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All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Electrical Discharge Machining of Additively Manufactured Superalloys Containing Oxide Dispersions

Superalloys can be strengthened by oxide dispersions to potentially improve their mechanical properties at high temperatures. Additive manufacturing has opened new paths for introducing oxide particles into superalloys with increased processing flexibility, to potentially provide oxide dispersion strengthening. Numerically controlled electrical discharge machining (EDM) has often been used as a machining process for initial sectioning, detailed roughing, and even finishing operations of conventional superalloys. The objective of this study was to examine how additively manufactured superalloys containing oxide dispersions respond when sectioned using EDM. Consistent sections of several superalloys, two containing an oxide dispersion, were sliced using a typical EDM machine with standard brass wire and a typical roughing condition set. Roughness, microstructure, and residual stress at the EDM surfaces were compared for the varied superalloys.

superalloys↗
NASA NTRS2013

Transmission Electron Microscopy of Itokawa Regolith Grains

Introduction: In a remarkable engineering achievement, the JAXA space agency successfully recovered the Hayabusa space-craft in June 2010, following a non-optimal encounter and sur-face sampling mission to asteroid 25143 Itokawa. These are the first direct samples ever obtained and returned from the surface of an asteroid. The Hayabusa samples thus present a special op-portunity to directly investigate the evolution of asteroidal sur-faces, from the development of the regolith to the study of the effects of space weathering. Here we report on our preliminary TEM measurements on two Itokawa samples. Methods: We were allocated particles RA-QD02-0125 and RA-QD02-0211. Both particles were embedded in low viscosity epoxy and thin sections were prepared using ultramicrotomy. High resolution images and electron diffraction data were ob-tained using a JEOL 2500SE 200 kV field-emission scanning-transmission electron microscope. Quantitative maps and anal-yses were obtained using a Thermo thin-window energy-dispersive x-ray (EDX) spectrometer. Results: Both particles are olivine-rich (Fo70) with μm-sized inclusions of FeS and have microstructurally complex rims. Par-ticle RA-QD02-0125 is rounded and has numerous sub-μm grains attached to its surface including FeS, albite, olivine, and rare melt droplets. Solar flare tracks have not been observed, but the particle is surrounded by a continuous ~50 nm thick, stuctur-ally disordered rim that is compositionally similar to the core of the grain. One of the surface adhering grains is pyrrhotite show-ing a S-depleted rim (~8-10 nm thick) with nanophase Fe metal grains (<5 nm) decorating the outermost surface. The pyrrhotite displays a complex superstructure in its core that is absent in the S-depleted rim. Particle RA-QD02-0211 contains solar flare particle tracks (~2x109 cm-2) and shows a structurally disordered rim ~100 nm thick. The track density corresponds to a surface exposure of ~103-104 years based on the track production rate of [1]. The dis-ordered rim is nanocrystalline with minor amorphous material between crystalline domains. Quantitative element maps show the outermost ~10 nm of the disordered rim is Si-rich. Discussion and Conclusions: Both particles record the ef-fects of space weathering processes on Itokawa. Noguchi et al. [2] proposed that the disordered rims they observed on Itokawa particles largely result from solar wind radiation damage and we arrive at a similar conclusion for the two particles we analyzed. The microstructure of the S-depleted layer on the pyrrhotite grain in RA-QD02-0125 is similar to that observed in troilite irradiated with ~1018 4 kV He+ [3, 4]. Prolonged irradiation has also been shown to disorder pyrrhotite such that the superstructure reflec-tions are lost [5].

Keller, Lindsay P.↗
DOE OSTI2022

Advantages of tandem versus simultaneous operation: The case of isomerization/hydrogenation of terpinolene epoxide to Terpinen-4-ol using a Ni/TiO 2 -SiO 2 bifunctional catalyst

The conversion of terpinolene epoxide to terpinen-4-ol is a desirable chemical transformation for the production of a valuable intermediate. Here this report describes a one-pot, two-step system for the reaction that uses a bifunctional Ni/TiO 2 -SiO 2 catalyst with isomerization and hydrogenation capabilities. The TiO 2 -SiO 2 serves to isomerize the starting epoxide. The Ni component works to hydrogenate the allylic double bond. The tandem system achieves a high 64% yield of terpinen-4-ol. X-ray diffraction analysis showed that TiO 2 -SiO 2 was a mixed binary oxide, and Fourier transform infrared spectroscopy of adsorbed pyridine suggested that acid sites were mainly Lewis acid sites. Electron microscopy showed that the Ni/TiO 2 -SiO 2 catalyst consisted of spherical particles comprising a titanosilicate phase with highly dispersed zero-valent Ni or anatase on the surface. Additionally, there was strong interaction between Ni and the TiO 2 -SiO 2 mixed oxides. Control kinetic experiments demonstrated that the tandem use of the catalysts was more effective than simultaneous operation.

42 ENGINEERING↗
NASA NTRS1973

A critical survey of wave propagation and impact in composite materials

A review of the field of stress waves in composite materials is presented covering the period up to December 1972. The major properties of waves in composites are discussed and a summary is made of the major experimental results in this field. Various theoretical models for analysis of wave propagation in laminated, fiber and particle reinforced composites are surveyed. The anisotropic, dispersive and dissipative properties of stress pulses and shock waves in such materials are reviewed. A review of the behavior of composites under impact loading is presented along with the application of wave propagation concepts to the determination of impact stresses in composite plates.

Moon, F. C.↗
NASA NTRS1973

Development of improved electroforming technique

Techniques were studied to reinforce or strengthen electroformed nickel to allow a fuller utilization of electroforming as a reliable and low cost fabrication technique for regenerately cooled thrust chambers. Techniques for wire wrapping while electrodepositing were developed that can result in a structurally strong wall with less weight than a conventional electroformed wall. Also a technique of codepositing submicron sized THO2 particles with the nickel to form a dispersion strengthened structure was evaluated. The standard nickel cylinders exhibited an average hoop strength of 80,000 psi with a yield strength of 65,000 psi and a modulus of 25.6 x 10 to the 6th power psi. The as produced dispersion strengthened nickel showed a hoop strength of 97,000 psi with a yield strength of 67,000 psi. This is an increase of 17,000 psi or 21% over the standard nickel hoop strength. The wire wrapping cylinders showed an increased strength over the standard nickel test samples of 26,000 to 66,800 psi which is in the range of 26 to 104% increase in strength over the base standard nickel. These latter test results are indicative of a volume percent wire reinforcement from 15 to 31. The measured hoop strengths agree with calculated composite strengths based upon rule of mixtures.

Mccandles, L. C.↗
NASA NTRS1978

Gravitational N-body problem on the accretion process of terrestrial planets

Numerical integration of the gravitational N-body problem has been carried out for a variety of protoplanetary clusters in the range N = 100 to 200. Particles are assumed to coagulate at collisions irrespective of relative velocity and mass ratio of the particles. It is shown graphically how the dispersed N-bodies accumulate to a single planet through mutual collisions. The velocity distribution and size distribution of bodies are also investigated as functions of time in the accretion process. Accretion rates of planets are found to be dependent strongly on the initial number density distribution, the initial size distribution, and the initial velocity distribution of bodies. Formation of satellites of about 10% in the planet mass is common to most cases in the present study. A substantial mass of bodies also escapes from the cluster. Many satellites and escapers formed during the accretion process of planets may be source materials of heavy bombardment in the early history of planets.

Matsui, T.↗
NASA NTRS1978

Multiphase dispersions by crystallization processing

The interaction between second-phase particles and crystal-liquid interfaces in the solidification process has been studied in ground-based experiments and experiments under microgravity conditions. An analysis of these data with a view toward the solidification processing of composite materials reveals a pronounced difference between high entropy of fusion and low entropy of fusion matrix materials, as well as a pronounced effect of differences in the thermal conductivity of particles and liquid on the behavior of materials. Effects of liquid viscosity surface topography of the particles, particle chemistry, and overall particle shape examined.

Uhlmann, D. R.↗
NASA NTRS1980

Preparation of monotectic alloys having a controlled microstructure by directional solidification under dopant-induced interface breakdown

Monotectic alloys having aligned spherical particles of rods of the minor component dispersed in a matrix of the major component are prepared by forming a melt containing predetermined amounts of the major and minor components of a chosen monotectic system, providing in the melt a dopant capable of breaking down the liquid solid interface for the chosen alloy, and directionally solidfying the melt at a selected temperature gradient and a selected rate of movement of the liquid-solid interface (growth rate). Shaping of the minor component into spheres or rods and the spacing between them are controlled by the amount of dopant and the temperature gradient and growth rate values. Specific alloy systems include Al Bi, Al Pb and Zn Bi, using a transition element such as iron.

Parr, R. A.↗
NASA NTRS1979

Investigations of submicron sized metal particles in glass coatings of lunar breccia 15286

Almost all the submicron metal particles in the glass coating of breccia 15286 are rounded and contain two phases, metal and sulfide (FeS). The Ni content of the metal phase as determined by scanning transmission electron microscope X-ray analysis ranged from 9.4 to 15.5 wt %. The sulfide was nearly stoichiometric troilite containing up to 1.3 wt % Ni. The close chemical and microstructural similarities between the coarse (greater than 1-micron) and the submicron sized metal indicate a common origin probably as meteoritic debris. Metal-silicate melt experiments under controlled oxygen partial pressured indicate that the metal particles may have formed from a fine dispersion of immiscible metal-sulfide droplets into an impact-generated silicate melt.

Mehta, S.↗
NASA NTRS1982

Experimental program on nucleation and structure in undercooled melts

Undercooling and structural refinements in droplets of molten metal levitated in an induction field and/or by dispersion in a fluid carrier were studied. Nickel base and lower melting point alloys levitated in molten carrier fluids are considered. The dispersion of molten alloy droplets in a high temperature fluid following the procedures developed by Perepezko and co-workers for lower melting point alloys; obtaining a similar dispersion by room temperature mechanical mixing of particles of the metal and solidified liquid carrier; and solidification of single relatively large droplets in a transparent fluid carrier, enabling high-speed temperature measurement of the recalescence and subsequent cooling behavior are described.

Source record↗
NASA NTRS1984

Predictions of lithium interactions with earth's bow shock in the presence of wave activity

The results of a test-particle simulation studying the movement of a lithium tracer ion injected upstream of the bow shock are reported. Wave activity consists of parallel and antiparallel propagating Alfven waves characterized by a frequency power spectrum within a frequency or range of amplitudes defined separately in the upstream and downstream regions. The results show that even a moderate level of wave activity can substantially change the results obtained in the absence of waves. Among the effects observed are: (1) increased ion transmission; (2) both the average energy gain and spread about the average are increased for transmitted and reflected particles; (3) the average final pitch angle for transmitted particles tends to 90 deg, and the spread of reflected particles is reduced; and (4) the spatial dispersion of the ions on the bow shock after a single encounter is increased.

Decker, R. B.↗
NASA NTRS1984

Electrocatalyst advances for hydrogen oxidation in phosphoric acid fuel cells

The important considerations that presently exist for achieving commercial acceptance of fuel cells are centered on cost (which translates to efficiency) and lifetime. This paper addresses the questions of electrocatalyst utilization within porous electrode structures and the preparation of low-cost noble metal electrocatalyst combinations with extreme dispersions of the metal. Now that electrocatalyst particles can be prepared with dimensions of 10 A, either singly or in alloy combinations, a very large percentage of the noble metal atoms in a crystallite are available for reaction. The cost savings for such electrocatalysts in the present commercially driven environment are considerable.

Stonehart, P.↗
NASA NTRS1990

Collisional electrostatic ion cyclotron waves as a possible source of energetic heavy ions in the magnetosphere

A new mechanism is proposed for the source of energetic heavy ions (NO/+/, O2/+/, and O/+/) found in the magnetosphere. Simulations using a multispecies particle simulation code for resistive current-driven electrostatic ion cyclotron waves show transverse and parallel bulk heating of bottomside ionospheric heavy ion populations. The dominant mechanism for the transverse bulk heating is resonant ion heating by wave-particle ion trapping. Using a linear kinetic dispersion relation for a magnetized, collisional, homogenous, and multiion plasma, it is found that collisional electrostatic ion cyclotron waves near the NO(+), O2(+), and O(+) gyrofrequencies are unstable to field-aligned currents of 50 microA/sq m for a typical bottomside ionosphere.

Providakes, Jason↗
NASA NTRS1991

A novel gas-droplet numerical method for spray combustion

This paper presents a non-iterative numerical technique for computing time-dependent gas-droplet flows. The method is a fully-interacting combination of Eulerian fluid and Lagrangian particle calculation. The interaction calculations between the two phases are formulated on a pressure-velocity coupling procedure based on the operator-splitting technique. This procedure eliminates the global iterations required in the conventional particle-source-in-cell (PSIC) procedure. Turbulent dispersion calculations are treated by a stochastic procedure. Numerical calculations and comparisons with available experimental data, as well as efficiency assessments are given for some sprays typical of spray combustion applications.

Chen, C. P.↗
NASA NTRS1992

A dynamic study of fragmentation and energy loss during high velocity impact

Research conducted under this contract can be divided into two main areas: hypervelocity (in the range up to 7 km/s) and high velocity (less than 1 km/s). Work in the former was performed at NASA-MSFC using the Light Gas Gun Facility. The lower velocity studies were conducted at Auburn University using the ballistic gun. The emphasis of the project was on the hypervelocity phenomenon especially in the characterization of the debris cloud formed by the primary impact events. Special devices were made to determine the angular distributions of momentum and energy of the debris cloud as a function of impact conditions. After several iteration processes, it was decided to concentrate on the momentum effort. Prototype devices were designed, fabricated, and tested. These devices were based on the conservation of momentum. Distributions of the debris cloud formed were measured by determining the amount of momentum transferred from the debris cloud to strategically placed pendulum measurement devices. The motion of the pendula was monitored using itegrated opto-interrupters. The distribution of momentum in the debris cloud was found to be a strong function of the impact condition. Small projectiles at high velocities were observed to produce finely dispersed debris whereas large projectiles generated discrete particles in the debris. Results also show that the momentum in the forward direction was enhanced due to the impact. This phenomenon of momentum multiplication was also observed in other studies and in computer simulations. It was initially planned to determine the energy distribution using deformation energy in a rod with strain gauges. Results from preliminary studies show that this technique is acceptable but too tedious. A new technique was explored based on measuring the heating effect of the debris cloud using an IR camera. The feasibility and sensitivity was established at Auburn University. This type of energy distribution measurement method can easily be adapted to the gas gun facility at MSFC. The objective of the lower velocity studies at Auburn was to simulate the damage produced in advanced materials by the lower energy debris cloud.

Zee, Ralph H.↗
NASA NTRS1993

Ion anisotropy instabilities in the magnetosheath

Recent observations in Earth's magnetosheath have delineated several different kinds of magnetic fluctuation spectra below the proton cyclotron frequency. This paper provides a theoretical interpretation for some of these observations describing solutions of the linear Vlasov dispersion equation for fully electromagnetic instabilities for particle distributions which model those observed in the magnetosheath. This model yields three growing modes: the proton cyclotron anisotropy the helium cyclotron anisotropy, and the mirror instabilities. The results show very good agreement with the observations of mirror-like and proton-cyclotron-like events. This agreement with observations implies that the transition between cyclotron and mirror fluctuation dominance is consistent with linear theory.

Gary, S. P.↗
NASA NTRS2003

Aluminum Alloy and Article Cast Therefrom

A cast article from an aluminum alloy, which has improved mechanical properties at elevated temperatures, has the following composition in weight percent: Silicon 14 - 25.0, Copper 5.5 - 8.0, Iron 0.05 - 1.2, Magnesium 0.5 - 1.5, Nickel 0.05 - 0.9, Manganese 0.05 - 1.0, Titanium 0.05 - 1.2, Zirconium 0.05 - 1.2, Vanadium 0.05 - 1.2, Zinc 0.05 - 0.9, Phosphorus 0.001 - 0.1, and the balance is Aluminum, wherein the silicon-to-magnesium ratio is 10 - 25, and the copper-to-magnesium ratio is 4 - 15. The aluminum alloy contains a simultaneous dispersion of three types of Al3X compound particles (X=Ti, V, Zr) having a LI2, crystal structure, and their lattice parameters are coherent to the aluminum matrix lattice. A process for producing this cast article is also disclosed, as well as a metal matrix composite, which includes the aluminum alloy serving as a matrix and containing up to about 60% by volume of a secondary filler material.

Lee, Jonathan A.↗