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NASA NTRS1977

Gaseous-fuel nuclear reactor research for multimegawatt power in space

In the gaseous-fuel reactor concept, the fissile material is contained in a moderator-reflector cavity and exists in the form of a flowing gas or plasma separated from the cavity walls by means of fluid mechanical forces. Temperatures in excess of structural limitations are possible for low-specific-mass power and high-specific-impulse propulsion in space. Experiments have been conducted with a canister filled with enriched UF6 inserted into a beryllium-reflected cavity. A theoretically predicted critical mass of 6 kg was measured. The UF6 was also circulated through this cavity, demonstrating stable reactor operation with the fuel in motion. Because the flowing gaseous fuel can be continuously processed, the radioactive waste in this type of reactor can be kept small. Another potential of fissioning gases is the possibility of converting the kinetic energy of fission fragments directly into coherent electromagnetic radiation, the nuclear pumping of lasers. Numerous nuclear laser experiments indicate the possibility of transmitting power in space directly from fission energy. The estimated specific mass of a multimegawatt gaseous-fuel reactor power system is from 1 to 5 kg/kW while the companion laser-power receiver station would be much lower in specific mass.

Thom, K.↗

NASA NTRS2022

Development of a Loop Antenna Deployment System for TEM-Based Subsurface Mars Water Detection

The subsurface of Mars has the potential to harbor existing deposits of liquid water, which are of great interest both scientifically (in the search for life) and as resources for future astronauts living on the red planet. However, the depth to a potential subsurface aquifer may be kilometers deep, which is well beyond what current surface or orbital approaches can survey while also confirming the unique signature for liquid water. Inspired by critical technology for exploring deep aquifers on Earth, we are developing the Transient H2O Reconnaissance (TH2OR) instrument at NASA’s Jet Propulsion Laboratory (JPL). TH2OR operates on the principle of transient electromagnetics (TEM), which leverages induction and electromotive force to induce a current in a subsurface water body using a loop-shaped antenna that provides both transmit and receive functions when placed on the surface. On Mars, TEM may be even more effective given the relative dryness of the subsurface compared to a more conductive, saline, liquid, water body on Earth. However, to probe deep within the subsurface (below 5 km) a large enclosed antenna is needed – specifically, a 100-m diameter effective loop or a shape with roughly equivalent area that can transmit at low frequencies (kHz-Hz). The deployment of a large-scale structure on the surface is complicated by the fact that the transmit wire must be both lightweight and robust to contact with the surface. Further, TH2OR may be delivered to the surface by a non-mobile vehicle, so it is desired that the deployment can be activated from a static location. This paper provides an overview of the deployment trade study, focusing on our current, favored approach, using a projectile wire launcher. Building on past approaches in the literature, we have developed and fielded an Earth-based, gas-projectile prototype for launching a triangle-shaped antenna onto analogue terrain. Our results compare simulated launch performance to actual field tests conducted under Earth gravity and pressure conditions. We discuss how Earth performance maps to a prospective Mars deployment under reduced gravity and pressure. We also provide lessons learned and next steps towards the development of an integrated TH2OR instrument for finding water on Mars.

Stamenkovic, Vlada↗

DOE OSTI2021

In situ X-ray imaging of pore formation mechanisms and dynamics in laser powder-blown directed energy deposition additive manufacturing

Directed energy deposition (DED) additive manufacturing (AM) is receiving growing attention in many applications, such as repair, remanufacturing, and fabrication of functionally graded structures. However, the laser-matter interactions and melt pool dynamics in laser DED with powder flow are still unclear, particularly in how pores form and flow inside the melt pool during the process. Understanding the porosity formation mechanisms is critical in the qualification, certification, and overall properties of a DED AM part. Porosity is a common phenomenon and can significantly hinder the quality of DED fabricated parts, as the pores can act as sites of crack nucleation and propagation. Here in this paper, we reveal four types of pore formation mechanisms through in-situ and operando high-speed high-resolution X-ray imaging in the DED AM process. Our results confirm that porosity within the feedstock powder induces pores in the process. We also observed pore formation mechanisms unique to the laser-based, powder-blown DED process as a result of powder delivery, keyhole dynamics, melt pool dynamics, and shield gas. High-speed X-ray images provide direct evidence for pore formation mechanisms and show that the pores related to the interaction between the delivered powder and melt pool are the largest in size in laser-based powder-blown DED AM. These results will guide porosity mitigation, elimination, and control in DED AM.

36 MATERIALS SCIENCE↗

NASA NTRS1990

High brightness neutral hydrogen in M31: A new probe of interstellar pressure

An observational parameter of our own Galaxy, the peak brightness temperature of neutral hydrogen in emission, was determined almost twenty years ago (Burton 1970). This quantity, although possessing a degree of local variations, has a remarkably consistent peak value of 125 K towards spiral arm segments with a few isolated peaks extending to 135 K, once sufficient spatial and velocity resolution are used (less than or equal to 70 pc, less than or equal to 5 km/s) to resolve the emission peaks. The higher spatial and velocity resolution of more recent surveys has not led to the detection of higher brightnesses. For many years this remarkable observational result has received little attention, primarily because similar data for other galaxies, which would allow a meaningful comparison and analysis, did not exist. Recently this situation has changed. A Westerbork survey of M33 (Deul and Van der Hulst 1987, and private comm.) with 40 pc x 8 km/s resolution has revealed consistent peak values of only 95 plus or minus 5 K (although there is still some question of whether the velocity resolution was sufficient in this case), while a Very Large Array (VLA) survey of M31 (Braun 1989a) with 35 pc x 5 km/s resolution has shown consistent peak values but at a temperature of 155 to 165 K. It has become clear that although peak HI brightness seems to be a well-defined quantity within individual galaxies (with a degree of local variation) there are very significant differences in this quantity amongst different galaxies. Researchers embarked on an observational program directed at a sample of 11 nearby galaxies: NGC 55, 247, 7793, 3031, 2366, 2403, 4236, 4826, 4736, 4244, and 5457. They hope to determine the gas properties and phases as a function of both galaxy type and position within the galaxies utilizing high resolution HI observations and optical narrow band imagery and spectroscopy which are now underway.

Braun, Robert↗

NASA NTRS1993

Ordered organic thin films self-assembled from the vapor phase

Organic films self-assembled from a liquid phase, as in Langmuir-Blodgett or adsorption from solution, have received much attention in the past decade as techniques to achieve highly oriented-ordered polymeric thin films. Many organic compounds including some of the same fatty acids have been vapor deposited as well. However, organic pigments and dyes comprise a major class of important materials which have very low solubilities yet excellent thermal stabilities, making them ideally suited for film deposition from the vapor phase. Surprisingly, such molecular systems exhibit a significant propensity to self order, a high sensitivity to deposition parameters, and a range of microstructural forms that cannot be duplicated by the less energetic mechanisms associated with solution adsorption processes. Molecular solids such as heterocyclic polynuclear aromatics are excellent candidates for film formation by vacuum deposition means. Over the past decade, our work and that of others investigating a wide variety of perylene and phthalocyanine derivatives identified five deposition parameters that can significantly affect film morphology, physical microstructure, and type and extent of ordering developed in vacuum and vapor transport grown films. These parameters are substrate temperature, deposition rate, substrate chemistry and epitaxy, ambient gas convective flows, and post deposition annealing. Examples of how each of these conditions manifest themselves in the film structure and ordering, most frequently revealed by scanning electron microscopy, reflection absorption infrared spectroscopy (RAIR), and grazing incidence x-ray diffraction (GIX), are presented.

Debe, M. K.↗

NASA NTRS2006

Summary of Stirling Convertor Testing at GRC

The NASA Glenn Research Center (GRC) has been testing free-piston Stirling convertors for potential use in radioisotope power systems. These convertors tend to be in the 35 to 80 watt electric power output range. Tests at GRC have accumulated over 80,000 hours of operation. Test articles have been received from Infinia Corporation of Kennewick, WA and from Sunpower of Athens, OH. Infinia designed and built the developmental Stirling Technology Demonstration Convertors (TDC) in addition to the more advanced Test Bed and Engineering Unit convertors. GRC has eight of the TDC's under test including two that operate in a thermal vacuum environment. Sunpower designed and developed the EE- 35 and the Advanced Stirling Convertor (ASC). GRC has six of the EE-35's and is preparing for testing multiple ASC's. Free-piston Stirling convertors for radioisotope power systems make use of non-contacting operation that eliminates wear and is suited for longterm operation. Space missions with radioisotope power systems are often considered that extend from three to 14 years. One of the key capabilities of the GRC test facility is the ability to support continuous, unattended operation. Hardware, software, and procedures for preparing the test articles were developed to support these tests. These included the processing of the convertors for minimizing the contaminants in the working fluid, developing a helium charging system for filling and for gas sample analysis, and the development of new control software and a high-speed protection circuit to insure safe, round-the-clock operation. Performance data of Stirling convertors over time is required to demonstrate that a radioisotope power system is capable of providing reliable power for multi-year missions. This paper will discuss the status of Stirling convertor testing at GRC.

Schreiber, Jeffrey G.↗

NASA NTRS2006

Summary of Stirling Convertor Testing at NASA Glenn Research Center

The NASA Glenn Research Center (GRC) has been testing free-piston Stirling convertors for potential use in radioisotope power systems. These convertors tend to be in the 35 to 80 W electric power output range. Tests at GRC have accumulated over 80,000 hr of operation. Test articles have been received from Infinia Corporation of Kennewick, Washington and from Sunpower of Athens, Ohio. Infinia designed and built the developmental Stirling Technology Demonstration Convertors (TDC) in addition to the more advanced Test Bed and Engineering Unit convertors. GRC has eight of the TDC's under test including two that operate in a thermal vacuum environment. Sunpower designed and developed the EE-35 and the Advanced Stirling Convertor (ASC). GRC has six of the EE- 35 s and is preparing for testing multiple ASC s. Free-piston Stirling convertors for radioisotope power systems make use of non-contacting operation that eliminates wear and is suited for long-term operation. Space missions with radioisotope power systems are often considered that extend from three to 14 years. One of the key capabilities of the GRC test facility is the ability to support continuous, unattended operation. Hardware, software, and procedures for preparing the test articles were developed to support these tests. These included the processing of the convertors for minimizing the contaminants in the working fluid, developing a helium charging system for filling and for gas sample analysis, and the development of new control software and a high-speed protection circuit to insure safe, round-the-clock operation. Performance data of Stirling convertors over time is required to demonstrate that a radioisotope power system is capable of providing reliable power for multi-year missions. This paper will discuss the status of Stirling convertor testing at GRC.

Schreiber, Jeffrey G.↗

DOE OSTI2023

Development of wind turbine blade recycling baselines in the United States

Over the past several years, the wind energy industry has received scrutiny regarding wind turbine blade (WTB) recycling due to the landfilling of WTBs caused by a lack of industrially viable recycling solutions. The amount of WTBs that will need to be recycled is set to increase in the United States as the deployment of wind energy is expected to rapidly grow to meet the nation's energy goals by 2035. While significant progress has been made worldwide, it is still unclear which WTB recycling solutions would be the most cost and energy effective within the United States for the existing fleet of wind turbines. To guide researchers and industry with a clear path forward, a range of options for WTB recycling in the United States are modeled through development of baseline scenarios and the use of formal life cycle assessment (LCA). Model data have been collected through literature review, industry engagement, and expert opinion regarding current end of life practices and considerations surrounding equipment, labor, and logistics. A detailed baseline for WTB decommissioning processes has been developed and used to assess alternative approaches, such as on-site shredding to compare the impacts on greenhouse gas (GHG) emissions. The developed LCA model and baseline scenarios for WTB recycling is used to assess the current WTB decommissioning practices in the United States along with emerging recycling pathways, including cement kiln co-processing and pyrolysis. Initial findings indicate that there are different approaches to decommissioning WTBs in the United States, each of which has unique implications for recycling. In light of this finding, additional results from the modeling will be used to better understand decommissioning practices and assist in making educated decisions on recycling pathways for the future. Throughout the analysis, focus was given to where international efforts might differ from the United States. WTB recycling is occurring worldwide, and different countries have different drivers for creating markets for recycled WTB materials. The contrasts and similarities between the United States and other countries offer insight to areas of opportunity that the United States could investigate and areas that can be readily transferred from existing solutions. By modeling and characterizing the current decommissioning practices and potential recycling solutions for the United States, a clearer vision will be created for pathways forward as to how to handle end of life WTBs to enable more efficient and cost-effective opportunities for material recovery from end-of-life WTBs.

Korey, Matt↗

NASA NTRS1993

Growing wheat to maturity in reduced gas pressures

The main objective of this project was to determine assimilation of CO2 and efficiency of water use in wheat grown to maturity in a low pressure total gas pressure environment. A functional test of the low pressure plant growth chamber system was accomplished in February and March of 1993 wherein this objective was partially achieved. Plants were grown to maturity in the chambers. Data were actively collected during the first 29 days. The plants were allowed to maintain themselves at the CO2 compensation point until day 45 of the study at which point active atmospheric regulation was resumed. This provided data at the vegetative and reproductive stages of the life cycle of the plants. However, this information may not be representative of the performance of the plants due to the loss of low pressure on a number of days during the study, which affected the plants by changing the pressure potential of the tissues. The performance of the system will be discussed on a component by component basis. The maintenance of the plants at the CO2 compensation point was driven by the failure of the computer program operating the system. The software problems that arose during the functional test have since been corrected. Results from the functional test also indicated that the plants were not receiving adequate light and nutrients. The growth chambers have been relocated and the growth room modified to compensate for these deficiencies.

Rykiel, Edward J., Jr.↗

NASA NTRS2020

A Second Look at 12 Candidate Dual AGNs Using BAYMAX

We present an analysis of 12 optically selected dual active galactic nucleus (AGN) candidates at z < 0.34. Each candidate was originally identified via double-peaked [O III] λ5007 emission lines and received follow-up Chandra and Hubble Space Telescope (HST) observations. Because the X-ray data are low-count (<100 counts) with small separations (<1''), a robust analysis is necessary for classifying each source. Pairing long-slit [O III] observations with existing Chandra observations, we re-analyze the X-ray observations with Bayesian AnalYsis of AGNs in X-rays to determine whether the X-ray emission from each system is more likely a single or dual point source. We find that 4 of the 12 sources are likely dual X-ray point-source systems. We examine each point source's spectra via a Monte Carlo method that probabilistically identifies the likely origin of each photon. When doing so, we find that (i) the secondary X-ray point sources in two of the systems have L(X)< 10(exp 40) erg/s, such that we cannot rule out a non-AGN origin, (ii) one source has a secondary with L(X)> 10(exp 40) erg/s but a spectrum that is too soft to definitively preclude being X-ray emitting diffuse gas that was photoionized by the primary AGN, and (iii) one system (SDSS J1126+2944) is a dual AGN. Additionally, using complementary HST observations, we analyze a subsample of systems that are visually identified as merging. Our results suggest that dual AGNs may preferentially reside in mergers with small separations, consistent with both simulations and observations.

Adi Foord↗

NASA NTRS2000

Lidar Technology at the Goddard Laser and Electro-Optics Branch

The Laser and Electro-Optics Branch at Goddard Space flight Center was established about three years ago to provide a focused center of engineering support and technology development in these disciplines with an emphasis on spaced based instruments for Earth and Space Science. The Branch has approximately 15 engineers and technicians with backgrounds in physics, optics, and electrical engineering. Members of the Branch are currently supporting a number of space based lidar efforts as well as several technology efforts aimed at enabling future missions. The largest effort within the Branch is support of the Ice, Cloud, and land Elevation Satellite (ICESAT) carrying the Geoscience Laser Altimeter System (GLAS) instrument. The ICESAT/GLAS primary science objectives are: 1) To determine the mass balance of the polar ice sheets and their contributions to global sea level change; and 2) To obtain essential data for prediction of future changes in ice volume and sea-level. The secondary science objectives are: 1) To measure cloud heights and the vertical structure of clouds and aerosols in the atmosphere; 2) To map the topography of land surfaces; and 3) To measure roughness, reflectivity, vegetation heights, snow-cover, and sea-ice surface characteristics. Our efforts have concentrated on the GLAS receiver component development, the Laser Reference Sensor for the Stellar Reference System, the GLAS fiber optics subsystems, and the prelaunch calibration facilities. We will report on our efforts in the development of the space qualified interference filter [Allan], etalon filter, photon counting detectors, etalor/laser tracking system, and instrument fiber optics, as well as specification and selection of the star tracker and development of the calibration test bed. We are also engaged in development work on lidar sounders for chemical species. We are developing new lidar technology to enable a new class of miniature lidar instruments that are compatible with small Discovery-class orbiters now in the NASA planetary program. The purpose of the lidar is to continuously profile the water vapor and dust in the Mars atmosphere from orbit in order to quantify its dynamics, their relationship in the diurnal cycles, and to infer water vapor exchange with the Mars surface. To remotely measure the water-vapor height profiles, we will use the differential absorption lidar (DIAL) technique. We are also developing a laser sensor for measuring the total column content of CO2 in the atmosphere of the earth. CO2 is the principal greenhouse gas and has increased by roughly 80 ppm in the last century and a half. We will report our efforts in the development of the laser transmitter and photon counting detector components for a Mars Orbiting DIAL system and for the CO2 sounder.

Heaps, William S.↗

NASA NTRS2012

Comparison of Inflation Processes at the 1859 Mauna Loa Flow, HI, and the McCartys Flow Field, NM

Basaltic lavas typically form channels or tubes during flow emplacement. However, the importance of sheet flow in the development of basalt ic terrains received recognition over the last 15 years. George Walke r?s research on the 1859 Mauna Loa Flow was published posthumously in 2009. In this paper he discusses the concept of endogenous growth, or inflation, for the distal portion of this otherwise channeldominated lava flow. We used this work as a guide when visiting the 1859 flow to help us better interpret the inflation history of the McCartys flow field in NM. Both well preserved flows display similar clues about the process of inflation. The McCartys lava flow field is among the you ngest (approx.3000 yrs) basaltic lava flows in the continental United States. It was emplaced over slopes of <1 degree, which is similar to the location within the 1859 flow where inflation occurred. Although older than the 1859 flow, the McCartys is located in an arid environ ment and is among the most pristine examples of sheet flow morphologies. At the meter scale the flow surface typically forms smooth, undula ting swales that create a polygonal terrain. The literature for simil ar features includes multiple explanatory hypotheses, original breakouts from adjacent lobes, or inflation related upwarping of crust or sa gging along fractures that enable gas release. It is not clear which of these processes is responsible for polygonal terrains, and it is po ssible that one explanation is not the sole cause of this morphology between all inflated flows. Often, these smooth surfaces within an inflated sheet display lineated surfaces and occasional squeeze-ups alon g swale contacts. We interpret the lineations to preserve original fl ow direction and have begun mapping these orientations to better interpret the emplacement history. At the scale of 10s to 100s of meters t he flow comprises multiple topographic plateaus and depressions. Some depressions display level floors with surfaces as described above, while some are bowl shaped with floors covered in broken lava slabs. Th e boundaries between plateaus and depressions are also typically smoo th, grooved surfaces that have been tilted to angles sometimes approaching vertical. The upper margin of these tilted surfaces displays lar ge cracks, sometimes containing squeeze-ups. The bottom boundary with smooth floored depressions typically shows embayment by younger lavas. It appears that this style of terrain represents the emplacement of an extensive sheet that experiences inflation episodes within prefer red regions where lateral spreading of the sheet is inhibited, thereby forming plateaus. Depressions are often the result of non-inflation and can be clearly identified by lateral squeeze-outs along the pit walls that form when the rising crust exposes the still liquid core of the sheet. Our current efforts are focused on.

Bleacher, Jacob E.↗

DOE OSTI2024

Heliostats with Adjustable Shape for High Concentration throughout the Day

Our motivation is to develop more efficient heliostats that can provide commercially viable solar thermal power at temperatures > 800°C. Such high temperatures will enable high-temperature industrial processes, as well as electrical generation after sunset with high efficiency. The importance of this research is that such heliostats have the potential to substantially expand the global use of solar energy, by adding solar thermal power as a major component. Thermal solar currently accounts for only 1% of all solar power (with PV being the rest), with heliostat fields providing just 0.25%. Our goals have been 1) to demonstrate a technical improvement for heliostats that can enable fields of them to more efficiently power receivers and reactors, and 2) to show a path to low-cost mass production. Our solution uses new opto-mechanical technology to correct a fundamental deficiency of present heliostats that limits their concentration, namely that they have fixed shape. Most of today’s heliostat research does not address this, but is directed simply toward cost reduction in an effort to make heliostats commercially viable. We are motivated to explore also improving heliostat efficiency, which can be done by continually changing their shape to maximize the concentration of sunlight throughout the day. This is not a new concept, but it has never been implemented in a practical, cost-effective way that approaches the theoretical limit to concentration while also improving mechanical performance; this is our goal. Our major accomplishments have been: 1) We have realized the planned design, construction, and test of a prototype heliostat that achieves the required shape changes in an 8 m2 single-piece glass mirror. The mirror is attached to a steel support frame that is automatically mechanically twisted by the heliostat drives that orient the mirror to direct sunlight to the tower-mounted receiver. Closed-loop tracking is done using a new beamsplitter camera that exploits the target-oriented mount configuration. Field tests of the heliostat show that the light is reflected through the day to always form a disc image of the sun, as needed to obtain the highest concentration. 2) We have developed the design for a field of 431 heliostats to deliver annual average of 1 MW of thermal power at 3,000 sun concentration, matched to a high-temperature ≥ 1000°C chemical reactor. 3) We have also developed, beyond the original stated goals of the project, a new concept for closed-loop tracking and shape-sensing for all the heliostats in the above field, using just 6 cameras around the concentrated reactor focus. Our research adds to the understanding of solar thermal energy by its demonstration of the technical effectiveness of a higher performing heliostat, and by its concept for a new powerful method for real-time tracking and shape sensing in the field, as described above. We have studied the economic feasibility of fields of our twisting heliostats to provide high- temperature heat at a price competitive with that of burning gas, to satisfy the DOE’s studied zero-emissions scenario, where the gas price has to include the cost of carbon capture. The project has the potential to greatly benefit the public if it helps limit global warming by 1) reducing carbon emission from industrial heating, which is currently a major contributor to the 40-billion-ton annual increase in atmospheric CO 2 . 2) Ultimately, the technology could prove to be the least expensive method to power direct air capture of CO 2 on the very large scale needed to remove the 1 trillion-ton excess of CO 2 already in the atmosphere.

14 SOLAR ENERGY↗

DOE OSTI2023

Hybrid Solar System (Final Scientific/Technical Report)

GTI Energy (GTI) teamed with the University of California at Merced (UCM) to scaleup the hybrid solar system (HSS) technology for demonstrating its performance at the US Gypsum (USG) plant in Plaster City, California. The technology integrates two-stage concentrating solar collector with matching particle thermal transport and storage (TSS) system to deliver cost-effective, and on-demand distributed high temperature industrial process heat up to 600°C with solar thermal, in this case to a gypsum kettle, to reduce its fuel use and carbon footprint. Current solar technologies, which reach these temperatures, are not distributable (towers) or cost-effective (dish). The research team developed a conceptual system design for host site retrofit, including preliminary heat balance, process flow diagram, particle to process heat exchanger and equipment placements at the site. Subsequently, parallel efforts were carried out at UCM to design, build and test a 12 m long commercial scale prototype concentrating thermal-only collector system and at GTI to design, build and test a matching 650°C capable particle TTS system. The nominal 50 kWth collector consists of a parabolic trough and three 4 m long two-stage receivers in series. Prior to on-sun testing, a 4 m long receiver was fabricated and successfully tested at 650 °C in a laboratory setting for 100 hrs of continuous operation showing less than 15% radiation loss. A 7 m wide x 17 m long parabolic trough was then installed at UCM for on-sun testing of the 12 m long receiver, and concurrently several 4 m long receivers were built. The optics of the parabolic trough were calibrated, and on-sun test were carried out on 12 m long receivers. During tests, the intense solar radiation (53x) caused the absorber tubes in the receivers to bend, reducing the overall optical efficiency. To address the bending issue, a self-consistent algorithm that includes ray tracing, thermal and deformation models was developed to perform thermal stress analysis on absorbers for parabolic solar collectors. Results obtained with this algorithm showed a dramatic rise in deformation as absorber tube length increases. A combined efficiency parameter that includes the occluded area for the mounts was developed to obtain an optimized tube length obtained. Based on the results, a length of 2.7 m for the absorber + 0.2 m for the coupler was chosen to minimize any bending and optimize optical efficiency while maintaining ease of mounting. The associated particle TTS system was designed, built and successfully tested at GTI. It includes storage, receiving and lock hoppers and piping that simulates the transfer of captured solar energy to an actual industrial furnace. Tests over 77 charge-discharge cycles demonstrated <2% particle degradation, with no problematic particle accumulations and no flow interruptions. The piping pressure drop was about 5 psi. The team also worked with Stanley Consultants (Stanley) to prepare conceptual and preliminary engineering packages to facilitate follow-on development and commercialization efforts. These include process and instrumentation diagram’s (P&ID’s), general arrangements, electrical one-line, project definitions document, equipment data sheets, schedule, and construction cost estimate for 2 MWth system. Updated HSS technology commercialization and customer engagement plans and detailed costs and evaluated market trade-offs and manufacturing.

03 NATURAL GAS↗

NASA NTRSDate not supplied

Integrated Bosch Process System Models for In-Situ Oxygen and Carbon Production

In-Situ Resource Utilization (ISRU) technology is a vital component to NASA’s mission of a sustainable presence on the Moon and Mars. Local resources can be leveraged to reduce resupply frequency and mass. Elements of the Bosch process, combined with the carbothermal reduction process, can produce oxygen on the lunar surface with minimal consumables. The Bosch process can also produce oxygen on the Martian surface by using the CO 2 -rich environment. Between both systems, adsorption pump, solar thermal energy, carbon formation reactor, and water recovery subsystems are modeled and integrated to create a functional model in MATLAB software. The model is used to simulate performance of the system and reduce mass, power, and volume requirements. This integrated system model provides a tool to scale ISRU technologies for oxygen and carbon production. The MATLAB model is created by developing a system of independent subsystem models that are solved for their quasi-steady state values which can be integrated with respect to time to determine the change in current states. A flexible time stepping method is used to ensure a high level of accuracy during periods of rapid change while still making use of a simple explicit integration method. The flexible time step is calculated for each independent subsystem and the minimum value from those is used as the overall time step. A flexible time step is calculated by dividing a resolution value, or the maximum change per time step, by the variables current rate of change. The maximum value from all points in space is used for subsystem models that contain multiple values. The process is done for every variable that is being monitored in each subsystem and the global minimum is used as that iteration’s timestep. Several assumptions used in the MATLAB model for fluid flow dynamics, such as 1-D gas flow through the sorption pump, are supported by modeling in Ansys Fluent software. The Lunar oxygen production system is outlined in Fig. 1. The carbothermal reduction subsystem uses solar energy to heat a mixture of lunar regolith and carbon powder to produce carbon monoxide. To begin, the carbon monoxide feeds to the modified Bosch subsystem along with hydrogen gas. The reactants then enter the carbon formation reactor where water and carbon powder are produced. Solar thermal energy is used to add energy to the reactor, but waste heat from the carbothermal process is another potential heat source. The water is collected and electrolyzed to produce hydrogen which reenters the Bosch subsystem, and the oxygen is stored for downstream use. The carbon powder is collected and feeds back into the carbothermal subsystem. The Martian oxygen production system uses the full Bosch process and is outlined in Fig 2. A CO 2 adsorption pump thermally cycles to scrub and pressurize CO 2 from the environment. Along with an initial supply of hydrogen, the reactants enter the Reverse Water Gas Shift Reactor (RWGSR) which produces carbon monoxide and water. Carbon monoxide and unreacted hydrogen enter the carbon formation reactor to produce water and carbon powder. The water is collected from both reactors and electrolyzed to reintroduce hydrogen and store oxygen for propellant production or life support. Carbon is removed from the carbon formation reactor and stored. The adsorption pump utilizes rapid cycle temperature swings within a stack of zeolite coated surfaces. The subsystem model solves 1-D quasi-steady conservation laws of the quasi-steady form, shown in Eq. 1, for the gas stream and heat exchange liquid to predict performance parameters such as breakthrough capacity and optimum cycle time. The source term S is used to capture interactions between the fluid flows and the sorbent. A quasi-steady-state scheme is used where no time derivatives appear in the governing equations, except for those in the source terms. This results in an autonomous system, where ∂F/∂x = ƒ(F). The fluxes F are provided at the inlet, and an explicit method is used to solve for the spatial distribution of F. The heat and mass flows to the sorbent are then extracted from the source terms. These flows are numerically integrated to produce a 1-D solution for the system’s state as a function of both time and space. The body of the adsorption pump is separated into two semi-independent models: the heat exchanger fluid flow and gas flow through the zeolite coated surfaces. Both models are solved using the above-described method to find a 1-D solution as a function of space and interact only once a timestep is taken. The interaction point is the sorbent through which all heat transfer between the two models must occur. Sorbent mass adsorption is calculated using the Lagergren model, shown in Eq. 2, where the transfer coefficient, λ D , is found by solving a system of nondimensionalized equations derived by using the heat and mass transfer analogy for transport phenomena. Using Grade 544 Type 13X zeolite as the sorbent material, the equilibrium concentration, θ eq , is calculated using the k-site Langmuir isotherm and fit parameters. Additionally, the enthalpy of adsorption used in the model is computed by interpolation of available data [1]. The subsystem model was validated using the Rapid Cycle Temperature Swing Adsorption (RC-TSA) pump. The solar thermal energy subsystem focuses on a solar concentrator concept with a heat exchanger to heat the reactants before entering the carbon formation reactor. The subsystem model assumes a fixed solar flux and reflector efficiency to calculate the reactant temperature given the incoming temperature, pressure, and exchanger geometry. The receiver is a custom manufactured series of copper blocks with serpentine channels to increase its surface area and the residence time of the reactants to heat up to 550 °C. The subsystem model was validated using a heat exchanger developed at NASA Glenn Research Center (GRC). The solar thermal energy subsystem focuses on a solar concentrator concept with a heat exchanger to heat the reactants before entering the carbon formation reactor. The subsystem model assumes a fixed solar flux and reflector efficiency to calculate the reactant temperature given the incoming temperature, pressure, and exchanger geometry. The receiver is a custom manufactured series of copper blocks with serpentine channels to increase its surface area and the residence time of the reactants to heat up to 550 °C. The subsystem model was validated using a heat exchanger developed at NASA Glenn Research Center (GRC).

In situ Resource Utilization↗

DOE OSTI2022

Mass transfer coefficients, kL, and air-CO2 ingassing rates in 3.4 m2 and 1-acre raceway ponds.

The US DOE 2016 Billion Ton Update (Langholtz 2016) projected that CO2 in flue-gas from power plants or similar sources would limit U.S. algal biofuel potential to under 5 billion gallons gasoline equivalent (gge) per year, due to lack of sufficient land, water and other requirements near such flue gas sources. 2nd generation carbon capture technologies are proposed to overcome this constraint (Davis 2017), and could expand this resource potential nearly 10-fold, assuming CO2 costs near the future, 2025 DOE NETL, goal of $40/metric ton CO2. An alternative pathway is the direct uptake of air CO2 into the algal ponds through an increase in the air-CO2 transfer rate resulting from the reaction of CO2 with hydroxide ions. However, such a ‘chemical enhancement’ in mass transfer depends on a high pH in the culture, and, by extension, the ability of microalgae to maintain high rates of carbon assimilation under such conditions. Abiotic experiments characterized the air-CO2 mass-transfer rate in 1-acre and 3.4 m2 raceway ponds as a function of pH, with rates approaching 10 g C/m2-day at pH 12 in the brackish water tested, equivalent to a biomass productivity potential of near 20 g AFDW/m2-day (@ 0.47 g C/g AFDW). The mass transfer rate was found to be nearly independent of the mass-transfer coefficient, indicating that at turbulence levels achievable in typical raceway ponds, the system is reaction rate, rather than diffusion limited. In biotic trials with an unknown green microalga, biomass productivity in ponds receiving CO2 from only direct surface air-CO2 exchange averaged 5 +/- 0.5 g AFDW/m2-day in August - September central California conditions, about half-that of experimental controls fertilized with supplemental CO2. pH in the air-only treatment reached a maximum of 10.5, supporting a model predicted air-CO2 ingassing rate between 2-3 g C/m2-day, consistent with the observed biomass carbon assimilation rate. Results suggest that unique alkaliphilic strains are required if reliant on direct in-pond air-CO2 transfer for algal inorganic carbon supply, and that reaching an economically viable biomass productivity will require strains that thrive at pH 11 and above.

09 BIOMASS FUELS↗

NASA NTRS1998

Galaxy Cluster Masses at Moderate Redshifts

The masses of galaxy clusters are dominated by dark matter, and a robust determination of their masses has the potential of indicating how much dark matter exists on large scales in the universe, and the cosmological parameter Omega. X-ray observations of galaxy clusters provide a direct measure of both the gas mass in the intra-cluster medium, and also the total gravitating mass of the cluster. We used new and archival ROSAT observations to measure these quantities for a sample of intermediate redshift clusters which have also been subject to intensive dynamical studies, in order to compare the mass estimates from different methods. We used data from 14 of the CNOC cluster sample at 0.18 less than z less than 0.55 for this study. A direct comparison of dynamical mass estimates from Carlberg, Yee & Ellingson (1997) yielded surprisingly good results. The X-ray/dynamical mass ratios have a mean of 0.96+/- 0.10, indicating that for this sample, both methods are probably yielding very robust mass estimates. Comparison with mass estimates from gravitational lensing studies from the literature showed a small systematic with weak lensing estimates, and large discrepancies with strong lensing estimates. This latter is not surprising, given that these measurement are made close to the central core, where optical and X-ray estimates are less certain, and where substructure and the effects of individual galaxies will be more pronounced. These results are presented in Lewis, Ellingson, Morris/Carlberg, 1998, submitted to the Astrophysical Journal. (Note that Lewis is Ellingson's Ph.D. thesis, who received direct support from this grant and is using this investigation as part of his thesis.) Three additional papers are in preparation. The first provides a comparison of the mass profiles as measured in X- rays and in galaxy dynamics. These profiles are difficult to determine for individual clusters, and are subject to asphericity and other individual quirks of each cluster. However, a composite profile for each method will allow us to test our assumptions of hydrostatic/dynamical equilibrium in the sample as a whole. A second paper provides a more detailed look at the cluster MS0906+11, which is a merging system. A third paper authord with J. Mohr at U. Chicago will invetigate the size-temoerature relationship for intermediate redshift clusters and its impications on cluster formation and cosmology. Future work on these data will include comparisons of the cluster galaxy populations and the extent of the intra-cluster medium, and a more homogeneous analysis of gravitational lensing.

Ellingson, E.↗

DOE OSTI2025

Using Separation-Enhanced Isotope Ratio Mass Spectrometry to Enable Increased Renewable Carbon Content in Transportation Fuels (CRADA 525)

Stable isotope ratio measurements of carbon atoms using isotope ratio mass spectrometry (IRMS) can be an effective tool for quantifying biogenic carbon in co-processed fuels, with results approaching the precision and accuracy of accelerator mass spectrometry (AMS). The lower cost of an IRMS may enable deployment to refineries, improving access and analysis turnaround times (≤2 hours), and, by extension, provide data that can allow process optimization to maximize renewable carbon in desired refinery products. This project explored the integration of chemical separation with IRMS analyses to enable highly detailed tracking of biogenic carbon into fuel product streams separated by boiling point range, chemical class, or specific compound. Forty-nine fuels and fuel components of fossil and biogenic origin, spanning gasoline and diesel boiling point ranges, were received from three refiners and were analyzed for their δ 13 C values via IRMS. Results spanned a 13 C range from ca. 10‰ to 44‰ and reflect materials derived from sustainable sources (e.g., C4 or C3 plants, animal-based pathways, syngas) or from fossil-derived fuels. Common ranges are approximately 18‰ to 9‰ and approximately 30‰ to 20‰ for C4 and C3 plants, respectively, and approximately 34‰ to 24‰ and approximately 70‰ to 33‰ for petroleum-derived fuels and methane, respectively. Fuel-like standards were developed and tested using direct-injection elemental analyzer (EA) IRMS for liquid fuels. This method was compared with the published methods, yielding statistically similar results. Four blend curve sets were produced ranging from 0% to 100% of a fuel containing biogenic carbon, focusing on 0% to 10% biogenic carbon. Linear fits were the most applicable for two of the four blend curve sets; however, two sets were found to exhibit slightly quadratic behavior, which was more pronounced in low biogenic blend samples, necessitating second-order fits. The origin of the slight quadratic behavior remains unclear; however, the discussion points to possible interpretations. CanmetENERGY thoroughly characterized a majority of the samples using one- and two-dimensional gas chromatography (GC and GC×GC, respectively) and other analyses. Selected samples were subjected to solid phase extraction (SPE) for saturate, olefin, aromatic, and polar (SOAP) analysis, and the resulting solvent-diluted fractions containing saturates and aromatics were returned to Pacific Northwest National Laboratory (PNNL), where the solvent was removed via evaporation or physical separation using GC techniques. Characterization and separations provided an understanding of saturate and aromatic content, as well as boiling point ranges for each sample and sample fraction. Samples resulting from SPE were examined using EA-IRMS and gas chromatography combustion IRMS (GC-C-IRMS) analyses. Both approaches suggest that the range in values between end-members can be increased by selecting the paraffinic or aromatic fraction of the end-member or by selecting among individual compounds resulting from GC separation of the paraffinic fractions. Considerable work remains to put these approaches into practice and statistically validate the benefit for using a fraction or individual compound over bulk analysis of a sample. However, initial results suggest that separations provide advantages for samples having blend ratios of less than 10% biogenic blendstocks. 13 C results showed statistically similar biofuel blend results to those obtained at PNNL, although additional work is needed to obtain better reproducibility. Select samples were sent to Los Alamos National Laboratory (LANL) for IRMS measurements and Beta Analytics for AMS measurements. This work suggests that IRMS and AMS yield closely comparable results and in some circumstances, IRMS could serve as a surrogate for AMS. While additional work is needed to better resolve statistical advantages for separations and better show the comparable nature of IRMS and AMS in both the biogenic carbon analysis of bulk chemical classes, initial results from this study suggest that these should be pursued in order to proliferate this approach for quantifying biogenic carbon in transportation fuels to the refinery level, thereby potentially enabling process optimization in co-processing scenarios.

09 BIOMASS FUELS↗