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At least 649 records · Page 36

Clustering Days with Similar Airport Weather Conditions

On any given day, traffic flow managers must often rely on past experience and intuition when developing traffic flow management initiatives that mitigate imbalances between the aircraft demand and the weather impacted airport capacity. The goal of this study was to build on recent efforts to apply data mining classification and clustering algorithms to vast archives of historical weather and air traffic data to identify patterns and past decisions that can ultimately inform day-of-operations decision-making. More specifically, this study identified similar weather impacted days at select U.S. airports, and analyzed the traffic management initiatives implemented on these representative days. The identification of the similar days was accomplished by applying a decision tree algorithm to the hourly Localized Aviation Model Output Statistics Program observations and the arrival delays for Newark Liberty International Airport. The branches from the trained decision tree were subsequently pruned to identify four weather conditions that resulted in medium to high delays for the arrivals scheduled to Newark in 2012. Using these weather conditions, four, daily airport-level Weather Impacted Traffic Index values were calculated using the Localized Aviation Model Output Statistics Program observations and the 2012 scheduled arrival counts from the FAAs Aviation System Performance Metric system. The four, daily Weather Impacted Traffic Index values for 2012 were subsequently clustered using an Expectation Maximization clustering algorithm, and nine unique types of weather days at Newark were identified. By far the most prominent type of day at Newark was a day associated with relatively good weather conditions, where there was little convective activity, winds were low, ceilings and visibility were high and there was little precipitation. Moderate levels of convective activity characterized the next most prominent type of day. Days with persistently high winds or low ceiling and visibility levels were relatively rare in 2012. Lastly, the frequency at which Ground Delay Programs, Ground Stops and Miles-in-Trail restrictions were implemented on each of the typical types of days at Newark were analyzed. Based on the results, it does appear as if the usage of Miles-in-Trail, Ground Delay Program and Ground Stop restrictions correlates well with the severity of the weather associated with each unique type of weather impacted day at Newark. Furthermore, the results demonstrate that it is feasible to use historical weather and air traffic archives to provide guidance on the types of traffic management restrictions to implement in response to the weather conditions impacting an airport.

traffic flow management↗

Clustering Days with Similar Airport Weather Conditions

On any given day, traffic flow managers must often rely on past experience and intuition when developing traffic flow management initiatives that mitigate imbalances between the aircraft demand and the weather impacted airport capacity. The goal of this study was to build on recent efforts to apply data mining classification and clustering algorithms to vast archives of historical weather and air traffic data to identify patterns and past decisions that can ultimately inform day-of-operations decision-making. More specifically, this study identified similar weather impacted days at select U.S. airports, and analyzed the traffic management initiatives implemented on these representative days. The identification of the similar days was accomplished by applying a decision tree algorithm to the hourly Localized Aviation Model Output Statistics Program observations and the arrival delays for Newark Liberty International Airport. The branches from the trained decision tree were subsequently pruned to identify four weather conditions that resulted in medium to high delays for the arrivals scheduled to Newark in 2012. Using these weather conditions, four, daily airport-level Weather Impacted Traffic Index values were calculated using the Localized Aviation Model Output Statistics Program observations and the 2012 scheduled arrival counts from the FAAs Aviation System Performance Metric system. The four, daily Weather Impacted Traffic Index values for 2012 were subsequently clustered using an Expectation Maximization clustering algorithm, and nine unique types of weather days at Newark were identified. By far the most prominent type of day at Newark was a day associated with relatively good weather conditions, where there was little convective activity, winds were low, ceilings and visibility were high and there was little precipitation. Moderate levels of convective activity characterized the next most prominent type of day. Days with persistently high winds or low ceiling and visibility levels were relatively rare in 2012. Lastly, the frequency at which Ground Delay Programs, Ground Stops and Miles-in-Trail restrictions were implemented on each of the typical types of days at Newark were analyzed. Based on the results, it does appear as if the usage of Miles-in-Trail, Ground Delay Program and Ground Stop restrictions correlates well with the severity of the weather associated with each unique type of weather impacted day at Newark. Furthermore, the results demonstrate that it is feasible to use historical weather and air traffic archives to provide guidance on the types of traffic management restrictions to implement in response to the weather conditions impacting an airport.

weather↗

Persistent Expression Changes of Fibrosis-Related Genes in the Lung Tissues of Rats Exposed to Lunar Dust Particles

The Moon's surface is covered by a layer of fine, potential reactive dust. Lunar dust contain about 1‐2% of very fine respirable dust (less than 3 micrometers). The habitable area of any lunar landing vehicle and outpost would inevitably be contaminated with lunar dust that could pose a health risk. The purpose of the study is to evaluate the toxicity of Apollo moon dust in rodents to assess the health risk of dust exposures to humans. One of the particular interests in the study is to evaluate dust‐induced changes of the expression of fibrosis‐related genes, and to identify specific signaling pathways involved in lunar dustinduced toxicity. F344 rats were exposed for 4 weeks (6h/d; 5d/wk) in nose‐only inhalation chambers to concentrations of 0 (control air), 2.1, 6.8, 21, and 61 milligrams per cubic meters of lunar dust. Five rats per group were euthanized at 1 day, 1 week, 1 month, and 3 months after the last inhalation exposure. The bronchoalveolar lavage fluid (BALF) was collected by lavaging with phosphate‐buffered saline (PBS). A zymosan‐induced luminolbased chemiluminescence assay was used to assess the activity of BAL cells. The lavaged lung tissue was snap frozen in LN2 and total RNA was isolated using the Qigen RNeasy kit. The expression of 84 fibrosisrelated genes were analyzed using the RT2 Profiler PCR Array technique. The expression of 18 genes of interest were further measured using real‐time PCR technique in all the samples. 10 out of 18 genes of interest showed persistently significant expression changes in the local lung tissue exposed to lunar dust, indicating a prolonged proinflammatory response. The expressions of several of these genes were dose‐ and time‐dependent and were significantly correlated with other pathological parameters. The potential signaling pathways and upstream regulators were further analyzed using IPA pathway analysis tool based on the gene expression data. The data presented in this study, for the first time, explore the molecular mechanisms of lunar dust induced toxicity, contributing not only the risk assessment for future space exploration, but also understandings of the dust‐induced toxicity in humans on earth.

Zhang, Ye↗

Indigenous Organic Matter Associated with Unusual Low Temperature Aqueous Secondary Phases in the Mars Meteorite Nakhla

In freshly fractured chips of the Mars meteorite Nakhla, we found carbonaceous phases intimately associated with secondary aqueous alteration phases, both mineral and amorphous, interpreted to have formed through the low-temperature, mineral-water dissolution of the host Martian basalt.We have characterized the nature of carbonaceous matter and spatially associated secondary phases within Nakhla using a multidisciplinary suite of optical and electron beam instrumentation(Thomas-Keprta et al., 2022). Secondary Phases: The preserved secondary mineral phases are best described as ‘juvenile’ hydrated amorphous silica formed when water interacts with mafic rocks. Although amorphous silica on Earth rarely persists through geologic time due to alteration into other phases, e.g.,microcrystalline opal-CT and eventually quartz, the lack of maturation of primarily amorphous silica with embedded nano phase ferrihydrite in Nakhla infers these phases formed in a limited water environment by low temperature, circumneutral pH fluids stabilized by the presence of coexisting amorphous silica.Additionally, we report the presence of the ferrous hydroxycarbonate mineral chukanovite (Fe2(OH)2CO3)within some of the secondary mineral aggregates studied. Organic Matter:Indigenous Nakhla carbonaceous matter is present both in condensed phases and in a dispersed state spatially associated with secondary alteration phases. In the former, discrete refractory micron to submicron assemblages were identified that appear macromolecular in nature and, in several cases, associated with F and, in one case, significant N. While organically bound Fhas yet to be detected remotely on Mars, the identification of organic N within one of the carbonaceous phases is considered a prerequisite for Martian astrobiological potential. Summary: Neither the intimate association of carbonaceous matter with secondary phases nor the identification of chukanovite have been previously reported in any of the Martian meteorites.A variety of habitability-related metastable solid-phase, oxidation-reduction, and organic-molecular sample attributes in Nakhla formed hundreds of millions of years ago near Mars’ surface; these alteration products persisted on Mars until very recentlyand resemble the amorphous materials observed at Gale crater by Mars Science Laboratory CuriosityRover (Rampe et al., 2020).Similar phases may be expected to occur elsewhere on Mars (e.g., Jezerocrater). References: Rampe E. B. et al.(2020) Mineralogy and geochemistry of sedimentary rocks and eolian sediments in Gale crater, Mars: A review after six Earth years of exploration with Curiosity.Geochemistry80, 125605; Thomas-Keprta K.L. et al. (2022) Indigenous carbon-rich matter associated with unusual aqueous alteration features in Nakhla: Complex formation and preservation history. Geochim. et Cosmochim. Acta320, 41-78 (online).

Mars meteorite↗

Overcoming persistent challenges in putting environmental flow policy into practice: a systematic review and bibliometric analysis

The implementation of environmental flows (e-flows) aims to reduce the negative impacts of hydrological alteration on freshwater ecosystems. Despite the growing attention to the importance of e-flows since the 1970s, actual implementation has lagged. Therefore, we explore the limitations in e-flows implementation, their systemic reasons, and solutions. We conducted a systematic review and a bibliometric analysis to identify peer-reviewed articles published on the topic of e-flows implementation research in the last two decades, resulting in 68 research and review papers. Co-occurrence of terms, and geographic and temporal trends were analyzed to identify the gaps in environmental water management and propose recommendations to address limitations on e-flows implementation. We identify the underlying causes and potential solutions to such challenges in environmental water management. The limitations to e-flow implementation identified were categorized into 21 classes. The most recognized limitation was the competing priorities of human uses of water (n = 29). Many secondary limitations, generally co-occurring in co-causation, were identified as limiting factors, especially for implementing more nuanced and sophisticated e-flows. The lack of adequate hydrological data (n = 24) and ecological data (n = 28) were among the most mentioned, and ultimately lead to difficulties in starting or continuing monitoring/adaptive management (n = 28) efforts. The lack of resource/capacity (n = 21), experimentation (n = 19), regulatory enforcement (n = 17), and differing authorities involved (n = 18) were also recurrent problems, driven by the deficiencies in the relative importance given to e-flows when facing other human priorities. In order to provide a clearer path for successful e-flow implementation, system mapping can be used as a starting point and general-purpose resource for understanding the sociohydrological problems, interactions, and inherited complexity of river systems. Secondly, we recommend a system analysis approach to address competing demands, especially with the use of coupled water-energy modeling tools to support decision-making when hydropower generation is involved. Such approaches can better assess the complex interactions among the hydrologic, ecological, socioeconomic, and engineering dimensions of water resource systems and their effective management. Lastly, given the complexities in environmental water allocation, implementation requires both scientific rigor and proven utility. Consequently, and where possible, we recommend a move from simplistic flow allocations to a more holistic approach informed by hydroecological principles. To ease conflicts between competing water demands, water managers can realize more 'pop per drop' by supporting key components of a flow regime that include functional attributes and processes that enhance biogeochemical cycling, structural habitat formation, and ecosystem maintenance.

54 ENVIRONMENTAL SCIENCES↗

What Are Medical Students in the United States Learning About Radiation Oncology? Results of a Multi-Institutional Survey

Purpose: The purposes of this study were to assess the exposure that medical students (MSs) have to radiation oncology (RO) during the course of their medical school career, as evidenced by 2 time points in current medical training (ie, first vs fourth year; MS1s and MS4s, respectively) and to assess the knowledge of MS1s, MS4s, and primary care physicians (PCPs) about the appropriateness of RT in cancer management in comparison with RO attendings. Methods: We developed and beta tested an electronic survey divided into 3 parts: RO job descriptions, appropriateness of RT, and toxicities of RT. The surveys were distributed to 7 medical schools in the United States. A concordance of >90% (either yes or no) among RO attendings in an answer was necessary to determine the correct answer and to compare with other subgroups using a χ{sup 2} test (P<.05 was significant). Results: The overall response rate for ROs, MS1s, MS4s, and PCPs was 26%; n (22 + 315 + 404 + 43)/3004. RT misconceptions decreased with increasing level of training. More than 1 of 10 MSs did not believe that RT alone could cure cancer. Emergent oncologic conditions for RT (eg, spinal cord compression, superior vena cava syndrome) could not be identified by >1 of 5 respondents. Multiple nontoxicities of RT (eg, emitting low-level radiation from the treatment site) were incorrectly identified as toxicities by >1 of 5 respondents. MS4s/PCPs with an RO rotation in medical school had improved scores in all prompts. Conclusions: Although MS knowledge of general RT principles improves from the first to the fourth year, a large knowledge gap still exists between MSs, current PCPs, and ROs. Some basic misconceptions of RT persist among a minority of MSs and PCPs. We recommend implementing formal education in RO fundamentals during the core curriculum of medical school.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Pressure-stabilized divalent ozonide CaO 3 and its impact on Earth's oxygen cycles

High pressure can drastically alter chemical bonding and produce exotic compounds that defy conventional wisdom. Especially significant are compounds pertaining to oxygen cycles inside Earth, which hold key to understanding major geological events that impact the environment essential to life on Earth. Here we report the discovery of pressure-stabilized divalent ozonide CaO3 crystal that exhibits intriguing bonding and oxidation states with profound geological implications. Our computational study identifies a crystalline phase of CaO 3 by reaction of CaO and O 2 at high pressure and high temperature conditions; ensuing experiments synthesize this rare compound under compression in a diamond anvil cell with laser heating. High-pressure x-ray diffraction data show that CaO 3 crystal forms at 35 GPa and persists down to 20 GPa on decompression. Analysis of charge states reveals a formal oxidation state of -2 for ozone anions in CaO 3 . These findings unravel the ozonide chemistry at high pressure and offer insights for elucidating prominent seismic anomalies and oxygen cycles in Earth’s interior. We further predict multiple reactions producing CaO 3 by geologically abundant mineral precursors at various depths in Earth’s mantle.

58 GEOSCIENCES↗

Room temperature persisting surface charge carriers driven by intense terahertz electric fields in a topological insulator Bi 2 Se 3

Topologically protected surface current is highly promising for next-generation low-dissipation and disorder-tolerant quantum electronics and computing. Yet, electric transport from the co-existing bulk state dominates the responses of the Dirac surface state, especially at elevated temperatures relevant to technological applications. Here, we present an approach that convincingly showcases the generation, disentanglement, and precise control of enduring surface charge carriers on a topological insulator, Bi 2 Se 3 , with high bulk conductivity, all achieved at room temperature. By using pump–probe modulation spectroscopy under ultrabroadband driving tunable from 4 meV to 1.55 eV, we show the terahertz (THz) field-induced surface carriers by discovering their initial temporal responses dominant over high density trivial bulk carriers. Strikingly, the response of the induced surface carrier responses persists for more than ~5 ps and is enhanced by reducing pump photon energy. The dynamics and lifetime of the distinct surface response manifest themselves as the enhanced THz pump-induced THz transmission, which directly correlates with the transient negative THz conductivity. Increasing the THz driving field reduces the induced surface carrier lifetime and identifies, particularly, an optimal pump field of E s ~ 224 kV cm -1 for generating the dominant surface response relative to the bulk. This surface carrier dominant regime is suppressed by a joint effect of enhanced surface-bulk scattering and a more rapid saturation of surface excitation compared to the bulk that sets in above E s . The controllability of room temperature topologically surface carriers through pump photon energy offer compelling possibilities for extending this approach to other topological complex materials.

36 MATERIALS SCIENCE↗

Evaluation of Leading Modes of Climate Variability in the CMIP Archives

The adequate simulation of internal climate variability is key for our understanding of climate as it underpins efforts to attribute historical events, predict on seasonal and decadal time scales, and isolate the effects of climate change. Here the skill of models in reproducing observed modes of climate variability is assessed, both across and within the CMIP3, CMIP5, and CMIP6 archives, in order to document model capabilities, progress across ensembles, and persisting biases. A focus is given to the well-observed tropical and extratropical modes that exhibit small intrinsic variability relative to model structural uncertainty. These include El Niño–Southern Oscillation (ENSO), the Pacific decadal oscillation (PDO), the North Atlantic Oscillation (NAO), and the northern and southern annular modes (NAM and SAM). Significant improvements are identified in models’ representation of many modes. Canonical biases, which involve both amplitudes and patterns, are generally reduced across model generations. For example, biases in ENSO-related equatorial Pacific sea surface temperature, which extend too far westward, and associated atmospheric teleconnections, which are too weak, are reduced. Stronger tropical expression of the PDO in successive CMIP generations has characterized their improvement, with some CMIP6 models generating patterns that lie within the range of observed estimates. For the NAO, NAM, and SAM, pattern correlations with observations are generally higher than for other modes and slight improvements are identified across successive model generations. Finally, for ENSO and PDO spectra and extratropical modes, changes are small compared to internal variability, precluding definitive statements regarding improvement.

54 ENVIRONMENTAL SCIENCES↗

The impact of freeze-thaw history on soil carbon response to experimental freeze-thaw cycles

This dataset contains data used for the paper "The impact of freeze-thaw history on soil carbon response to experimental freeze-thaw cycles". The Related References field will be updated with a full citation when available.Freeze-thaw is a disturbance process in cold regions where permafrost soils are becoming vulnerable to temperature fluctuations above 0˚C. Freeze-thaw alters soil physical and biogeochemical properties with implications for carbon persistence and emissions in Arctic landscapes. We examined whether different freeze-thaw histories in two soil systems led to contrasting biogeochemical responses under a laboratory-controlled freeze-thaw incubation. We investigated controls on soil organic matter (SOM) composition through Fourier-transform ion cyclotron resonance mass spectroscopy (FT-ICR-MS) to identify nominal carbon oxidation states and relative abundances of aliphatic-type carbon molecules in both surface and subsurface soils. Soil cores (~ 60 cm-depth) were sampled from two sites in Alaskan permafrost landscapes with different in situ freeze-thaw characteristics: Healy (>40 freeze-thaw cycles annually) and Toolik (<150 freeze-thaw cycles annually). FT-ICR-MS was coupled with in situ temperature data and soil properties (i.e., soil texture, mineralogy) to assess (1) differences in SOM composition associated with previous freeze-thaw history and (2) sensitivity to experimental freeze-thaw in the extracted cores. Control (freeze-only) samples showed greater carbon oxidation in Healy soils compared with Toolik, even in lower mineral horizons where freeze-thaw history was comparable across both sites. Healy showed the most loss of carbon compounds following experimental freeze-thaw in the lower mineral depths, including a decrease in aliphatics. Toolik soils responded more slowly to freeze-thaw as shown by intermediary carbon oxidation distributed across multiple carbon compound classes. Variations in the response of permafrost carbon chemistry to freeze-thaw is an important factor for predicting changes in soil function as permafrost thaws in high northern latitudes.This dataset contains a compressed (.zip) archive of the data and R scripts used for this manuscript. The dataset includes files in .csv format, which can be accessed and processed using MS Excel or R. This archive can also be accessed on GitHub at https://github.com/Erin-Rooney/FTC-FTICR (DOI 10.5281/zenodo.6533064).

54 ENVIRONMENTAL SCIENCES↗

Persistent Sub-Yearly Chromospheric Variations in Lower Main-Sequence Stars: Tau Booe and alpha Com

The recent discoveries of extrasolar planetary systems around lower main-sequence stars such as tau Booe (HD 120136) has prompted further investigation into their stellar activity. A cursory analysis of tau Booe for cyclic chromospheric activity, based on its 30-yr record of Ca 2 H and K fluxes obtained as part of the HK Project from Mount Wilson Observatory, finds an intermediate, sub-yearly period (approximately 117 d) in chromospheric activity in addition to, and separate from, both its rotation (3.3 d) and long-term variability. As a persistent subyearly period in surface magnetic activity is unprecedented, we investigate this apparent anomaly further by examining chromospheric activity levels of other stars with similar mass, searching for variability in chromospheric activity with periods of less than one year, but longer than measured or predicted rotation. An examination of the time series of 40 mid-to-late F dwarfs yielded one other star for further analysis: alpha Com (HD 114378, P approximately 132 d). The variations for these two stars were checked for persistence and coherence. Based on these determinations, we eliminate the possibilities of rotation, long-term activity cycle, and the evolution of active regions as the cause of this variation in both stars. In particular, for tau Booe we infer that the phenomenon may be chromospheric in origin; however, beyond this, it is difficult to identify anything further regarding the cause of the activity variations, or even whether the observed modulation in the two stars have the same origin.

Maulik, Davesh↗

Defect energy levels and persistent luminescence in Cu-doped ZnS

Zinc sulfide (ZnS) based materials are widely used in many applications. Yet, due to a lack of detailed knowledge of defect energy levels, the electrical properties and luminescence mechanisms in the materials still give rise to debate. Here, we report a first-principles study of native point defects and impurities in zincblende ZnS using hybrid density-functional calculations. We find that cation and anion vacancies and antisite defects introduce deep defect levels in the band gap and can act as donors or acceptors depending on the position of the Fermi level. The substitutional impurity Cu Zn acts as a deep acceptor and thus does not contribute to p-type conductivity. Substitutional impurities Al Zn and Cl S , on the other hand, are shallow donors. More importantly, we identify the isolated (i.e., unassociated) Cu Zn as a source of the green luminescence observed in ZnS-based phosphors and Cu Zn – Al Zn and Cu Zn – Cl S defect complexes as sources of blue luminescence. Further, the materials may have both green and blue emissions with the relative intensity dependent on the ratio between the unassociated defect and defect complex concentrations, which is also consistent with experimental observations.

36 MATERIALS SCIENCE↗

Phase transitions and dimensional cross-over in layered confined solids

The nature of solid phases and cross-over of order–disorder phase transitions from two-dimensional (2D) layers to three-dimensional (3D) bulk in confined atomic systems remain largely unexplained. To this end, we consider noble gases and aluminum confined between graphene sheets at different pressures and temperatures. Using crystal structure search methods and molecular dynamics based on machine-learned potentials with quantum-mechanical accuracy, we identify structures of multilayer confined solids that deviate from simple close packing. Upon heating, we find that confined 2D monolayers melt according to the two-step continuous Kosterlitz–Thouless–Halperin–Nelson–Young theory. However, multilayer solids transition continuously into an intermediate layered-hexatic phase before melting discontinuously into an isotropic liquid. This intermediate phase persists at least up to 12 layers studied here. This change can be qualitatively understood based on the cross-over from 2D topological defects toward 3D ones during melting as the number of layers increases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Microbial Communities Influence Soil Dissolved Organic Carbon Concentration by Altering Metabolite Composition

Rapid microbial growth in the early phase of plant litter decomposition is viewed as an important component of soil organic matter (SOM) formation. However, the microbial taxa and chemical substrates that correlate with carbon storage are not well resolved. The complexity of microbial communities and diverse substrate chemistries that occur in natural soils make it difficult to identify links between community membership and decomposition processes in the soil environment. To identify potential relationships between microbes, soil organic matter, and their impact on carbon storage, we used sand microcosms to control for external environmental factors such as changes in temperature and moisture as well as the variability in available carbon that exist in soil cores. Using Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) on microcosm samples from early phase litter decomposition, we found that protein- and tannin-like compounds exhibited the strongest correlation to dissolved organic carbon (DOC) concentration. Proteins correlated positively with DOC concentration, while tannins correlated negatively with DOC. Through random forest, neural network, and indicator species analyses, we identified 42 bacterial and 9 fungal taxa associated with DOC concentration. The majority of bacterial taxa (26 out of 42 taxa) belonged to the phylum Proteobacteria while all fungal taxa belonged to the phylum Ascomycota. Additionally, we identified significant connections between microorganisms and protein-like compounds and found that most taxa (12/14) correlated negatively with proteins indicating that microbial consumption of proteins is likely a significant driver of DOC concentration. This research links DOC concentration with microbial production and/or decomposition of specific metabolites to improve our understanding of microbial metabolism and carbon persistence.

59 BASIC BIOLOGICAL SCIENCES↗

A derecho climatology (2004–2021) in the United States based on machine learning identification of bow echoes

Due to their persistent widespread severe winds, derechos pose significant threats to human safety and property, with impacts comparable to many tornadoes and hurricanes. Yet, automated detection of derechos remains challenging due to the absence of spatiotemporally continuous observations and the complex criteria employed to define the phenomenon. This study presents an objective derecho detection approach capable of automatically identifying derechos through both observations and model results. The approach is grounded in a physically based definition of derechos and integrates three algorithms: (1) the Python Flexible Object Tracker (PyFLEXTRKR) algorithm to track mesoscale convective systems (MCSs), (2) a semantic segmentation convolutional neural network to identify bow echoes, and (3) a comprehensive classification algorithm to detect derechos within MCS life cycles and distinguish derecho-producing from non-derecho-producing MCSs. Using this approach, we developed a novel high-resolution (4 km and hourly) observational dataset of derechos and accompanying derecho-producing MCSs over the United States east of the Rocky Mountains from 2004 to 2021. The dataset consists of two subsets based on different gust speed data sources and is analyzed to document the climatology of derechos in the United States. On average, 12–15 derechos are identified per year, aligning with previous estimations (∼6–21 events annually). The spatial distribution and seasonal variation patterns are consistent with prior studies, showing peak occurrences in the Great Plains and the Midwest during the warm season. Additionally, during the study period, derechos account for approximately 3.1 % of measured damaging gusts (≥25.93 m s−1) over the eastern United States. The dataset is publicly available at https://doi.org/10.5281/zenodo.14835362 (Li et al., 2025).

54 ENVIRONMENTAL SCIENCES↗

High charge state carbon and oxygen ions in Earth's equatorial quasi-trapping region

Observations of energetic (1.5 - 300 keV/e) medium-to-high charge state (+3 less than or equal to Q less than or equal to +7) solar wind origin C and O ions made in the quasi-trapping region (QTR) of Earth's magnetosphere are compared to ion trajectories calculated in model equatorial magnetospheric magnetic and electric fields. These comparisons indicate that solar wind ions entering the QTR on the nightside as an energetic component of the plasma sheet exit the region on the dayside, experiencing little or no charge exchange on the way. Measurements made by the CHarge Energy Mass (CHEM) ion spectrometer on board the Active Magnetospheric Particle Tracer Explorer/Charge Composition Explorer (AMPTE/CCE) spacecraft at 7 less than L less than 9 from September 1984 to January 1989 are the source of the new results contained herein: quantitative long-term determination of number densities, average energies, energy spectra, local time distributions, and their variation with geomagnetic disturbance level as indexed by Kp. Solar wind primaries (ions with charge states unchanged) and their secondaries (ions with generally lower charge states produced from primaries in the magnetosphere via charge exchange)are observed throughout the QTR and have distinctly different local time variations that persist over the entire 4-year analysis interval. During Kp larger than or equal to 3 deg intervals, primary ion (e.g., O(+6)) densities exhibit a pronounced predawn maximum with average energy minimum and a broad near-local-noon density minimum with average energy maximum. Secondary ion (e.g., O(+5)) densities do not have an identifiable predawn peak, rather they have a broad dayside maximum peaked in local morning and a nightside minimum. During Kp less than or equal to 2(-) intervals, primary ion density peaks are less intense, broader in local time extent, and centered near midnight, while secondary ion density local time variations diminish. The long-time-interval baseline helps to refine and extend previous observations; for example, we show that ionospheric contribution to O(+3)) is negligible. Through comparison with model ion trajectories, we interpret the lack of pronounced secondary ion density peaks colocated with the primary density peaks to indicate that: (1) negligible charge exchange occurs at L greater than 7, that is, solar wind secondaries are produced at L less than 7, and (2) solar wind secondaries do not form a significant portion of the plasma sheet population injected into the QTR. We conclude that little of the energetic solar wind secondary ion population is recirculated through the magnetosphere.

Christon, S. P.↗

FY13 High Performance EVA Glove (HPEG) Collaboration: Glove Injury Data Mining Effort - Training Data Overview

From the time hand-intensive tasks were first created for EVAs, discomforts and injuries have been noted.. There have been numerous versions of EVA gloves for US crew over the past 50 years, yet pain and injuries persist. The investigation team was tasked with assisting in a glove injury assessment for the High Performance EVA Glove (HPEG) project.center dot To aid in this assessment, the team was asked to complete the following objectives: - First, to develop the best current understanding of what glove-related injuries have occurred to date, and when possible, identify the specific mechanisms that caused those injuries - Second, to create a standardized method for comparison of glove injury potential from one glove to another. center dot The overall goal of the gloved hand injury assessment is to utilize ergonomics in understanding how these glove injuries are occurring, and to propose mitigations to current designs or design changes in the next generation of EVA gloves.

Reid, Christopher↗

Megadroughts in Southwestern North America in ECHO-G Millennial Simulations and Their Comparison to Proxy Drought Reconstructions

Simulated hydroclimate variability in millennium-length forced transient and control simulations from the ECHAM and the global Hamburg Ocean Primitive Equation (ECHO-G) coupled atmosphere-ocean general circulation model (AOGCM) is analyzed and compared to 1000 years of reconstructed Palmer drought severity index (PDSI) variability from the North American Drought Atlas (NADA). The ability of the model to simulate megadroughts in the North American southwest is evaluated. (NASW: 25deg42.5degN, 125deg-105degW). Megadroughts in the ECHO-G AOGCM are found to be similar in duration and magnitude to those estimated from the NADA. The droughts in the forced simulation are not, however, temporally synchronous with those in the paleoclimate record, nor are there significant differences between the drought features simulated in the forced and control runs. These results indicate that model-simulated megadroughts can result from internal variability of the modeled climate system rather than as a response to changes in exogenous forcings. Although the ECHO-G AOGCM is capable of simulating megadroughts through persistent La Nina-like conditions in the tropical Pacific, other mechanisms can produce similarly extreme NASW moisture anomalies in the model. In particular, the lack of low-frequency coherence between NASW soil moisture and simulated modes of climate variability like the El Nino-Southern Oscillation, Pacific decadal oscillation, and Atlantic multidecadal oscillation during identified drought periods suggests that stochastic atmospheric variability can contribute significantly to the occurrence of simulated megadroughts in the NASW. These findings indicate that either an expanded paradigm is needed to understand multidecadal hydroclimate variability in the NASW or AOGCMs may incorrectly simulate the strength and/or dynamics of the connection between NASW hydroclimate variability and the tropical Pacific.

variability↗