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At least 631 records · Page 35

A Terrestrial Analogue from Spitsbergen (Svalbard, Norway) for the Comanche Carbonate at Gusev Crater, Mars

Carbonate occurs at the Comanche outcrops in Gusev Crater on the basis of analyses made by the Mars Exploration Rover Spirit [1]. Taken together, mineralogical data from Spirit's Moessbauer (MB) and Mini-TES spectrometer and chemical data from the APXS spectrometer show that Comanche carbonate has an Mg-Fe-rich bulk chemical composition, is present at high concentrations, and is distributed throughout the outcrop and not just at the MB and APXS analysis location. The granular outcrop texture and the observation that it appears to be resistant to weathering compared with surrounding material [1] imply that the carbonate may be present as a cement. A hydrothermal origin for the Comanche carbonate was inferred by analogy with laboratory experiments and with a carbonate occurrence within the Bockfjord volcanic complex on the island Spitsbergen (Svalbard, Norway) [1]. The laboratory carbonates, synthesized by precipitation from hydrothermal solutions, have (MB) parameters and average bulk chemical compositions that are characteristic of Comanche carbonate. The connection to Comanche carbonate is only through chemical data for certain occurrences of Spitsbergen carbonates. In fact, the common average bulk chemical composition for these Spitsbergen carbonates, the synthetic carbonates, the Comanche carbonate, and also the carbonate globules found in martian meteorite ALH84001 is a chemical constraint consistent with a hydrothermal formation process for all the carbonates [e.g., 1-3]. We develop here a link between MB data for the Comanche carbonate from MER and MB data for certain Spitsbergen carbonate occurrences from laboratory measurements. We also obtained visible and near- IR spectra on Spitsbergen carbonates for comparison with martian carbonate detections made on the basis of CRISM spectral data, e.g., in Nili Fossae [4].

Morris, Richard V.↗

Acoustic Data Processing and Transient Signal Analysis for the Hybrid Wing Body 14- by 22-Foot Subsonic Wind Tunnel Test

An advanced vehicle concept, the HWB N2A-EXTE aircraft design, was tested in NASA Langley's 14- by 22-Foot Subsonic Wind Tunnel to study its acoustic characteristics for var- ious propulsion system installation and airframe con gurations. A signi cant upgrade to existing data processing systems was implemented, with a focus on portability and a re- duction in turnaround time. These requirements were met by updating codes originally written for a cluster environment and transferring them to a local workstation while en- abling GPU computing. Post-test, additional processing of the time series was required to remove transient hydrodynamic gusts from some of the microphone time series. A novel automated procedure was developed to analyze and reject contaminated blocks of data, under the assumption that the desired acoustic signal of interest was a band-limited sta- tionary random process, and of lower variance than the hydrodynamic contamination. The procedure is shown to successfully identify and remove contaminated blocks of data and retain the desired acoustic signal. Additional corrections to the data, mainly background subtraction, shear layer refraction calculations, atmospheric attenuation and microphone directivity corrections, were all necessary for initial analysis and noise assessments. These were implemented for the post-processing of spectral data, and are shown to behave as expected.

Bahr, Christopher J.↗

Comparison of column water vapor measurements using downward-looking near-infrared and infrared imaging systems and upward-looking microwave radiometers

Remote soundings of precipitable water vapor from three systems are compared with each other and with ground truth from radiosondes. Ancillary data from a mesoscale network of surface observing stations and from wind-profiling radars are also used in the analysis. The three remote-sounding techniques are: (a) a reflectance technique using spectral data collected by the Airborne Visible-Infrared Imaging Spectrometer; (b) an emission technique using Visible-Infrared Spin Scan Radiometer Atmospheric Sounder (VAS) data acquired from the NOAA's GOES; and (c) a microwave technique using data from a limited network of three ground-based dual-channel microwave radiometers. The data were taken over the Front Range of eastern Colorado on 22-23 March 1990. The generally small differences between the three types of remote-sounding measurements are consistent with the horizontal and temporal resolutions of the instruments. The microwave and optical reflectance measurements agreed to within 0.1 cm; comparisons of the microwave data with radiosondes were also either as good or explainable. The largest differences between the VAS and the microwave radiometer at Elbert were between 0.4 and 0.5 cm and appear to be due to variable terrain within the satellite footprint.

Gao, Bo-Cai↗

Transient Infall Events in the Disk of AB Aurigae: The Beta Pictoris Phenomenon at 2-4 Mega Years

Surveys of Herbig Ae/Be stars have indicated that infalling circumstellar gas similar to that routinely detected toward beta Pic is preferentially observed close to the disk midplane. Recent millimeter interferometry of the historically prototypical Herbig Ae star, AB Aur, indicates that this star is viewed slightly above the disk midplane (i = 76 deg). The wealth of archival spectroscopic data for this star makes it an ideal test of the geometry for infalling or accreting gas in these stars. We present a review of the extant IUE and Hubble Space Telescope GHRS spectral data for AB Aur and find, in contrast to previous studies of this star, which focused on Mg II, that infalling gas is detected at all epochs with covering factors similar to those reported for HD 100546 and that an episode of enhanced infall was serendipitously detected during the 1990 monitoring run.

Grady, C. A.↗

Using Multi-Angle Imaging SpectroRadiometer (MISR) bidirectional reflectances for land surface studies

MISR imagery enables new methods for cloud screening and retrieval of aerosol properties over a wide range of surface types, and these data are used to compensate for atmospheric effects in the surface retrievals. The derived surface angular signatures are governed, at least in part, by macroscopic texture at the subpixel scale. Such information complements spectral data in distinguishing different types of surface cover, retrieving land surface hemispherical reflectance,and determining biogeophysical properties such as leaf area index and fractional absorbed photosynthetically active radiation. Regional and global MISR data products will be presented to illustrate the capabilities of the instrument andassociated retrieval methodologies.

MISR bidirectional surface studies spectr↗

Beta-delayed gamma spectra compilation and analysis following the thermal-neutron induced fission of 235 U, 239,241 Pu

The integral gamma and electron spectra emitted by fission products, also known as delayed gamma and electron spectra, were measured at Oak Ridge National Laboratory in the 1970s for the thermal-neutron induced fission of 235 U and 239,241 Pu. Scintillator detectors were used to measure these spectra, data used later on to obtain decay heat values - that is, the spectra mean values per unit time as function of time - work that was published in the Nuclear Science and Technology journal; the spectral data, however, was only published in laboratory reports. Here, in this work, we analyze the gamma spectra data using modern methods and nuclear databases to reveal the signature of individual fission products as well as to gauge the performance of the ENDF/B-VIII.0 decay data sub-library, concluding about possible future enhancements in predictive capabilities.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Reducing the matrix effect in mass spectral imaging of biofilms using flow-cell culture

The interactions between soil microorganisms and soil minerals play a crucial role in the formation and evolution of minerals and the stability of soil aggregates. Due to the heterogeneity and diversity of the soil environment, the under-standing of the functions of bacterial biofilms in soil minerals at the microscale is limited. A soil mineral-bacterial biofilm system was used as a model in this study, and it was analyzed by time-of-flight secondary ion mass spectrometry (ToF-SIMS) to acquire molecular level information. Static culture in multi-wells and dynamic flow-cell culture in microfluidics of biofilms were investigated. Our results show that more characteristic molecules of biofilms can be observed in SIMS spectra of the flow-cell culture. In contrast, biofilm signature peaks are buried under the mineral components in SIMS spectra in the static culture case. Spectral overlay was used in peak selection prior to performing Principal component analysis (PCA). Comparisons of the PCA results between the static and flow-cell culture show more pronounced molecular features and higher loadings of organic peaks of the dynamic cultured specimens. For example, fatty acids secreted from bacterial biofilm extracellular polymeric substance are likely to be responsible for biofilm dispersal due to mineral treatment up to 48 h. Such findings suggest that the use of microfluidic cells to dynamically culture biofilms be a more suitable method for reducing the matrix effect arisen from the growth medium and minerals as a perturbation fac-tor for improved spectral and multivariate analysis of complex mass spectral data in ToF-SIMS. These results show that the interaction mechanism between biofilms and soil minerals at the molecular level can be better studied using the flow-cell culture and advanced mass spectral imaging techniques like ToF-SIMS.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Distinguishing vegetation from soil background information

In aircraft and satellite multispectral scanner data, soil background signals are superimposed on or intermingled with information about vegetation. A procedure which accounts for soil background would, therefore, make a considerable contribution to an operational use of Landsat and other spectral data for monitoring the productivity of range, forest, and crop lands. A description is presented of an investigation which was conducted to obtain information for the development of such a procedure. The investigation included a study of the soil reflectance that supplies the background signal of vegetated surfaces. Landsat data as recorded on computer compatible tapes were used in the study. The results of the investigation are discussed, taking into account a study reported by Kauth and Thomas (1976). Attention is given to the determination of Kauth's plane of soils, sun angle effects, vegetation index modeling, and the evaluation of vegetation indexes. Graphs are presented which show the results obtained with a gray mapping technique. The technique makes it possible to display plant, soil, water, and cloud conditions for any Landsat overpass.

Richardson, A. J.↗

Progress In Plasma Accelerator Development for Dynamic Formation of Plasma Liners

An experimental plasma accelerator for magnetic target fusion (MTF) applications under development at the NASA Marshall Space Flight Center is described. The accelerator is a coaxial pulsed plasma thruster (Figure 1). It has been tested experimentally and plasma jet velocities of approx.50 km/sec have been obtained. The plasma jet has been photographed with 10-ns exposure times to reveal a stable and repeatable plasma structure (Figure 2). Data for velocity profile information has been obtained using light pipes and magnetic probes embedded in the gun walls to record the plasma and current transit respectively at various barrel locations. Preliminary spatially resolved spectral data and magnetic field probe data are also presented. A high speed triggering system has been developed and tested as a means of reducing the gun "jitter". This jitter is being characterized and future work for second generation "ultra-low jitter" gun development is being identified.

Thio, Y. C. Francis↗

Demonstration of the Wide-Field Imaging Interferometer Testbed Using a Calibrated Hyperspectral Image Projector

The Wide-field Imaging Interferometer testbed (WIIT) at NASA's Goddard Space Flight Center uses a dual-Michelson interferometric technique. The WIIT combines stellar interferometry with Fourier-transform interferometry to produce high-resolution spatial-spectral data over a large field-of-view. This combined technique could be employed on future NASA missions such as the Space Infrared Interferometric Telescope (SPIRIT) and the Sub-millimeter Probe of the Evolution of Cosmic Structure (SPECS). While both SPIRIT and SPECS would operate at far-infrared wavelengths, the WIIT demonstrates the dual-interferometry technique at visible wavelengths. The WIIT will produce hyperspectral image data, so a true hyperspectral object is necessary. A calibrated hyperspectral image projector (CHIP) has been constructed to provide such an object. The CHIP uses Digital Light Processing (DLP) technology to produce customized, spectrally-diverse scenes. CHIP scenes will have approximately 1.6-micron spatial resolution and the capability of . producing arbitrary spectra in the band between 380 nm and 1.6 microns, with approximately 5-nm spectral resolution. Each pixel in the scene can take on a unique spectrum. Spectral calibration is achieved with an onboard fiber-coupled spectrometer. In this paper we describe the operation of the CHIP. Results from the WIIT observations of CHIP scenes will also be presented.

Bolcar, Matthew R.↗

Spectroscopy on the A 1 Π←X 1 Σ + Transition of Buffer-Gas Cooled AlCl

Aluminum monochloride (AlCl) has been proposed as an excellent candidate for laser cooling. Here we present absorption spectroscopy measurements on the A 1 Π←X 1 Σ + transition in AlCl inside a cryogenic helium buffer-gas beam cell. The high resolution absorption data enables a rigorous, quantitative comparison with our high-level ab initio calculations of the electronic and rovibronic energies, providing a comprehensive picture of the AlCl quantum structure. Further, the combination of high resolution spectral data and theory permits the evaluation of spectroscopic constants and associated properties, like equilibrium bond length, with an order of magnitude higher precision. Based on the measured molecular equilibrium constants of the A 1 Π state, we estimate a Franck-Condon factor of the A 1 Π←X 1 Σ + of 99.88%, which confirms that AlCl is amenable to laser cooling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The nature and origin of interstellar diamond

The C-delta component of the Allende meteorite is a microscopic diamond some of whose properties seem in conflict with those expected of diamond. High spatial resolution analytical data are presented here which may help explain such results. Surface and interfacial carbon atoms in the component, which may comprise as much as 25 percent of the total, impart an 'amorphous' character to some spectral data. These data support the proposed high-pressure conversion of amorphous carbon and graphite into diamonds due to grain-grain collisions in the ISM, although a low-pressure mechanism of formation cannot be ruled out.

Blake, David F.↗

Evidence for a Hematite Ore Body on Mars

The Mars Global Surveyor (MGS) spacecraft was launched from Cape Kennedy in November 1996. MGS was put into orbit around Mars in September of 1997 and has since been sending back data from a suite of instruments, including the Thermal Emission Spectrometer (TES). The TES instrument is an interferometric spectrometer designed to map the surface mineralogy of Mars by measuring the midinfrared emitted radiation over the spectral region of about 1600 to 200 cm(exp -1) (about 6 to 50 microns). This mineralogically sensitive technique utilizes the characteristic intra- and inter-molecular vibrations of minerals that are manifested in the midinfrared spectra. These spectral "fingerprints" are unique because they are dependent upon chemical composition, crystal structure, crystal orientation, and other factors. Midinfrared spectral data received from the MGS-TES instrument have indicated the presence of a large deposit of hematite (alpha-Fe2O3) in Sinus Meridiani, Mars. This hematite ore body, that is accompanied by basalt, is really extensive, encompassing an area about 350 by 500 km. To better understand the geologic context of this large deposit, a detailed laboratory spectroscopic investigation was conducted using more than 20 hematite samples so that their spectra could be compared to the martian spectra. The samples included red and gray polycrystaline hand samples, gray single-crystal hand samples, and red and gray fine- and coarse-grained particulates. The laboratory analyses provided thermal emissivity spectra that, when compared to the hematite emissivity spectra from Mars, suggest the Sinus Meridiani hematite is possibly an exposure of oriented hematite grains. These grains are likely coarser that 10 microns (and may be much larger) and gray in color. The characteristic of oriented grains is suggested by the apparent crystal axis-dependence of the energy emitted from the surface of Mars. The strong degree of crystal alignment exhibited in the emissivity spectra of Mars suggests that these oriented hematite crystals most likely occur as bedrock of aligned specular hematite grains (possibly schistose in texture) or as a secondary coating on bedrock, rather than as discrete particles. We are investigating the nature of this vast hematite deposit in order to understand better the geologic setting and infer past conditions and geological evolution on Mars.

Morris, Richard V.↗

Evidence for a Hematite Ore Body on Mars

The Mars Global Surveyor (MGS) spacecraft was launched from Cape Kennedy in November 1996. MGS was put into orbit around Mars in September of 1997 and has since been sending back data from a suite of instruments, including the Thermal Emission Spectrometer (TES). The TES instrument is an interferometric spectrometer designed to map the surface mineralogy of Mars by measuring the midinfrared emitted radiation over the spectral region of approximately 1600 to 200 per centimeter (appjroximately 6 to 50 microns). This mineralogically sensitive technique utilizes the characteristic intra- and inter-molecular vibrations of minerals that are manifested in the midinfrared spectra. These spectral "fingerprints" are unique because they are dependent upon chemical composition, crystal structure, crystal orientation, and other factors. Midinfrared spectral data received from the MGS-TES instrument have indicated the presence of a large deposit of hematite (alpha-Fe2O3) in Sinus Meridiani, Mars. This hematite ore body, that is accompanied by basalt, is areally extensive, encompassing and area approximately 350 by 500 km. To better understand the geologic context of this large deposit, a detailed laboratory spectroscopic investigation was conducted using more than 20 hematite samples so that their spectra could be compared to the martian spectra. The samples included red and gray polycrystaline hand samples, gray single-crystal hand samples, and red and gray fine- and coarse-grained particulates. The laboratory analyses provided thermal emissivity spectra that, when compared to the hematite emissivity spectra from Mars, suggest the Sinus Meridiani hematite is possibly an exposure of oriented hematite grains. These grains are likely coarser that 10 microns (and may be much larger) and gray in color The characteristic of oriented grains is suggested by the apparent crystal axis-dependence of the energy emitted from the surface of Mars. The strong degree of crystal alignment exhibited in the emissivity spectra of Mars suggests that these oriented hematite crystals most likely occur as bedrock of aligned specular hematite grains (possibly schistose in texture) or as a secondary coating on bedrock, rather than as discrete particles. We are investigating the nature of this vast hematite deposit in order to understand better the geologic setting and infer past conditions and geological evolution on Mars.

Lane, M. D.↗

Description of Data Archiving Associated With the NASA Goddard Grant NAGS-9590

Data restoration and archiving activities for this project have resulted in the restoration of 100% of the original Mariner 9 raw data set as well as many of the secondary analysis data sets. These data sets have been submitted to the Planetary Data System (PDS) Atmospheric Node, along with their PDS labels and descriptive metadata. In addition, a useful visualization and analysis tool has also been developed which allows the user to compare these Mariner 1971 Ultraviolet spectral data with several choices of related data sets: Mariner 9 images, USGS geologic data, MGS MOLA topography, Viking images (Viking MDIM) and thermal inertia data (MGS TES).

Simmons, K. E.↗

Optical spectra and the mass of SMC X-1

Photographic spectral data are presented for Sanduleak 160, an SMC B-type supergiant with which the strong binary X-ray source SMC X-1 is identified. These data show several important features: (1) Emission is conspicuously present at 4686 A at phases 0.1-0.3 and 0.7-0.85 (where phase 0.0 denotes X-ray eclipse) and undetectable near phase 0.5; (2) the emission has a large amplitude in velocity approximately out of phase with the expected motion of the primary star; (3) the absorption spectrum does not show any detectable change in spectral type throughout the orbit. The basic parameters of the system are studied on the basis of the new data, and a mass of near 2 solar masses is computed for the X-ray object. The data also furnish a number of constraints for models of the system.

Osmer, P. S.↗

Bayesian inference for plasmonic nanometrology

Here, we introduce a Bayesian method for the characterization of plasmonic nanoparticles, which is applicable to both near- and far-field problems. Designed to combine data generated from any photon-plasmon interaction experiment with physically motivated theoretical models, our approach leverages state-of-the-art Markov chain Monte Carlo sampling techniques and returns parameter estimates on nanometric scales. Simulated spectral data sets, describing resonant scattering of photons from ellipsoidal and toroidal nanoparticles, are explored as concrete examples of our approach, with the resulting Bayesian estimates showing excellent agreement with the ground truth, even under conditions of high statistical noise. By incorporating Bayes factors into the method as well, we reveal how model selection can determine which one of competing geometric shapes better explains the observed data. Our comprehensive nanometrology procedure can be tailored to a variety of light-particle interaction models, and its reliance on Bayesian inference furnishes automatic uncertainty quantification. In addition to applicability to a host of plasmonic configurations such as nanoparticle dimers, trimers, and array studies, it is proposed that the presented analysis can be extended to the quantum regime, where nonclassical photon statistics may provide additional insight for inference of scatterer properties.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗