides. The ORAU laboratory reanalyzed sample 5198W0012 using the remaining portion of the sample volume and a result of 11.3 &plusmn 1.1 pCi/L was determined. As directed, the laboratory also counted the filtrate using gamma spectrometry analysis and identified only naturally occurring or ubiquitous man-made constituents, including beta emitters that are presumably responsible for the elevated gross beta values.

54 ENVIRONMENTAL SCIENCES↗

Methylmercury and Ethylmercury Analytical Performance in SRR Samples Measured by SRNL and Eurofins Frontier Global Sciences

Existing models and simulants of tank disposition media at the Savannah River Site (SRS) have presumed the presence of high concentrations of inorganic mercury. However, quarterly Tank 50 analyses have shown that mercury is present as organomercurial species at concentrations that may present challenges to its remediation and disposition and may challenge the Waste Acceptance Criteria (WAC) for Saltstone. Todate, methylmercury analyses for Savannah River Remediation (SRR) have been performed at an off-site laboratory by Eurofins Frontier Global Sciences (FGS) in Bothell, WA. Savannah River Remediation requested the development of methylmercury and ethylmercury determination capabilities at the Savannah River National Laboratory (SRNL) to support the Liquid Waste Operations at SRS. As part of that method development, SRR requested that SRNL Analytical Development (AD) compare their results with those obtained from their outside contract laboratory, Eurofins FGS. This document reports on this method development work as well as the comparative analyses conducted between the two laboratories. A series of optimization and validation experiments has been performed at SRNL, which has resulted in the development of on-site methylmercury and ethylmercury speciation capabilities using purge and trap (P&T) gas chromatography (GC) coupled with thermal desorption (TD) cold vapor – atomic fluorescence spectroscopy (CVAFS). Speciation has been achieved for both species, with a methylmercury method reporting limit (MRL) value of 1.13 pg and an overall uncertainty (1σ) of 5.1%. An ethylmercury MRL of 11.5 pg and an overall uncertainty (1σ) of 4.8% were obtained. These analytical parameters compare favorably with Eurofins FGS, which demonstrates uncertainties (1σ) for methylmercury and ethylmercury of 13% and 9.1%, respectively. Results obtained by SRNL from the routine analysis of Tanks 21, 40, 50, and 51 samples have provided statistically indistinguishable results compared with Eurofins FGS. Based upon the work performed by SRNL-AD and the data currently available, the following recommendations can be made: Further work should be performed to determine a “best practices” for sample holding time prior to analysis (both preserved and non-preserved samples), as well as any detrimental effects sample age may have on data quality. Analysis of ethylmercury is only recommended for tank samples that are reasonably expected to have significant quantities of ethylmercury, such as from the DWPF SMECT. Trace levels of ethylmercury in the presence of large quantities of methylmercury can be difficult or impossible to quantify. SRNL-AD development of methods for total mercury, purgeable mercury (which includes Hg(0) and dimethylmercury), inorganic mercury (Hg(I) and Hg(II)), dissolved mercury, and particulate mercury are underway and will be reported upon separately.

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Impact of model predictive control-enabled home energy management on large-scale distribution systems with photovoltaics

Residential customers use more than one-quarter of the electricity in the world. Optimally managing home energy consumption is an effective way of easing the operational challenges facing the electric grid with increasing solar photovoltaics (PV). This paper studies the impact of the future proliferation of home energy management systems (HEMS) in the presence of PV on large-scale distribution systems. First, we present a stochastic HEMS model that minimizes residential customers' thermal discomfort and energy costs under uncertainty. The HEMS model schedules the optimal operations of residential appliances in the presence of PV within a mixed-integer linear programming-based model predictive control framework that links the proposed HEMS to a quasi-steady-state time-series simulation tool. Additionally, extensive simulations are conducted for a stand-alone residential home using two tariff structures and for 1977 homes on an 8,500-node distribution feeder. Simulation results quantify the impact of the future proliferation of HEMS on the large-scale distribution system with PV.

14 SOLAR ENERGY↗

Assessment of Comprehensive Analysis Calculation of Airloads on Helicopter Rotors

Blade section normal force and pitching moment were investigated for six rotors operating at transition and high speeds: H-34 in flight and wind tunnel, SA 330 (research Puma), SA 349/2, UH-60A full-scale and BO-105 model (HART-I). The measured data from flight and wind tunnel tests were compared with calculations obtained using the comprehensive analysis CAMRAD II. The calculations were made using two free wake models: rolled-up and multiple-trailer with consolidation models. At transition speed, there is fair to good agreement for the blade section normal force between the test data and analysis for the H-34, research Puma, and SA 349/2 with the rolled-up wake. The calculated airloads differ significantly from the measurements for the UH-60A and BO-105. Better correlation is obtained for the UH-60A and BO-105 by using the multiple-trailer with consolidation wake model. In the high speed condition, the analysis shows generally good agreement with the research Puma flight data in both magnitude and phase. However, poor agreement is obtained for the other rotors examined. The analysis shows that the aerodynamic tip design (chord length and quarter chord location) of the Puma has an important influence on the phase correlation.

Yeo, Hyeonsoo↗

A Few Thoughts on the E-Tunnel Discharge at Rainier Mesa, Nevada National Security Site

In reviewing the Quarterly Monitoring Reports assembled by Navarro for the Rainier Mesa E-Tunnel discharge for the past year (the “Navarro” data), Greg Raab of the Nevada Department of Environmental Proctection (NDEP) noticed a decreasing trend in the pH and was curious as to what was causing it. He noticed an upswing in the March 2016 data and speculated as to whether the trend would go up. Irene Farnham (Navarro) sent along the Navarro chemical and flow data from ETunnel, going back for some of the variables to 1997. Previously I was curious as to whether there was a trend in the discharge flow rates from E-Tunnel that corresponded to Greg Raab’s observations and comments about the decreasing trend in pH observed between 2015 and 2016. So, I plotted the two time series from the Navarro data over roughly the same time period that Greg looked at. There does not appear to be much of a correlation. (NB: The value of 7.1 for January 2016 differs from the value of ~6.55 in Greg’s data).

54 ENVIRONMENTAL SCIENCES↗

Monitoring Regional Forest Disturbances across the US with near Real Time MODIS NDVI Products Resident to the ForWarn Forest Threat Early Warning System

Forest threats across the US have become increasingly evident in recent years. Sometimes these have resulted in regionally evident disturbance progressions (e.g., from drought, bark beetle outbreaks, and wildfires) that can occur across multiyear durations and have resulted in extensive forest overstory mortality. In addition to stand replacement disturbances, other forests are subject to ephemeral, sometimes yearly defoliation from various insects and varying types and intensities of ephemeral damage from storms. Sometimes, after prolonged severe disturbance, signs of recovery in terms of Normalized Difference Vegetation Index (NDVI) can occur. The growing prominence and threat of forest disturbances in part have led to the formation and implementation of the 2003 Healthy Forest Restoration Act which mandated that national forest threat early warning system be developed and deployed. In response, the US Forest Service collaborated with NASA, DOE Oakridge National Laboratory, and the USGS Eros Data Center to build and roll-out the near real time ForWarn early warning system for monitoring regionally evident forest disturbances. Given the diversity of disturbance types, severities, and durations, ForWarn employs multiple historical baselines that are used with current NDVI to derive a suite of six forest change products that are refreshed every 8 days. ForWarn employs daily quarter kilometer MODIS NDVI data from the Aqua and Terra satellites, including MOD13 data for deriving historical baseline NDVIs and eMODIS 7 NDVI for compiling current NDVI. In doing so, the Time Series Product Tool and the Phenological Parameters Estimation Tool are used to temporally de-noise, fuse, and aggregate current and historical MODIS NDVIs into 24 day composites refreshed every 8 days with 46 dates of products per year. The 24 day compositing interval enables disturbances to be detected, while minimizing the frequency of residual atmospheric contamination. Forest change products are computed versus the previous 1, previous 3, and all previous years in the MODIS record for a given 24 day interval. Other "weekly" forest change products include one computed using an adaptive length compositing method for quicker detection of disturbances, two others that adjust for seasonal fluctuations in normal vegetation phenology (e.g., early versus late springs). This overall approach enables forest disturbance dynamics from a variety of regionally evident biotic and abiotic forest disturbances to be viewed and assessed through the calendar year. The change products are also being utilized for forest change trend analysis and for developing regional forest overstory mortality products. ForWarn's forest change products are used to alert forest health specialists about new forest disturbances. Such alerts are also typically based on available Landsat, aerial, and ground data as well as communications with forest health specialists and previous experience. ForWarn products have been used to detect and track many types of regional disturbances to multiple forest types, including defoliation from caterpillars and severe storms, as well as mortality from both biotic and abiotic agents (e.g., bark beetles, drought, fire, anthropogenic clearing). ForWarn offers products that could be combined with other geospatial data on forest biomass to assess forest disturbance carbon impacts within the conterminous US.

Spruce, Joseph P.↗

Effects of Outboard Thickened and Blunted Leading Edges on the Wave Drag of a 45 Degree Swept-Wing and Body Combination

An investigation to evaluate the effects of thickened and blunted leading-edge modifications on the wave drag of a swept wing has been made at Mach numbers from 0.65 to 2.20 and at a Reynolds number of 2,580,000 based on the mean aerodynamic chord of the basic wing. Two leading-edge designs were investigated and they are referred to as the thickened and the blunted modifications although both sections had equally large leading-edge radii. The thickened leading edge was formed by increasing the thickness over the forward 40 percent of the basic wing section. The blunted modification was formed by reducing the wing chords about 1 percent and by increasing the section thickness slightly over the forward 6 percent of the basic section in a manner to keep the wing sweep and volume essentially equal to the respective values for the basic wing. The basic wing had an aspect ratio of 3, a leading-edge sweep of 45 deg., a taper ratio of 0.4, and NACA 64AO06 sections perpendicular to a line swept back 39.45 deg., the quarter-chord line of these sections. Test results indicated that the thickened modification resulted in an increase in zero-lift drag coefficient of from 0.0040 to 0.0060 over values for the basic model at Mach numbers at which the wing leading edge was sonic or supersonic. Although drag coefficients of both the basic and thickened models were reduced at all test Mach numbers by body indentations designed for the range of Mach numbers from 1.00 to 2.00, the greater drag of the thickened model relative to that of the basic model was not reduced. The blunted model, however, had less than one quarter of the drag penalty of the thickened model relative to the basic model at supersonic leading-edge conditions (M greater or equal to root-2).

Holdaway, George H.↗

A systematic analysis and data mining of opioid-related adverse events submitted to the FAERS database

The opioid epidemic has become a serious national crisis in the United States. An indepth systematic analysis of opioid-related adverse events (AEs) can clarify the risks presented by opioid exposure, as well as the individual risk profiles of specific opioid drugs and the potential relationships among the opioids. In this study, 92 opioids were identified from the list of all Food and Drug Administration (FDA)-approved drugs, annotated by RxNorm and were classified into 13 opioid groups: buprenorphine, codeine, dihydrocodeine, fentanyl, hydrocodone, hydromorphone, meperidine, methadone, morphine, oxycodone, oxymorphone, tapentadol, and tramadol. A total of 14,970,399 AE reports were retrieved and downloaded from the FDA Adverse Events Reporting System (FAERS) from 2004, Quarter 1 to 2020, Quarter 3. After data processing, Empirical Bayes Geometric Mean (EBGM) was then applied which identified 3317 pairs of potential risk signals within the 13 opioid groups. Based on these potential safety signals, a comparative analysis was pursued to provide a global overview of opioid-related AEs for all 13 groups of FDA-approved prescription opioids. The top 10 most reported AEs for each opioid class were then presented. Both network analysis and hierarchical clustering analysis were conducted to further explore the relationship between opioids. Results from the network analysis revealed a close association among fentanyl, oxycodone, hydrocodone, and hydromorphone, which shared more than 22 AEs. In addition, much less commonly reported AEs were shared among dihydrocodeine, meperidine, oxymorphone, and tapentadol. On the contrary, the hierarchical clustering analysis further categorized the 13 opioid classes into two groups by comparing the full profiles of presence/absence of AEs. The results of network analysis and hierarchical clustering analysis were not only consistent and cross-validated each other but also provided a better and deeper understanding of the associations and relationships between the 13 opioid groups with respect to their adverse effect profiles.

Research & Experimental Medicine↗

CFD Parametric Study of Consortium Impeller

Current design of high performance turbopumps for rocket engines requires effective and robust analytical tools to provide design impact in a productive manner. The main goal of this study is to develop a robust and effective computational fluid dynamics (CFD) pump model for general turbopump design and analysis applications. A Finite Difference Navier-Stokes flow solver, FDNS, which includes the extended k-epsilon turbulence model and appropriate moving interface boundary conditions, was developed to analyze turbulent flows in turbomachinery devices. A second-order central difference scheme plus adaptive dissipation terms was employed in the FDNS code, along with a predictor plus multi-corrector pressure-based solution procedure. The multi-zone, multi-block capability allows the FDNS code to efficiently solve flow fields with complicated geometry. The FDNS code has been benchmarked by analyzing the pump consortium inducer, and it provided satisfactory results. In the present study, a CFD parametric study of the pump consortium impeller was conducted using the FDNS code. The pump consortium impeller, with partial blades, is a new design concept of the advanced rocket engines. The parametric study was to analyze the baseline design of the consortium impeller and its modification which utilizes TANDEM blades. In the present study, the TANDEM blade configuration of the consortium impeller considers cut full blades for about one quarter chord length from the leading edge and clocks the leading edge portion with an angle of 7.5 or 22.5 degrees. The purpose of the present study is to investigate the effect and trend of the TANDEM blade modification and provide the result as a design guideline. A 3-D flow analysis, with a 103 x 23 x 30 mesh grid system and with the inlet flow conditions measured by Rocketdyne, was performed for the baseline consortium impeller. The numerical result shows that the mass flow rate splits through various blade passages are relatively uniform. Due to the complexity of blade geometries, the TANDEM blade configurations were analyzed with the multi-zone grid structure. Both the 7.5 deg- and the 22.5 deg-clocking TANDEM blade cases utilized a 80K mesh system. The numerical result of two TANDEM blade modifications indicates the efficiency and the head are worse than those of the baseline case due to larger flow distortion. The gap between the TANDEM blade and the full blade allows the flow passes through and heavily loads the pressure side of the partial blade such that flow reversal occurs near the suction side of the splitter. The flow split at the exit of impeller blades is very non-uniform for TANDEM blade cases, and this will greatly induce the side load on the diffuser. Therefore, the TANDEM blade modification in the present CFD analysis does not improve the performance of the consortium impeller.

Cheng, Gary C.↗

A New Scientific use of Total Eclipses of the Moon: Studies of the Generation and Loss of Atmospheres of Primitives Bodies

This grant supported observational campaigns to record the size and brightness of the lunar atmosphere as seen in sodium gas (Na) emissions during the totality phase of lunar eclipses. Three eclipse events were attempted, two from the Mc Donald Observatory in Fort Davis Texas, and one from the site of Italy's Galileo National Telescope (GNT) in La Palma, in the Canary Islands. In all three cases, clear skies prevailed and excellent datasets were obtained. Following the observational component of the grant, a period of detailed processing and analysis began. Eclipse events were chosen for study because when the moon is in full phase it has been within the terrestrial magnetosphere for a few days, thereby shielded from solar wind impact upon its surface. Since sputtering of Na from the lunar regolith by solar wind particles had been proposed as a source of the Moon's atmosphere, this was a test of the mechanism. If the lunar Na appeared to be diminished in comparison to abundances seen at other phases (e.g., at quarter phase when the moon is directly in the solar wind), the solar wind sputtering would indeed be a major source of lunar Na. These experiments could not be conducted during any full moon night because scattering of bright moonlight is so strong that low-light-level imaging of the lunar atmosphere could not be achieved. Hence, the use of eclipses. The final result of these experiments was, for once, clear and unambiguous. The robust size and Na brightness levels measured during all of the eclipses showed that solar wind sputtering could not be a major source of the lunar atmosphere. A major paper on this conclusion was published in ICARUS, and an oral presentation of partial results given at the The Three Galileos conference in Padova (Italy) in January 1997 and at the DPS meeting in Cambridge, MA, in July 1997.

Mendillo, Michael↗

A Novel Spacecraft Charge Monitor for LEO

Five years ago we introduced a new method for measuring spacecraft chassis floating potential relative to the space plasma (absolute spacecraft potential) in low Earth orbit. The method, based on a straightforward interpretation of photoelectron spectra, shows promise for numerous applications, but has not yet been tried. In the interest of testing the method, and ultimately supplying another tool for measuring absolute spacecraft charge, we are producing a flight prototype Spacecraft Charge Monitor (SCM) with support from NASA's Small Business Innovation Research (SBIR) program. Although insight into the technique came from data collected in space over two decades ago, very little data are available. The data indicate that it may be possible to determine spacecraft floating potential to within 0.1 volt each with the SCM second under certain conditions. It is debatable that spacecraft floating potential has ever been measured with such accuracy. The compact, easily deployed SCM also offers the advantage of long-term stability in calibration. Accurate floating potential determinations from the SCM could be used to correct biases in space plasma measurements and evaluate charge mitigation and/or sensing devices. Although this paper focuses on the device's use in low Earth orbit (LEO), the device may also be able to measure spacecraft charge at higher altitudes, in the solar wind, and in orbits around other planets. The flight prototype SCM we are producing for delivery to NASA in the third quarter of 2004 will measure floating potential from 0 to -150 volts with 0.1 volt precision, weigh approximately 600-700 grams, consume approximately 2 watts, and will measure approximately 8 x 10 x 17 cm.

Goembel, Luke↗

Acquisition and Implementation of a Comprehensive Environmental Permits Linking Tool at Savannah River Site - 20234

Historically, Savannah River Nuclear Solutions LLC (SRNS) tracked environmental regulatory commitments and the requirements from hundreds of permits at the Savannah River Site (SRS) using several separate methods, making integrated compliance assurance cumbersome and labor-intensive. When SRNS experienced an increase in environmental issues in 2017, SRNS management and U.S. Department of Energy - Savannah River (DOE-SR) management decided a single, proactive approach was needed to capture environmental permit information (including regulations, Consent Orders, DOE Orders, and any other state or federally issued statement of requirements), track the tasks necessary to ensure compliance with these requirements, and thereby mitigate the risk of noncompliance. SRNS developed a list of mandatory objectives that the tool must meet to function as a Comprehensive Environmental Permits Linking Tool (CEPLT). A key requirement was the ability to map Site permits to their governed locations and display the associated requirements at the compliance point (e.g., outfall, stack, waste unit, etc.). Several options included modifying existing onsite resources, building a custom onsite solution, purchasing an off-the-shelf solution, and contracting an offsite developer to build a custom solution. SRNS concluded an off-the-shelf solution with configuration and customization options would provide the flexibility to fit the unique needs of Savannah River Site (SRS) while taking advantage of industry-tested software and providing a reduced deployment timeline. SRNS chose Gensuite{sup R} a, a cloud-based solution that offers numerous a la carte applications in the environmental, health, and safety arenas, as the best candidate. SRNS selected three (3) integrated applications (Compliance Calendar, Permit Manager, and Mapper) to function as the CEPLT. The Compliance Calendar module allows for creation and tracking of regulatory commitment tasks assigned to responsible environmental professionals. Permit Manager organizes permits and other requirement documents, linking the commitments in each to Compliance Calendar tasks and/or implementing procedures. Mapper provides GIS capability for mapping the data from the other two modules to their physical onsite locations. The CEPLT was configured to allow for other SRS Site Tenants to eventually utilize the applications. Additionally, DOE-SR uses the CEPLT to provide an overview of contractor environmental compliance activities and to organize DOE-specific documents and tasks. The CEPLT fulfilled the requirement of meeting current compliance needs as well as providing the ability to grow as new organizations are incorporated and functionality is expanded. SRNS now uses the CEPLT to more effectively manage permit requirements, improve knowledge transfer, and increase the Site's overall protection of the environment, the Site worker, and the public. Possible future uses of the system include integration of mobile applications for timely communication of potential non-compliant conditions and DOE complex-wide deployment allowing for enhanced DOE site and Head Quarters oversight. Implementation of CEPLT will result in cost savings, both in terms of dollars and man-hours. (authors)

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Thermal Insulation for a High Temperature Molten Salt Storage Tank in a CSP Plant

A ternary molten chloride has been suggested as a high temperature (550-720 °C) sensible heat storage medium for a two-tank system. An effective thermal insulation is proposed to provide an opportunity for the fabrication of both the hot and cold storage tanks from lower cost metals, e.g. A240-347H, by maintaining the tank wall below 500 °C. To achieve this, the hot storage tank mainly comprises of inner shell (11.4 cm of a refractory brick as liner (KX-99®), 30 cm of insulation brick) and outer metal shell, where 5 cm of frozen layer of PCM800 (NaCl), and 5 cm of ceramic wool fill the annular space between the shells. Another layer of ceramic wool was introduced at the outer side of the metal shell to keep the temperature lower than 60 °C. ANSYS Fluent was used for the numerical study of the cool down behavior of the system during idle period when tank is quarter-filled. The heat transfer modes were considered as radiation and natural convection heat transfer from the hot molten salt at 720 °C, conduction through the solid layers and convection heat transfer from the outer shell to the environment at 15 °C. The results showed that the proposed insulation system including a frozen layer of PCM800 maintains the temperature at the metal wall lower than 500 °C, and lower than 60°C at the outer side of the tank. Apart from the insulation property of the frozen layer of PCM800, it absorbs any leak of hot molten salt, acting as a barrier between salt and the metal shell. The thermal performance analysis provide an insight into the benefits of the multilayer insulation.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Thermal Insulation for a High Temperature Molten Salt Storage Tank in a CSP Plant: Preprint

A ternary molten chloride has been suggested as a high temperature (550-720 °C) sensible heat storage medium for a two-tank system. An effective thermal insulation is proposed to provide an opportunity for the fabrication of both the hot and cold storage tanks from lower cost metals, e.g. A240-347H, by maintaining the tank wall below 500 °C. To achieve this, the hot storage tank mainly comprises of inner shell (11.4 cm of a refractory brick as liner (KX-99 ®), 30 cm of insulation brick) and outer metal shell, where 5 cm of frozen layer of PCM800 (NaCl), and 5 cm of ceramic wool fill the annular space between the shells. Another layer of ceramic wool was introduced at the outer side of the metal shell to keep the temperature lower than 60 °C. ANSYS Fluent was used for the numerical study of the cool down behavior of the system during idle period when tank is quarter-filled. The heat transfer modes were considered as radiation and natural convection heat transfer from the hot molten salt at 720 °C, conduction through the solid layers and convection heat transfer from the outer shell to the environment at 15 °C. The results showed that the proposed insulation system including a frozen layer of PCM800 maintains the temperature at the metal wall lower than 500 °C, and lower than 60 °C at the outer side of the tank. Apart from the insulation property of the frozen layer of PCM800, it absorbs any leak of hot molten salt, acting as a barrier between salt and the metal shell. The thermal performance analysis provide an insight into the benefits of the multilayer insulation.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Chiral spin liquid and quantum phase transition in the triangular-lattice Hofstadter-Hubbard model

Recent advances in moiré engineering motivate the study of lattice models of strongly correlated electrons subjected to substantial orbital magnetic flux. We analyze the triangular-lattice Hofstadter-Hubbard model at one-quarter flux quantum per plaquette and a density of one electron per site, where a chiral spin liquid phase may exist between weak-coupling integer quantum Hall and strong-coupling 120° antiferromagnetic phases. Here, we use matrix product state methods and analytical arguments to investigate this model compactified to cylinders of finite circumference. We uncover a glide particle-hole symmetry operation which, we argue, is spontaneously broken at the quantum Hall to spin liquid transition on odd-circumference cylinders. We numerically verify the spontaneous symmetry breaking and further demonstrate that this transition is associated with algebraic long-range correlations of various spin-singlet, charge-neutral operators. For even-circumference cylinders, the transition becomes a crossover associated with a large correlation length that grows substantially with circumference. Our findings suggest that in the two-dimensional limit, the transition to a chiral spin liquid phase is continuous and features critical fluctuations of the current.

Divic, Stefan [University of Pennsylvania, Philade↗

Solar Coronal Structure Study

The subject of this investigation is the study the physics of the solar corona through the analysis of the EUV and UV data produced by two flights (12 May 1992 and 25 April 1994) of the Lockheed Solar Plasma Diagnostics Experiment (SPDE) sounding rocket payload, in combination with Yohkoh and groundbased data. These joint datasets are useful for understanding the physical state of the solar atmosphere from the photosphere to the corona at the time of the rocket flights. Each rocket flight produced both spectral and imaging data. Highlights of this initial year of the contract included compilation, scaling and co-alignment of image sets, substantial progress on the Bright Point study, initial work on the Active Region and Large Scale Structure studies, DRSC slit-aspect determination work and calibration activities. One paper was presented at the 1997 Annual Meeting of the AAS/SPD in Bozeman, Montana. An initial set of calibrated spectra were placed into the public domain via the World Wide Web. Three Quarterly Progress Reports have been submitted; progress for the fourth quarter of the contract is summarized in this Final Contract Report. The intent of the investigation is to compare the physics of small- and medium-scale structure with that of large-scale structures with weak fields. A study has been identified in each size domain. The calibration of the rocket data forms an important element of the work. Of equal importance is the slit-aspect solution, which determines the correspondence between locations along the spectrograph slit and points on the solar disk.

Bruner, Marilyn E.↗

Realization of the National Disposal Facility for Radioactive Waste in Bulgaria - 16611

Radioactive waste is generated in the Republic of Bulgaria from the operation and decommissioning of the country's nuclear power plants and from other sources in research, medical applications, and the industry. The need for building a National Disposal Facility (NDF) is recognized by the Bulgarian government and described and justified in its Environment Impact Assessment Decision. The Bulgarian State Enterprise for Radioactive Waste Management (SERAW) is endeavoring to build a near-surface repository for short-lived low- and intermediate-level radioactive waste (SL-LILW) to discharge its statutory responsibilities in waste management is. The European Union (EU) finances the establishment of the NDF through the Kozloduy International Decommissioning Support Fund (KIDSF). After an international tendering procedure, SERAW placed a contract for the development of the design of the NDF to the Consortium of Westinghouse Electric Spain S.A.R and DBE Technology GmbH of Germany, with ENRESA, the Spanish National Waste Management Agency providing technical review and support. Two Bulgarian companies participate also in the project as subcontractors - EQE Bulgaria and to a lesser extent KK-Project. The repository project official name is 'Technical Design and ISAR Preparation for the National Disposal Facility at Bulgaria', usually abbreviated as 'R-Project 5'. After obtaining SERAW's approval for the preferred repository conceptual design variant, the R Project 5 focused on developing the Technical Design on the one hand, and on preparing the Intermediate Safety Analysis Report (ISAR) to demonstrate the safety and suitability of the proposed NDF design on the other. These documents were handed over to the Bulgarian Nuclear Regulatory Authority (BNRA) as well as to the different authorities involved in the comprehensive licensing process required for nuclear facilities in the country. The corresponding permits have mostly been received or are expected for early 2016. In the last quarter of 2015 the procurement procedure for repository construction as turn-key project was started with the pre-qualification of possible constructors for the Phase I repository realization on a lump sum contract basis. Repository construction is now expected to start in 2016, with the start of waste disposal now scheduled for around 2020. With the realization of the Bulgarian National Disposal Facility an important milestone for waste disposal in the European Union is about to be achieved. This paper is a sequel of previously presented papers on the NDF construction, now including details of the complex licensing process that this disposal facility underwent, now in its final stages. (authors)

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