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Results for “OPTICAL EMISSION SPECTROSCOPY”

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At least 649 records · Page 36

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DOE OSTI2021

Ultraviolet spectra of extreme nearby star-forming regions: Evidence for an overabundance of very massive stars

ABSTRACT As deep spectroscopic campaigns extend to higher redshifts and lower stellar masses, the interpretation of galaxy spectra depends increasingly upon models for very young stellar populations. Here we present new HST/COS ultraviolet spectroscopy of seven nearby (<120 Mpc) star-forming regions hosting very young stellar populations (∼4–20 Myr) with optical Wolf–Rayet stellar wind signatures, ideal laboratories in which to benchmark these stellar models. We detect nebular C iii] in all seven, but at equivalent widths uniformly <10 Å. This suggests that even for very young stellar populations, the highest equivalent width C iii] emission at ≥15 Å is reserved for inefficiently cooled gas at metallicities at or below that of the SMC. The spectra also reveal strong C iv P-Cygni profiles and broad He ii emission formed in the winds of massive stars, including some of the most prominent He ii stellar wind lines ever detected in integrated spectra. We find that the latest stellar population synthesis prescriptions with improved treatment of massive stars nearly reproduce the entire range of stellar He ii wind strengths observed here. However, we find that these models cannot simultaneously match the strongest wind features alongside the optical nebular line constraints. This discrepancy can be naturally explained by an overabundance of very massive stars produced by a high incidence of binary mass transfer and mergers occurring on short ≲10 Myr time-scales, suggesting these processes may be crucial for understanding systems dominated by young stars both nearby and in the early Universe.

Senchyna, Peter↗

DOE OSTI2024

Disorder and diffuse scattering in single-chirality (TaSe 4 ) 2 ⁢I crystals

The quasi-one-dimensional chiral compound (TaSe 4 ) 2 I has been extensively studied as a prime example of a topological Weyl semimetal. Upon crossing its phase transition temperature $T$ CDW ≈263K, (TaSe 4 ) 2 I exhibits incommensurate charge density wave (CDW) modulations described by the well-defined propagation vector ∼(0.05,0.05,0.11), oblique to the TaSe 4 chains. Although optical and transport properties greatly depend on chirality, there is no systematic report about chiral domain size for (TaSe 4 ) 2 I. In this study, our single-crystal scattering refinements reveal a bulk iodine deficiency, and Flack parameter measurements on multiple crystals demonstrate that separate (TaSe 4 ) 2 I crystals have uniform handedness, supported by direct imaging and helicity-dependent terahertz emission spectroscopy. Our single-crystal x-ray scattering and calculated diffraction patterns identify multiple diffuse features and create a real-space picture of the temperature-dependent (TaSe 4 ) 2 I crystal structure. Further, the short-range diffuse features are present at room temperature and decrease in intensity as the CDW modulation develops. These transverse displacements, along with electron pinning from the iodine deficiency, help explain why (TaSe 4 ) 2 I behaves as an electronic semiconductor at temperatures above and below $T$ CDW , despite a metallic band structure calculated from density functional theory of the ideal structure.

36 MATERIALS SCIENCE↗

NASA NTRS1990

The ultraviolet and visible light variability of BP Tauri - Possible clues for the origin of T Tauri star activity

BP Tau is a moderate-strength T Tauri star, which has previously been studied photometrically by Vrba et al. (1986, 1989) and shown to have a 7.6-day light cycle. Here, BP Tau was reobserved in order to monitor this star with the IUE satellite. In conjunction with the UV spectroscopy, nearly simultaneous ground-based optical photometry was also obtained. At optical wavelengths, the star was initially found to be varying with a period of 7.6 days. This variability suddenly vanished and was followed by a quiescent state that lasted about 11 days. The star then resumed its variability with a period of about 6.1 days. The UV continuum and most of the UV emission lines appeared to vary in phase with the optical flux. No variations were observed on the very short timescales ranging from several hours to half a day, expected on the basis of axisymmetric, quasi-steady-state accretion disk models of T Tauri stars. However, the nearly week-long variations that were observed may be consistent with a magnetically buffered accretion model, which has been proposed by Uchida and Shibata.

Simon, Theodore↗

NASA NTRS1992

Conceptual design and structural analysis of the spectroscopy of the atmosphere using far infrared emission (SAFIRE) instrument

The conceptual design and structural analysis for the Spectroscopy of the Atmosphere using Far Infrared Emission (SAFIRE) Instrument are provided. SAFIRE, which is an international effort, is proposed for the Earth Observing Systems (EOS) program for atmospheric ozone studies. A concept was developed which meets mission requirements and is the product of numerous parametric studies and design/analysis iterations. Stiffness, thermal stability, and weight constraints led to a graphite/epoxy composite design for the optical bench and supporting struts. The structural configuration was determined by considering various mounting arrangements of the optical, cryo, and electronic components. Quasi-static, thermal, modal, and dynamic response analyses were performed, and the results are presented for the selected configuration.

Moses, Robert W.↗

NASA NTRS1997

The STIS parallel survey: Introduction and first results

The installation of the Space Telescope Imaging Spectrograph (STIS) on the Hubble Space Telescope (HST) allows for the first time two-dimensional optical and ultraviolet slitless spectroscopy of faint objects from space. The STIS Parallel Survey (SPS) routinely obtains broad band images and slitless spectra of random fields in parallel with HST observations using other instruments. The SPS is designed to study a wide variety of astrophysical phenomena, including the rate of star formation in galaxies at intermediate to high redshift through the detection of emission-line galaxies. We present the first results of the SPS, which demonstrate the capability of STIS slitless spectroscopy to detect and identify high-redshift galaxies.

Gardner, Jonathan P.↗

NASA NTRS1982

A search for UV line variability in R136a

The brightest object in the central cluster of stars in the 30 Doradus nebula is R136a. Optical imaging and ultraviolet spectroscopy show that a luminosity originates in a volume less than 0.1 pc across. A very tight cluster of approximately 30 luminous O and WR stars produces this energy. An alternative interpretation is the possibility that a single supermassive object dominates the light. The visual spectrum is classified as WN 4.5. A common characteristic of WN spectra is variability of the emission lines, especially He II lambda 4686.

Ebbets, D. C.↗

NASA NTRS1992

Optical luminescence spectroscopy as a probe of the surface mineralogy of Mars

Optical luminescence (OpL) spectroscopy is an attractive use of a visible-near-IR spectrometer on a Mars lander because mineral products of atmosphere-surface interactions on Mars will probably have characteristic OpL spectra. Optical luminescence spectra would be taken at night, when a spectrometer might otherwise sit idle. Also needed would be a source of exciting radiation, which could be shared with other experiments. Optical luminescence is emission of nonthermal optical photons (near-UV through near-IR) as a response to energy input. On absorption of energy, an atom (or ion) will enter an excited state. The favored decay of many such excited states involving valence-band electrons is emission of an optical photon. Optical luminescence spectra can be useful in determining mineralogy and mineral composition. Optical luminescence in crystals can arise from essential elements (or ions), trace-element substituents (activators), or defects. Common activators in salts of alkali and alkaline earth elements include Mn(2+)(VI), other transition metals, the rare earths, and the actinides. Trace substituents of other species can enhance or quench OpL (e.g., Pb(2+) vs. Fe(3+)). Optical luminescence can also arise from defects in crystal structures, including those caused by radiation and shock.

Treiman, A. H.↗

DOE OSTI2025

Remote quantification of Cm(III) and HNO 3 by fluorescence spectroscopy and chemometrics

A unique approach to remotely quantify Cm(III) (0–100 µg mL −1 ) in HNO 3 (1–12 M) using steady-state laser fluorescence spectroscopy and multivariate regression models was developed. Photoluminescence is amenable to remote measurements using fiber-optic cables and is sensitive to numerous lanthanide and actinide species. In-line measurements can provide feedback to support complex processing in harsh environments (e.g., hot cells) to help guide and optimize radiochemical separations. In this work, Cm(III) spectra were acquired remotely in a glove box as a function of HNO 3 concentration to better understand spectral characteristics and evaluate the utility of multivariate regression models in this system. Furthermore, the Cm(III) fluorescence peak shape, width, position, and intensity changed significantly as a function of HNO 3 concentration, likely because of the displacement of emission quenching inner-sphere water molecules and complexation with nitrate ions. Despite significant covariance and nonlinearity in the data, a D-optimal design strategy successfully minimized training set sample size and was used to build effective partial least squares regression models for Cm(III) and HNO 3 concentrations without a priori knowledge of solution conditions. Chemometrics for modeling complex fluorescence spectra are promising and may find widespread applicability for online analysis in numerous chemical systems found in the nuclear field.

Actinide↗

DOE OSTI2020

MACHO 311.37557.169: A VY Scl star

Abstract Optical surveys, such as the MACHO project, often uncover variable stars whose classification requires follow‐up observations by other instruments. We performed X‐ray spectroscopy and photometry of the unusual variable star MACHO 311.37557.169 with XMM‐Newton in April 2018, supplemented by archival X‐ray and optical spectrographic data. The star has a bolometric X‐ray luminosity of about 1 × 10 32 erg s −1 cm −2 and a heavily absorbed two‐temperature plasma spectrum. The shape of its light curve, its overall brightness, its X‐ray spectrum, and the emission lines in its optical spectrum suggest that it is most likely a VY Scl cataclysmic variable.

Wörpel, Hauke↗

NASA NTRS1989

Interstellar matter in early-type galaxies - Optical observations

Results of optical observations of 26 bright elliptical galaxies selected on the basis of IRAS data are discussed. Optical broadband imaging (using B and R filters) and narrow-band imaging (using H-alpha interference filters) have been performed to study dust patches and ionized gas. Long-split spectroscopy has also been made to determine gas kinematics and relative line ratios. The spectroscopic data confirm the presence and distribution of interstellar matter (dust lanes and ionized gas) seen in the direct imaging. Decoupled kinematics of interstellar gas and stars favors an external origin of the interstellar matter. However, for one isolated galaxy, an internal origin is not excluded. The rotation curves determined by optical emission lines are symmetric around the center in most galaxies observed. Galaxy masses and mass-to-light ratios are estimated using the rotation curves of the ionized gas.

Kim, Dong-Woo↗

NASA NTRS2019

A Dissection of Spatially Resolved AGN Feedback across the Electromagnetic Spectrum

We present optical SuperNova Integral Field Spectrograph integral field spectroscopy, Hubble Space Telescope optical imaging, Chandra X-ray imaging, and Very Large Array radio interferometry of the merging galaxy 2MASX J04234080+0408017, which hosts a Seyfert 2 active galactic nucleus (AGN) at z = 0.046. Our observations reveal that radiatively driven, ionized gas outflows are successful to distances >10 kpc due to the low mass of the host system, encompassing the entirety of the observed optical emission. We also find that at large radii, where observed velocities cannot be reproduced by radiative driving models, high-velocity kinematics are likely due to mechanical driving from AGN winds impacting high-density host material. This impacting deposits sufficient energy to shock the host material, producing thermal X-ray emission and cosmic rays, which in turn promote the formation of in situ radio structure in a pseudo-jet morphology along the high-density lanes.

Travis Fischer↗

DOE OSTI2026

Signatures of Antisymmetric Vibrations in the Ultrafast Dynamics of Quadrupolar Dyes

Antisymmetric molecular vibrations are central to ultrafast, nonadiabatic photophysical and photochemical processes such as conical intersection dynamics, Herzberg–Teller couplings and, potentially, singlet fission. Direct spectroscopic identification of such vibrations is, however, challenging, since they are typically Raman inactive and affect optical transitions only weakly. Here, we report experimental signatures of vibronic couplings to a high-frequency antisymmetric vibration in the excited state dynamics of a quasi-quadrupolar molecule by ultrafast two-dimensional electronic spectroscopy (2DES). The early time, sub-50 fs 2DES maps reveal an asymmetric peak pattern with characteristic low-energy cross-peaks. We show that these peaks arise from stimulated emission transitions from an anharmonic, double-minimum excited state potential energy surface formed by vibronic coupling to a high-frequency antisymmetric mode. Simulations based on a phenomenological essential state model support the results. Our findings offer a new approach for identifying antisymmetric vibrations in ultrafast 2DES and track excited state wavepacket motion before relaxation washes out the spectra.

36 MATERIALS SCIENCE↗

NASA NTRS1988

Study of nonlinear optical sBs phenomena in mid IR fibers

This is the first reported attempt at investigation of the sBs phenomena in mid IR fibers using externally fed or laser self generated low frequency and microwave frequency phonon waves as diagnostic probes of such processes. The observation of laser excited phonon emissions in the mid IR fiber and direct modulation of CO2 laser pulse transmission by externally imposed low frequency radiation is the first indication of the predicted low sBs threshold in these fibers in the phonon rich mid IR spectral region. The prospect of wide applications of the sBs process in optical switching, phase conjugation and ultimately optical computing and possible deleterious effects in mid IR laser heterodyne spectroscopy, sideband modulation and transmitted power limitation is discussed.

Yu, Chung↗

NASA NTRS1993

PG 0308 + 096 and PG 1026 + 002 - Two new short period binary stars resulting from common-envelope evolution

Ultraviolet spectroscopy, optical spectroscopy, and spectrophotometry have been used to study the excess UV stars PG 0308 + 096 and PG 1026 + 002. Both objects are short-period binary systems, each containing a DA white dwarf star and a dM star. Orbital periods of approximately 0.284 day for PG 0308 + 096, and aproximately 0.597 day for PG 1026, have been found by spectroscopic analysis of the H-alpha emission line. Ly-alpha and Balmer line profile fitting were used to estimate the mass of white dwarf stars; mass estimates for the dM stars are based on their spectral types. The orbital inclinations are derived from these masses, the periods, and amplitudes of the H-alpha radial velocity curves. The equivalent width of the H-alpha emission line, in each binary system, varies with the orbital phase in such a manner as to imply that it arises, in large part at least, from the hemisphere of the M star that faces the white dwarf star.

Saffer, Rex A.↗

NASA NTRS1995

Spectroscopy of luminous infrared galaxies at 2 microns: 1. The ultraluminous galaxies (L(sub IR) approximately greater than 10 (exp 12) solar luminosity)

We present high-quality spectra covering the K window at a resolving power of 340 for a sample of 13 ultraluminous (L(sub IR) approximately greater than 10(exp 12) solar luminosity) infrared-selected galaxies, and line fluxes for a comparison sample of 24 lower luminosity galaxies. The 2 micrometers spectra of 10 of the ultraluminous galaxies are characterized by emission and absorption features commonly associated with stars and star formation; two others have the red power-law spectra and Br gamma line widths of Seyfert 1 galaxies; the final galaxy has strong emission from hot dust. We have found no broad-line active nuclei not already known from optical observations, despite the fact that the extinction at 2 micrometers is 1/10 that at optical wavelengths; any putative Seyfert 1 nuclei must be deeply buried. Powerful continua and emission lines from H2 and Br gamma are detected in all the ultraluminous galaxies. Comparing the H2 1-0 S(1), Br gamma, and 2 micrometers and far-infrared luminosities to those of the lower luminosity galaxies yields several major results. First, the dereddened Br gamma emission, relative to the far-infrared luminosity is significantly depressed in the ultraluminous sample, when compared to the lower luminosity galaxies. Five of the ultraluminous galaxies have L(sub Br gamma)L(sub IR) ratios lower than for any of the comparison objects. Second, the H2 1-0 S(1) luminosity is also responsible, directly or indirectly, for producing the excited H2, and that the H2 apparently comes from optically thin regions in both classes of objects. Third, eight of the 13 ultraluminous systems have lower 2 micrometers/far-infrared luminosity ratios than any of the lower luminosity galaxies, and five of these are the galaxies also deficient in Br gamma. These three findings may be understood if the the H2, Br gamma, and 2 mircometers continua in the ultraluminous galaxies arise from spatially distinct regions, with the continuum and Br gamma largely coming from volumes optically thick even at 2 micrometers, and obscured in such a fashion that the extinctions measured using optical spectroscopy do not properly measure the true optical depths. If this is the case, then even near-infrared spectroscopy may be unable to exclude the presence of undetected powerful active galactive nuclei in the ultraluminous galaxies.

Goldader, Jeffrey D.↗

DOE OSTI2021

Ultra-wide bandgap β-Ga 2 O 3 films: Optical, phonon, and temperature response properties

Optical and phonon interactions of Ga 2 O 3 thin films with nanocrystalline morphology were studied at extreme temperatures. The films were grown using a sputtering technique and analyzed via temperature response transmission, Raman scattering, and high-resolution deep-UV photoluminescence (PL). Raman modes indicated that the structure corresponds to the β-phase. The optical-gap at the range of 77–620 K exhibited a redshift of ~200 meV, with a temperature coefficient of ~0.4 meV/K. The optical-gap at room-temperature is 4.85 eV. The electron–phonon interaction model at that temperature range pointed to a low energy phonon, ~31 meV, that is involved in the thermal properties of the optical-gap. Detailed Urbach energy analysis indicated that defects are the dominant mechanism controlling the band-edge characteristics even at an elevated temperature regime where phonon dominance is usually expected. Defects are attributed to the disordered forms of graphite that were detected via Raman scattering and to the granular morphology of the film. A deep-UV laser with an above bandgap exaction line of 5.1 eV was employed to map the PL of the films. The highly resolved spectra, even at room-temperature, show a strong emission of ~3.56 eV attributed to self-trapped holes (STHs). The STH is discussed and modeled in terms of the self-trapped exciton. Moreover, a very distinct but low-intensity emission was found at 4.85 eV that agrees with the value of the optical-gap and is attributed to bandgap recombination. The intensity ratio between the STH and that of the bandgap was found to be 6:1.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Strain-Induced Growth of Twisted Bilayers during the Coalescence of Monolayer MoS 2 Crystals

Tailoring the grain boundaries (GBs) and twist angles between two-dimensional (2D) crystals are two crucial synthetic challenges to deterministically enable envisioned applications such as moiré excitons, emerging magnetism, or single-photon emission. Here, we reveal how twisted 2D bilayers can be synthesized from the collision and coalescence of two growing monolayer MoS 2 crystals during chemical vapor deposition. The twisted bilayer (TB) moiré angles are found to preserve the misorientation angle (θ) of the colliding crystals. The shapes of the TB regions are rationalized by a kink propagation model that predicts the GB formed by the coalescing crystals. Optical spectroscopy measurements reveal a θ-dependent long-range strain in crystals with stitched grain boundaries and a sharp (θ > 20°) threshold for the appearance of TBs, which relieves this strain. Reactive molecular dynamics simulations explain this strain from the continued growth of the crystals during coalescence due to the insertion of atoms at unsaturated defects along the GB, a process that self-terminates when the defects become saturated. The simulations also reproduce atomic-resolution electron microscopy observations of faceting along the GB, which is shown to arise from the growth-induced long-range strain. These facets align with the axes of the colliding crystals to provide favorable nucleation sites for second-layer growth of a TB with twist angles that preserve the misorientation angle θ. This interplay between strain generation and aligned nucleation provides a synthetic pathway for the growth of TBs with deterministic angles.

2D materials↗

DOE OSTI2023

Laser induced breakdown spectroscopy of liquid

Chemical composition of liquid phase samples is determined based on laser induced ablation spectroscopy of droplets. An aerosol jet comprising a carrier gas and liquid phase sample droplets, less than about 10 microns in diameter, is formed. An emissive plasma plume is generated from the sample droplets using a pulsed laser to deposit energy at a focal point in the aerosol jet. Light from the plasma plume is gathered with a concave mirror and focused into one end of a fiber optic lightguide. The lightguide can transmit spectral emissions from the plume to a spectrometer/detector which can send wavelength and intensity values to a computer. The computer is operable to determine a liquid sample composition based on the wavelength and intensity values.

Bol'shakov, Alexander A.↗