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At least 649 records · Page 36

Paleoproterozoic snowball earth: extreme climatic and geochemical global change and its biological consequences

Geological, geophysical, and geochemical data support a theory that Earth experienced several intervals of intense, global glaciation ("snowball Earth" conditions) during Precambrian time. This snowball model predicts that postglacial, greenhouse-induced warming would lead to the deposition of banded iron formations and cap carbonates. Although global glaciation would have drastically curtailed biological productivity, melting of the oceanic ice would also have induced a cyanobacterial bloom, leading to an oxygen spike in the euphotic zone and to the oxidative precipitation of iron and manganese. A Paleoproterozoic snowball Earth at 2.4 Giga-annum before present (Ga) immediately precedes the Kalahari Manganese Field in southern Africa, suggesting that this rapid and massive change in global climate was responsible for its deposition. As large quantities of O(2) are needed to precipitate this Mn, photosystem II and oxygen radical protection mechanisms must have evolved before 2.4 Ga. This geochemical event may have triggered a compensatory evolutionary branching in the Fe/Mn superoxide dismutase enzyme, providing a Paleoproterozoic calibration point for studies of molecular evolution.

Earth (Planet)↗

Modeled estimates of permafrost hydrology and related fields for pan-Arctic region over the period 1980-2100

This dataset contains gridded estimates of total runoff (mm/day); subsurface runoff (mm/day); snow water equivalent (SWE, mm/day); vertical upward water flux of combined surface evaporation, evapotranspiration, and snow sublimation (mm/day); and soil temperature (C) across the pan-Arctic basin from simulations of the Permafrost Water Balance Model (PWBM v4). These data were generated to allow researchers to advance understanding of the changes unfolding in the Arctic's terrestrial water cycle under the influences of climate warming, hydrological cycle intensification, and permafrost thaw. The dataset will enable researchers to address important questions spanning multiple disciplines. For example, how will rising river flows exported to the coast impact critical zone ecosystems, near-shore ice dynamics, and ocean biogeochemical processes. Spatial resolution is 25x25 km with N=39926 grid cells spanning the domain. Three forcing datasets were used to drive simulations at an implicit daily time step over the period 1980-2100. Daily air temperature, precipitation, and wind speed data from the WATCH Forcing Data methodology applied to ERA5 reanalysis (W5E5) were used for meteorological forcings over the period 1980-2019. Simulations for the period 1980-2100 used meteorological data from two global climate models; IPSL-CM6A-LR and MPI-ESM1-2-HR. The PWBM hydrological outputs are organized by grid and month in gzipped ASCII text files within each archived tar file. Soil temperature is organized by grid cell and day of year from DOY 205 to DOY 260. No special software is required to work with these data. The package contains spatial domain and river basin information files. These data are most useful for analyses of the spatial and temporal variations in terrestrial hydrology and soil thermal dynamics. A manuscript describing the model simulations and associated analysis has been accepted for publication in The Cryosphere (Rawlins and Karmalkar, 2024).

54 ENVIRONMENTAL SCIENCES↗

The influence of the hydrologic cycle on the extent of sea ice with climatic implications

The role was analyzed of the hydrologic cycle on the distribution of sea ice, and its influence on forcings and fluxes between the marine environment and the atmosphere. River discharge plays a significant role in degrading the sea ice before any melting occurs elsewhere along the coast. The influence is considered of river discharge on the albedo, thermal balance, and distribution of sea ice. Quantitative atmospheric-hydrologic models are being developed to describe these processes in the coastal zone. Input for the models will come from satellite images, hydrologic data, and field observations. The resulting analysis provides a basis for the study of the significance of the hydrologic cycle throughout the Arctic Basin and its influence on the regional climate as a result of possible climatic scenarios. The area offshore from the Mackenzie River delta was selected as the study area.

Dean, Ken↗

The Colorado East River Community Observatory Data Collection

Abstract The U.S. Department of Energy's (DOE) Colorado East River Community Observatory (ER) in the Upper Colorado River Basin was established in 2015 as a representative mountainous, snow‐dominated watershed to study hydrobiogeochemical responses to hydrological perturbations in headwater systems. The ER is characterized by steep elevation, geologic, hydrologic and vegetation gradients along floodplain, montane, subalpine, and alpine life zones, which makes it an ideal location for researchers to understand how different mountain subsystems contribute to overall watershed behaviour. The ER has both long‐term and spatially‐extensive observations and experimental campaigns carried out by the Watershed Function Scientific Focus Area (SFA), led by Lawrence Berkeley National Laboratory, and researchers from over 30 organizations who conduct cross‐disciplinary process‐based investigations and modelling of watershed behaviour. The heterogeneous data generated at the ER include hydrological, genomic, biogeochemical, climate, vegetation, geological, and remote sensing data, which combined with model inputs and outputs comprise a collection of datasets and value‐added products within a mountainous watershed that span multiple spatiotemporal scales, compartments, and life zones. Within 5 years of collection, these datasets have revealed insights into numerous aspects of watershed function such as factors influencing snow accumulation and melt timing, water balance partitioning, and impacts of floodplain biogeochemistry and hillslope ecohydrology on riverine geochemical exports. Data generated by the SFA are managed and curated through its Data Management Framework. The SFA has an open data policy, and over 70 ER datasets are publicly available through relevant data repositories. A public interactive map of data collection sites run by the SFA is available to inform the broader community about SFA field activities. Here, we describe the ER and the SFA measurement network, present the public data collection generated by the SFA and partner institutions, and highlight the value of collecting multidisciplinary multiscale measurements in representative catchment observatories.

54 ENVIRONMENTAL SCIENCES↗

Performance Simulation and Analysis of Occupancy-Based Control for Office Buildings with Variable-Air-Volume Systems

Variable-air-volume (VAV) systems are used in many office buildings. The minimum airflow rate setting of VAV terminal boxes has a significant impact on both energy consumption and indoor air quality. Conventional controls usually have the terminal’s minimum airflow rate at a constant (e.g., 30% or more of the terminal design airflow rate), irrespective of the occupancy status, which may cause problems, such as excessive simultaneous heating and cooling, under ventilation, and thermal comfort issues. This paper examines the potential of energy savings from occupancy-based controls (OBCs). The sensed occupancy information, either occupant presence or people count, is used to determine the airflow rate of terminal boxes, the thermostat setpoints, and the lighting control. Using EnergyPlus, a whole-building energy modeling software, the energy savings of OBC strategies are evaluated for representative existing medium office buildings in the U.S. The simulation results show that the conventional OBC, based on occupant presence sensing, can save 8% of whole-building energy use in Miami (hot climate) for systems without air-side economizer and about 13% in both Baltimore (mixed climate) and Chicago (cold climate). Comparatively, the advanced OBC, based on people counting, can save 8% in Miami to 23% in Baltimore for systems with economizers. The outdoor-air fraction of the supply air from air-handling units significantly affects the potential energy savings from the advanced OBC strategy. In addition to energy savings, the advanced OBC satisfies the zone ventilation during all occupied hours over the whole year.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Seasonal Evolution of Saturn's Polar Temperatures and Composition

The seasonal evolution of Saturn's polar atmospheric temperatures and hydrocarbon composition is derived from a decade of Cassini Composite Infrared Spectrometer (CIRS) 7-16 micrometers thermal infrared spectroscopy. We construct a near-continuous record of atmospheric variability poleward of 60 deg from northern winter/southern summer (2004, Ls = 293 deg) through the equinox (2009, Ls= 0 deg) to northern spring/southern autumn (2014, Ls = 56 deg). The hot tropospheric polar cyclones that are entrained by pro-grade jets within 2-3 deg of each pole, and the hexagonal shape of the north polar belt, are both persistent features throughout the decade of observations. The hexagon vertices rotated westward by approx. equal to 30 deg longitude between March 2007 and April 2013, confirming that they are not stationary in the Voyager-defined System III longitude system as previously thought. Tropospheric temperature contrasts between the cool polar zones (near 80-85 deg) and warm polar belts (near 75-80 deg) have varied in both hemispheres, resulting in changes to the vertical wind shear on the zonal jets in the upper troposphere and lower stratosphere. The extended region of south polar stratospheric emission has cooled dramatically poleward of the sharp temperature gradient near 75 deg S (by approximately -5 K/yr), coinciding with a depletion in the abundances of acetylene (0030 +/- 0.005 ppm/yr) and ethane (0.35 +/- 0.1 ppm/yr), and suggestive of stratospheric upwelling with vertical wind speeds of w approx. equal to +0.1 mm/s. The upwelling appears most intense within 5 deg latitude of the south pole. This is mirrored by a general warming of the northern polar stratosphere (+5 K/yr) and an enhancement in acetylene (0.030 +/- 0.003 ppm/yr) and ethane (0.45 +/- 0.1 ppm/yr) abundances that appears to be most intense poleward of 75 deg N, suggesting subsidence at w approx. equal to -0.15 mm/ s. However, the sharp gradient in stratospheric emission expected to form near 75 deg N by northern summer solstice (2017, Ls = 90 deg) has not yet been observed, so we continue to await the development of a northern summer stratospheric vortex. The peak stratospheric warming in the north occurs at lower pressure levels (p less than 1 mbar) than the peak stratospheric cooling in the south (p greater than 1 mbar). Vertical motions are derived from both the temperature field (using the measured rates of temperature change and the deviations from the expectations of radiative equilibrium models) and hydrocarbon distributions (solving the continuity equation). Vertical velocities tend towards zero in the upper troposphere where seasonal temperature contrasts are smaller, except within the tropospheric polar cyclones where w approx. equal to +0.02 mm/s. North polar minima in tropospheric and stratospheric temperatures were detected in 2008-2010 (lagging one season, or 6-8 years, behind winter solstice); south polar maxima appear to have occurred before the start of the Cassini observations (1-2 years after summer solstice), consistent with the expectations of radiative climate models. The influence of dynamics implies that the coldest winter temperatures occur in the 75-80 deg region in the stratosphere, and in the cool polar zones in the troposphere, rather than at the poles themselves. In addition to vertical motions, we propose that the UV-absorbent polar stratospheric aerosols entrained within Saturn's vortices contribute significantly to the radiative budget at the poles, adding to the localized enhancement in the south polar cooling and north polar warming poleward of +/-75 deg.

polar temperatures↗

Disturbances in North American boreal forest and Arctic tundra: impacts, interactions, and responses

Ecosystems in the North American Arctic-Boreal Zone (ABZ) experience a diverse set of disturbances associated with wildfire, permafrost dynamics, geomorphic processes, insect outbreaks and pathogens, extreme weather events, and human activity. Climate warming in the ABZ is occurring at over twice the rate of the global average, and as a result the extent, frequency, and severity of these disturbances are increasing rapidly. Disturbances in the ABZ span a wide gradient of spatiotemporal scales and have varying impacts on ecosystem properties and function. However, many ABZ disturbances are relatively understudied and have different sensitivities to climate and trajectories of recovery, resulting in considerable uncertainty in the impacts of climate warming and human land use on ABZ vegetation dynamics and in the interactions between disturbance types. Here we review the current knowledge of ABZ disturbances and their precursors, ecosystem impacts, temporal frequencies, spatial extents, and severity. We also summarize current knowledge of interactions and feedbacks among ABZ disturbances and characterize typical trajectories of vegetation loss and recovery in response to ecosystem disturbance using satellite time-series. We conclude with a summary of critical data and knowledge gaps and identify priorities for future study.

54 ENVIRONMENTAL SCIENCES↗

Interdisciplinary Determination of Ice Sheet Accumulation Patterns: Combined Atmospheric Modeling and Field and Remote Sensing Studies

This research is focusing on two related areas that are fundamental to the NASA PARCA (Program for Arctic Regional Climate Assessment) program. The primary research area is the determination of the amount, rate, and timing of accumulation at distributed sites in the dry snow zone of Greenland and evaluation of these results in light of accumulation modeling results. The secondary research area is the calibration of the isotope "thermometer" at these ice sheet sites as well as the determination of long-term temperature trends in Greenland.

Shuman, C. A.↗

The Unique Capabilities of the Global Hawk Aircraft for the Study of Climate Changes

Due to unprecedented extent and flexibility of the coverage that is now attainable both in space and time, stratospheric unmanned aircraft, such as the Global Hawk (GH), offers new opportunities for the study of climate changes. The capability of performing long flights at altitudes close to the boundary conditions of radiative processes, and of following the diurnal variation of chemical species and clouds, make the GH competitive with LEO and geosynchronous satellites, and even capable of new observations that are not possible from satellites. This paper discusses how the GH can be used to make relevant advancements in most of the issues that are related to climate change studies, such as: Earth Radiation Budget, Water Cycle, Ecosystems and Upper Troposphere-Lower Stratosphere, as well as to the monitoring and control of Greenhouse Gases and Air Quality . Collaboration between NASA and Italian scientific institutions, within the framework of the US.-Italy Cooperation on Climate Change, is providing the opportunity to rapidly deploy new instruments on the GH and to possibly operate the aircraft from an Italian site in the Mediterranean area. From this area, which is considered highly vulnerable to climate change, meridional transects would allow the crossing of Polar and Sub Tropical Jets, as well as a complete crossing of the Inter Tropical Convergence Zone, while latitudinal ones would follow the influx from Asia and North America. Regions otherwise difficult to access, such as Central Africa and the Tibetan Plateau, could be reached and better investigated. An overview of these new opportunities will be given and discussed.

Cairo, F.↗

High Latitude Considerations in the Latest GPCP monthly and daily products (V3.1)

The Global Precipitation Climatology Project (GPCP) product is a popular combined satellite-gauge precipitation data set in which the long-term standards of consistency and homogeneity is underlined. Here we discuss various high latitude analysis considered in the recently released GPCP V3.1 monthly and daily products. Satellite data are used over land and ocean and obtained from the Special Sensor Microwave Imager (SSMI), Special Sensor Microwave Imager/Sounder (SSMIS), geostationary imagers and polar orbiting infrared sounders. GPCP uses the Global Precipitation Climatology Centre (GPCC) over land, as its in situ component, but prior to combination with satellite data GPCC estimates are adjusted for gauge undercatch. Advanced sensors aboard the Tropical Rainfall Measuring Mission (TRMM), CloudSat, and Global Precipitation Measurement (GPM) mission have enabled more accurate estimation of rain and snowfall rates in recent years. Started with GPCP V3.1 these observations are integrated into GPCP through the development of the Tropical Combined Climatology (TCC) used at lower latitudes and the Merged CloudSat, TRMM, and GPM (MCTG) climatology used over the extra tropics and higher latitudes. Improved calibrations of Television-Infrared Operational Satellite (TIROS) Operational Vertical Sounder (TOVS) and Advanced Infrared Sounder (AIRS) precipitation are used outside 60ºN-S, where inside this zone the Goddard Profiling (GPROF) algorithm retrievals from SSMI/SSMIS is used to calibrate geostationary IR based precipitation estimate at monthly scale. The Gravity Recovery and Climate Experiment (GRACE) mass change observations are used to determine snowfall accumulations over frozen land and arctic basins and to assess gauge undercatch corrections. Observations of snow on sea ice from NASA’s Operation IceBridge (OIB) flights are utilized as an additional tool for snowfall assessment over sea ice. GPCP V3.1 has higher spatial resolution (0.5ox0.5o) than earlier versions (2.5ox2.5o) over both land and ocean, going back to 1983. Version 3 Daily product uses the Integrated Multi-satellitE Retrievals for Global Precipitation Measurement (GPM) mission (IMERG) Final Run V06 estimates, where available (initially restricted to 60°N-S), as well as rescaled TOVS/AIRS data in high-latitude areas, all calibrated to the GPCP V3.1 Monthly estimate. GPCP V3.1 shows about 6% increase in global oceanic precipitation and about 4.5% increase over global land and ocean compared to the previous version (V2.3), some major changes occur over the ocean and around 40oS and 60 oS. We will discuss other important changes of GPCP V3.1, compared to the earlier versions, and our future plans. Through this presentation we will also discuss that while ACCP will provide key information about precipitation, synergistic use of other Earth observing systems (e.g., mass change; recognized as a designated mission in 2017 decadal survey) can also help refine precipitation analysis, especially in high latitude and cold regions.

Ali Behrangi↗

Disturbances in North American Boreal Forest and Arctic Tundra: Impacts, Interactions, and Responses

Ecosystems in the North American Arctic-Boreal Zone (ABZ) experience a diverse set of disturbances associated with wildfire, permafrost dynamics, geomorphic processes, insect outbreaks and pathogens, extreme weather events, and human activity. Climate warming in the ABZ is occurring at over twice the rate of the global average, and as a result the extent, frequency, and severity of these disturbances are increasing rapidly. Disturbances in the ABZ span a wide gradient of spatiotemporal scales and have varying impacts on ecosystem properties and function. However, many ABZ disturbances are relatively understudied and have different sensitivities to climate and trajectories of recovery, resulting in considerable uncertainty in the impacts of climate warming and human land use on ABZ vegetation dynamics and in the interactions between disturbance types. Here we review the current knowledge of ABZ disturbances and their precursors, ecosystem impacts, temporal frequencies, spatial extents, and severity. We also summarize current knowledge of interactions and feedbacks among ABZ disturbances and characterize typical trajectories of vegetation loss and recovery in response to ecosystem disturbance using satellite time-series. We conclude with a summary of critical data and knowledge gaps and identify priorities for future study.

high-latitude↗

Early Mission Maneuver Operations for the Deep Space Climate Observatory

DSCOVR Lissajous Orbit sized such that orbit track never extends beyond 15 degrees from Earth-Sun line (as seen from Earth). Requiring delta-V maneuvers, control orbit to obey a Solar Exclusion Zone (SEZ) cone of half-angle 4 degrees about the Earth-Sun line. Spacecraft should never be less than 4 degrees from solar center as seen from Earth. Following Lissajous Orbit Insertion (LOI), DSCOVR should be in an opening phase that just skirts the 4-degree SEZ. Maximizes time to the point where a closing Lissajous will require avoidance maneuvers to keep it out of the SEZ. Station keeping maneuvers should take no more than 15 minutes

OPERATIONS↗

Reducing uncertainty of polar to midlatitude linkages using DOE’s E3SM in a coordinated model-experiment setting

This project brought DOE’s climate modeling effort with the Energy Exascale Earth System Model into the Polar Amplification Model Intercomparison Project (PAMIP), which is part of the sixth and latest Coupled Model Intercomparison Project, CMIP6. PAMIP examines the causes and consequences of polar amplification, when external forcing results in a larger temperature increase in high latitudes than the global average, in a coordinated set of model experiments with a common modeling protocol. Our teams from UC Irvine and the University of Toronto have designed, carried out, analyzed, and disseminated PAMIP output from the Energy Exascale Earth System Model (E3SM) and the Community Earth System Model (CESM). PAMIP’s ongoing stream of significant new results have advanced progress in the community’s understanding and led to new outstanding research questions that have motivated further work. PAMIP has led to improved consensus on the atmospheric response to sea ice loss. The important finding is that for a similar sea ice anomaly forcing, the simulated atmospheric response in the troposphere is remarkably consistent among the 16 models’ runs analyzed. The zonal-mean tropospheric response consists of a very robust equatorward shift of the westerly flow in mid-latitudes. However, while the multi-model mean response is robust, it has a weak amplitude relative to internal variability. We identified a weakness in the models (including E3SM) in terms of their response to sea-ice forcing that is related to eddy forcing (or nonlinear dynamical effects) at mid- to high latitudes. In fact, E3SM is an outlier in terms of the models participating, and in that sense, it turned out to be a vital participant model. We found that reductions in energy transport due sea-ice loss and involving dry air only are compensated by increases in moist energy transport from warmer sea surface temperature in midlatitudes. This leads to a large spread in energy transport into the Arctic and is a potential source of spread in Arctic amplification. We identified an important role that climate modes, including tropical modes of variability (El Nino and the Southern Oscillation (ENSO); the Quasi-biennial Oscillation (QBO)) play in the response to sea-ice anomalies, including in ocean coupled experiments. Similarly, we identified and quantified the contribution of sea-ice thickness to the atmospheric response compared to the response to sea-ice extent only. We found that it is important to run large ensembles and even with an ensemble size of 100 simulations the response is largely influenced by internal variability. We demonstrated convincingly that Ural blocking, not sea-ice loss, provides the weakening of the stratospheric polar vortex in fall/early winter and a negative phase of the North Atlantic Oscillation that can last for up to two months. However, sea-ice anomalies can influence the background flow so that the response to Ural blocking is more persistent under low sea-ice conditions in the Barents/Kara Sea than high sea ice Atmospheric model hierarchies that progressively add individual processes have a long history in providing dynamical insight for modeling the atmosphere. Similarly, coupled model hierarchies that progressively add individual ocean processes can provide insights into the workings of the coupled climate system, however such hierarchies have not been available except for a non-dynamical slab ocean model. Because of the missing processes, surface flux corrections must be added to produce a target climate. In this project, we managed to overcome this problem and develop a globally coupled ocean model hierarchy in CESM that can turn on and off the processes of mixed-layer entrainment and Ekman flow. We used the hierarchy to study the impact of Arctic sea-ice loss on the climate system. We find that the effect of mixed-layer entrainment on ocean heat uptake influences the atmospheric circulation by shifting the latitudinal positions of the mid-latitude westerly jet and the Intertropical Convergence Zone (ITCZ). In quadrupled CO 2 experiments, we studied how air-sea coupling affects the response of tropical rainfall under global warming. In order to identify the importance of individual ocean processes, we used the hierarchy of ocean models to separate the effects of seasonal mixed-layer entrainment, wind-driven Ekman flows, and frictional flows. We showed that including Ekman and frictional flows allows our simulation to produce the Pacific Ocean's enhanced equatorial warming pattern and equatorward ITCZ contraction noted in previous climate simulations. We also showed that the frictional flow, which has yet to receive much attention, is as important as the Ekman flow in generating equatorial heat convergence.

54 ENVIRONMENTAL SCIENCES↗

Sensitivity of the Atmospheric Response to Warm Pool El Nino Events to Modeled SSTs and Future Climate Forcings

Warm pool El Nino (WPEN) events are characterized by positive sea surface temperature (SST) anomalies in the central equatorial Pacific. Under present-day climate conditions, WPEN events generate poleward propagating wavetrains and enhance midlatitude planetary wave activity, weakening the stratospheric polar vortices. The late 21st century extratropical atmospheric response to WPEN events is investigated using the Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM), version 2. GEOSCCM simulations are forced by projected late 21st century concentrations of greenhouse gases (GHGs) and ozone-depleting substances (ODSs) and by SSTs and sea ice concentrations from an existing ocean-atmosphere simulation. Despite known ocean-atmosphere model biases, the prescribed SST fields represent a best estimate of the structure of late 21st century WPEN events. The future Arctic vortex response is qualitatively similar to that observed in recent decades but is weaker in late winter. This response reflects the weaker SST forcing in the Nino 3.4 region and subsequently weaker Northern Hemisphere tropospheric teleconnections. The Antarctic stratosphere does not respond to WPEN events in a future climate, reflecting a change in tropospheric teleconnections: The meridional wavetrain weakens while a more zonal wavetrain originates near Australia. Sensitivity simulations show that a strong poleward wavetrain response to WPEN requires a strengthening and southeastward extension of the South Pacific Convergence Zone; this feature is not captured by the late 21st century modeled SSTs. Expected future increases in GHGs and decreases in ODSs do not affect the polar stratospheric responses to WPEN.

stratosphere↗

Observations of Land Surface Variability Using Passive Microwave Sensing

Understanding the global variability of land surface wetness (soil moisture), skin temperature, and related surface fluxes of heat and moisture is key to assessing the importance of the land surface in influencing climate. The feasibility of producing model estimates of these quantities is being studied as part of the International Satellite Land Surface Climatology Project (ISLSCP) Global Soil Wetness Project (GSWP). In the GSWP approach, meteorological observations and analyses are used to drive global circulation models. Satellite measurements can provide independent estimates of key land surface parameters that are needed for initializing and validating the climate models and for monitoring long-term change. Satellite observations of the land surface can also be assimilated into soil models to estimate moisture in the root zone. In our research, passive microwave satellite data recorded during 1978-1987 from the Nimbus-7 Scanning Multichannel Microwave Radiometer (SMMR) are being used to examine spatial and temporal trends in surface soil moisture, vegetation, and temperature. These data include observations at C and X bands (6.6 and 10.7 GHz), which are not available on the current Special Sensor Microwave/Imager (SSM/I) and are precursors to data that will become available from the Advanced Microwave Scanning Radiometer (AMSR) on Advanced Earth Observing Satellite (ADEOS-II) and Earth Observing System (EOS) PM1 in the year 2000. A chart shows a time-series of SMMR-derived surface temperature, T-e and surface soil moisture M, retrieved on a 0.5 deg x 0.5 deg grid and further averaged over a 4 deg x 10 deg study region in the African Sahel. Also shown are National Center for Environmental Prediction (NCEP) model outputs of surface temperature, T-sfc, and soil wetness, Soil-w. The variables have been scaled to have similar dynamic ranges on the plots. The NCEP data from the NCEP Reanalysis Project are monthly averages on a 2.5 deg x 2.5 deg grid averaged over the 4 deg x 10 deg study area. Comparisons of SMMR retrievals with forecast model output show the potential of the satellite data for validating model output and monitoring long-term trends. Continuing work will extend these results to other regions to validate the retrievals more quantitatively. In preparation for the launch of AMSR, field experiments are planned in collaboration with the Global Energy and Water Cycle Experiment (GEWEX) Coordinated Enhanced Observing Period (CEOP) experiments to evaluate the satellite-derived soil moisture measurements and to demonstrate their usefulness for land surface hydrology and climate. Additional information is contained in the original.

Njoku, Eni G.↗

Interactions between molecular-scale processes and hyporheic exchange for understanding Fe-S-C cycling in riparian wetlands (Final Report)

Wetlands represent some of the most productive ecosystems on the planet and critically influence global environmental health. Specifically, wetlands promote water quality by transforming nutrients and organic compounds and sequestering metals and contaminants. Riparian wetland hyporheic zones, where toxic surface water and anoxic groundwater mix, exhibit dynamic conditions that drive steep redox gradients and promote hotspots of diverse and fluctuating microbial activity. Changes in climate, water quality, and water quantity can disturb hydrologic flow and biogeochemical processing in these environments. Understanding how sulfate loading, impacted by hydrologic flux and anthropogenic inputs, influences iron and carbon cycling in wetlands will be crucial for predicting water quality issues driven by iron mineral precipitation and sorption, such as the release of heavy metals and other toxic elements. We used a fully integrated multi-scale and multi-method approach to develop a mechanistic understanding of how hydrologic flow influences coupled iron and sulfur cycles in riparian wetlands. This entailed hydrological, geochemical, and microbial observations at two locations: an anthropogenic sulfate-impacted riparian wetland in northern Minnesota, and a low-sulfate Fe-rich riparian wetland in Tims Branch at the Savannah River Site (SRS). These sites were characterized by hydrologically dynamic conditions where the stream and wetland systems oscillated between gaining (upward flow) and losing (downward flow) conditions that recharged the system occasionally with oxidants that fueled a variety of biogeochemical reactions. Aqueous geochemical measurements of surface water, groundwater, and porewater samples were made alongside solid-phase geochemical analyses of sediment gravity cores. Bulk X-ray absorption spectroscopy at the Advanced Photon Source (APS; Argonne) interrogated the speciation and distribution of Fe and S mineral phases of the sediments. Interestingly, it was discovered that, despite strongly reducing conditions, Fe(III) compounds and a variety of intermediate valence S compounds were stable in the subsurface. Indeed, compounds like thiosulfate, S(0), and intermediate valence organosulfur compounds were more prevalent than FeS and pyrite. The composition of the sediments did change with changes in hydrologic flow, showing their reactivity in changing redox conditions. The abundance of these intermediate S compounds was likely formed as a result of anaerobic oxidation by aqueous and solid-phase Fe(III) compounds, fueling a cryptic S cycle that is driving the breakdown of organic matter in the hyporheic zone. Microbiome surveys showed a core community that seemed stable across the landscape, but changed with increasing depth into the sediment. The community composition did not seem to change dramatically with changes in season or hydrologic flow, except for some organisms that have the potential to contribute to S cycling. More work is needed to confirm their functional activity. These fine process-scale analyses were placed within a dynamic field context using physical flow parameters from surface water and groundwater level measurements. These data helped shed light on sulfur-driven biogeochemical processes in hydrologically dynamic riparian wetlands, addressing a gap in our understanding about the impacts of pollution and other anthropogenic changes on ecologically sensitive environments.

54 ENVIRONMENTAL SCIENCES↗

Seeing the Disturbed Forest for the Trees: Remote Sensing Is Underutilized to Quantify Critical Zone Response to Unprecedented Disturbance

Understanding the severity and extent of near surface critical zone (CZ) disturbances and their ecosystem response is a pressing concern in the face of increasing human and natural disturbances. Predicting disturbance severity and recovery in a changing climate requires comprehensive understanding of ecosystem feedbacks among vegetation and the surrounding environment, including climate, hydrology, geomorphology, and biogeochemistry. Field surveys and satellite remote sensing have limited ability to effectively capture the spatial and temporal variability of disturbance and CZ properties. Technological advances in remote sensing using new sensors and new platforms have improved observations of changes in vegetation canopy structure and productivity; however, integrating measures of forest disturbance from various sensing platforms is complex. By connecting the potential for remote sensing technologies to observe different CZ disturbance vectors, we show that lower severity disturbance and slower vegetation recovery are more difficult to quantify. Case studies in montane forests from the western United States highlight new opportunities, including evaluating post-disturbance forest recovery at multiple scales, shedding light on understory vegetation regrowth, detecting specific physiological responses, and refining ecohydrological modeling. Learning from regional CZ disturbance case studies, we propose future directions to synthesize fragmented findings with (a) new data analysis using new or existing sensors, (b) data fusion across multiple sensors and platforms, (c) increasing the value of ground-based observations, (d) disturbance modeling, and (e) synthesis to improve understanding of disturbance.

54 ENVIRONMENTAL SCIENCES↗

Causal relationships of vegetation productivity with root zone water availability and atmospheric dryness at the catchment scale

Abstract. This study explores the causal relationships between catchment water availability, vapor pressure deficit, and gross primary productivity (GPP) across 341 catchments in the contiguous US. Seasonal climatic, hydrological, and vegetation characteristics were represented using the Horton index, ecological aridity index, evaporative fraction index, and carbon uptake efficiency. Statistical methods, including circularity statistics, correlation analysis, and causality tests, were employed to determine the complex interactions between catchment wetness, atmospheric dryness, and vegetation carbon uptake. The results revealed a maximum lag of 2 months in the intra-annual variability of catchment water supply–productivity and atmospheric water demand–productivity relationships, with hysteresis patterns varying with the catchment's hydrological characteristics. In catchments not permanently under water-limited or energy-limited conditions, vegetation experiences hydrological stress during the peak growing period, coinciding with the highest gross primary productivity and carbon uptake efficiency being out of phase with the Horton index and in phase with the evaporative fraction index. Causality analysis highlights strong temporal continuity in GPP seasonal characteristics, with a cause–effect relationship between catchment water supply, atmospheric demand, and vegetation productivity spanning a maximum of 2 months. These findings underscore the need for a comprehensive functional framework that integrates catchment water supply, atmospheric demand, and vegetation productivity to enhance our understanding and predictive capabilities with regard to ecosystem responses to climate change.

54 ENVIRONMENTAL SCIENCES↗