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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Mineral Separation in a CELSS by Ion-exchange Chromatography

Operational parameters pertinent to ion exchange chromatography separation were identified. The experiments were performed with 9 mm diameter ion exchange columns and conventional column accessories. The cation separation beds were packed with AG 50W-X2 strong acid cation exchange resin in H(+) form and 200-400 dry mesh particle size. The stripper beds used in some experiments were packed with AG 1-XB strong base cation exchange resin in OH(-) form and 200-400 dry mesh particle size.

Ballou, E. V.↗
NASA NTRSDate not supplied

Metal Fused Filament Fabrication of Titanium Alloy for In Space Manufacturing

NASA is developing materials and processes for the in-space manufacturing of many items for the International Space Station (ISS) and future exploration platforms. These new manufacturing processes will require the further development of current 3D printing processes to achieve high-performance metal parts within the power and space constraints of the ISS. Manufacturing Ti-6Al-4V alloy parts with 3D printing using a metal fused filament fabrication (MF3) process is an alternative process to the Direct Metal Laser Sintering (DMLS) of the metal powders additive manufacturing process. Our initial work fabricating Ti-6Al-4V parts from Ti-6Al-4V powder-binder feedstock and processed with the MF3 process has resulted in 95-97% sintered densities. The current development work of optimized sintered properties investigates the effects of variation in sintering time, temperature, and vacuum on the sintered properties of Ti-6Al-4V MF3 printed tensile bars. Sintered properties such as density, hardness, and tensile properties were characterized followed by microstructural and chemical (O/C/N) analysis to understand the role of sintering process on the ensuing material properties. Future development of the MF3 process will also involve investigation of the effects of micro-milling the Ti-64Al-4V powder to nanometer particle sizes and the investigation of laser sintering of the 3D printed devices. This new micro-milling technique will have broad application to other areas that require particle size reduction of hard metallic materials, such as Nuclear Thermal Propulsion and other NASA technologies. Laser sintering in lieu of high temperature thermal sintering should allow for significant power reduction and improved processing speeds.

sintering, alloys, 3D printing↗
NASA NTRS1985

Microdunes and Other Aeolian Bedforms on Venus: Wind Tunnel Simulations

The development of aeolian bedforms in the simulated Venusian environment has been experimentally studied in the Venus Wind tunnel. It is found that the development of specific bedforms, including ripples, dunes, and waves, as well as their geometry, are controlled by a combination of factors including particle size, wind speed, and atmospheric density. Microdunes are formed which are analogous to full-size terrestrial dunes and are characterized by the development of slip faces, internal cross-bedding, a low ratio of saltation path length to dune length, and a lack of particle-size sorting. They begin to develop at wind speeds just above saltation threshold and evolve into waves at higher velocities. At wind speeds of about 1.5 m/sec and higher, the bed is flat and featureless. This evolution is explained by a model based on the interaction of alternating zones of erosion and deposition and particle saltation distances.

Greeley, R.↗
NASA NTRS1984

Microdunes and other aeolian bedforms on Venus - Wind Tunnel simulations

The development of aeolian bedforms in the simulated Venusian environment has been experimentally studied in the Venus Wind Tunnel. It is found that the development of specific bedforms, including ripples, dunes, and 'waves', as well as their geometry, are controlled by a combination of factors including particle size, wind speed, and atmospheric density. Microdunes are formed which are analogous to full-size terrestrial dunes and are characterized by the development of slip faces, internal cross-bedding, a low ratio of saltation path length to dune length, and a lack of particle-size sorting. They begin to develop at wind speeds just above saltation threshold and evolve into waves at higher velocities. At wind speeds of about 1.5 m/sec and higher, the bed is flat and featureless. This evolution is explained by a model based on the interaction of alternating zones of erosion and deposition and particle saltation distances.

Greeley, R.↗
NASA NTRS1998

A New Optical Aerosol Spectrometer

An optical particle spectrometer capable of measuring aerosol particle size distributions from 0.02 to 100 micrometers has been developed. This instrument combines several optical methods in one, in-situ configuration; it can provide continuous data collection to encompass the wide dynamic size ranges and concentrations found in studies of modeled planetary atmospheres as well as terrestrial air quality research. Currently, the system is incorporated into an eight liter capacity spherical pressure vessel that is appropriate both for flowthrough and for in-situ particle generation. The optical sizing methods include polarization ratio, The scattering, and forward scattering detectors, with illumination from a fiber-coupled, Argon-ion laser. As particle sizes increase above 0.1 micrometer, a customized electronics and software system automatically shifts from polarization to diffraction-based measurements as the angular scattering detectors attain acceptable signal-to-noise ratios. The number concentration detection limits are estimated to be in the part-per-trillion (ppT by volume) range, or roughly 1000 submicron particles per cubic centimeter. Results from static experiments using HFC134A (approved light scattering gas standard), flow-through experiments using sodium chloride (NaCl) and carbon particles, and dynamic 'Tholin' (photochemical produced particles from ultraviolet (UV)-irradiated acetylene and nitrogen) experiments have been obtained. The optical spectrometer data obtained with particles have compared well with particle sizes determined by electron microscopy. The 'Tholin' tests provided real-time size and concentration data as the particles grew from about 30 nanometers to about 0.8 micrometers, with concentrations ranging from ppT to ppB, by volume. Tests are still underway, to better define sizing accuracy and concentration limits, these results will be reported.

Fonda, Mark↗
NASA NTRS1981

Holographic microscopy studies of emulsions

A holographic microscopy system that records and observes the dynamic properties of separation of dispersed immiscible fluids is described. The holographic construction system and reconstruction system that were used to obtain particle size and distribution information from the holograms are discussed. The holographic microscopy system is used to observed the phase separating processes in immiscible fluids that were isothermally cooled into the two phase region. Nucleation, growth rates, coalescence, and particle motion are successfully demonstrated with this system. Thus a holographic particle sizing system with a resolution of 2 micrometers and a field of view of 100 cu cm was developed that provides the capability of testing the theories of separating immiscible fluids for particle number densities in the range of 10 to 10 to the 7th power particles.

Witherow, W. K.↗
NASA NTRS2010

Comparison of GOES-Retrieved and In Situ Measurements of Deep Convective Anvil Cloud Microphysical Properties During the Tropical Composition, Cloud and Climate Coupling Experiment (TC(sup 4))

One of the main goals of the Tropical Composition, Cloud and Climate Coupling Experiment (TC(sup 4)) during July and August 2007 was to gain a better understanding of the formation and life cycle of cirrus clouds in the upper troposphere and lower stratosphere and how their presence affects the exchange of water vapor between these layers. Additionally, it is important to compare in situ measurements taken by aircraft instruments with products derived from satellite observations and find a meaningful way to interpret the results. In this study, cloud properties derived using radiance measurements from the Geostationary Operational Environmental Satellite (GOES) imagers are compared to similar quantities from aircraft in situ observations and are examined for meaningful relationships. A new method using dual \angle satellite measurements is used to derive the ice water content (IWC) for the top portion of deep convective clouds and anvils. The results show the in situ and remotely sensed mean microphysical properties agree to within approx.10 microns in the top few kilometers of thick anvils despite the vastly different temporal and spatial resolutions of the aircraft and satellite instruments. Mean particle size and IWC are shown to increase with decreasing altitude in the top few kilometers of the cloud. Given these relationships, it may be possible to derive parameterizations for effective particle size and IWC as a function of altitude from satellite observations

Yost, Christoher R.↗
NASA NTRS2019

The Effect of Solution Chemistries and Freezing Temperatures on the Morphology of Cryogenic Opal-A (COA): Implications for Past Climates on Mars

Cryogenic opal-A (COA) is a type of hydrated amorphous silica that forms when silica-rich geothermal fluids erupt sub-aerially and are exposed to air temperatures below 0 °C. As the fluid cools and water-ice forms, the solution increases in ionic strength and reaches saturation of opal-A. This results in the precipitation of opal-A between water ice crystals. Natural COA is found embedded within frozen fluids near hydrothermal sources, and has been shown to preserve signs of biological activity. In this study, two solution chemistries (hydrochloric acid (HCl) and sulfuric acid (H2SO4)) and three freezing temperatures (-20, -80, -196 ºC) were used to synthesize COA in the lab. SEM analyses showed that COA frozen at -20 ºC in HCl solutions produced smooth silica branches similar to what was observed in previous studies. COA precipitated at lower freezing temperatures demonstrated progressively smaller particle sizes and unique morphologies such as halite dendrites within silica, desiccation cracks, and pores. COA made in H2SO4 solutions was more angular and fragmented than COA made in HCl solutions. Particle size also decreased with decreasing freezing temperature. COA textures have implications for terrestrial samples as well as future samples returned from Mars because they can provide information about past climate and fluid chemistry.

J V Hogancamp↗
NASA NTRS1975

Analysis of spectrophotometric observations of Venus in the 3-4 micron region

Spectrophotometric data of Venus in the 3-4 micron region are analyzed in the context of current ideas concerning cloud properties. The results show that a homogeneous cloud model, using a unimodal particle size distribution compatible with the results of previous polarization studies, cannot satisfactorily explain the infrared observations. Assuming a composition of 75% H2SO4, agreement is possible if an upper layer of smaller particles is added to the homogeneous cloud. This inhomogeneous cloud structure, however, is not in agreement with the polarization results. Other models, involving bimodal particle size distributions, were also unsuccessful in explaining both sets of observations in a consistent manner.

Martonchik, J. V.↗
NASA NTRS1996

Computer Modeling of Non-Isothermal Crystallization

A realistic computer model for simulating isothermal and non-isothermal phase transformations proceeding by homogeneous and heterogeneous nucleation and interface-limited growth is presented. A new treatment for particle size effects on the crystallization kinetics is developed and is incorporated into the numerical model. Time-dependent nucleation rates, size-dependent growth rates, and surface crystallization are also included. Model predictions are compared with experimental measurements of DSC/DTA peak parameters for the crystallization of lithium disilicate glass as a function of particle size, Pt doping levels, and water content. The quantitative agreement that is demonstrated indicates that the numerical model can be used to extract key kinetic data from easily obtained calorimetric data. The model can also be used to probe nucleation and growth behavior in regimes that are otherwise inaccessible. Based on a fit to data, an earlier prediction that the time-dependent nucleation rate in a DSC/DTA scan can rise above the steady-state value at a temperature higher than the peak in the steady-state rate is demonstrated.

Kelton, K. F.↗
NASA NTRS1982

Creep of plasma-sprayed-ZrO2 thermal-barrier coatings

Specimens of plasma-sprayed-zirconia thermal-barrier coatings with three different porosities and different initial particle sizes were deformed in compression at initial loads of 6900, 13,800, and 24,100 kPa (1000, 2000, and 3500 psi) and temperatures of 1100, 1250, and 1400 C. The coatings were stabilized with lime, MgO, and two different concentrations of Y2O3. Creep began as soon as the load was applied and continued at a constantly decreasing rate until the load was removed. Temperature and stabilization had a pronounced effect on creep rate while the stress, particle size, and porosity had a lesser effect. Creep deformation was due to cracking and particle sliding.

Firestone, R. F.↗
NASA NTRS2004

Formation and Destruction Processes of Interstellar Dust: From Organic Molecules to carbonaceous Grains

The study of the formation and destruction processes of cosmic dust is essential to understand and to quantify the budget of extraterrestrial organic molecules. interstellar dust presents a continuous size distribution from large molecules, radicals and ions to nanometer-sized particles to micron-sized grains. The lower end of the dust size distribution is thought to be responsible for the ubiquitous spectral features that are seen in emission in the IR (UIBs) and in absorption in the visible (DIBs). The higher end of the dust-size distribution is thought to be responsible for the continuum emission plateau that is seen in the IR and for the strong absorption seen in the interstellar UV extinction curve. All these spectral signatures are characteristic of cosmic organic materials that are ubiquitous and present in various forms from gas-phase molecules to solid-state grains. Although dust with all its components plays an important role in the evolution of interstellar chemistry and in the formation of organic molecules, little is known on the formation and destruction processes of dust. Recent space observations in the UV (HST) and in the IR (ISO) help place size constraints on the molecular component of carbonaceous IS dust and indicate that small (ie., subnanometer) PAHs cannot contribute significantly to the IS features in the UV and in the IR. Studies of large molecular and nano-sized IS dust analogs formed from PAH precursors have been performed in our laboratory under conditions that simulate diffuse ISM environments (the particles are cold -100 K vibrational energy, isolated in the gas phase and exposed to a high-energy discharge environment in a cold plasma). The species (molecules, molecular fragments, ions, nanoparticles, etc) formed in the pulsed discharge nozzle (PDN) plasma source are detected with a high-sensitivity cavity ring-down spectrometer (CRDS). We will present new experimental results that indicate that nanoparticles are generated in the plasma. From these unique measurements, we derive information on the nature, the size and the structure of interstellar dust particles, the growth and the destruction processes of IS dust and the resulting budget of extraterrestrial organic molecules.

Salama, F.↗
NASA NTRS2020

Characterizing Deposits Emplaced by Cryovolcanic Plumes on Europa

In the absence of direct observations of Europa’s particle plumes, deposits left behind during eruptive events would provide the best evidence for recent geological activity, and would serve as indicators of the best places to search for ongoing activity on the icy moon. Here, we model the morphological and spectral signatures of europan plume deposits, utilizing constraints from recent Hubble Space Telescope observations as model inputs. We consider deposits emplaced by plumes that are 1 km to 300 km tall, and find that in the time between the Galileo Mission and the arrival of the Europa Clipper spacecraft, plumes that are < 7 km tall are most likely to emplace deposits that could be detected by spacecraft cameras. Deposits emplaced by larger plumes could be detected by cameras operating at visible wavelengths provided that their average particle size is sufficiently large, their porosity is high, and/or they are salt-rich. Conversely, deposits emplaced by large plumes could be easily detected by near-IR imagers regardless of porosity, or individual particle size or composition. If low-albedo deposits flanking lineated features on Europa are indeed cryoclastic mantlings, they were likely emplaced by plumes that were less than 4 km tall, and deposition could be ongoing today. Comparisons of the sizes and albedos of these deposits between the Galileo and Europa Clipper missions could shed light on the size and frequency of cryovolcanic eruptions on Europa.

Lynnae C Quick↗
NASA NTRS2020

Characterizing Deposits Emplaced by Cryovolcanic Plumes on Europa

In the absence of direct observations of Europa’s particle plumes, deposits left behind during eruptive events would provide the best evidence for recent geological activity, and would serve as indicators of the best places to search for ongoing activity on the icy moon. Here, we model the morphological and spectral signatures of europan plume deposits, utilizing constraints from recent Hubble Space Telescope observations as model inputs. We consider deposits emplaced by plumes that are 1 km to 300 km tall, and find that in the time between the Galileo Mission and the arrival of the Europa Clipper spacecraft, plumes that are <7 km tall are most likely to emplace deposits that could be detected by spacecraft cameras. Deposits emplaced by larger plumes could be detected by cameras operating at visible wavelengths provided that their average particle size is sufficiently large, their porosity is high, and/or they are salt-rich. Conversely, deposits emplaced by large plumes could be easily detected by near-IR imagers regardless of porosity, or individual particle size or composition. If low-albedo deposits flanking lineated features on Europa are indeed cryoclastic mantlings, they were likely emplaced by plumes that were <4 km tall, and deposition could be ongoing today. Comparisons of the sizes and albedos of these deposits between the Galileo and Europa Clipper missions could shed light on the size and frequency of cryovolcanic eruptions on Europa.

Lynnae C Quick↗
NASA NTRS1975

Analysis of cloud polarization measurements

The polarization of sunlight reflected by various cloud types was measured in the near-infrared with a polarimeter flown aboard the NASA Convair 990. The data reduction has been completed and detailed comparisons have been made between the observations and theoretical computations. The analysis presented shows that the polarization in the near-infrared can be used on a routine basis to reliably yield the cloud particle phase (water or ice) and the average particle size in the top part of water clouds (usually within + or - 25%). In some cases the polarization also yields the cloud optical thickness (or a lower limit) and a measure of the width of the particle size distribution in the top of the water clouds.

Hansen, J. E.↗
NASA NTRS2012

Fischer-Tropsch Cobalt Catalyst Improvements with the Presence of TiO2, La2O3, and ZrO2 on an Alumina Support

The objective of this study was to evaluate the effect of titanium oxide, lanthanum oxide, and zirconium oxide on alumina supported cobalt catalysts. The hypothesis was that the presence of lanthanum oxide, titanium oxide, and zirconium oxide would reduce the interaction between cobalt and the alumina support. This was of interest because an optimized weakened interaction could lead to the most advantageous cobalt dispersion, particle size, and reducibility. The presence of these oxides on the support were investigated using a wide range of characterization techniques such as SEM, nitrogen adsorption, x-ray diffraction (XRD), temperature programmed reduction (TPR), temperature programmed reduction after reduction (TPR-AR), and hydrogen chemisorptions/pulse reoxidation. Results indicated that both La2O3 and TiO2 doped supports facilitated the reduction of cobalt oxide species in reference to pure alumina supported cobalt catalysts, however further investigation is needed to determine the effect of ZrO2 on the reduction profile. Results showed an increased corrected cluster size for all three doped supported catalysts in comparison to their reference catalysts. The increase in reduction and an increase in the cluster size led to the conclusion that the support-metal interaction weakened by the addition of TiO2 and La2O3. It is also likely that the interaction decreased upon presence of ZrO2 on the alumina, but further research is necessary. Preliminary results have indicated that the alumina-supported catalysts with titanium oxide and lanthanum oxide present are of interest because of the weakened cobalt support interaction. These catalysts showed an increased extent of reduction, therefore more metallic cobalt is present on the support. However, whether or not there is more cobalt available to participate in the Fischer-Tropsch synthesis reaction (cobalt surface atoms) depends also on the cluster size. On one hand, increasing cluster size alone tends to decrease the active site density; on the other hand, by increasing the size of the cobalt clusters, there is less likelihood of forming oxidized cobalt complexes (cobalt aluminate) during Fischer-Tropsch synthesis. Thus, from the standpoint of stability, improving the extent of reduction while increasing the particle size slightly may be beneficial for maintaining the sites, even if there is a slight decrease in overall initial active site density.

Klettlinger, Jennifer Lindsey Suder↗
NASA NTRS1999

Coarsening in Solid-Liquid Mixtures Studied on the Space Shuttle

Ostwald ripening, or coarsening, is a process in which large particles in a two-phase mixture grow at the expense of small particles. It is a ubiquitous natural phenomena occurring in the late stages of virtually all phase separation processes. In addition, a large number of commercially important alloys undergo coarsening because they are composed of particles embedded in a matrix. Many of them, such as high-temperature superalloys used for turbine blade materials and low-temperature aluminum alloys, coarsen in the solid state. In addition, many alloys, such as the tungsten-heavy metal systems, coarsen in the solid-liquid state during liquid phase sintering. Numerous theories have been proposed that predict the rate at which the coarsening process occurs and the shape of the particle size distribution. Unfortunately, these theories have never been tested using a system that satisfies all the assumptions of the theory. In an effort to test these theories, NASA studied the coarsening process in a solid-liquid mixture composed of solid tin particles in a liquid lead-tin matrix. On Earth, the solid tin particles float to the surface of the sample, like ice in water. In contrast, in a microgravity environment this does not occur. The microstructures in the ground- and space-processed samples (see the photos) show clearly the effects of gravity on the coarsening process. The STS-83-processed sample (right image) shows nearly spherical uniformly dispersed solid tin particles. In contrast, the identically processed, ground-based sample (left image) shows significant density-driven, nonspherical particles, and because of the higher effective solid volume fraction, a larger particle size after the same coarsening time. The "Coarsening in Solid-Liquid Mixtures" (CSLM) experiment was conducted in the Middeck Glovebox facility (MGBX) flown aboard the shuttle in the Microgravity Science Laboratory (MSL-1/1R) on STS-83/94. The primary objective of CSLM is to measure the temporal evolution of the solid particles during coarsening.

Caruso, John J.↗