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Electron microprobe analysis was employed to study north ray crater breccia 67015 from the Moon. The melting history of lunar troctolite 130-9 was investigated, along with the presence of Mg-26 in anorthite grains recovered from the Vaca Meurta mesosiderite. Geographic distributions of meteorites in Antarctica were plotted. The Allende meteorite was analyzed with the electron microprobe method.
The minerology and textural properties of three lunar meteorites (Yamato 791197, ALH81005, and Yamato 82192) were analyzed and compared with lunar surface rock samples. The chemical composition and textures of pyroxene and the occurrance of glass matrices were specifically addressed. The study of glass in the lunar meteorites suggests that the glass was not produced by a meteorite impact which excavated the mass into orbit towards the Earth. The glass had been devitrified on the lunar surface before the excavation, and new glass was not produced by the last impact.
The Earth is the prototype if not typical terrestrial planet. Ideas about the origin, evolution, structure and chemistry of the planets can be tested most thoroughly on the Earth. Similarly, the study of the other planets has generated new ideas which may be applicable to the Earth. For example the concepts of magma oceans, large polar wander, global stress fields, buoyant lithosphere, deep cumulate reservoirs, multiple tectonic styles and crust generation may also apply to the Earth, present or past. It is no longer valid to think of the mantle as an essentially homogeneous undifferentiated shell of olivine with pockes of basalt providing melts to midocean ridges and oceanic islands. It appears to be a well differentiated, outgassed body with both radial and lateral chemical variations. The lower mantle is close to chondritic in its major element chemistry. The transition region is garnet and clinopyroxene rich and may be a major basalt reservoir. This would explain the thin crust paradox. Chemical stratification of the Earth probably occurred during accretion.
Lunar sample 77135, an impact melt breccia full of vesicles, has been reinvestigated by electron microprobe and X-ray diffraction techniques and compared with a vesicular melt LL chondrite, Yamato 790964, in an attempt to understand their impact heating processes and subsequent cooling history. Notable similarities between the lunar and chondritic melt breccias include: abundant vesicles, similar pyroxene chemical zoning trends, the presence of variable amounts of clastic material, and similar chemical compositions except for K and Na contents of glass and mesostasis. Some constraints on the cooling history are estimated from Mg-Fe diffusion profiles in olivine and pyroxene. The burial depth of lunar sample 77135 during cooling was 0.2-100 m; the depth for the chondrite was probably smaller. Impact melts were probably produced and a layer of regolith retained on the parent body sufficiently thick to allow the olivines to homogenize during slow cooling.
Experiments were performed to determine the factors influencing ice nucleation detected in Viking Lander data from the Mars surface. The study focused on the relationship between mineral properties and condensate formation under Mars conditions. Pulverized particles of the primary phases of basaltic rocks and their alteration products, expandable clay minerals and a nonexpandable clay mineral, and petrologically well-characterized regolith materials ranging from 10-60 microns in size, were studied. The powders were individually or in combinations mixed with water in a flowing CO2 atmosphere while calorimetry data was taken on the ice nucleation threshold. The ice-forming characteristics of the mixes were found to be a function of the crystallographic disregistry, chemical bonding, and active-site properties of the individual minerals. The crystalline materials were better nucleators of condensates than were the cryptocrystalline mineral specimens, while nonexpandable clay materials, particularly zeolite, were the more effective nucleators among the weathering product materials.
Experiments were performed to examine if the ubiquitousness of a weak magnetic component in all Martian surface fines tested with the Viking Landers can be attributed to ferric iron precipitation in aqueous solution under oxidizing conditions at neutral pH. Ferrous solutions were mixed in deionized water and various minerals were added to separate liquid samples. The iron-bearing additives included hematite, goethite, magnetite, maghemite, lepidocrocite and potassium bromide blank at varying concentrations. IR spectroscopic scans were made to identify any precipitates resulting from bubbling oxygen throughout the solutions; the magnetic properties of the precipitates were also examined. The data indicated that the lepidocrocite may have been preferentially precipitated, then aged to maghemite. The process would account for the presumed thin residue of maghemite on the present Martian surface, long after abundant liquid water on the Martian surface vanished.
Bulk chemical compositions of matrix material were determined in eleven Antarctic CM chondrites and five non-Antarctic CM and CI chondrites, using microprobe defocused-beam technique. The results, along with previously published data, are used to provide mass balance constraints on the relative proportions of intergrown and intermixed phyllosilicate phases in carbonaceous chondrite matrices. In terms of Fe, Si, and Mg, the CM matrix bulk compositions plot within a triangle defined by the compositions of PCP (a mixture of 25 percent tochilinite and 75 percent cronstedtite), Mg-rich serpentine, and Fe-rich serpentine. Results indicate differing amounts of PCP and serpentines in individual CM matrices. The discrepancies found between predicted and measured S and Ni values require additional sulfide phases. CI matrices were found to contain little, if any, PCP; they consist mostly of serpentine and montmorillonite.
Two airborne flight systems were developed for geological studies: the airborne imaging spectrometer (AIS) and the advanced visible and infrared imaging spectrometer. A satellite imaging spectrometer system, the high resolution imaging spectrometer, is currently being developed and is planned for flight on the proposed NASA Earth Orbiting System. Examples of the application of these instruments in mineral and vegetation studies are described. Experiments conducted with AIS over the Cuprite Mining District (Nevada) and the Owens Valley (California) demonstrate the power of this new approach to remote sensing.
Sulfide samples obtained from Alvin dives on the southern Juan de Fuca Ridge were examined, showing the presence of two previously undiscovered minerals, both formed at low temperatures. The first detection of lizardite, starkeyite, and anatase in such an environment is also reported. Sulfide geothermometry involving the Cu-Fe-S system shows a vent temperature of less than 328 C for one sample. Ice-melting temperatures on inclusions from this sample are about -2.8 C, and fluid inclusion studies on crystals near this sample show pressure-corrected homogenization temperatures of 268 and 285 C. Volatile concentrations from vesicle-free basalt glass from the vent field are found to be about 0.0013 wt pct CO2 and 0.16 wt pct H2O.
The Lattengebirge K/T section reveals three distinct Ir spikes. Two of them are contained in the K/T transition zone sensu-strictu termed clayey interval, with 4.4 ppb Ir at the actual K/T boundary, and 2.8 ppb Ir 10 cm above the boundary. The highest Ir enrichment of 9 ppb, however, was detected in semi-cleaned organic material from a thin sandstone layer of Upper Maastrichtian age at 16 cm below the boundary. In this layer various discernible phases are preserved, contrasting with the worldwide observed K/T transition zones which are generally entirely composed of diagenetically altered materials. Given that, important clues to understanding the Cretaceous terminal events may be provided. The phases of the Cretaceous Ir bearing layer at Lattengebirge consist of: sandstone fragmental minerals in a carbonate matrix, coal which is partly burnt, melt glasses presumably of combustion-metamorphic origin, and sulfides, mainly chalcopyrite, contained in the coal. Like many known K/T sections and the Lattengebirge boundary sensu-strictu, the Cretaceous horizon is enriched in Ir and chalcophile elements as well. Although the Lattengebirge section offers the freshest materials, including melt glasses, of all K/T localities investigated, no unequivocal evidence of formation by impact has been found there.
Three lunar highland regions containing abundant high-Ca pyroxene are investigated in order to constrain the chemistry of the pyroxene assemblage of gabbroic regions and determine the state of gabbroic materials in the highland crust. The compositional gap between orthopyroxenes and clinopyroxenes noted in remote sensing observations corresponds to that found in lunar rock samples. It is found that Mg-gabbronorite or KREEP basalt with abundant high-Ca pyroxene are the most likely rock types of those thus far identified that may be responsible for gabbroic areas in the highlands. The western lunar highlands are shown to be distinct from the east in minerology.
Coordinated petrologic and spectroscopic analyses were undertaken for a specially prepared 1-cm chip of regolith breccia 60019. The mafic minerals of each large clast were readily identified from spectral reflectance measurements of the same clasts, and mineral abundance was shown to be directly related to absorption strength. Although most clasts of 60019 are noritic in composition, the presence of abundant olivine and/or high-Ca pyroxene in several clasts is easily noted spectroscopically. The origin of an unusual absorption feature near 0.6 micron in an anorthositic clast was determined by petrographic analysis to be due to very fine-grained translucent ilmenite. The 60019 matrix is dark and glassy, and although a variety of clasts occur on all scales, particulate powders of 60019 are all very similar and have spectral properties that indicate a noritic breccia bulk composition.
Olivine-rich chondritic interplanetary dust particles (IDPs) are an important subset of fluffy chondritic IDPs collected in the earth's stratosphere. Particles in this subset are characterized by a matrix of nonporous, ultrafine-grained granular units. Euhedral single crystals, crystals fragments, and platey single crystals occur dispersed in the matrix. Analytical electron microscopy of granular units reveals predominant magnesium-rich olivines and FeNi-sulfides embedded in amorphous carbonaceous matrix material. The variable ratio of ultrafine-grained minerals vs. carbonaceous matrix material in granular units support variable C/Si ratios, and some fraction of sulfur is associated with carbonaceous matrix material. The high Mg/(Mg+Fe) ratios in granular units is similar to this distribution in P/Comet Halley dust. The chondritic composition of fine-grained, polycrystalline IDPs gradually breaks down into nonchondritic, and ultimately, single mineral compositions as a function of decreased particle mass. The relationship between particle mass and composition in the matrix of olivine-rich chondritic IDPs is comparable with the relationship inferred for P/Comet Halley dust.
The objectives and instrumental requirements of a petrographic analysis of porous comet nucleus material are reviewed. Assumptions about its composition and texture, and the available techniques for the microscopic analysis of comet analogue material are investigated. New techniques required for the petrographic investigation of natural and artificial comet nucleus samples are also considered.
In a search for diagnostic spectral parameters which can be used to distinguish different materials on the surface of asteroids and to provide information on the detection limits for mafic silicates, the 0.3- to 2.6-micron reflectance spectra of meteoritic enstatite (nearly pure MgSiO3), iron meteorite metal, magnetite, and amorphous carbon as well as various mixtures of these materials with mafic silicates were examined. Results are presented on the dependence of the spectral detectability of mafic silicates associated with metal, carbon, and magnetite on the particle sizes of the phases, their chemistries, crystal structures, and abundances. It is shown that the observational data for a representative M-class asteroid, (16) Psyche, are largely consistent with a fine-grained metal-rich surface assemblage, whereas data for the E-class asteroid (44) Nysa indicate that its surface is composed of fine-grained material similar to enstatite achondrites, with a small amount of material comparable to the chondritic inclusions found in the Cumberland Falls aubrite.
The Machinga, southern Malawi, Africa, L6 chondrite (observed fall, January 22, 1981) contains accessory phases of metal, troilite, chromite, and native Cu (which is associated with limonite and found in zones of aqueous alteration). Rare accessory phases are apatite and pentlandite, which are uncommon in L6 chondrites. Major mineral constituents (olivine, orthopyroxene, and plagioclase) indicate shock effects at a level of about 15-20 GPa shock pressure. The meteorite is thus classified to be of L6d type. Melt pockets of widely variable composition are abundant.
The petrology of type II porphyritic olivine chondrules in Semarkona (LL3.0) has been studied in detail. Olivines in these chondrules are euhedral, Fe-rich, and are strongly zoned from cores to rims of grains in FeO (Fa10-30), Cr2O3 (0.2-0.6 wt pct), MnO (0.2-0.7 wt pct), and CaO (0.1-0.4 wt pct). Interstitial mesostasis is rich in Si, Al, and Ca and is glassy with abundant microcrystallites. Minor minerals include troilite, Fe,Ni metal, and chromite. Some olivine grains contain euhedral, fayalite-rich cores that are probably produced during initial supercooling of the chondrule melt. Rare relict grains of forsteritic olivine have compositions very similar to olivines in type IA chondrules in Semarkona and may result from disaggregation of such chondrules. Apart from these relics, all properties of type II chondrules can be described by closed-system fractional crystallization of droplets which were essentially entirely molten. Type IA chondrules may have formed from type II chondrules by loss of Fe and volatiles. Alternatively, the two chondrule types may have formed in regions of considerable diversity in the solar nebula from precursor materials with different Fe/Mg ratios.
Models are developed for the magmatic evolution and the oxidative weathering of sulfide minerals on Mars, based on petrogenetic associations among komatiitic rock types, Viking geochemical data, SNC meteorites, and terrestrial Fi-Ni deposits. The weathering model was tested by exposing komatiitic pyrrhotites and olivines to sulfuric acid solutions, with or without dissolved ferric iron, and identifying the reaction products by Moessbauer spectroscopy. The results suggest that, on Mars, acidic groundwater has induced oxidative weathering of pyrrhotite, yielding FeS2 and then FeOOH.