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At least 649 records · Page 36

Space processing applications of ion beam technology

Ion thruster engines for spacecraft propulsion can serve as ion beam sources for potential space processing applications. The advantages of space vacuum environments and the possible gravity effects on thruster ion beam materials operations such as thin film growth, ion milling, and surface texturing were investigated. The direct gravity effect on sputter deposition and vapor deposition processes are discussed as well as techniques for cold and warm welding.

Grodzka, P. G.↗

Video requirements for materials processing experiments in the space station US laboratory

Full utilization of the potential of the materials research on the Space Station can be achieved only if adequate means are available for interactive experimentation between the science facilities and ground-based investigators. Extensive video interfaces linking these three elements are the only alternative for establishing a viable relation. Because of the limit in the downlink capability, a comprehensive complement of on-board video processing, and video compression is needed. The application of video compression will be an absolute necessity since it's effectiveness will directly impact the quantity of data which will be available to ground investigator teams, and their ability to review the effects of process changes and the experiment progress. Video data compression utilization on the Space Station is discussed.

Baugher, Charles R.↗

Aerosol Retrievals Using Channel 1 and 2 AVHRR Data

The effect of tropospheric aerosols on global climate via the direct and indirect radiative forcings is one of the largest remaining uncertainties in climate change studies. Current assessments of the direct aerosol radiative effect mainly focus on sulfate aerosols. It has become clear, however, that other aerosol types like soil dust and smoke from biomass burning are also likely to be important climate forcing factors. The magnitude and even the sign of the climate forcing caused by these aerosol types is still unknown. General circulation models (GCMs) can be used to estimate the climatic effect of the direct radiative forcing by tropospheric and stratospheric aerosols. Aerosol optical properties are already parameterized in the Goddard Institute for Space Studies GCM. Once the global distribution of aerosol properties (optical thickness, size distribution, and chemical composition) is available, the calculation of the direct aerosol forcing is rather straighfforward. However, estimates of the indirect aerosol effect require additional knowledge of the physics and chemistry of aerosol-cloud interactions which are still poorly understood. One of the main objectives of the Global Aerosol Climatology Project, established in 1998 as a joint initiative of NASA's Radiation Science Program and GEWEX, is to infer the global distribution of aerosols, their properties, and their seasonal and interannual variations for the full period of available satellite data. This will be accomplished primarily through a systematic application of multichannel aerosol retrieval algorithms to existing satellite data and advanced 3-dimensional aerosol chemistry/transport models. In this paper we outline the methodology of analyzing channel 1 and 2 AVHRR radiance data over the oceans and describe preliminary retrieval results.

Mishchenko, Michael I.↗

Charge ordering in Ir dimers in the ground state of Ba 5 AlIr 2 O 11

It has been well established experimentally that the interplay of electronic correlations and spin-orbit interactions in Ir 4+ and Ir 5+ oxides results in insulating J eff = 1/2 and J eff = 0 ground states, respectively. However, in compounds where the structural dimerization of iridium ions is favorable, the direct Ir d-d hybridization can be significant and takes a key role. Here, in this study, we investigate the effects of direct Ir d-d hybridization in comparison with electronic correlations and spin-orbit coupling in Ba 5 AlIr 2 O 11 , a compound with Ir dimers. Using a combination of ab initio many-body wave-function quantum chemistry calculations and resonant inelastic x-ray scattering experiments, we elucidate the electronic structure of Ba 5 AlIr 2 O 11 . We find excellent agreement between the calculated and the measured spin-orbit excitations. Contrary to expectations, the analysis of the many-body wave function shows that the two Ir (Ir 4+ and Ir 5+ ) ions in the Ir 2 O 9 dimer unit in this compound preserve their local J eff character close to 1/2 and 0, respectively. The local point group symmetry at each of the Ir ions plays an important role, significantly limiting the direct d-d hybridization. Our results emphasize that minute details in the local crystal field environment can lead to dramatic differences in the electronic states in iridates and 5d oxides in general.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Atmospheres of the Moon and Mercury

Mercury and the Moon have long been considered to be similar objects, but this view was based on limited information at visible wavelengths. It is now known that real differences exist in the atmospheres and in the rock types as deduced from mid-infrared observations. Lunar Ar and perhaps Ne were observed from Apollo landed experiments in spite of a large local background. An ultraviolet spectrometer (UVS) in orbit placed upper limits on a number of gases including H and O. At Mercury, the UVS on Mariner 10 measured H, He, and perhaps O and again a number of upper limits for other gases. Less than a decade ago, emissions of Na and K were observed from the ground, with abundances 2 orders of magnitude smaller on the Moon than on Mercury. It is likely that impacting meteoroids bring a significant amount of water to Mercury, whose atmosphere should therefore contain water vapor. This notion is supported by the recent discovery of radar-bright polar deposits almost certainly composed of ice. A variety of origins is likely for the different components. Impact of meteoroids could supply water, Na, and K, and could also vaporize surface material; Na, K, and Ar could be degassed from the crust. H is probably from the solar wind, and He could reasonably come from degassing or the solar wind. A substantial loss process for all components is photoionization (or dissociation); ions on one side are swept away into the solar wind and on the other are swept back to the surface. This process is complicated at Mercury by its permanent magnetic field, but there is little doubt that both loss and recycling still occur. Some of the recycling probably occurs by way of the magnetotail through night side auroral precipitation; atoms implanted in the surface will diffuse back into the atmosphere shortly after dawn, an effect that seems to be present for K. Finally the light atoms H and He have high enough velocities to escape directly, an effect that may be enhanced by the suprathermal velocity distributions that are likely to be present.

Hunten, D. M.↗

Commensuration effects on skyrmion Hall angle and drag for manipulation of skyrmions on two-dimensional periodic substrates

Here, we examine the dynamics of an individually driven skyrmion moving through a background lattice of skyrmions coupled to a 2D periodic substrate as we vary the ratio of the number of skyrmions to the number of pinning sites across commensurate and incommensurate conditions. As the skyrmion density increases, the skyrmion Hall angle is nonmonotonic, dropping to low or zero values in commensurate states and rising to an enhanced value in incommensurate states. Under commensuration, the driven skyrmion is channeled by a symmetry direction of the pinning array and exhibits an increased velocity. At fillings for which the skyrmion Hall angle is zero, the velocity has a narrow band noise signature, while for incommensurate fillings, the skyrmion motion is disordered and the velocity noise is broad band. Under commensurate conditions, multi-step depinning transitions appear and the skyrmion Hall angle is zero at low drives but becomes finite at higher drives, while at incommensurate fillings there is only a single depinning transition. As the gyrotropic component of the skyrmion dynamics, called the Magnus force, increases, peaks in the velocity that appear in commensurate regimes cross over to dips, and new types of directional locking effects can arise in which the skyrmion travels along other symmetry directions of the background lattice. At large Magnus forces, and particularly at commensurate fillings, the driven skyrmion can experience a velocity boost in which the skyrmion moves faster than the applied drive due to the alignment of the Magnus-induced velocity with the driving direction. In some cases, an increase of the Magnus force can produce regimes of enhanced pinning when the skyrmion is forced to move along a nonsymmetry direction of the periodic pinning array. This is in contrast to systems with random pinning, where increasing the Magnus force generally reduces the pinning effect. We demonstrate these dynamics for both square and triangular substrates and map out the different regimes as a function of filling fraction, pinning force, and the strength of the Magnus force in a series of dynamic phase diagrams.

36 MATERIALS SCIENCE↗

Directional and Spectral Irradiance in Ocean Models: Effects on Simulated Global Phytoplankton, Nutrients, and Primary Production

The importance of including directional and spectral light in simulations of ocean radiative transfer was investigated using a coupled biogeochemical-circulation-radiative model of the global oceans. The effort focused on phytoplankton abundances, nutrient concentrations and vertically-integrated net primary production. The importance was approached by sequentially removing directional (i.e., direct vs. diffuse) and spectral irradiance and comparing results of the above variables to a fully directionally and spectrally-resolved model. In each case the total irradiance was kept constant; it was only the pathways and spectral nature that were changed. Assuming all irradiance was diffuse had negligible effect on global ocean primary production. Global nitrate and total chlorophyll concentrations declined by about 20% each. The largest changes occurred in the tropics and sub-tropics rather than the high latitudes, where most of the irradiance is already diffuse. Disregarding spectral irradiance had effects that depended upon the choice of attenuation wavelength. The wavelength closest to the spectrally-resolved model, 500 nm, produced lower nitrate (19%) and chlorophyll (8%) and higher primary production (2%) than the spectral model. Phytoplankton relative abundances were very sensitive to the choice of non-spectral wavelength transmittance. The combined effects of neglecting both directional and spectral irradiance exacerbated the differences, despite using attenuation at 500 nm. Global nitrate decreased 33% and chlorophyll decreased 24%. Changes in phytoplankton community structure were considerable, representing a change from chlorophytes to cyanobacteria and coccolithophores. This suggested a shift in community function, from light-limitation to nutrient limitation: lower demands for nutrients from cyanobacteria and coccolithophores favored them over the more nutrient-demanding chlorophytes. Although diatoms have the highest nutrient demands in the model, their relative abundances were generally unaffected because they only prosper in nutrient-rich regions, such as the high latitudes and upwelling regions, which showed the fewest effects from the changes in radiative simulations. The results showed that including directional and spectral irradiance when simulating the ocean light field can be important for ocean biology, but the magnitude varies with variables and regions. The quantitative results are intended to assist ocean modelers when considering improved irradiance representations relative to other processes or variables associated with the issues of interest.

Phytoplankton↗

Exploring the Elevated Water Vapor Signal Associated with Biomass Burning Aerosol over the Southeast Atlantic Ocean

The quantification of radiative forcing due to the cumulative effects of aerosols, both directly and on cloud properties, remains the biggest source of uncertainty in our understanding of the physical climate. How the magnitude of these effects may be modified by meteorological conditions is an important aspect of this question. The Southeast Atlantic Ocean (SEA), with seasonal biomass burning (BB) smoke plumes overlying a persistent stratocumulus cloud deck, offers a perfect natural observatory in which to study the complexities of aerosol-cloud interactions. The NASA ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) campaign consists of three field deployments over three years (2016-2018) with the goal of gaining a better understanding of the complex processes (direct and indirect) by which BB aerosols affect clouds. We present results from the first ORACLES field deployment, which took place in September 2016 out of Walvis Bay, Namibia. Two NASA aircraft were flown with a suite of aerosol, cloud, radiation, and meteorological instruments for remote-sensing and in-situ observations. A strong correlation was observed between the aircraft-measured pollution indicators (carbon monoxide and aerosol properties) and atmospheric water vapor content, at all altitudes. Atmospheric reanalysis indicates that convective dynamics over the continent, near likely contribute to this elevated signal. Understanding the mechanisms by which water vapor covaries with plume strength is important to quantifying the magnitude of the aerosol direct and semi-direct effects in the region.

Pistone, Kristina↗

Gyrokinetic simulations of electrostatic microturbulence in ADITYA-U tokamak

Global gyrokinetic simulations of the electrostatic microturbulence driven by the pressure gradients of thermal ions and electrons are carried out for the ADITYA-U tokamak geometry using its experimental plasma profiles and with collisional effects. The dominant instability is trapped electron mode (TEM) based on the linear eigenmode structure and its propagation in the electron diamagnetic direction. Collisional effects suppress turbulence and transport to a certain extent. Zonal flow is not playing a critical role in the TEM saturation, which is dominated by the inverse cascade. The frequency spectrum of the electrostatic fluctuations is in broad agreement with the experimentally recorded spectrum in the ADITYA-U, with a bandwidth ranging from ~0 to 50 kHz.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Supersonic Aftbody Closure Wind-Tunnel Testing, Data Analysis, and Computational Results

This paper reports on the model, test, and results from the Langley Supersonic Aftbody Closure wind tunnel test. This project is an experimental evaluation of the 1.5% Technology Concept Aircraft (TCA) aftbody closure model (Model 23) in the Langley Unitary Plan Wind Tunnel. The baseline TCA design is the result of a multidisciplinary, multipoint optimization process and was developed using linear design and analysis methods, supplemented with Euler and Navier-Stokes numerical methods. After a thorough design review, it was decided to use an upswept blade attached to the forebody as the mounting system. Structural concerns dictated that a wingtip support system would not be feasible. Only the aftbody part of the model is metric. The metric break was chosen to be at the fuselage station where prior aft-sting supported models had been truncated. Model 23 is thus a modified version of Model 20. The wing strongback, flap parts, and nacelles from Model 20 were used, whereas new aftbodies, a common forebody, and some new tails were fabricated. In summary, significant differences in longitudinal and direction stability and control characteristics between the ABF and ABB aftbody geometries were measured. Correcting the experimental data obtained for the TCA configuration with the flared aftbody to the representative of the baseline TCA closed aftbody will result in a significant reduction in longitudinal stability, a moderate reduction in stabilizer effectiveness and directional stability, and a moderate to significant reduction in rudder effectiveness. These reductions in the stability and control effectiveness levels of the baseline TCA closed aftbody are attributed to the reduction in carry-over area.

Allen, Jerry↗

Flicker: A review of temporal light modulation stimulus, responses, and measures

Flicker has been an important lighting system consideration for over a century. More precise terms are temporal light modulation (TLM) as the stimulus, and responses to TLM as the unwanted visual, cognitive, or physiological consequences. As lighting technology evolved, different forms of TLM emerged, and so did responses to them. Today, some LED systems – encompassing the LED, driver, and control – can result in TLM causing severe unwanted effects, while other LED systems produce no unwanted effects at all. LED systems can deliver a much wider range of luminous waveforms than conventional lighting systems, some exhibiting very high modulation depths. More than any light source before, they can elicit perceptions of the phantom array. Direct flicker effects at modulation frequencies less than about 80 Hz and the stroboscopic effect at frequencies greater than 80 Hz are fairly well understood, but the phantom array effect needs more exploration and characterisation. This review focuses on the technology and research history that led to current metrics for quantifying TLM and human responses to TLM. Notably, visually impaired individuals may exhibit alterations in their response to TLM, but such a discussion is beyond the intent of this review. Thus, the focus is on individuals with normal visual function.

60 APPLIED LIFE SCIENCES↗

Direct Aerosol Radiative Forcing: Calculations and Measurements from the Tropospheric

Radiative forcing is defined as the change in the net (downwelling minus upwelling) radiative flux at a given level in the atmosphere. This net flux is the radiative power density available to drive climatic processes in the earth-atmosphere system below that level. Recent research shows that radiative forcing by aerosol particles is a major source of uncertainty in climate predictions. To reduce those uncertainties, TARFOX was designed to determine direct (cloud-free) radiative forcing by the aerosols in one of the world's major industrial pollution plumes--that flowing from the east coast of the US over the Atlantic Ocean. TARFOX measured a variety of aerosol radiative effects (including direct forcing) while simultaneously measuring the chemical, physical, and optical properties of the aerosol particles causing those effects. The resulting data sets permit a wide variety of tests of the consistency, or closure, among the measurements and the models that link them. Because climate predictions use the same or similar model components, closure tests help to assess and reduce prediction uncertainties. In this work we use the TARFOX-determined aerosol, gas, and surface properties to compute radiative forcing for a variety of aerosol episodes, with inadvisable optical depths ranging from 0.07 to 0.6. We calculate forcing by several techniques with varying degrees of sophistication, in part to test the range of applicability of simplified techniques--which are often the only ones feasible in climate predictions by general circulation models (GCMs). We then compare computed forcing to that determined from: (1) Upwelling and downwelling fluxes (0.3-0.7 mm and 0.7-3.0 mm) measured by radiometers on the UK MRF C-130. and (2) Daily average cloud-free absorbed solar and emitted thermal radiative flux at the top of the atmosphere derived from the AVHRR radiometer on the NOAA- 14 satellite. The calculations and measurements all yield aerosol direct radiative forcing in the range -50 to -190 W sq m per unit inadvisable optical depth. The magnitudes are about 15 to 100 times larger than the global-average direct forcing expected for the global-average sulfate aerosol optical depth of 0.04. The reasons for the larger forcing in TARFOX include the relatively large optical depths and the focus on cloud-free, daytime conditions over the dark ocean surface. These are the conditions that produce the actual major radiative forcing events that contribute to any global-average climate effect. Detailed comparisons of calculated and measured forcings for specific events are used for more refined tests of closure.

Russell, P. B.↗

Pair momentum dependence of a tilted source in heavy-ion collisions

In noncentral heavy-ion collisions, the particle-emitting source can be tilted away from the beam direction, an effect that becomes particularly significant at collision energies of a few GeV and lower. This phenomenon, manifest itself in many observables such as directed flow, polarization, and vorticity, is therefore important to investigate. Here, in this paper, we study the consistency between the tilt extracted directly from the freeze-out distribution of pions and the tilt parameter obtained using the azimuthally sensitive femtoscopy (asHBT) method. Using the Ultrarelativistic Quantum Molecular Dynamics model, we demonstrate a strong dependence of the tilt parameter extracted with asHBT on the momentum of the particle pair. Considering the experimental challenges in accessing low particle momenta—where the tilt parameter extracted with asHBT closely matches the tilt of the freeze-out distribution of pions—we propose an exponential extrapolation method to obtain the tilt of the entire freeze-out distribution. This approach aims to enhance the accuracy of experimental measurements of tilt in noncentral heavy-ion collisions.

particle correlations & fluctuations↗

Structure-guided design of direct-acting antivirals that exploit the gem-dimethyl effect and potently inhibit 3CL proteases of severe acute respiratory syndrome Coronavirus-2 (SARS-CoV-2) and middle east respiratory syndrome coronavirus (MERS-CoV)

The high morbidity and mortality associated with SARS-CoV-2 infection, the etiological agent of COVID-19, has had a major impact on global public health. Significant progress has been made in the development of an array of vaccines and biologics, however, the emergence of SARS-CoV-2 variants and breakthrough infections are an ongoing major concern. Furthermore, there is an existing paucity of small-molecule host and virus-directed therapeutics and prophylactics that can be used to counter the spread of SARS-CoV-2, and any emerging and re-emerging coronaviruses. Here, we describe herein our efforts to address this urgent need by focusing on the structure-guided design of potent broad-spectrum inhibitors of SARS-CoV-2 3C-like protease (3CL pro or Main protease), an enzyme essential for viral replication. The inhibitors exploit the directional effects associated with the presence of a gem-dimethyl group that allow the inhibitors to optimally interact with the S4 subsite of the enzyme. Several compounds were found to potently inhibit SARS-CoV-2 and MERS-CoV 3CL proteases in biochemical and cell-based assays. Specifically, the EC50 values of aldehyde 1c and its corresponding bisulfite adduct 1d against SARS-CoV-2 were found to be 12 and 10 nM, respectively, and their CC50 values were >50 μM. Furthermore, deuteration of these compounds yielded compounds 2c/2d with EC50 values 11 and 12 nM, respectively. Replacement of the aldehyde warhead with a nitrile (CN) or an α-ketoamide warhead or its corresponding bisulfite adduct yielded compounds 1g, 1e and 1f with EC50 values 60, 50 and 70 nM, respectively. High-resolution cocrystal structures have identified the structural determinants associated with the binding of the inhibitors to the active site of the enzyme and, furthermore, have illuminated the mechanism of action of the inhibitors. Overall, the high Safety Index (SI) (SI=CC50/EC50) displayed by these compounds suggests that they are well-suited to conducting further preclinical studies.

3-Chymotrypsin-like protease (3CLpro)↗

Effects of vortex flaps on the low-speed aerodynamic characteristics of an arrow wing

Tests were conducted in the Langley 12-foot low-speed wind-tunnel to determine the longitudinal and lateral-directional aerodynamic effects of plain and tabbed vortex flaps on a flat-plate, highly swept arrow-wing model. Flow-visualization studies were made using a helium-bubble technique. Static forces and moments were measured over an angle-of-attack range from 0 deg to 50deg for sideslip angles of 0 deg and + or - 4 deg.

Yip, L. P.↗

Deep space communications, weather effects, and error control

Deep space telemetry is and will remain signal-to-noise limited and vulnerable to interference. A need exists to increase received signal power and decrease noise. This includes going to Ka-band in the mid-1990's to increase directivity. The effects of a wet atmosphere can increase the noise temperature by a factor of 5 or more, even at X-band, but the order of magnitude increase in average data rate obtainable at Ka-band relative to X-band makes the increased uncertainty a good trade. Lowbit error probabilities required by data compression are available both theoretically and practically with coding, at an infinitesimal power penalty rather than the 10 to 15 dB more power required to reduce error probabilities without coding. Advances are coming rapidly in coding, as with the new constraint-length 15 rate 1/4 convolutional code concatenated with the already existing Reed-Solomon code to be demonstrated on Galileo. In addition, high density spacecraft data storage will allow selective retransmissions, even from the edge of the Solar System, to overcome weather effects. In general, deep space communication was able to operate, and will continue to operate, closer to theoretical limits than any other form of communication. These include limits in antenna area and directivity, system noise temperature, coding efficiency, and everything else. The deep space communication links of the mid-90's and beyond will be compatible with new instruments and compression algorithms and represent a sensible investment in an overall end-to-end information system design.

Posner, Edward C.↗

A review of coarse mineral dust in the Earth system

Mineral dust particles suspended in the atmosphere span more than three orders of magnitude in diameter, from <0.1 µm to more than 100 µm. This wide size range makes dust a unique aerosol species with the ability to interact with many aspects of the Earth system, including radiation, clouds, hydrology, atmospheric chemistry, and biogeochemistry. This review focuses on coarse and super-coarse dust aerosols, which we respectively define as dust particles with a diameter of 2.5–10 µm and 10–62.5 µm. We review several lines of observational evidence indicating that coarse and super-coarse dust particles are transported farther than previously expected and that the abundance of these particles is substantially underestimated in current global models. We synthesize previous studies that used observations, theories, and model simulations to highlight the impacts of coarse and super-coarse dust aerosols on the Earth system, including their effects on dust-radiation interactions, dust-cloud interactions, atmospheric chemistry, and biogeochemistry. Specifically, coarse and super-coarse dust aerosols produce a net positive direct radiative effect (warming) at the top of the atmosphere and can modify temperature and water vapor profiles, influencing the distribution of clouds and precipitation. In addition, coarse and super-coarse dust aerosols contribute a substantial fraction of ice-nucleating particles, especially at temperatures above –23 °C. They also contribute a substantial fraction to the available reactive surfaces for atmospheric processing and the dust deposition flux that impacts land and ocean biogeochemistry by supplying important nutrients such as iron and phosphorus. Furthermore, we examine several limitations in the representation of coarse and super-coarse dust aerosols in current model simulations and remote-sensing retrievals. Because these limitations substantially contribute to the uncertainties in simulating the abundance and impacts of coarse and super-coarse dust aerosols, we offer some recommendations to facilitate future studies. Overall, we conclude that an accurate representation of coarse and super-coarse properties is critical in understanding the impacts of dust aerosols on the Earth system.

54 ENVIRONMENTAL SCIENCES↗

Net Radiative Effects of Dust in the Tropical North Atlantic Based on Integrated Satellite Observations and in Situ Measurements

In this study, we integrate recent in situ measurements with satellite retrievals of dust physical and radiative properties to quantify dust direct radiative effects on shortwave (SW) and longwave (LW) radiation (denoted as DRESW and DRELW, respectively) in the tropical North Atlantic during the summer months from 2007 to 2010. Through linear regression of the CERES-measured top-of atmosphere (TOA) flux versus satellite aerosol optical depth (AOD) retrievals, we estimate the instantaneous DRESW efficiency at the TOA to be -49+/-7.1 W/sq.m AOD(exp -1) and -36+/-4:8W/sq.m AOD(exp -1) based on AOD from MODIS and CALIOP, respectively. We then perform various sensitivity studies based on recent measurements of dust particle size distribution (PSD), refractive index, and particle shape distribution to determine how the dust microphysical and optical properties affect DRE estimates and its agreement with the above-mentioned satellite-derived DREs. Our analysis shows that a good agreement with the observation-based estimates of instantaneous DRESW and DRELW can be achieved through a combination of recently observed PSD with substantial presence of coarse particles, a less absorptive SW refractive index, and spheroid shapes. Based on this optimal combination of dust physical properties we further estimate the diurnal mean dust DRE(sub SW) in the region of -10W/sq.m at TOA and -26W/sq.m at the surface, respectively, of which ~30% is canceled out by the positive DRE(sub LW). This yields a net DRE of about -6:9 and -18.3 W/sq.m at TOA and the surface, respectively. Our study suggests that the LW flux contains useful information on dust particle size, which could be used together with SW observations to achieve a more holistic understanding of the dust radiative effect.

Song, Qianqian↗