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At least 649 records · Page 36

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NASA NTRS1989

Structures of cyano-biphenyl liquid crystals

The structures of p-alkyl- p'-cyano- bicyclohexanes, C(n)H(2n+1) (C6H10)(C6H10) CN (n-CCH), and p-alkyl- p'-cyano- biphenyls, C(n)H(2n+1) (C6H4)(C6H4) CN (n-CBP), were studied. It is convenient to use an x ray image intensification device to search for symmetric x ray diffraction patterns. Despite the similarities in molecular structures of these compounds, very different crystal structures were found. For the smectic phase of 2CCH, the structure is close to rhombohedral with threefold symmetry. In contrast, the structure is close to hexagonal close-packed with two molecules per unit cell for 4CCH. Since intermolecular forces may be quite weak for these liquid crystals systems, it appears that crystal structures change considerably when the alkyl chain length is slightly altered. Different structures were also found in the crystalline phase of n-CBP for n = 6 to 9. For n = 7 to 9, the structures are close to monclinic. The structures are reminiscent of the smectic-A liquid crystal structures with the linear molecules slightly tilted away from the c-axis. In contrast, the structure is quite different for n = 6 with the molecules nearly perpendicular to the c-axis.

Chu, Yuan-Chao↗

NASA NTRS1989

The UV photochemistry of C2N2

The absorption, emission, and photodissociation yield spectra of C2N2 were measured in the 220 and 210 nm region near the 4(0)1 and 1(0)1 4(0)1 bands of the A 1 sigma + from the X 1 sigma + system. The emission spectrum showed very few lines which appeared in the absorption spectrum. Moreover, the emission had 660 ns lifetime and, at 210 nm a very large electronic emission quenching rate. Laser induced fluorescence was used to measure the relative yield of CN radicals as a function of photolysis wavelength. This spectrum seemed to follow the absorption spectrum below the dissociation threshold. Energy in the CN fragments appeared to be statistically distributed.

Halpern, Joshua B.↗

NASA NTRS1991

The spin state and homogeneity of Comet Halley's nucleus

The present model of the spin rate of Comet Halley, which takes the form of an excited, axially symmetric rotator with prolate spheroid shape, accommodates both the imaging data from the Vega and Giotto encounters and a range of ground-based data for CN jets and shells, C2 production rates, and photometric variability. The model ratio of moments-of-inertia maxima to minima, at 2.28, implies a nearly constant density distribution throughout its interior. One of the five localized areas on the nucleus which dominate the activity observed appears to be uniquely responsible for the initiation of CN-shell boundaries which propagate through the coma, and may be indicative of either large-scale chemical inhomogeneity or a surface region with unusual physical structure.

Belton, Michael J. S.↗

NASA NTRS1991

Cloud condensation nuclei near marine stratus

Extensive airborne measurements of cloud condensation nucleus (CCN) spectra and concentrations of total particles, or condensation nuclei (CN), below, in, and above the stratus cloud decks off the southern California coast point to important aerosol-cloud interactions. Consistently low CCN concentrations below cloud appear to be due to cloud scavenging processes which include Brownian coagulation, nucleation, coalescence, and drizzle. The higher CCN and CN concentrations above cloud are associated with ambient ozone concentrations which suggest a link with continental, probably anthropogenic, sources, even at distances of 500 km from the California coast.

Hudson, James G.↗

NASA NTRS1992

Coherent 1-micron lidar measurements of atmospheric-turbulence-induced spatial decorrelation using a multielement heterodyne detector array

A coherent 1-micron Nd:YAG lidar system is employed to measure directly the reduced spatial coherence length rho 0 of the lidar returns caused by atmospheric turbulence. The experiments were conducted by using a 2 x 2 heterodyne detector array, which permitted real-time spatial correlation measurements of the lidar returns at two different detector spacings. The spatial correlation coefficients and spatial coherence length of the lidar returns from a hard target were measured during a day-to-night time period when the atmospheric turbulence parameter, Cn-squared, was measured to vary from 2 x 10 exp -13 to 2 x 10 exp -4 m exp -2/3. These directly measured values of rho 0 as a function of Cn-squared were found to be in good agreement with theoretical predictions.

Chan, Kin P.↗

NASA NTRS1992

Linear and nonlinear propagation of water wave groups

Results are presented from a study of the evolution of waveforms with known analytical group shapes, in the form of both transient wave groups and the cloidal (cn) and dnoidal (dn) wave trains as derived from the nonlinear Schroedinger equation. The waveforms were generated in a long wind-wave tank of the Canada Centre for Inland Waters. It was found that the low-amplitude transients behaved as predicted by the linear theory and that the cn and dn wave trains of moderate steepness behaved almost as predicted by the nonlinear Schroedinger equation. Some of the results did not fit into any of the available theories for waves on water, but they provide important insight on how actual groups of waves propagate and on higher-order effects for a transient waveform.

Pierson, W. J., Jr.↗

NASA NTRS1992

Comet Yanaka (1988r) - A new class of carbon-poor comet

As part of a program to determine the chemical composition of a sample population of comets, a very unusual comet, Yanaka (1988r), was observed in January 1989. Although the comet showed the usual emissions of OI and NH2, it did not display any hint of C2 or CN emission. The comet is depleted in C2 by at least a factor of 100 and in CN by a factor of 25 relative to typical comets. If comets originate from interstellar clouds, Yanaka (1988r) could be an interloper from a cloud of different composition. If Yanaka (1988r) was formed within our solar system, the solar nebula was less uniform than assumed by most present models of formation.

Fink, Uwe↗

NASA NTRS1993

On the formation and evolution of gaseous structures in Comet P/Halley

The possibility of a dynamic connection between the CN jets and CN shells in the coma of Comet P/Halley is here investigated through numerical simulations on the spatial and temporal evolution of gaseous jets. The evolution of such a jet into a shell is found to be straightforward for several geometries. It is noted that a closed shell structure may be due to a near-equatorial observational view of material derived from the active region near the nucleus equator.

Schulz, Rita↗

NASA NTRS1993

What is new about the new Comet Yanaka (1988r)?

A deficiency in the observed abundances of C2 and CN in Comet Yanaka (1988r) is explained in terms of the properties of its organic refractory dust component and the fact that it is a new comet. Because the major fraction of the carbon in comets is in a mixture of complex organic molecules which earlier explained the 'missing' carbon mystery it is shown that substantial carbon depletions are impossible. The low C2 and CN production rates may be understood as consequences of Yanaka (1988r) being a new comet in combination with the small central area of coma observed. The surface of new comets resulting from cosmic-ray processing in the Oort cloud gives rise to dust which is relatively nonfragile and which remains relatively large and cool within the limits of a small diaphragm making the comet appear to be dust poor. This dust yields smaller abundances of carbon-rich species by evaporation than customary for the smaller and hotter fragmented particles further out in the coma.

Greenberg, J. M.↗

NASA NTRS1993

The anomalous molecular abundances of Comet P/Wolf-Harrington

Production rates of OH, CN, C2, C3, NH, and NH2 were derived from different data sets for the Comet P/Wolf-Harrington, and a dust production measure was calculated. This comet is found to be depleted by more than an order of magnitude in its pure carbon species compared with OH and CN. The data obtained suggest that a nonnegligible fraction of comets or their constituent components formed at a different temperature and thus at a different location and/or time than the majority of comets.

Schleicher, David G.↗

NASA NTRS1993

The abundance of CH(+) in translucent molecular clouds - Further tests of shock models

Observations of interstellar absorption lines of CH(+) in the (0, 0) and (1, 0) bands of the A 1Pi - X 1Sigma(+) system are presented for 17 stars with reddenings up to E(B-V) about 1.5 mag. Complementary data on interstellar CH in the (0, 0) bands of the A 2Delta - X 2Pi and B 2Sigma(-) - X 2Pi systems and C2 in the A 1Pi(u) - X 1Sigma(g)(+) red system have been obtained as well. The derived CH(+) column densities continue to increase with total column density, and values up to 10 exp 14/sq cm are reported for highly-reddened lines of sight. In most cases, the CH(+) and CH absorptions are dominated by a single strong component, with weaker features displaced by a few km/s. No significant velocity difference is found between CH(+) and neutral species such as CH and CN for this sample of randomly oriented lines of sight. In contrast with CN, the CH(+) abundance does not increase with the density in the cloud as derived from the observed C2 excitation. For the two clouds with the largest density, HD 62542 and HD 94413, no CH(+) absorption is found with CH(+)/CH less than 0.03 and 0.14, respectively. The CH(+) findings do not support a single-shock origin for the formation of the ion.

Gredel, R.↗

NASA NTRS1994

Fourier transform spectroscopy of the Swan (d(sup 3)pi(sub g) - a(sup 3)pi(sub u)) system of the jet-cooled C2 molecule

The Swan (d(sup 3)pi(sub g) - a(sup 3)pi(sub u)) system of the C2 molecule was produced in a jet-cooled corona excited supersonic expansion of helium using diazoacetonitrile as a percursor molecule. This spectrum was recorded using the McMath Fourier transform spectrometer of the National Solar Observatory at Kitt Peak. A total of nine bands with v prime = 0 to 3 and v prime prime = 0 to 4 in the range 16,570-22,760/cm were observed and rotationally analyzed. The C2 molecules in this source had a rotational temperature of only 90 K so that only the low-J lines were present in the spectrum. In some sense the low temperatures in the jet source simulate conditions in the interstellar medium. The Swan system of C2 was also produced in a composite wall hollow cathode made Al4C3/Cu, and the rotational structure of the 1-0, 2-1, 3-2, 0-0, and 1-1 bands were analyzed. The data obtained from both these spectra were fitted together along with some recently published line positions. The rotational constants, lambda doubling parameters and the vibrational constants were estimated from this global fit. Our work on jet-cooled C2 follows similar work on the violet and red systems of CN. A summary of this CN work is also presented. also presented.

Prasad, C. V. V.↗

NASA NTRS1994

Pre- and postperihelon abundances of gas and dust in comet Halley

Photometrically calibrated spectra of comet P/Halley (1986 III) were recorded between 1985 September 12-1986 June 10 using the Ohio State University Image Dissector Scanner on the Perkins 72 inch telescope at the Lowell Observatory. Column densities of CN, C3, CH, C2, and NH2 were calculated from measured fluxes in these spectra, and molecular scale lengths were deduced from the radial distribution of CN, C3, C2, and NH2. Production rates were computed using the new scale lengths and a Haser model analysis. Continuum emission at 4260 A was used to derive gas-to-dust ratios. The data indicate than comet Halley was approximately 2-5 times more abundant in gas and dust at postperihelion than preperihelion. On 1986 June 8 we observed the onset of a cometary ourburst which appeared very strong in dust production. The gas-to-dust ratios appeared to be subject to changes as a result of short-term outbursts but otherwise did not exhibit any systematic dependence on heliocentric distance. Reflectivity gradients of the continuum were also measured from the spectra. While most of the continua were red, blue continua were also observed which may be correlated with dust outbursts.

Womack, Maria↗

NASA NTRS1994

Variability in Comet P/Swift-Tuttle

Spatial profiles of the coma of Comet P/Swift-Tuttle perpendicular to the projected Sun-comet line were obtained for the emission bands of CN, C2, and C3 as well as for two continuum bands from spectrophotometric observations taken from Oct. 5 to 8, 1992. The intensities were converted into emissivities per sq km in the cases of the continua and into column densities for the emission band profiles. Spatial and temporal variabilities have been found in all five investigated components, which are consistent with the rotational period of the nucleus determined from the observations of the comet during its last perihelion passage in 1862. The emission band profiles were fitted with the vectorial model and the production rates of CN, C2, and C3 were determined. One half of the profiles was fitted adequately under steady state conditions for the production rate in a first approximation, whereas the other half showed prominent bumps, which could only be explained by introducing a time-dependent production rate. Further investigations showed evidence for the presence of gaseous as well as dust jets in the coma, which indicated the presence of at least two active areas on the surface of the nucleus. The projected radial expansion velocities of two different features were determined to be (430 +/- 100) and (460 +/- 100) m/sec, respectively.

Schulz, Rita↗

NASA NTRS1995

Origin of condensation nuclei in the springtime polar stratosphere

An enhanced sulfate aerosol layer has been observed near 25 km accompanying springtime ozone depletion in the Antarctic stratosphere. We use a one-dimensional aerosol model that includes photochemistry, particle nucleation, condensational growth, coagulation, and sedimentation to study the origin of the layer. Annual cycles of sunlight, temperature, and ozone are incorporated into the model. Our results indicate that binary homogeneous nucleation leads to the formation of very small droplets of sulfuric acid and water under conditions of low temperature and production of H2SO4 following polar sunrise. Photodissociation of carbonyl sulfide (OCS) alone, however, cannot provide sufficient SO2 to create the observed condensation nuclei (CN) layer. When subsidence of SO2 from very high altitudes in the polar night vortex is incorporated into the model, the CN layer is reasonably reproduced. The model predictions, based on the subsidence in polar vortex, agree with in situ measurements of particle concentration, vertical distribution, and persistence during polar spring.

Zhao, Jingxia↗

NASA NTRS1995

Space flight data from the isothermal dendritic growth experiment

The Isothermal Dendritic Growth Experiment (IDGE) is a NASA space flight experiment which flew as part of the United States Microgravity Payload (USMP-2), in early 1994. The IDGE measured dendritic growth rates, tip radii, and crystal morphologies of ultra-pure succinonitrile (CN-(CH2)2-CN) at supercoolings in the range from 0.05 - 2.0 K. Data taken in the form of slow-scan binary digitized images telemetered to the ground from orbit in near-real time, combined with the IDGE terrestrial data set, provide the first quantitative assessment of various theories on dendritic solidification and the effects of convection on dendritic growth.

Glicksman, M. E.↗

NASA NTRS1995

Origin of Condensation Nuclei in the Springtime Polar Stratosphere

Zhao, Jingxia↗

NASA NTRS1997

Boron Abundances in A and B-type Stars

Boron abundances in A- and B-type stars may be a successful way to track evolutionary effects in these hot stars. The light elements - Li, Be, and B - are tracers of exposure to temperatures more moderate than those in which the H-burning CN-cycle operates. Thus, any exposure of surface stellar layers to deeper layers will affect these light element abundances. Li and Be are used in this role in investigations of evolutionary processes in cool stars, but are not observable in hotter stars. An investigation of boron, however, is possible through the B II 1362 A resonance line. We have gathered high resolution spectra from the IUE database of A- and B-type stars near 10 solar mass for which nitrogen abundances have been determined. The B II 1362 A line is blended throughout; the temperature range of this program, requiring spectrum syntheses to recover the boron abundances. For no star could we synthesize the 1362 A region using the meteoritic/solar boron abundance of log e (B) = 2.88; a lower boron abundance was necessary which may reflect evolutionary effects (e.g., mass loss or mixing near the main-sequence), the natal composition of the star forming regions, or a systematic error in the analyses (e.g., non-LTE effects). Regardless of the initial boron abundance, and despite the possibility of non-LTE effects, it seems clear that boron is severely depleted in some stars. It may be that the nitrogen and boron abundances are anticorrelated, as would be expected from mixing between the H-burning and outer stellar layers. If, as we suspect, a residue of boron is present in the A-type supergiants, we may exclude a scenario in which mixing occurs continuously between the surface and the deep layers operating the CN-cycle. Further exploitation of the B II 1362 A line as an indicator of the evolutionary status of A- and B-type stars will require a larger stellar sample to be observed with higher signal-to-noise as attainable with the Hubble Space Telescope.

Lambert, David L.↗