SEARCH · Engineering Papers

Results for “Co”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 649 records · Page 36

All sources NASA NTRS DOE OSTI

NASA NTRS1975

A photoionization study of the formation of CO2/+/ by reaction of excited O2/+/ ions with CO

The production of CO2(+) by the ion-molecule reaction O2(+) + CO yields CO2(+) + O has been investigated using a photoionization mass spectrometer. The photoionization efficiency for production of CO2(+) by this reaction was measured from threshold at 924 A (13.42 eV) to 650 A (19.07 eV). The appearance potential corresponds to reaction of ground vibronic O2(+) ions formed in the nu-prime = 6 level. The high-vibrational-level ions of the ground ionic state are most likely produced by autoionization of O2. At wavelengths shorter than 760 A, there is a large increase in the reaction cross section associated with formation of ions in the metastable state. The peak reaction cross section occurs at 720 A.

Ajello, J. M.↗

NASA NTRS1975

Further development of a global pollution model for CO, CH4, and CH2 O

Global tropospheric pollution models are developed that describe the transport and the physical and chemical processes occurring between the principal sources and sinks of CH4 and CO. Results are given of long term static chemical kinetic computer simulations and preliminary short term dynamic simulations.

Peters, L. K.↗

NASA NTRS1976

Low-energy electron scattering from CO. 2: Ab-initio study using the frame-transformation theory

The Wigner-Eisenbud R matrix method has been combined with the frame transformation theory to study electron scattering from molecular systems. The R matrix, calculated at the boundary point of the molecular core radius, has been transformed to the space frame in order to continue the solution of the scattering equations in the outer region where rotational motion of the nuclei is taken into account. This procedure has been applied to a model calculation of thermal energy electron scattering from CO.

Chandra, N.↗

NASA NTRS1976

NO sub X destruction by CO in NO sub X to NO converters of chemiluminescent NO analyzers

An instrument modification for chemiluminescent NO - NOx analyzers was developed which minimizes the NOx destruction in the NOx to NO converters of NO analyzers due to high concentrations of CO. This mechanism causes the NO analyzers to indicate incorrect NOx concentrations when the analyzers are operated in the NOx analysis mode. The modification is applicable to analyzers in which the detection chamber is evacuated.

Summers, R. L.↗

NASA NTRS1975

Low-energy electron scattering from CO

The scattering of electrons from carbon monoxide has been studied in the framework of a previously proposed pseudopotential method. It is found that the single-center expansion of the continuum electron orbital about the center of mass of the molecule is very well converged when the two noncoincident nuclear singularities and the nonlocal exchange interactions are properly taken into account in the scattering equations. An analytical proof has been given to show that unlike the total cross section, the momentum-transfer cross section in the fixed-nuclei approximation is finite even for polar molecules. The calculated results of the momentum-transfer cross section for e(-)-CO scattering in the energy range between 0.1 and 10.0 eV are in good accord with the experimental measurements.

Chandra, N.↗

NASA NTRS1976

Accuracy of decoupling approximations for rotational excitation - Low-energy CO-He collisions

Scattering calculations have been performed for low-energy collisions of CO with He using the 'effective potential' approximation of Rabitz (1972) and the 'coupled states' approximation of McGuire and Kouri (1973). These are compared with the accurate quantum close-coupling scattering results of Green and Thaddeus. All calculations employed a theoretical potential believed to represent accurately the true interaction. The effective potential method is found to be in qualitative agreement, and the coupled states method is found to be in semi-quantitative agreement, with close-coupling results for rotationally inelastic integral cross sections.

Green, S.↗

NASA NTRS1976

CO observations of the expanding envelope of IRC + 10216

The paper reports high-sensitivity observations of (C-12)O and (C-13)O in the infrared source IRC + 10216, which were made with the NRAO 11-m telescope at frequencies of 115.2712 and 110.2014 GHz, respectively. The emission-line profiles are found to be in good qualitative agreement with model profiles predicted for a spherically symmetric and uniformly expanding envelope. Analysis of the profile shapes indicates that the (C-12)O line is optically thick, while the (C-13)O line is both optically thin and double-peaked. It is shown that the shape of the (C-12)O line is determined largely by the motion of the gas and that the expansion velocity at the edges of the CO cloud is 15 km/s, in contrast to 12 km/s for more centrally confined molecules. Based on the estimated (C-13)O content, the envelope mass is estimated to be 0.5 solar mass.

Kuiper, T. B. H.↗

NASA NTRS1976

CO observations of NGC 1579 /S222/ and S239

The 2.6-mm lines of (C-12)O and (C-13)O have been observed toward the small galactic diffuse nebulae NGC 1579 (S222) and S239. The H92-alpha recombination line has also been detected from NGC 1579. Toward NGC 1579, evidence was observed for self-absorption in the (C-12)O line. For both regions, high-velocity wings and line broadening are observable in the (C-12)O line; the features observed toward S239 suggest ordered free-fall collapse of a localized region of the cloud onto a newborn stellar cluster. Examination of the available data suggests that NGC 1579 is both a reflection nebula (illuminated by LKH-alpha 101) and an obscured H II region excited by a star of spectral type near B1, while S239 is a reflection nebula or a Herbig-Haro object. The present studies of these regions show that line widening in CO is at least as important an indicator of star-formation activity as enhanced line emission.

Knapp, G. R.↗

NASA NTRS1975

Decomposition of NO studied by infrared emission and CO laser absorption

A diagnostic technique for monitoring the concentration of NO using absorption of CO laser radiation has been developed and applied in a study of the decomposition kinetics of NO. Simultaneous measurements of infrared emission by NO at 5.3 microns were also made to validate the laser absorption technique. The data were obtained behind incident shocks in NO-N2O-Ar (or Kr) mixtures, with temperatures in the range 2400-4100 K. The rate constant for the dominant reaction of O and NO to yield N and O2 was inferred from comparisons with computer simulations of the reactive flow.

Hanson, R. K.↗

NASA NTRS1976

Discharge stabilization studies of CO laser gas mixtures in quasi-steady supersonic flow

Experiments were conducted to study the applicability of a double discharge stabilization scheme in conditions appropriate for high energy CO lasers in supersonic flows. A Ludwieg tube impulse flow facility and a ballasted capacitor bank provided essentially steady flow and discharge conditions (d.c.) for times longer than ten electrode length-flow transit times. Steady, arc-free, volume discharges were produced in a Mach 3 test cavity using an auxiliary discharge to stabilize the main discharge in N2 and He/CO mixture. A signigicant result is the lack of observed plasma E/N changes in response to auxiliary discharge current changes. Also, where glow discharges were obtained, the energy loading achieved was very much less than the threshold level required for laser operation.

Srinivasan, G.↗

NASA NTRS1977

Redetermination of the Fe-rich portion of the Fe-Ni-Co phase diagram

The iron rich portion of the Fe-Ni-Co ternary diagram was determined at four temperatures. The phase boundaries and tie-lines of the (alpha + gamma) phase field were measured by analyzing the alpha and gamma phases with an electron microprobe. Grain boundary allotrimorphs of the alpha phase were observed in the polished and etched sections of samples which were step cooled from the gamma phase into the (alpha + gamma) region. Widmanstaetten-type microstructures composed of gamma-precipitates were observed in samples which were directly heated from room temperature into the (alpha + gamma) region.

Widge, S.↗

NASA NTRS1977

Isotopic abundance of CO in interstellar clouds

The fractional abundances of the isotopic species of carbon monoxide in interstellar clouds are calculated on a basis of gas-phase ion-molecule reactions. The (C-13)O/(C-12)O ratio varies significantly with extinction of the ultraviolet radiation field, and in the outer regions of dark dense clouds (C-13)O may be enhanced by a factor of 10. The observational interpretation of the CO to H2 or interstellar-reddening relation and the isotopic abundances of carbon are complicated by these effects.

Langer, W. D.↗

NASA NTRS1977

CO observations of galactic reflection nebulae

Carbon monoxide emission has been observed toward about 35 galactic reflection nebulae. The peaking of CO temperatures near the hotter stars indicates substantial local heating of the gas and dust by the embedded stars. Wide low-level emission wings are seen on several of the (C-12)O line profiles; these are most plausibly interpreted as due to cloud material accelerated by such processes as radiation pressure from the newborn stars.

Knapp, G. R.↗

NASA NTRS1977

Isotope ratios and chemical fractionation of CO in Lynds 134

A radio observation of (C-12)(O-17) in the dust cloud Lynds 134 is reported, and the question of the (C-13)(O-16)/(C-12)(O-18) ratio across this cloud is considered. A value of approximately 0.28 is obtained for the (C-12)(O-17) column-density ratio, and it is shown that the (C-13)(O-16)/(C-12)(O-18) ratio is very different at two positions in the cloud separated by about 3.75 arcmin. (C-13)(O-16)/(C-12)(O-18) column-density ratios are calculated on the assumption of LTE and found to have a mean value of 4.8 at six positions in the most obscured part of the cloud; the same ratio is determined to be much larger and variable outside the cloud core. It is suggested that chemical fractionation of CO is occurring in this cloud, that (C-13)(O-16) is considerably enriched in its outer regions, and that the cloud's C-12/C-13 ratio is approximately 104.

Dickman, R. L.↗

NASA NTRS1978

Photometric studies of composite stellar systems. I - CO and JHK observations of E and S0 galaxies

Multiaperture infrared photometric observations of the central regions of 51 early-type galaxies and of the integrated light of five globular clusters are presented. These data are compared with selected optical observations and with various model predictions. The main results of the work are: (1) the observed parameters for the brighter galaxies, particularly the CO index and the V-K color, agree with the predictions of stellar synthesis models characterized by giant-dominated populations with mass/visual luminosity ratios less than 10; (2) the galaxian broad-band colors tend to redden with increasing luminosity and decreasing aperture size; (3) for the globular clusters, there is evidence that the integrated colors become redder with increasing metallicity; and (4) in bright galaxies the relative changes of U-V, V-J, and J-K as functions of radius may differ from the relative changes as functions of luminosity at a fixed radius.

Frogel, J. A.↗

NASA NTRS1978

Vibrational intensity distributions for the various electronic states of O2/+/, N2/+/ and CO/+/ produced by photoionization

Vibrational intensity distributions obtained with many discrete emission lines are presented for all major electronic states of O2(+), N2(+) and CO(+) subjected to photoionization. The vibrational distributions are reported as a function of wavelength between 745 and 304 A. The data, provided by photoelectron spectroscopy with an electron energy analyzer of known luminosity, appear to be consistent with calculated Franck-Condon Factors. Evidence for autoionization in the data is also discussed.

Gardner, J. L.↗

NASA NTRS1978

Collisional excitation of interstellar molecules - Linear molecules CO, CS, OCS, and HC3N

Rates for excitation of CO, CS, OCS, and HC3N by collisions with He atoms and H2 molecules are presented. These have been obtained from extensive theoretical calculations using methods of known reliability. In general, rates necessary for modeling interstellar molecular clouds with kinetic temperatures to 100 K have been included. Methods for fitting these rates in more compact form are discussed.

Green, S.↗

NASA NTRS1978

CO fluorescence in the extreme-ultraviolet solar spectrum

Emission lines in the fourth positive system of CO have been identified in the extreme-ultraviolet solar spectrum 1540-1660 A. These lines are excited by the C IV transition-zone lines at 1548 and 1551 A. They are strong in the spectrum of a sunspot and in parts of the adjacent active region. Some of them appear as weak, broad emission features in the quiet sun.

Bartoe, J.-D. F.↗