SEARCH · Engineering Papers

Results for “sublimation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 631 records · Page 35

All sources NASA NTRS DOE OSTI

NASA NTRS1992

CHON as a component of dust from Comet Halley

Three sets of particle mass spectra are used here to investigate the relationship between CHON (dust composed predominantly of carbon, hydrogen, oxygen, and nitrogen) and silicate materials in Comet Halley. It is found that there are essentially no pure CHON particles in the 0.1-1 micron size range sampled; instead, essentially all Halley particles sampled by the mass spectrometers are a mixture of both CHON and silicate components. The data show that the CHON and silicate components are interdispersed at submicron scales, and there is evidence that sublimation of volatile organic material occurs, bringing many particles to a common proportion of CHON and silicate material.

Lawler, Mark E.↗

NASA NTRS1993

The brightness of Jupiter's satellite Io following emergence from eclipse - Selected observations, 1981-1989

Io's brightness was monitored following emergence from eclipse by Jupiter on 14 occasions during the Jupiter apparitions from 1981 to 1989 and no instance is found of what has been called posteclipse brightening. If all the observations are averaged, a 2 percent effect cannot be ruled out; however, this effect is also the size of the rms errors of the summed data set. If condensation followed by sublimation of SO2 frost is hypothesized to be the mechanism which causes posteclipse brightening, then solar insolation alone may not be sufficient to remove an optically thick layer of SO2 frost in the time required to conform with the positive reports of posteclipse brightening in the literature. An additional source of energy is required, such as warming caused by the impact of magnetospheric particles as they dissipate the energy of their motion into Io's surface.

Nelson, Robert M.↗

NASA NTRS1993

The Mars water cycle at other epochs - Recent history of the polar caps and layered terrain

A numerical model is presented of the integrated role of seasonal water cycle on the evolution of polar deposits on Mars over the last 10 million years. From the model, it is concluded that the only major difference between the polar caps which affects their long-term behavior is ultimately the difference in their elevations. Because of that difference, there is a preference for CO2 frost to stay longer on the northern polar cap. The average difference in sublimation at the caps results in a net south-to-north transport of water ice over long time scales. Superimposed on any long-term behavior is a transfer of water ice between the caps on the 10 exp 5 - 10 exp 6 yr time scales. The amount of water exchanged is small compared to the total ice content of the polar deposits.

Jakosky, Bruce M.↗

NASA NTRS1992

Convective effects during the physical vapor transport process. I - Thermal convection

The effects of convection on diffusive-convective physical vapor transport process are examined computationally. We analyze conditions ranging from typical laboratory conditions to conditions achievable only in a low gravity environment. This corresponds to thermal Rayleigh numbers Ra(T) ranging from 1.80 to 1.92 x 10 exp 6. Our results indicate that the effect of the sublimation and condensation fluxes at the boundaries is 10 increase the threshold of instability. For typical ground based conditions time dependent oscillatory convection can occur. This results in nonuniform temperature and concentration gradients at the crystal interface. Spectral analysis of the flow field shows regions of both periodic and quasi-periodic states. Low gravity conditions can effectively reduce convective effects, thus resulting in uniform temperature and concentration gradients at the interface, a desirable condition for crystal growth.

Duval, Walter M. B.↗

NASA NTRS1993

H2 in interstellar and extragalactic ices - Infrared characteristics, ultraviolet production, and implications

H2 is the most abundant molecule in the universe. We demonstrate that this molecule may be an important component of interstellar and possibly intergalactic ices, both because it can be formed in situ, within the ices, and because gas-phase H2 can freeze out onto dust grains in some astrophysical environments. The condensation-sublimation and infrared spectral properties of ices containing H2 are presented. We show that solid H2 in H2O-rich ices can be detected by an infrared absorption band at 4137/cm (2.417 microns). The surface binding energy of H2 to H2O ice was measured to be Delta-H(s)/k = 555 +/- 35 K. Surface binding energies can be used to calculate the residence times of H2 on grain surfaces as a function of temperature. Some of the implications of these results are considered.

Sandford, Scott A.↗

NASA NTRS1993

On the microphysical state of the Martian seasonal caps

An analysis of the microphysical processes involved in pressureless sintering leads to the view that CO2 in the Martian seasonal polar caps can metamorphose into an annealed polycrystalline layer, if freshly condensed grains are smaller than 10 microns. Such large-area/low-porosity CO2 deposits may be associated with the mm-to-cm-scaled path lengths entailed by the explanation of several weak absorption features in the 1.5- and 2.3-micron spectral regions. Such an annealed layer would become transparent enough during the later stages of spring sublimation to establish a basis for the dichotomy between the north and south caps' albedos in the underlying substrate.

Eluszkiewicz, Janusz↗

NASA NTRS1993

The Martian annual atmospheric pressure cycle - Years without great dust storms

A model of the annual cycle of pressure on Mars for a 2-yr period, chosen to include one year at the Viking Lander 2 and to minimize the effect of great dust storms at the 22-deg N Lander 1 site, was developed by weighted least squares fitting of the Viking Lander pressure measurements to an annual mean, and fundamental and the first four harmonics of the annual cycle. Close agreement was obtained between the two years, suggesting that an accurate representation of the annual CO2 condensation-sublimation cycle can be established for such years. This model is proposed as the 'nominal' Martian annual pressure cycle, and applications are suggested.

Tillman, James E.↗

NASA NTRS1993

Atmospheric entry of Mars-return nuclear-powered vehicles due to accidental termination of operations

The entry of nuclear reactors into Earth's atmosphere resulting from an accidental or inadvertent abort of a space vehicle powered by nuclear-thermal rockets is investigated. The study is made for a typical piloted Mars mission vehicle incapacitated by an accident or malfunction during the Earth-arrival phase of the Mars-return journey due to simultaneous, multiple failures of its component systems. A single accident/abort scenario resulting in three entry possibilities is considered for a nominal hyperbolic in-bound approach velocity of 8 km/sec. The most severe case involving a direct entry is then analyzed over a broad range of approach velocities extending to 12 km/sec to include sprint-type missions. The results indicate that the severe surface heating, stagnation pressures, and g-loads are greater than 150 kW/sq cm, 300 atm, and 800-g, respectively. The wall heat transfer rate exceeds the value that can be accommodated by a carbon heatshield through radiation equilibrium prior to sublimation at 5500 K. These conditions are beyond our previous experience in crew safety, structural design, and thermal protection.

Menees, Gene P.↗

NASA NTRS1992

Growth and characterizaton of 3C-SiC and 6H-SiC films on 6H-SiC wafers

Single crystal SiC films were grown by CVD on vicinal (0001) SiC wafers cut from boules produced by the modified sublimation method. Wafers with tilt angles less than 0.5 deg yielded 3C-SiC; tilt angles of 3 to 4 deg resulted in 6H-SiC films. The surface morphology of these films, up to 24 microns thick, were investigated as a function of growth parameters such as the Si/C ratio in the input gases and the presence of dopant materials such as nitrogen and trimethylaluminum.

Powell, J. A.↗

NASA NTRS1993

Carbon analyses of IDP's sectioned in sulfur and supported on beryllium films

Carbon is the only major element in interplanetary dust whose abundance, distribution and chemical state are not well understood. Information about carbon could clarify the relationship between the various classes of IDP's, conventional meteorites, and sources (e.g., comets vs. asteroids). To date, the most reliable estimates of C abundance in Interplanetary Dust Particles (IDP's) have been obtained by analyzing particles on thick-flat Be substrates using thin-window energy-dispersive spectroscopy in the SEM. These estimates of C abundance are valid only if C is homogeneously distributed, because detected C x-rays originate from the outer 0.1 micrometers of the particle. An alternative and potentially more accurate method of measuring C abundances is to analyze multiple thin sections (each less than 0.1 less than 0.1 micrometers thick) of IDP's. These efforts however, have been stymied because of a lack of a suitable non-carbonaceous embedding medium and the availability of C-free conductive substrates. We have embedded and thin-sectioned IDP's in glassy sulfur, and transferred the thin sections to Be support films approximately 25 nm thick. The sections were then analyzed in a 200 KeV analytical TEM. S sublimes rapidly under vacuum in the TEM, leaving non-embedded sections supported on Be. Apart from quantitative C (and O) analyses, S sectioning dramatically expands the range of analytical measurements that can be performed on a single IDP.

Bradley, J. P.↗

NASA NTRS1993

The physical mechanism of comet outbursts: An experiment

During a series of impact experiments into regolith-like powders at the NASA Ames Research Center Vertical Gun Facility in 1976, I observed and filmed a unique anomalous event that may illuminate outburst mechanisms in comets. During one test, a new batch of basalt powder (half the mass in particles less than 800 microns in diameter) retained some air pressure while the vacuum chamber was being evacuated. As a result, the projectile impacted into gas-charged regolith. Instead of ejecting the normal, relatively negligible amount of debris, the disturbance triggered a major eruption that lasted at least 18 seconds. The experimental results have been recently re-analyzed with reference to cometary phenomena. A series of frames from this eruption experiment are shown. The ejecta velocities of 150 to 300 cm/s would have been sufficient to drive debris into the coma of a comet nucleus smaller than a few kilometers diameter. The event suggests a mechanism for comet outbursts, discussed briefly by Hartmann et al.: the pore space in a layer of regolith, possibly with weak effective tensile strength, becomes gas charged as ice slowly sublimates. Once the effective tensile strength is exceeded by the gas pressure, the surface fails locally, triggering an eruption such as photographed here. This model is consistent with the emerging view of regolith materials on comets and is closest to the recent model of Rickman et al. The earlier models generally picture a more uniform flow of debris off the comet, not outbursts. Rickman et al. allow gas pressure to build until it matches the overburden pressure, followed by 'instantaneous blow-off'. They note that as soon as the mantle is found to be unstable, we consider it to be instantaneously swept away by the gas pressure. The main new points made here are that the experiment gives a more realistic view of the blow-off process after surface failure occurs, and the present model gives a recharge mechanism that can explain recurrent outbursts on comets such as P/Schwassmann-Wachmann 1 and 2060 Chiron. In fact, the resulting jets resemble distinct jet structures in high-resolution comet comae.

Hartmann, William K.↗

NASA NTRS1993

Thermal inertia and radar reflectivity of the Martian north polar ERG: Low-density aggregates

The north polar layered deposits on Mars appear to be the source of the dark material that comprises the north polar erg. The physical properties and chemical composition of the erg material therefore have important implications for the origin and evolution of the Martian layered deposits. Viking bistatic radar and infrared thermal mapping (IRTM) data indicate that the bulk density of the erg material is lower than that of the average Martian surface. These data are consistent with hypotheses involving formation of filamentary sublimation residue (FSR) particles from erosion of the layered deposits. The color and albedo of the erg and of the layered deposits, and the presence of magnetic material on Mars, suggest that the dark material is composed of low-density aggregates of magnetic dust grains, perhaps similar to FSR particles created in laboratory experiments.

Herkenhoff, K. E.↗

NASA NTRS1993

Possible occurrence and origin of massive ice in Utopia Planitia

F. M. Costard recently discovered a large field of possible thermokarst depressions near latitude 45 deg N, longitude 270 deg, in western Utopia Planitia. Oval to circular pits are typically 300-1000 m across and approximately 25 m deep; larger depressions, 3-5 km across, are compound and seem to have formed by coalescence of smaller pits. Small domical hills occur on the floors of two pits. These depressions characteristically have steep, scalloped edges and one or more inner benches. Truncation relations of the benches suggest a discontinuous, lenslike stratification of the material in which the pits are developed. Based on a close analogy in form and scale with coalesced thawlake basins (alases) on Earth, the Martian pits may have formed by thermophysical interactions of pooled water with ice-rich permafrost. This interpretation is not unique; sublimation of ice-rich permafrost or possibly even eolian processes acting on ice-free material might have formed the pits. However, the regional setting contains many other indications of massive ice. Some of these features are examined.

Kargel, J. S.↗

NASA NTRS1994

Close-up analysis of inflight ice accretion

The objective of this effort was to validate in flight, data that has been gathered in the NASA Lewis Research Center's Icing Research Tunnel (IRT) over the past several years. All data was acquired in flight on the NASA Lewis Research Center's Twin Otter Icing Research Aircraft. A faired 3.5 in. diameter metal-clad cylinder exposed to the natural icing environment was observed by a close-up video camera. The grazing angle video footage was recorded to S-VHS video tape and after the icing encounter, the resultant ice shape was documented by 35 mm photography and pencil tracings. The feather growth area was of primary interest; however, all regions of the ice accretion, from the stagnation line to the aft edge of run back were observed and recorded. After analysis of the recorded data several interesting points became evident: (1) the measured flight feather growth rate is consistent with IRT values, (2) the feather growth rate appears to be influenced by droplet size, (3) the feathers were straighter in the lower, spottier LWC of flight in comparison to those observed in the IRT, (4) feather shedding and ice sublimation may be significant to the final ice shape, and (5) the snow encountered on these flights appeared to have little influence on ice growth.

Reehorst, Andrew L.↗

NASA NTRS1993

Numerical modeling of physical vapor transport under microgravity conditions: Effect of thermal creep and stress

One of the most promising applications of microgravity (micro-g) environments is the manufacture of exotic and high-quality crystals in closed cylindrical ampoules using physical vapor transport (PVT) processes. The quality enhancements are believed to be due to the absence of buoyant convection in the weightless environment - resulting in diffusion-limited transport of the vapor. In a typical experiment, solid-phase sample material is initially contained at one end of the ampoule. The sample is made to sublime into the vapor phase and deposit onto the opposite end by maintaining the source at an elevated temperature with respect to the deposit. Identification of the physical factors governing both the rates and uniformity of crystal growth, and the optimization of the micro-g technology, will require an accurate modeling of the vapor transport within the ampoule. Previous micro-g modeling efforts have approached the problem from a 'classical' convective/diffusion formulation, in which convection is driven by the action of buoyancy on thermal and solutal density differences. The general conclusion of these works have been that in low gravity environments the effect of buoyancy on vapor transport is negligible, and vapor transport occurs in a diffusion-limited mode. However, it has been recently recognized than in the non-isothermal (and often low total pressure) conditions encountered in ampoules, the commonly-assumed no-slip boundary condition to the differential equations governing fluid motion can be grossly unrepresentative of the actual situation. Specifically, the temperature gradients can give rise to thermal creep flows at the ampoule side walls. In addition, temperature gradients in the vapor itself can, through the action of thermal stress, lead to bulk fluid convection.

Mackowski, Daniel W.↗

NASA NTRS1993

The annual pressure cycle on Mars: Results from the LMD Martian atmospheric general circulation model

We have been developing a General Circulation Model (GCM) of the martian atmosphere since 1989. The model has been described rather extensively elsewhere and only the main characteristics are given here. The dynamical part of the model, adapted from the LMD terrestrial climate model, is based on a finite-difference formulation of the classical 'primitive equations of meteorology.' The radiative transfer code includes absorption and emission by CO2 (carefully validated by comparison to line-by-line calculations) and dust in the thermal range and absorption and scattering by dust in the visible range. Other physical parameterizations are included: modeling of vertical turbulent mixing, dry convective adjustment (in order to prevent vertical unstable temperature profiles), and a multilayer model of the thermal conduction in the soil. Finally, the condensation-sublimation of CO2 is introduced through specification of a pressure-dependent condensation temperature. The atmospheric and surface temperatures are prevented from falling below this critical temperature by condensation and direct precipitation onto the surface of atmospheric CO2. The only prespecified spatial fields are the surface thermal inertia, albedo, and topography.

Hourdin, Frederic↗

NASA NTRS1993

Metal hydride heat pump engineering demonstration and evaluation model

Future generations of portable life support systems (PLSS's) for space suites (extravehicular mobility units or EMU's) may require regenerable nonventing thermal sinks (RNTS's). For purposes of mobility, a PLSS must be as light and compact as possible. Previous venting PLSS's have employed water sublimators to reject metabolic and equipment heat from EMU's. It is desirable for long-duration future space missions to minimize the use of water and other consumables that need to be periodically resupplied. The emission of water vapor also interferes with some types of instrumentation that might be used in future space exploration. The test article is a type of RNTS based on a metal hydride heat pump (MHHP). The task of reservicing EMU's after use must be made less demanding in terms of time, procedures, and equipment. The capability for quick turnaround post-EVA servicing (30 minutes) is a challenging requirement for many of the RNTS options. The MHHP is a very simple option that can be regenerated in the airlock within the 30 minute limit by the application of a heating source and a cooling sink. In addition, advanced PLSS's must provide a greater degree of automatic control, relieving astronauts of the need to manually adjust temperatures in their liquid cooled ventilation garments (LCVG's). The MHHP includes automatic coolant controls with the ability to follow thermal load swings from minimum to maximum in seconds. The MHHP includes a coolant loop subsystem with pump and controls, regeneration equipment for post-EVA servicing, and a PC-based data acquisition and control system (DACS).

Lynch, Franklin E.↗

NASA NTRS1993

Thermal and hydraulic considerations regarding the fate of water discharged by the outflow channels to the Martian northern plains

The identification of possible shorelines in the Martian northern plains suggests that the water discharged by the circum-Chryse outflow channels may have led to the formation of transient seas, or possibly even an ocean, covering as much as one-third of the planet. Speculations regarding the possible fate of this water have included local ponding and reinfiltration into the crust; freezing, sublimation, and eventual cold-trapping at higher latitudes; or the in situ survival of this now frozen water to the present day -- perhaps aided by burial beneath a protective cover of eolian sediment or lavas. Although neither cold-trapping at higher latitudes nor the subsequent freezing and burial of flood waters can be ruled out, thermal and hydraulic considerations effectively eliminate the possibility that any significant reassimilation of this water by local infiltration has occurred given climatic conditions resembling those of today. The arguments against the local infiltration of flood water into the northern plains are two-fold. First, given the climatic and geothermal conditions that are thought to have prevailed on Mars during the Late Hesperian (the period of peak outflow channel activity in the northern plains), the thickness of the cryosphere in Chryse Planitia is likely to have exceeded 1 km. A necessary precondition for the widespread occurrence of groundwater is that the thermodynamic sink represented by the cryosphere must already be saturated with ice. For this reason, the ice-saturated cryosphere acts as an impermeable barrier that effectively precludes the local resupply of subpermafrost groundwater by the infiltration of water discharged to the surface by catastraphic floods. Note that the problem of local infiltration is not significantly improved even if the cryosphere were initially dry, for as water attempts to infiltrate the cold, dry crust, it will quickly freeze, creating a seal that prevents any further infiltration from the ponded water above. The second argument against the local infiltration of flood water in the northern plains is based on hydraulic considerations. Repeated impacts have likely brecciated the Martian crust down to a depth of roughly 10 km. Given a value of permeability no greater than that inferred for the top 10 km of the Earth's crust (approximately 10(exp -2) darcies), a timescale as much as a billion years or more for the Martian groundwater system to achieve hydrostatic equilibrium, and the approximately 2-4 km elevation difference between the outflow channel source regions and the northern plains, the water confined beneath the frozen crust of the northern plains should have been under a significant hydraulic head. Thus, the existence of a hydraulic pathway between the ponded flood waters above the northern plains and the confined aquifer lying beneath it would not have led to the infiltration of flood water back into the crust, but rather the additional expulsion of groundwater onto the surface.

Clifford, S. M.↗