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At least 649 records · Page 36

Preliminary volcanic hazards evaluation for Los Alamos National Laboratory Facilities and Operations : current state of knowledge and proposed path forward

The integration of available information on the volcanic history of the region surrounding Los Alamos National Laboratory indicates that the Laboratory is at risk from volcanic hazards. Volcanism in the vicinity of the Laboratory is unlikely within the lifetime of the facility (ca. 50–100 years) but cannot be ruled out. This evaluation provides a preliminary estimate of recurrence rates for volcanic activity. If further assessment of the hazard is deemed beneficial to reduce risk uncertainty, the next step would be to convene a formal probabilistic volcanic hazards assessment.

58 GEOSCIENCES↗

Idaho National Laboratory’s Greenhouse Gas FY08 Baseline

A greenhouse gas (GHG) inventory is a systematic attempt to account for the production and release of certain gasses generated by an institution from various emission sources. The gasses of interest are those which have become identified by climate science as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2008 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho. Concern about the environmental impact of GHGs has grown in recent years. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of a baseline estimate of total GHGs generated at the INL. Additionally, the INL has a desire to see how its emissions compare with similar institutions, including other DOE-sponsored national laboratories. Executive Order 13514 requires that federally-sponsored agencies and institutions document reductions in GHG emissions in the future, and such documentation will require knowledge of a baseline against which reductions can be measured. INL’s FY08 GHG inventory was calculated according to methodologies identified in Federal recommendations and an as-yet-unpublished Technical and Support Document (TSD) using operational control boundary. It measures emissions generated in three Scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL’s organizational boundaries but are a consequence of INL’s activities). This inventory found that INL generated a total of 114,256 MT of CO2-equivalent emissions during fiscal year 2008 (FY08). The following conclusions were made from looking at the results of the individual contributors to INL’s baseline GHG inventory: • Electricity is the largest contributor to INL’s GHG inventory, with over 50% of the net anthropogenic CO2e emissions • Other sources with high emissions were stationary combustion, fugitive emissions from the onsite landfill, mobile combustion (fleet fuels) and the employee commute • Sources with low emissions were contracted waste disposal, wastewater treatment (onsite and contracted) and fugitive emissions from refrigerants. This report details the methods behind quantifying INL’s GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to stress that the methodology behind this inventory followed guidelines that have not yet been formally adopted. Thus, some modification of the conclusions may be necessary as additional guidance is received. Further, because this report differentiates between those portions of the INL that are managed and operated by the Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only that large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

C{sub 60}{sup +} and the Diffuse Interstellar Bands: An Independent Laboratory Check

In 2015, Campbell et al. presented spectroscopic laboratory gas phase data for the fullerene cation, C{sub 60}{sup +}, that coincide with the reported astronomical spectra of two diffuse interstellar band (DIB) features at 9633 and 9578 Å. In the following year, additional laboratory spectra were linked to three other and weaker DIBs at 9428, 9366, and 9349 Å. The laboratory data were obtained using wavelength-dependent photodissociation spectroscopy of small (up to three) He-tagged C{sub 60}{sup +}--He{sub n} ion complexes, yielding rest wavelengths for the bare C{sub 60}{sup +} cation by correcting for the He-induced wavelength shifts. Here we present an alternative approach to derive the rest wavelengths of the four most prominent C{sub 60}{sup +} absorption features, using high-resolution laser dissociation spectroscopy of C{sub 60}{sup +} embedded in ultracold He droplets. Accurate wavelengths of the bare fullerene cation are derived from linear wavelength shifts recorded for He{sub n} C{sub 60}{sup +} species with n up to 32. A careful analysis of all of the available data results in precise rest wavelengths (in air) for the four most prominent C{sub 60}{sup +} bands: 9631.9(1) Å, 9576.7(1) Å, 9427.5(1) Å, and 9364.9(1) Å. The corresponding bandwidths have been derived and the relative band intensity ratios are discussed.

79 ASTRONOMY AND ASTROPHYSICS↗

Interaction of Hemispherical Blast Waves with Inhomogeneous Spheres: Probing the Collision of a Supernova Ejecta with a Nearby Companion Star in the Laboratory

Past laboratory experiments at high energy density have provided insights into the physics of supernovae, supernova remnants, and the destruction of interstellar clouds. In a typical experimental setting, a laser-driven planar blast wave interacts with a compositionally homogeneous spherical or cylindrical target. In this work we propose a new laboratory platform that accounts for curvature of the impacting shock and density stratification of the target. Both characteristics reflect the conditions expected to exist shortly after a supernova explosion in a close binary system. We provide details of a proposed experimental design (laser drive, target configuration, diagnostic system), optimized to capture the key properties of recent ejecta–companion interaction models. Good qualitative agreement found between our experimental models and their astrophysical counterparts highlights the strong potential of the proposed design to probe details of the ejecta–companion interaction for broad classes of objects by means of laboratory experiments at high energy density.

79 ASTRONOMY AND ASTROPHYSICS↗

C{sub 60}{sup +} in diffuse clouds: laboratory and astronomical comparison

The wavelengths of the strongest absorptions in the electronic spectrum of C{sub 60}{sup +} have been determined by experimental investigation into the perturbation caused by the helium in the laboratory spectra of C{sub 60}{sup +}−He{sub n}(n=1--3). The extrapolation of these gives absorption bands of bare C{sub 60}{sup +} at 9348.4, 9365.2, 9427.8, 9577.0, and 9632.1 Å, with ±0.2 Å as the 2σ uncertainty. The laboratory data are compared with the complete set of astronomical observations reported in the literature. The spectral characteristics are found to be in agreement with five diffuse interstellar bands, for which the systematic uncertainties are larger than for the laboratory data.

79 ASTRONOMY AND ASTROPHYSICS↗

Kinetic Simulations of Electron Pre-energization by Magnetized Collisionless Shocks in Expanding Laboratory Plasmas

Collisionless shocks are common features in space and astrophysical systems where supersonic plasma flows interact, such as in the solar wind, the heliopause, and supernova remnants. Recent experimental capabilities and diagnostics allow detailed laboratory investigations of high-Mach-number shocks, which therefore can become a valuable way to understand shock dynamics in various astrophysical environments. Using 2D particle-in-cell simulations with a Coulomb binary collision operator, we demonstrate the mechanism for generation of energetic electrons and experimental requirements for detecting this process in the laboratory high-Mach-number collisionless shocks. We show through a parameter study that electron acceleration by magnetized collisionless shocks is feasible in laboratory experiments with laser-driven expanding plasmas.

79 ASTRONOMY AND ASTROPHYSICS↗

Glaciation of mixed-phase clouds: insights from bulk model and bin-microphysics large-eddy simulation informed by laboratory experiment

Abstract. Mixed-phase clouds affect precipitation and radiation differently from liquid and ice clouds, posing greater challenges to their representation in numerical simulations. Recent laboratory experiments using the Pi Cloud Chamber explored cloud glaciation conditions based on increased injection of ice-nucleating particles. In this study, we use two approaches to reproduce the results of the laboratory experiments: a bulk scalar mixing model and large-eddy simulation (LES) with bin microphysics. The first approach assumes a well-mixed domain to provide an efficient assessment of the mean cloud properties for a wide range of conditions. The second approach resolves the energy-carrying turbulence, the particle size distribution, and their spatial distribution to provide more details. These modeling approaches enable a separate and detailed examination of liquid and ice properties, which is challenging in the laboratory. Both approaches demonstrate that, with an increased ice number concentration, the flow and microphysical properties exhibit the same changes in trends. Additionally, both approaches show that the ice integral radius reaches the theoretical glaciation threshold when the cloud is subsaturated with respect to liquid water. The main difference between the results of the two approaches is that the bulk model allows for the complete glaciation of the cloud. However, LES reveals that, in a dynamic system, the cloud is not completely glaciated as liquid water droplets are continuously produced near the warm lower boundary and subsequently mixed into the chamber interior. These results highlight the importance of the ice mass fraction in distinguishing the mixed-phase clouds and ice clouds.

54 ENVIRONMENTAL SCIENCES↗

Cosmogenic 10 Be in pyroxene: laboratory progress, production rate systematics, and application of the 10 Be– 3 He nuclide pair in the Antarctic Dry Valleys

Here, we present cosmogenic- 10 Be and cosmogenic- 3 He data from Ferrar dolerite pyroxenes in surficial rock samples and a bedrock core from the McMurdo Dry Valleys, Antarctica, with the goal of refining the laboratory methods for extracting beryllium from pyroxene, further estimating the 10 Be production rate in pyroxene and demonstrating the applicability of 10 Be– 3 He in mafic rock. The ability to routinely measure cosmogenic 10 Be in pyroxene will open new opportunities for quantifying exposure durations and Earth surface processes in mafic rocks. We describe scalable laboratory methods for isolating beryllium from pyroxene, which include a simple hydrofluoric acid leaching procedure for removing meteoric 10 Be and the addition of a pH 8 precipitation step to reduce the cation load prior to ion exchange chromatography. 10 Be measurements in pyroxene from the surface samples have apparent 3 He exposure ages of 1–6 Myr. We estimate a spallation production rate for 10 Be in pyroxene, referenced to 3 He, of 3.6 ± 0.2 atoms g –1 yr –1 . 10 Be and 3 He measurements in the bedrock core yield initial estimates for parameters associated with 10 Be and 3 He production by negative-muon capture ($f_{10}^{*}$ = 0.00183 and $f_{3}^{*}f_{C}f_{D}$ = 0.00337). Next, we demonstrate that the 10 Be– 3 He pair in pyroxene can be used to simultaneously resolve erosion rates and exposure ages, finding that the measured cosmogenic-nuclide concentrations in our surface samples are best explained by 2–8 Myr of exposure at erosion rates of 0–35 cm Myr –1 . Finally, given the low 10 Be in our laboratory blanks (average of 5.7 × 10 3 atoms), the reported measurement precision, and our estimated production rate, it should be possible to measure 2 g samples with 10 Be concentrations of 6 × 10 4 and 1.5 × 10 4 atoms g –1 with 5 % and 15 % uncertainty, respectively. With this level of precision, Last Glacial Maximum to Late Holocene surfaces can now be dated with 10 Be in pyroxene. Application of 10 Be in pyroxene, alone or in combination with 3 He, will expand possibilities for investigating glacial histories and landscape change in mafic rock.

58 GEOSCIENCES↗

Materials Capability Review Los Alamos National Laboratory April 29-May 2, 2012

Los Alamos National Laboratory (LANL) uses Capability Reviews to assess the quality and institutional integration of science, technology and engineering (STE) and to advise Laboratory Management on the current and future health of LANL STE. The capabilities are deliberately chosen to be crosscutting over the Laboratory and therefore will include experimental, theoretical and simulation disciplines from multiple line organizations. Capability Reviews are designed to provide a more holistic view of the STE quality, integration to achieve mission requirements, and mission relevance. The scope of these capabilities necessitate that there will be significant overlap in technical areas covered by capability reviews (e.g., materials research and weapons science and engineering). In addition, LANL staff may be reviewed in different capability reviews because of their varied assignments and expertise. The principal product of the Capability Review is the report that includes the review committee's assessments, recommendations, and recommendations for STE.

36 MATERIALS SCIENCE↗

Observation of neutral sulfuric acid-amine containing clusters in laboratory and ambient measurements

Recent ab initio calculations showed that amines can enhance atmospheric sulfuric acid-water nucleation more effectively than ammonia, and this prediction has been substantiated in laboratory measurements. Laboratory studies have also shown that amines can effectively displace ammonia in several types of ammonium clusters. However, the roles of amines in cluster formation and growth at a microscopic molecular scale (from molecular sizes up to 2 nm) have not yet been well understood. Processes that must be understood include the incorporation of amines into sulfuric acid clusters and the formation of organic salts in freshly nucleated particles, which contributes significantly to particle growth rates. We report the first laboratory and ambient measurements of neutral sulfuric acid-amine clusters using the Cluster CIMS, a recently-developed mass spectrometer designed for measuring neutral clusters formed in the atmosphere during nucleation. An experimental technique, which we refer to as Semi-Ambient Signal Amplification (SASA), was employed. Sulfuric acid was added to ambient air, and the concentrations and composition of clusters in this mixture were analyzed by the Cluster CIMS. This experimental approach led to significantly higher cluster concentrations than are normally found in ambient air, thereby increasing signal-to-noise levels and allowing us to study reactions between gas phase species in ambient air and sulfuric acid containing clusters. Mass peaks corresponding to clusters containing four H{sub 2}SO{sub 4} molecules and one amine molecule were clearly observed, with the most abundant sulfuric acid-amine clusters being those containing a C2- or C4-amine (i.e. amines with masses of 45 and 73 amu). Evidence for C3- and C5-amines (i.e. amines with masses of 59 and 87 amu) was also found, but their correlation with sulfuric acid tetramer was not as strong as was observed for the C2- and C4-amines. The formation mechanisms for those sulfuric acid-amine clusters were investigated by varying the residence time in the inlet. It was concluded that the amines react directly with neutral clusters and that ion-induced clustering of sulfuric acid cluster ions with amines was not a dominant process. Results from ambient measurements using the Cluster CIMS without addition of sulfuric acid have shown that the sulfuric acid-amine clusters were reasonably well correlated with sulfuric acid tetramer and consistent with the SASA experiments at the same Boulder sampling site. Also, clusters that contain C2- or C4-amines were more abundant and better correlated with sulfuric acid tetramer than other types of amine containing clusters. However, ambient measurements of sulfuric acid-amine clusters remain difficult and highly uncertain because their concentrations are only slightly above background levels, even during nucleation events.

54 ENVIRONMENTAL SCIENCES↗

Nuclear Forensics at Los Alamos National Laboratory

The overview of this presentation is: (1) Introduction to nonproliferation efforts; (2) Scope of activities at Los Alamos National Laboratory; (3) Facilities for radioanalytical work at LANL; (4) Radiochemical characterization capabilities; and (5) Bulk chemical and materials analysis capabilities. Some conclusions are: (1) Analytical chemistry measurements on plutonium and uranium matrices are critical to numerous defense and non-defense programs including safeguards accountancy verification measurements; (2) Los Alamos National Laboratory operates capable actinide analytical chemistry and material science laboratories suitable for nuclear material forensic characterization; (3) Actinide analytical chemistry uses numerous means to validate and independently verify that measurement data quality objectives are met; and (4) Numerous LANL nuclear facilities support the nuclear material handling, preparation, and analysis capabilities necessary to evaluate samples containing nearly any mass of an actinide (attogram to kilogram levels).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

ChemCam for Mars Science Laboratory rover, undergoing pre-flight testing

Los Alamos National Laboratory and partners developed a laser instrument, ChemCam, that will ride on the elevated mast of the Mars Science Laboratory rover Curiosity. The system allows Curiosity to "zap" rocks from a distance, reading their chemical composition through spectroscopic analysis. In this video, laboratory shaker-table testing of the instrument ensures that all of its components are solidly attached and resistant to damage from the rigors of launch, travel and landing.

79 ASTRONOMY AND ASTROPHYSICS↗

ChemCam rock laser for Mars Science Laboratory "Curiosity"

Los Alamos has a long history of space-related instruments, tied primarily to its role in defense-related treaty verification. Space-based detectors have helped determine the differences between signals from lightning bolts and potential nuclear explosions. LANL-developed gamma-ray detection instruments first revealed the existence of what we now know as gamma-ray bursts, an exciting area of astrophysical research. And the use of LANL instruments on varied space missions continues with such products as the ChemCam rock laser for NASA, shown here. The Engineering Model of the ChemCam Mars Science Laboratory rover instrument arrived at NASA's Jet Propulsion Laboratory on February 6, 2008. The Flight Model was shipped in August, 2010 for installation on the rover at JPL. ChemCam will use imaging and laser-induced breakdown spectroscopy (LIBS) to determine rock and soil compositions on Mars, up to 9 meters from the rover. The engineering model is being integrated into the rover test bed for the development and testing of the rover software. The actual flight model components were concurrently assembled at Los Alamos and in Toulouse, France. The Mars Science Laboratory is scheduled to launch in 2011. Animations courtesy of JPL/NASA.

79 ASTRONOMY AND ASTROPHYSICS↗

Design and Laboratory Evaluation of Future Elongation and Diameter Measurements at the Advanced Test Reactor

New materials are being considered for fuel, cladding, and structures in next generation and existing nuclear reactors. Such materials can undergo significant dimensional and physical changes during high temperature irradiations. In order to accurately predict these changes, real-time data must be obtained under prototypic irradiation conditions for model development and validation. To provide such data, researchers at the Idaho National Laboratory (INL) High Temperature Test Laboratory (HTTL) are developing several instrumented test rigs to obtain data real-time from specimens irradiated in well-controlled pressurized water reactor (PWR) coolant conditions in the Advanced Test Reactor (ATR). This paper reports the status of INL efforts to develop and evaluate prototype test rigs that rely on Linear Variable Differential Transformers (LVDTs) in laboratory settings. Although similar LVDT-based test rigs have been deployed in lower flux Materials Testing Reactors (MTRs), this effort is unique because it relies on robust LVDTs that can withstand higher temperatures and higher fluxes than often found in other MTR irradiations. Specifically, the test rigs are designed for detecting changes in length and diameter of specimens irradiated in ATR PWR loops. Once implemented, these test rigs will provide ATR users with unique capabilities that are sorely needed to obtain measurements such as elongation caused by thermal expansion and/or creep loading and diameter changes associated with fuel and cladding swelling, pellet-clad interaction, and crud buildup.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Annual Technology Baseline (Including Supporting Data); NREL (National Renewable Energy Laboratory)

Consistent cost and performance data for various electricity generation technologies can be difficult to find and may change frequently for certain technologies. With the Annual Technology Baseline (ATB), National Renewable Energy Laboratory provides an organized and centralized dataset that was reviewed by internal and external experts. It uses the best information from the Department of Energy laboratory's renewable energy analysts and Energy Information Administration information for conventional technologies. The ATB will be updated annually in order to provide an up-to-date repository of current and future cost and performance data. Going forward, we plan to revise and refine the values using best available information. The ATB includes both a presentation with notes (PDF) and an associated Excel Workbook. The ATB includes the following electricity generation technologies: land-based wind; offshore wind; utility-scale solar PV; concentrating solar power; geothermal power; hydropower plants (upgrades to existing facilities, powering non-powered dams, and new stream-reach development); conventional coal; coal with carbon capture and sequestration; integrated gasification combined cycle coal; natural gas combustion turbines; natural gas combined cycle; conventional biopower. Nuclear laboratory's renewable energy analysts and Energy Information Administration information for conventional technologies. The ATB will be updated annually in order to provide an up-to-date repository of current and future cost and performance data. Going forward, we plan to revise and refine the values using best available information.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

WUFI (Wärme and Feuchte Instationär)-Oak Ridge National Laboratory (ORNL)/Fraunhofer IBP

WUFI - Oak Ridge National Laboratory (ORNL)/Fraunhofer IBP is a menu-driven PC program which allows realistic calculation of the transient coupled one-dimensional heat and moisture transport in multi-layer building components exposed to natural weather. It is based on the newest findings regarding vapor diffusion and liquid transport in building materials and has been validated by detailed comparison with measurements obtained in the laboratory and on outdoor testing fields. Together with Oak Ridge National Laboratory (ORNL) Fraunhofer IBP has developed a special version of WUFI ® for North America. WUFI® ORNL is a functionally limited free version of WUFI® Pro for non-commercial purposes. It contains climate data for 62 cities in the USA and Canada which are all available in the free version. http://web.ornl.gov/sci/ees/etsd/btric/wufi/ http://www.WUFI.com/ORNL

Manfred Kehrer, ORNL↗

Special Technology Laboratory (STL) Capabilities

Special Technologies Laboratory (STL), located in Santa Barbara, California, was formed in 1986 to provide specialized solutions to national security problems. This highly diverse science and engineering laboratory includes a team dedicated to supporting the programmatic mission of the NNSA in collaboration with key National Laboratories. STL’s workforce is highly leveraged across a variety of other national security activities. Our culture is one of sponsor focus, collaboration, quick response, and technical achievement. Key staff have training and experience in radiation physics, shock physics, optical spectroscopy, mechanical and electrical engineering, and are supported by seasoned prototype engineers and fabricators. This background has enabled us to develop and advance critical diagnostics for NNSA science experiments.

DiBenedetto, John A.↗

International Safeguards and the Pacific Northwest National Laboratory

Established in 1965, Pacific Northwest National Laboratory’s (PNNL) strong technical ties and shared heritage with the nearby U.S. Department of Energy Hanford Site were central to the early development of expertise in nuclear fuel cycle signatures, separations chemistry, plutonium chemistry, environmental monitoring, modeling and analysis of reactor systems, and nuclear material safeguards and security. From these Hanford origins, PNNL has grown into a multi-program science and engineering enterprise that utilizes this diversity to strengthen the international safeguards regime. Today, PNNL supports the International Atomic Energy Agency (IAEA) in its mission to provide assurances to the international community that nations do not use nuclear materials and equipment outside of peaceful uses. PNNL also serves in the IAEA’s Network of Analytical Laboratories (NWAL) by providing analysis of environmental samples gathered around the world. PNNL is involved in safeguards research and development activities in support of many U.S. Government programs such as the National Nuclear Security Administration’s (NNSA) Office of Research and Development, NNSA Office of Nonproliferation and Arms Control, and the U.S. Support Program to IAEA Safeguards. In addition to these programs, PNNL invests internal resources including safeguards-specific training opportunities for staff, and laboratory-directed research and development funding to further ideas that may grow into new capabilities. This paper and accompanying presentation highlight some of PNNL’s contributions in technology development, implementation concepts and approaches, policy, capacity building, and human capital development, in the field of international safeguards.

Olsen, Khris B.↗