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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
DOE OSTI2013

ON THE FORMATION OF DIPEPTIDES IN INTERSTELLAR MODEL ICES

The hypothesis of an exogenous origin and delivery of biologically important molecules to early Earth presents an alternative route to their terrestrial in situ formation. Dipeptides like Gly-Gly detected in the Murchison meteorite are considered as key molecules in prebiotic chemistry because biofunctional dipeptides present the vital link in the evolutionary transition from prebiotic amino acids to early proteins. However, the processes that could lead to the exogenous abiotic synthesis of dipeptides are unknown. Here, we report the identification of two proteinogenic dipeptides-Gly-Gly and Leu-Ala-formed via electron-irradiation of interstellar model ices followed by annealing the irradiated samples to 300 K. Our results indicate that the radiation-induced, non-enzymatic formation of proteinogenic dipeptides in interstellar ice analogs is facile. Once synthesized and incorporated into the ''building material'' of solar systems, biomolecules at least as complex as dipeptides could have been delivered to habitable planets such as early Earth by meteorites and comets, thus seeding the beginning of life as we know it.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

RADIATIVE INTERACTION OF SHOCKS WITH SMALL INTERSTELLAR CLOUDS AS A PRE-STAGE TO STAR FORMATION

Cloud compression by external shocks is believed to be an important triggering mechanism for gravitational collapse and star formation in the interstellar medium. We have performed MHD simulations to investigate whether the radiative interaction between a shock wave and a small interstellar cloud can induce the conditions for Jeans instability and how the interaction is influenced by magnetic fields of different strengths and orientation. The simulations use the NIRVANA code in three dimensions with anisotropic heat conduction and radiative heating/cooling at an effective resolution of 100 cells per cloud radius. Our cloud has radius 1.5 pc, has density 17 cm{sup -3}, is embedded in a medium of density 0.17 cm{sup -3}, and is struck by a planar Mach 30 shock wave. The simulations produce dense, cold fragments similar to those of Mellema et al. and Fragile et al. We do not find any regions that are Jeans unstable but do record transient cloud density enhancements of factors {approx}10{sup 3}-10{sup 5} for the bulk of the cloud mass, which then decline and converge toward seemingly stable net density enhancement factors {approx}10{sup 2}-10{sup 4}. Our run with a weak, initial magnetic field ({beta} = 10{sup 3}) perpendicular to the shock normal stands out as producing the most lasting density enhancements. We interpret this field strength as being the compromise between weak internal magnetic pressure preventing compression and sufficiently strong magnetic field to thermally insulate the condensations, thus helping them cool radiatively.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

ON THE FORMATION OF SILACYCLOPROPENYLIDENE (c-SiC{sub 2}H{sub 2}) AND ITS ROLE IN THE ORGANOSILICON CHEMISTRY IN THE INTERSTELLAR MEDIUM

Organosilicon species such as silicon carbide and silicon dicarbide are considered as key molecular building blocks in the chemical evolution of the interstellar medium and are associated with the formation of silicon-carbide dust grains in the outflow of circumstellar envelopes of carbon-rich asymptotic giant branch (AGB) stars. However, the formation mechanisms of even the simplest silicon-bearing organic molecules have remained elusive for decades. Here, we demonstrate in crossed molecular beam experiments combined with ab initio calculations that the silacyclopropenylidene molecule (c-SiC{sub 2}H{sub 2}) can be synthesized in the gas phase under single-collision conditions via the reaction of the silylidyne radical (SiH) with acetylene (C{sub 2}H{sub 2}). This system denotes the simplest representative of a previously overlooked reaction class, in which the formation of an organosilicon molecule can be initiated via barrierless and exoergic reactions of silylidyne radicals with hydrocarbon molecules in circumstellar envelopes of evolved carbon stars such as IRC+10216. Since organosilicon molecules like silacyclopropenylidene can be eventually photolyzed to carbon-silicon clusters such as silicon dicarbide (c-SiC{sub 2}), silacyclopropenylidene might even represent the missing link between simple molecular precursors and silicon-carbide-rich interstellar grains.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

EXPLORING THE POTENTIAL FORMATION OF ORGANIC SOLIDS IN CHONDRITES AND COMETS THROUGH POLYMERIZATION OF INTERSTELLAR FORMALDEHYDE

Polymerization of interstellar formaldehyde, first through the formose reaction and then through subsequent condensation reactions, provides a plausible explanation for how abundant and highly chemically complex organic solids may have come to exist in primitive solar system objects. In order to gain better insight on the reaction, a systematic study of the relationship of synthesis temperature with resultant molecular structure was performed. In addition, the effect of the presence of ammonia on the reaction rate and molecular structure of the product was studied. The synthesized formaldehyde polymer is directly compared to chondritic insoluble organic matter (IOM) isolated from primitive meteorites using solid-state {sup 13}C nuclear magnetic resonance, Fourier transform infrared, and X-ray absorption near edge structure spectroscopy. The molecular structure of the formaldehyde polymer is shown to exhibit considerable similarity at the functional group level with primitive chondritic IOM. The addition of ammonia to the solution enhances the rate of polymerization reaction at lower temperatures and results in substantial incorporation of nitrogen into the polymer. Morphologically, the formaldehyde polymer exists as submicron to micron-sized spheroidal particles and spheroidal particle aggregates that bare considerable similarity to the organic nanoglobules commonly observed in chondritic IOM. These spectroscopic and morphological data support the hypothesis that IOM in chondrites and refractory organic carbon in comets may have formed through the polymerization of interstellar formaldehyde after planetesimal accretion, in the presence of liquid water, early in the history of the solar system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

THE HELIOTAIL REVEALED BY THE INTERSTELLAR BOUNDARY EXPLORER

Recent combined observations from the first three years of Interstellar Boundary Explorer (IBEX) data allow us to examine the heliosphere's downwind region-the heliotail-for the first time. In contrast to a preliminary identification of a narrow ''offset heliotail'' structure, we find a broad slow solar wind plasma sheet crossing essentially the entire downwind side of the heliosphere at low to mid-latitudes, with fast wind tail regions to the north and south. The slow wind plasma sheet exhibits the steepest ENA spectra in the IBEX sky maps, appears as a two-lobed structure (lobes on the port and starboard sides), and is twisted in the sense of (but at a smaller angle than) the external magnetic field. The overall heliotail structure clearly demonstrates the intermediate nature of the heliosphere's interstellar interaction, where both the external dynamic and magnetic pressures strongly affect the heliosphere.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

SURVIVAL OF INTERSTELLAR MOLECULES TO PRESTELLAR DENSE CORE COLLAPSE AND EARLY PHASES OF DISK FORMATION

An outstanding question of astrobiology is the link between the chemical composition of planets, comets, and other solar system bodies and the molecules formed in the interstellar medium. Understanding the chemical and physical evolution of the matter leading to the formation of protoplanetary disks is an important step for this. We provide some new clues to this long-standing problem using three-dimensional chemical simulations of the early phases of disk formation: we interfaced the full gas-grain chemical model Nautilus with the radiation-magnetohydrodynamic model RAMSES, for different configurations and intensities of the magnetic field. Our results show that the chemical content (gas and ices) is globally conserved during the collapsing process, from the parent molecular cloud to the young disk surrounding the first Larson core. A qualitative comparison with cometary composition suggests that comets are constituted of different phases, some molecules being direct tracers of interstellar chemistry, while others, including complex molecules, seem to have been formed in disks, where higher densities and temperatures allow for an active grain surface chemistry. The latter phase, and its connection with the formation of the first Larson core, remains to be modeled.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

CIRCULARITY OF THE INTERSTELLAR BOUNDARY EXPLORER RIBBON OF ENHANCED ENERGETIC NEUTRAL ATOM (ENA) FLUX

As a sharp feature in the sky, the ribbon of enhanced energetic neutral atom (ENA) flux observed by the Interstellar Boundary Explorer (IBEX) mission is a key signature for understanding the interaction of the heliosphere and the interstellar medium through which we are moving. Over five nominal IBEX energy passbands (0.7, 1.1, 1.7, 2.7, and 4.3 keV), the ribbon is extraordinarily circular, with a peak location centered at ecliptic (λ{sub RC}, β{sub RC}) = (219.°2 ± 1.°3, 39.°9 ± 2.°3) and a half cone angle of φ{sub C} = 74.°5 ± 2.°0. A slight elongation of the ribbon, generally perpendicular to the ribbon center-heliospheric nose vector and with eccentricity ∼0.3, is observed over all energies. At 4.3 keV, the ribbon is slightly larger and displaced relative to lower energies. For all ENA energies, a slice of the ribbon flux peak perpendicular to the circular arc is asymmetric and systematically skewed toward the ribbon center. We derive a spatial coherence parameter δ{sub C} ≤ 0.014 that characterizes the spatial uniformity of the ribbon over its extent in the sky and is a key constraint for understanding the underlying processes and structure governing the ribbon ENA emission.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

Long-term evolution of decaying magnetohydrodynamic turbulence in the multiphase interstellar medium

Supersonic turbulence in the interstellar medium (ISM) is believed to decay rapidly within a flow crossing time irrespective of the degree of magnetization. However, this general consensus of decaying magnetohydrodynamic (MHD) turbulence relies on local isothermal simulations, which are unable to take into account the roles of the global structures of magnetic fields and the ISM. Utilizing three-dimensional MHD simulations including interstellar cooling and heating, we investigate decaying MHD turbulence within cold neutral medium sheets embedded in a warm neutral medium. The early evolution of turbulent kinetic energy is consistent with previous results for decaying compressible MHD turbulence characterized by rapid energy decay with a power-law form of E∝t {sup –1} and by a short decay time compared with the flow crossing time. If initial magnetic fields are strong and perpendicular to the sheet, however, long-term evolution of the kinetic energy shows that a significant amount of turbulent energy (∼0.2E {sub 0}) still remains even after 10 flow crossing times for models with periodic boundary conditions. The decay rate is also greatly reduced as the field strength increases for such initial and boundary conditions, but not if the boundary conditions are those for a completely isolated sheet. We analyze velocity power spectra of the remaining turbulence to show that in-plane, incompressible motions parallel to the sheet dominate at later times.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Search for the infrared emission features from deuterated interstellar polycyclic aromatic hydrocarbons

We report the results of a search for emission features from interstellar deuterated polycyclic aromatic hydrocarbons (PAHs) in the 4 μm region with the Infrared Camera (IRC) on board AKARI. No significant excess emission is seen in 4.3-4.7 μm in the spectra toward the Orion Bar and M17 after the subtraction of line emission from the ionized gas. A small excess of emission remains at around 4.4 and 4.65 μm, but the ratio of their intensity to that of the band emission from PAHs at 3.3-3.5 μm is estimated as 2%-3%. This is an order of magnitude smaller than the values previously reported and also those predicted by the model of deuterium depletion onto PAHs. Since the subtraction of the ionized gas emission introduces an uncertainty, the deuterated PAH features are also searched for in the reflection nebula GN 18.14.0, which does not show emission lines from ionized gas. We obtain a similar result that excess emission in the 4 μm region, if present, is about 2% of the PAH band emission in the 3 μm region. The present study does not find evidence for the presence of the large amount of deuterated PAHs that the depletion model predicts. The results are discussed in the context of deuterium depletion in the interstellar medium.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Probing Oort cloud and local interstellar medium properties via dust produced in cometary collisions

The Oort cloud remains one of the most poorly explored regions of the solar system. We propose that its properties can be constrained by studying a population of dust grains produced in collisions of comets in the outer solar system. We explore the dynamics of μm-sized grains outside the heliosphere (beyond ∼250 AU), which are predominantly affected by the magnetic field of the interstellar medium (ISM) flow past the Sun. We derive analytic models for the production and motion of small particles as a function of their birth location in the cloud and calculate the particle flux and velocity distribution in the inner solar system. These models are verified by direct numerical simulations. We show that grains originating in the Oort cloud have a unique distribution of arrival directions, which should easily distinguish them from both interplanetary and interstellar dust populations. We also demonstrate that the distribution of particle arrival velocities is uniquely determined by the mass distribution and dust production rate in the cloud. Cometary collisions within the cloud produce a flux of μm-sized grains in the inner solar system of up to several m{sup –2} yr{sup –1}. The next generation dust detectors may be sensitive enough to detect and constrain this dust population, which will illuminate the Oort cloud's properties. We also show that the recently detected mysterious population of large (μm-sized) unbound particles, which seems to arrive with the ISM flow, is unlikely to be generated by collisions of comets in the Oort cloud.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

The evolution of interstellar medium mass probed by dust emission: Alma observations at z = 0.3-2

The use of submillimeter dust continuum emission to probe the mass of interstellar dust and gas in galaxies is empirically calibrated using samples of local star-forming galaxies, Planck observations of the Milky Way, and high-redshift submillimeter galaxies. All of these objects suggest a similar calibration, strongly supporting the view that the Rayleigh-Jeans tail of the dust emission can be used as an accurate and very fast probe of the interstellar medium (ISM) in galaxies. We present ALMA Cycle 0 observations of the Band 7 (350 GHz) dust emission in 107 galaxies from z = 0.2 to 2.5. Three samples of galaxies with a total of 101 galaxies were stellar-mass-selected from COSMOS to have M {sub *} ≅ 10{sup 11} M {sub ☉}: 37 at z ∼ 0.4, 33 at z ∼ 0.9, and 31 at z = 2. A fourth sample with six infrared-luminous galaxies at z = 2 was observed for comparison with the purely mass-selected samples. From the fluxes detected in the stacked images for each sample, we find that the ISM content has decreased by a factor ∼6 from 1 to 2 × 10{sup 10} M {sub ☉} at both z = 2 and 0.9 down to ∼2 × 10{sup 9} M {sub ☉} at z = 0.4. The infrared-luminous sample at z = 2 shows a further ∼4 times increase in M {sub ISM} compared with the equivalent non-infrared-bright sample at the same redshift. The gas mass fractions are ∼2% ± 0.5%, 12% ± 3%, 14% ± 2%, and 53% ± 3% for the four subsamples (z = 0.4, 0.9, and 2 and infrared-bright galaxies).

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Anthracene clusters and the interstellar infrared emission features

The unidentified infrared bands are ubiquitous in the interstellar medium and typically attributed to emission from neutral and ionized polycyclic aromatic hydrocarbons (or PAHs). The contribution of neutral PAH clusters to these bands has been impossible to determine due to a paucity of infrared spectral data. Here we investigated neutral clusters of the three-ring PAH anthracene using FTIR absorption spectroscopy of anthracene matrix-isolated at varying concentrations in solid argon. In order to determine likely cluster structures of the embedded molecules, we also calculated theoretical absorption spectra for the anthracene monomer through hexamer using density functional theory with a dispersion correction (DFT-D). The DFT-D calculations have been calibrated for the anthracene dimer using the second-order Møller-Plesset approach. Because there is some support for the hypothesis that three or four-ring PAHs are present in the Red Rectangle nebula, we discuss the application of our results to this nebula in particular as well as to the interstellar infrared emission in general.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

First time-dependent study of H{sub 2} and H{sub 3}{sup +} ortho-para chemistry in the diffuse interstellar medium: Observations meet theoretical predictions

The chemistry in the diffuse interstellar medium (ISM) initiates the gradual increase of molecular complexity during the life cycle of matter. A key molecule that enables build-up of new molecular bonds and new molecules via proton donation is H{sub 3}{sup +}. Its evolution is tightly related to molecular hydrogen and thought to be well understood. However, recent observations of ortho and para lines of H{sub 2} and H{sub 3}{sup +} in the diffuse ISM showed a puzzling discrepancy in nuclear spin excitation temperatures and populations between these two key species. H{sub 3}{sup +}, unlike H{sub 2}, seems to be out of thermal equilibrium, contrary to the predictions of modern astrochemical models. We conduct the first time-dependent modeling of the para-fractions of H{sub 2} and H{sub 3}{sup +} in the diffuse ISM and compare our results to a set of line-of-sight observations, including new measurements presented in this study. We isolate a set of key reactions for H{sub 3}{sup +} and find that the destruction of the lowest rotational states of H{sub 3}{sup +} by dissociative recombination largely controls its ortho/para ratio. A plausible agreement with observations cannot be achieved unless a ratio larger than 1:5 for the destruction of (1, 1)- and (1, 0)-states of H{sub 3}{sup +} is assumed. Additionally, an increased cosmic-ray ionization rate to 10{sup –15} s{sup –1} further improves the fit whereas variations of other individual physical parameters, such as density and chemical age, have only a minor effect on the predicted ortho/para ratios. Thus, our study calls for new laboratory measurements of the dissociative recombination rate and branching ratio of the key ion H{sub 3}{sup +} under interstellar conditions.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Ulysses observations of magnetic waves due to newborn interstellar pickup ions. II. Application of turbulence concepts to limiting wave energy and observability

The low-frequency magnetic waves that arise from the isotropization of newborn interstellar pickup ions (PUIs) are reasonably well described by linear and quasi-linear kinetic theory in so far as those theories predict the wave frequency and polarization in the spacecraft frame. Those theories fail to describe the scarce observability of the waves. Quasilinear theory predicts that the wave power should accumulate over long periods of time as the relatively weak kinetic instability slowly adds power to the observed spectrum. At the same time it has been argued that the same wave energy must serve as a secondary source of thermal ion heating in the outer heliosphere once the initial turbulence is depleted. To the extent that turbulent transport of the wave energy acts against the spectrally confined accumulation of wave energy, turbulence should be a limiting factor in observability. We argue that turbulence does limit the observability of the waves and we use turbulence theory to predict the observed wave energy. We compare this prediction against a database of 502 wave observations attributed to newborn interstellar PUIs observed by the Ulysses spacecraft.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Interstellar scintillation of the double pulsar J0737–3039

We report a series of observations of the interstellar scintillation (ISS) of the double pulsar J0737–3039 over the course of 18 months. As in earlier work, the basic phenomenon is the variation in the ISS caused by the changing transverse velocities of each pulsar, the ionized interstellar medium (IISM), and the Earth. The transverse velocity of the binary system can be determined both by very long baseline interferometry and timing observations. The orbital velocity and inclination is almost completely determined from timing observations, but the direction of the orbital angular momentum is not known. Since the Earth's velocity is known, and can be compared with the orbital velocity by its effect on the timescale of the ISS, we can determine the orientation Ω of the pulsar orbit with respect to equatorial coordinates (Ω = 65 ± 2°). We also resolve the ambiguity (i = 88.°7 or 91.°3) in the inclination of the orbit deduced from the measured Shapiro delay by our estimate i = 88.°1 ± 0.°5. This relies on the analysis of the ISS over both frequency and time, and provides a model for the location, anisotropy, turbulence level, and transverse phase gradient of the IISM. We find that the IISM can be well-modeled during each observation, typically of a few orbital periods, but its turbulence level and mean velocity vary significantly over the 18 months.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Paramagnetic alignment of small grains: A novel method for measuring interstellar magnetic fields

We present a novel method to measure the strength of interstellar magnetic fields using ultraviolet (UV) polarization of starlight that is in part produced by weakly aligned, small dust grains. We begin with calculating the degrees of the paramagnetic alignment of small (size a ∼ 0.01 μm) and very small (a ∼ 0.001 μm) grains in the interstellar magnetic field due to the Davis-Greenstein relaxation and resonance relaxation. To calculate the degrees of paramagnetic alignment, we use Langevin equations and take into account various interaction processes essential for the rotational dynamics of small grains. We find that the alignment of small grains is necessary to reproduce the observed polarization in the UV, although the polarization arising from these small grains is negligible at the optical and infrared (IR) wavelengths. Based on fitting theoretical models to observed extinction and polarization curves, we find that the best-fit model for the case with the peak wavelength of polarization λ{sub max} < 0.55 μm requires a higher degree of alignment of small grains than for the typical case with λ{sub max} = 0.55 μm. We interpret the correlation between the systematic increase of the UV polarization relative to maximum polarization (i.e., of p(6 μm{sup –1})/p{sub max}) with λ{sub max}{sup −1} for cases of low λ{sub max} by appealing to the higher degree of alignment of small grains. We utilize the correlation of the paramagnetic alignment of small grains with the magnetic field strength B to suggest a new way to measure B using the observable parameters λ{sub max} and p(6 μm{sup –1})/p{sub max}.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

A theoretical study on the interstellar synthesis of H{sub 2}NCS{sup +} and HNCSH{sup +} cations

HNCS and NCSH molecules, recently discovered in the interstellar medium, are likely formed via the dissociative recombination of H{sub 2}NCS{sup +} or HNCSH{sup +} isomeric ions. Interstellar synthesis of the latter is discussed on theoretical grounds. The analysis of relevant potential energy surfaces suggests a key role for chemical processes in which CSH{sup +} or HCS{sup +} cations (most likely formed in CS+H{sub 3}{sup +} collisions) react with NH{sub 2} or NH{sub 3}. The astrochemical kinetic database (kida.uva.2011), appended with 7 sulfur-bearing molecules and 48 corresponding reactions, has been applied to model the evolution of HNCS, NCSH, and their cationic precursors in a quiescent molecular cloud. Based on the model and on spectroscopic predictions, for an object like TMC-1, we expect the total intensity of H{sub 2}NCS{sup +} microwave lines to be comparable to that observed for HSCN. Theoretically derived molecular parameters, of interest for radio spectroscopy, are given for the most stable cations sharing the H{sub 2}NCS{sup +} stoichiometry.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

A high-resolution study of near-infrared diffuse interstellar bands

We present high-resolution echelle spectroscopic observations of the two near-infrared (NIR) diffuse interstellar bands (DIBs) at 13175 Å and 11797.5 Å. The DIBs have been observed in a number of diffuse interstellar medium sightlines that exhibit a wide range of visual extinctions. Band profiles are similar to those seen in narrow DIBs, clearly asymmetric and can be closely fitted in most cases using two simple Gaussian components. Gaussian fits were generally found to be more successful than fits based on a multiple-cloud model using a template DIB profile. For a sample of nine objects in which both bands are observed, the strength of both NIR DIBs generally increases with A(V), and we report a correlation between the two observed bands over a large A(V) range and widely separated lines of sight. The strength of the two bands is also compared against those of two visual DIBs and the diffuse ISM aliphatic dust absorption feature at 3.4 μm previously detected in the same sightlines. We find that the NIR DIBs do not exhibit notable (anti)correlations with either. Implications of these observations on possible DIB carrier species are discussed.

79 ASTRONOMY AND ASTROPHYSICS↗