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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 649 records · Page 36
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Performance of selected polymeric materials on LDEF

The NASA Long Duration Exposure Facility (LDEF) provided a unique environmental exposure of a wide variety of materials for potential advanced spacecraft application. This paper examines the molecular level response of selected polymeric materials which flew onboard this vehicle. Polymers include epolyimide, polysulfone, and polystyrene film and polyimide, polysulfone, and epoxy matrix resin/graphite fiber reinforced composites. Several promising experimental films were also studied. Most specimens received 5.8 years of low Earth orbital (LEO) exposure on LDEF. Several samples received on 10 months of exposure. Chemical characterization techniques included ultraviolet-visible and infrared spectroscopy, thermal analysis, x-ray photoelectron spectroscopy, and selected solution property measurements. Results suggest that many molecular level effects present during the first 10 months of exposure were not present after 5.8 years of exposure for specimens on or near Row 9. Increased AO fluence near the end of the mission likely eroded away much environmentally induced surface phenomena. The objective of this work is to provide fundamental information for use in improving the performance of polymeric materials for LEO application. A secondary objective is to gain an appreciation for the constraints and limitations of results from LDEF polymeric materials experiments.

Young, Philip R.↗
NASA NTRS1995

LDEF polymeric materials: A summary of Langley characterization

The NASA Long Duration Exposure Facility (LDEF) enabled the exposure of a wide variety of materials to the low earth orbit (LEO) environment. This paper provides a summary of research conducted at the Langley Research Center into the response of selected LDEF polymers to this environment. Materials examined include graphite fiber reinforced epoxy, polysulfone, and additional polyimide matrix composites, films of FEP Teflon, Kapton, several experimental high performance polyimides, and films of more traditional polymers such as poly(vinyl toluene) and polystyrene. Exposure duration was either 10 months or 5.8 years. Flight and control specimens were characterized by a number of analytical techniques including ultraviolet-visible and infrared spectroscopy, thermal analysis, scanning electron and scanning tunneling microscopy, x-ray photoelectron spectroscopy, and, in some instances, selected solution property measurements. Characterized effects were found to be primarily surface phenomena. These effects included atomic oxygen-induced erosion of unprotected surfaces and ultraviolet-induced discoloration and changes in selected molecular level parameters. No gross changes in molecular structure or glass transition temperature were noted. The intent of this characterization is to increase our fundamental knowledge of space environmental effects as an aid in developing new and improved polymers for space application. A secondary objective is to develop benchmarks to enhance our methodology for the ground-based simulation of environmental effects so that polymer performance in space can be more reliably predicted.

Young, Philip R.↗
NASA NTRS1995

Evaluation of monthly rainfall estimates derived from the special sensor microwave/imager (SSM/I) over the tropical Pacific

Estimates of monthly rainfall have been computed over the tropical Pacific using passive microwave satellite observations from the special sensor microwave/imager (SSM/I) for the period from July 1987 through December 1990. These monthly estimates are calibrated using data from a network of Pacific atoll rain gauges in order to account for systematic biases and are then compared with several visible and infrared satellite-based rainfall estimation techniques for the purpose of evaluating the performance of the microwave-based estimates. Although several key differences among the various techniques are observed, the general features of the monthly rainfall time series agree very well. Finally, the significant error sources contributing to uncertainties in the monthly estimates are examined and an estimate of the total error is produced. The sampling error characteristics are investigated using data from two SSM/I sensors and a detailed analysis of the characteristics of the diurnal cycle of rainfall over the oceans and its contribution to sampling errors in the monthly SSM/I estimates is made using geosynchronous satellite data. Based on the analysis of the sampling and other error sources the total error was estimated to be of the order of 30 to 50% of the monthly rainfall for estimates averaged over 2.5 deg x 2.5 deg latitude/longitude boxes, with a contribution due to diurnal variability of the order of 10%.

Berg, Wesley↗
NASA NTRS1999

Structure and Morphology of Phthalocyanine Films Grown in Electrical Fields by Vapor Deposition

Phthalocyanine is a very stable organic material in the atmosphere and has been used in numerous applications, such as optical switching and optical storage devices. Although this material has already been discovered for several decades and has had extensive studies conducted on it, many properties still need to be better understood, for example, the mechanisms of forming different solid phases and of changing film morphology by external forces. Phthalocyanine has two preferred solid phases (alpha and beta phases) for which the crystal structures, surface morphology and optical properties are different. In order to investigate these phenomena and the relationship among them, phthalocyanine films have been synthesized by vapor deposition on quartz substrates with and without an external electrical field. Some substrates were coated with a very thin gold film for the electrical field. These films have been characterized using x-ray diffraction, scanning electron microscopy, Fourier transfer infrared spectroscopy, and Z-scan technique. The films have excellent chemical and thermal stability. However, the surface of these films grown without the electrical field shows flower-like morphology. When films are deposited under an electrical field (approximately 3000 V/cm), an aligned structure is revealed on the surface. A comparison of the structure, morphology, optical properties, and the growth mechanism for these films with and without an electrical field will be discussed.

Zhu, Shen↗
NASA NTRS1998

Measurements and Model Calculations of HNO4: Implications for HO(x)

Establishing a quantitative understanding of the abundance of peroxynitric acid (HNO4) is of interest because the reaction of OH with HNO4 is believed to be a significant sink for HO(x) in the lower stratosphere and upper troposphere. We present concentration profiles of KNO4 obtained by the MkIV Fourier transform infrared spectrometer using the solar occultation technique during two flights, one at 35 N on 25 September 1993 (930925) and the other near 66 N on 7 May 1997 (970507). The observations of HN04 present an apparent dilemma: the calculated profile for HNO4 found using standard kinetics is in relatively good agreement with the mid-latitude observations, but the calculated profile for HNO4 found using the same kinetics overestimates the high-latitude summer observations by nearly a factor of two. Resolution of this dilemma is the focus of our investigation. We show that introduction into our photochemical model of a speculative long-wave (lambda greater than 650 nm) photolytic pathway for HNO4 leads to good agreement between theory and observation of HN04 for both the mid-latitude and high-latitude regions. Implications for the budget of HO(x) are also discussed.

Osterman, G. B.↗
NASA NTRS2001

Intercomparison of GOES-8 Imager and Sounder Land Surface Temperature Retrievals

Recent studies at the Global Hydrology and Climate Center (GHCC) have shown that the assimilation of land skin temperature (LST) tendencies into a mesoscale model can significantly improve short term forecasts of near surface temperature and moisture. The high spatial and temporal resolution of GOES derived land surface products provide valuable information about the spatial and temporal variability of the land surface forcing simulated in the model. In the GHCC studies LST was derived using a split window technique requiring at least two longwave infrared window channels and thus, utilized the 11 and 12 micron channels found on the GOES-8 Imager with a nadir spatial resolution of 4km. However, beginning with the launch of GOES-M (scheduled for mid 2001 ) and subsequent satellites the 12 micron channel will be removed from the Imager leaving only one longwave window channel. The GOES Sounder will continue to have more than one longwave infrared window channel (including a 12 micron channel) but, with a spatial resolution of 10 km nadir. LST retrievals from the newer GOES satellites will thus be derived from Sounder measurements at a reduced spatial resolution. This paper intercompares the LST retrievals from the GOES-8 Imager and Sounder. The effects on the LST retrievals due to the Sounder's reduced resolution from that of the Imager and its different longwave infrared channel characteristics are examined. The effects of transitioning from Imager to Sounder LST products on the results from model assimilation of these products are also examined.

Suggs, Ronnie J.↗
NASA NTRS2001

Imaging Radar in the Mojave Desert-Death Valley Region

The Mojave Desert-Death Valley region has had a long history as a test bed for remote sensing techniques. Along with visible-near infrared and thermal IR sensors, imaging radars have flown and orbited over the area since the 1970's, yielding new insights into the geologic applications of these technologies. More recently, radar interferometry has been used to derive digital topographic maps of the area, supplementing the USGS 7.5' digital quadrangles currently available for nearly the entire area. As for their shorter-wavelength brethren, imaging radars were tested early in their civilian history in the Mojave Desert-Death Valley region because it contains a variety of surface types in a small area without the confounding effects of vegetation. The earliest imaging radars to be flown over the region included military tests of short-wavelength (3 cm) X-band sensors. Later, the Jet Propulsion Laboratory began its development of imaging radars with an airborne sensor, followed by the Seasat orbital radar in 1978. These systems were L-band (25 cm). Following Seasat, JPL embarked upon a series of Space Shuttle Imaging Radars: SIRA (1981), SIR-B (1984), and SIR-C (1994). The most recent in the series was the most capable radar sensor flown in space and acquired large numbers of data swaths in a variety of test areas around the world. The Mojave Desert-Death Valley region was one of those test areas, and was covered very well with 3 wavelengths, multiple polarizations, and at multiple angles. At the same time, the JPL aircraft radar program continued improving and collecting data over the Mojave Desert Death Valley region. Now called AIRSAR, the system includes 3 bands (P-band, 67 cm; L-band, 25 cm; C-band, 5 cm). Each band can collect all possible polarizations in a mode called polarimetry. In addition, AIRSAR can be operated in the TOPSAR mode wherein 2 antennas collect data interferometrically, yielding a digital elevation model (DEM). Both L-band and C-band can be operated in this way, with horizontal resolution of about 5 m and vertical errors less than 2 m. The findings and developments of these earlier investigations are discussed.

Farr, Tom G.↗
NASA NTRS1995

Near-Infrared Monitoring of Model Chronic Compartment Syndrome In Exercising Skeletal Muscle

Chronic compartment syndrome (CCS) is characterized by muscle ischemia, usually in the anterior oompartment of the leg, caused by high intramuscular pressure during exercise. Dual-wave near-infrared (NIR) spectroscopy is an optical technique that allows noninvasive tracking of variations in muscle tissue oxygenation (Chance et al., 1988). We hypothesized that with a model CCS, muscle tissue oxygenation will show a greater decline during exercise and a slower recovery post-exercise than under normal conditions.

Hargens, Alan R.↗
NASA NTRS2006

Measurement Sets and Sites Commonly Used for High Spatial Resolution Image Product Characterization

Scientists within NASA's Applied Sciences Directorate have developed a well-characterized remote sensing Verification & Validation (V&V) site at the John C. Stennis Space Center (SSC). This site has enabled the in-flight characterization of satellite high spatial resolution remote sensing system products form Space Imaging IKONOS, Digital Globe QuickBird, and ORBIMAGE OrbView, as well as advanced multispectral airborne digital camera products. SSC utilizes engineered geodetic targets, edge targets, radiometric tarps, atmospheric monitoring equipment and their Instrument Validation Laboratory to characterize high spatial resolution remote sensing data products. This presentation describes the SSC characterization capabilities and techniques in the visible through near infrared spectrum and examples of calibration results.

Pagnutti, Mary↗
NASA NTRS2018

Tropical Cyclone Intensity Estimation Using Deep Convolutional Neural Networks

Estimating tropical cyclone intensity by just using satellite image is a challenging problem. With successful application of the Dvorak technique for more than 30 years along with some modifications and improvements, it is still used worldwide for tropical cyclone intensity estimation. A number of semi-automated techniques have been derived using the original Dvorak technique. However, these techniques suffer from subjective bias as evident from the most recent estimations on October 10, 2017 at 1500 UTC for Tropical Storm Ophelia: The Dvorak intensity estimates ranged from T2.3/33 kt (Tropical Cyclone Number 2.3/33 knots) from UW-CIMSS (University of Wisconsin-Madison - Cooperative Institute for Meteorological Satellite Studies) to T3.0/45 kt from TAFB (the National Hurricane Center's Tropical Analysis and Forecast Branch) to T4.0/65 kt from SAB (NOAA/NESDIS Satellite Analysis Branch). In this particular case, two human experts at TAFB and SAB differed by 20 knots in their Dvorak analyses, and the automated version at the University of Wisconsin was 12 knots lower than either of them. The National Hurricane Center (NHC) estimates about 10-20 percent uncertainty in its post analysis when only satellite based estimates are available. The success of the Dvorak technique proves that spatial patterns in infrared (IR) imagery strongly relate to tropical cyclone intensity. This study aims to utilize deep learning, the current state of the art in pattern recognition and image recognition, to address the need for an automated and objective tropical cyclone intensity estimation. Deep learning is a multi-layer neural network consisting of several layers of simple computational units. It learns discriminative features without relying on a human expert to identify which features are important. Our study mainly focuses on convolutional neural network (CNN), a deep learning algorithm, to develop an objective tropical cyclone intensity estimation. CNN is a supervised learning algorithm requiring a large number of training data. Since the archives of intensity data and tropical cyclone centric satellite images is openly available for use, the training data is easily created by combining the two. Results, case studies, prototypes, and advantages of this approach will be discussed.

tropical cyclone intensity↗
NASA NTRS1988

Optical measurements of soot and temperature profiles in premixed propane-oxygen flames

Two laser diagnostic techniques were used to measure soot volume fractions, number densities and soot particle radii in premixed propane/oxygen flat flames. The two techniques used were two wavelength extinction, using 514.5 nm to 632.8 nm and 457.9 nm to 632.8 nm wavelength combinations, and extinction/scattering using 514.5 nm light. The flames wre fuel-rich (equivalence ratios from 2.1 to 2.8) and had cold gas velocities varying from 3.4 to 5.5 cm/s. Measurements were made at various heights above the sintered-bronze, water-cooled flat flame burner with the equivalence ratio and cold gas velocity fixed. Also, measurements were made at a fixed height above the burner and fixed cold gas velocity while varying the equivalence ratio. Both laser techniques are based on the same underlying assumptions of particle size distribution and soot optical properties. Full Mie theory was used to determine the extinction coefficients K sub ext, and the scattering efficiencies, Q sub vv. Temperature measurements in the flames were made using infrared radiometry. Good agreement between the two techniques in terms of soot particle radii, number density and volume fraction was found for intensity ratios (I/I sub o) between 0.1 and 0.8. For intensity ratios higher or lower than this range, the differences in extinction coefficients at the wavelengths chosen for the two-wavelength method are too small to give accurate results for comparing particle radii and number densities. However, when comparing only soot volume fractions, the agreement between the two techniques continued to be good for intensity ratios up to 0.95.

Lyons, Valerie J.↗
NASA NTRS1988

Optical measurements of soot and temperature profiles in premixed propane-oxygen flames

Two laser diagnostic techniques were used to measure soot volume fractions, number densities and soot particle radii in premixed propane/oxygen flat flames. The two techniques used were two wavelength extinction, using 514.5 nm to 632.8 nm and 457.9 nm to 632.8 nm wavelength combinations, and extinction/scattering using 514.5 nm light. The flames were fuel-rich (equivalence ratios from 2.1 to 2.8) and had cold gas velocities varying from 3.4 to 5.5 cm/s. Measurements were made at various heights above the sintered-bronze, water-cooled flat flame burner with the equivalence ratio and cold gas velocity fixed. Also, measurements were made at a fixed height above the burner and fixed cold gas velocity while varying the equivalence ratio. Both laser techniques are based on the same underlying assumptions of particle size distribution and soot optical properties. Full Mie theory was used to determine the extinction coefficients K sub ext, and the scattering efficiencies, Q sub vv. Temperature measurements in the flames were made using infrared radiometry. Good agreement between the two techniques in terms of soot particle radii, number density and volume fraction was found for intensity ratios (I/I sub o) between 0.1 and 0.8. For intensity ratios higher or lower than this range, the differences in extinction coefficients at the wavelengths chosen for the two-wavelength method are too small to give accurate results for comparing particle radii and number densities. However, when comparing only soot volume fractions, the agreement between the two techniques continued to be good for intensity ratios up to 0.95.

Lyons, V. J.↗
NASA NTRS1983

Ab initio infrared and Raman spectra

It is pointed out that with increased computer power and improved computational techniques, such as the gradients developed in recent years, it is becoming practical to compute spectra ab initio, from the fundamental constants of nature, for systems of increasing complexity. The present investigation has the objective to explore several possible ab initio approaches to spectra, giving particular attention to infrared and nonresonance Raman. Two approaches are discussed. The sequential approach, in which first the electronic part and then later the nuclear part of the Born-Oppenheimer approximation is solved, is appropriate for small systems. The simultaneous approach, in which the electronic and nuclear parts are solved at the same time, is more appropriate for many-atom systems. A review of the newer quantum gradient techniques is provided, and the infrared and Raman spectral band contours for the water molecule are computed.

Fredkin, D. R.↗
NASA NTRS2014

Additive Manufacturing Infrared Inspection

Additive manufacturing is a rapid prototyping technology that allows parts to be built in a series of thin layers from plastic, ceramics, and metallics. Metallic additive manufacturing is an emerging form of rapid prototyping that allows complex structures to be built using various metallic powders. Significant time and cost savings have also been observed using the metallic additive manufacturing compared with traditional techniques. Development of the metallic additive manufacturing technology has advanced significantly over the last decade, although many of the techniques to inspect parts made from these processes have not advanced significantly or have limitations. Several external geometry inspection techniques exist such as Coordinate Measurement Machines (CMM), Laser Scanners, Structured Light Scanning Systems, or even traditional calipers and gages. All of the aforementioned techniques are limited to external geometry and contours or must use a contact probe to inspect limited internal dimensions. This presentation will document the development of a process for real-time dimensional inspection technique and digital quality record of the additive manufacturing process using Infrared camera imaging and processing techniques.

Gaddy, Darrell↗
NASA NTRS1997

Field Thermal Infrared Imaging Experiments

Day/night radiant temperature differences acquired from thermal imaging techniques proved effective in separating four seral stage and one deciduous forest class.

temperature↗
NASA NTRS1976

Absolute integrated intensity for the 3.44-microns NO2 band

A grating monochromator infrared spectrometer and a curve of growth technique were used to obtain the absolute integrated intensity for the 3.44 micron NO2 vibration-rotation band at very small NO2 partial pressures. The intensity was found to be 78.9 plus or minus 1.6/cm/(atm cm) at 296 K at the 95% confidence level. The study has relevance to the infrared spectral measurement of atmospheric NO2.

Shafer, J. H.↗
NASA NTRS2009

Fiber Optic Bragg Grating Sensors for Thermographic Detection of Subsurface Anomalies

Conventional thermography with an infrared imager has been shown to be an extremely viable technique for nondestructively detecting subsurface anomalies such as thickness variations due to corrosion. A recently developed technique using fiber optic sensors to measure temperature holds potential for performing similar inspections without requiring an infrared imager. The structure is heated using a heat source such as a quartz lamp with fiber Bragg grating (FBG) sensors at the surface of the structure to detect temperature. Investigated structures include a stainless steel plate with thickness variations simulated by small platelets attached to the back side using thermal grease. A relationship is shown between the FBG sensor thermal response and variations in material thickness. For comparison, finite element modeling was performed and found to agree closely with the fiber optic thermography results. This technique shows potential for applications where FBG sensors are already bonded to structures for Integrated Vehicle Health Monitoring (IVHM) strain measurements and can serve dual-use by also performing thermographic detection of subsurface anomalies.

Allison, Sidney G.↗