Compact Li-doped Gd{sub 2}Ti{sub 2}O{sub 7} prepared with LiO{sub 0.5} self-flux
Graphical abstract: Left figure is the unit cell a-axis of the GLT-2L (■), GLT (●) and GT (▴) as a function of x. Both of the GLT-2L and GLT have the same results so that they have the same chemical formula, (Gd{sub 2−x}Li{sub x})Ti{sub 2}O{sub 7−x}, in which GT has a formula of Gd{sub 2−x}Ti{sub 2}O{sub 7−x}. Relative densities are shown in the right figure. GLT-2L (■) has higher values than GLT (●). 2x moles of LiO{sub 0.5} were added as a self-flux to prepare GLT-2L at 1250 °C, which was about 300 °C lowered than required without the co-existence of the flux and Li ion substitution. - Highlights: • A new series of compounds with a formula as (Gd{sub 2−x}Li{sub x})Ti{sub 2}O{sub 7−x} was synthesized. • Each GLT-2L sample contains (Gd{sub 2−x}Li{sub x})Ti{sub 2}O{sub 7−x} and 2x moles of LiO{sub 0.5} self-flux. • 1250 °C was used to prepare the GLT-2L samples; 300 °C lower than required. • Electrical conductivity of the GLT-2L is not affected by the presence of the flux. • Average valence of the Ti ions is slightly less than 4. - Abstract: A series of (Gd{sub 2−x}Li{sub x})Ti{sub 2}O{sub 7−x} with x = 0.040–0.110 was first reported. Parent compound with 2x moles of LiO{sub 0.5} self-flux was prepared at 1250 °C and abbreviated as GLT-2L. Relative density of all the samples is higher than 92%. By the addition of flux and Li ions substitution, preparation temperature is lowered for more than 300 °C. Comparing the unit cell a-axis, GLT with a formula as (Gd{sub 2−x}Li{sub x})Ti{sub 2}O{sub 7−x} without flux addition has exactly the same as the GLT-2L with the same x. By the addition of flux, materials become more compact and grains grow bigger for the GLT-2L than the corresponding GLT samples. Electrical conductivity of a GLT-2L with x = 0.110 at 700 °C is 3 times larger than the measurements done by other research groups in the Gd{sub 2}Ti{sub 2}O{sub 7}. In order to demonstrate the successful substitution of the Li ion into the Gd site, a series of GT samples was prepared with a formula of Gd{sub 2−x}Ti{sub 2}O{sub 7−1.5x}. With the same amount of x, every GLT samples have a longer unit cell a-axis than that of the GT. The difference is caused by the substitution of the Li ion into the Gd site. Valence of the Ti atoms of the GLT-2L samples is slightly less than 4 studied by the XANES spectroscopy.