Charge ratio of cosmic-ray electrons
Excess of positrons to electrons from high energy cosmic ray secondaries
POSITRON↗
SEARCH · Engineering Papers
Results for “secondary electrons”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Time-resolved Auger–Meitner spectroscopy of the photodissociation dynamics of CS 2
The photodissociation dynamics of UV excited CS 2 are investigated using time-resolved Auger–Meitner (AM) spectroscopy. AM decay is initiated by inner-shell ionisation with a femtosecond duration x-ray (179.9 eV) probe generated by the FERMI free electron laser. The time-delayed x-ray probe removes an electron from the S(2p) orbital leading to secondary emission of a high energy electron through AM decay. We monitor the electron kinetic energy of the AM emission as a function of pump-probe delay and observe time-dependent changes in the spectrum that correlate with the formation of bound, excited-state CS 2 molecules at early times, and CS + S fragments on the picosecond timescale. The results are analysed based on a simplified kinetic scheme that provides a time constant for dissociation of approximately 1.2 ps, in agreement with previous time-resolved x-ray photoelectron spectroscopy measurements (Gabalski, et al 2023 J. Phys. Chem. Lett. 14 7126–7133).
Auger spectroscopy↗
Rare earth metals from secondary sources: Review of potential supply from waste and byproducts
Current concerns about lack of diversity in supply of critical metals have spurred research into utilizing domestic sources, particularly from waste streams. Sustainability strategies like urban mining, industrial symbiosis, and the circular economy suggest avenues to realize new supplies of critical metals. In this work we explore the resource and economic potential for extracting rare earth elements (REEs) from industry byproducts (e.g. coal combustion products, red mud) and secondary sources (e.g. waste electronics and light bulbs). Combining materials flow analysis and characterization data, we find that while REE concentrations in waste and byproduct streams are mostly much lower than current REE ores, some secondary sources are richer than ores in high value REEs such as scandium. The quantities of REEs contained in secondary sources could meet current global demand even with low extraction yield rates. Phosphogypsum, coal ash and red mud from aluminum production stand out as promising candidates for recovery due to high concentrations of valuable REEs and sufficient quantities to potentially meet demand. Processes to extract REEs from secondary sources are under development, it is not clear yet which will be profitable at scale and which can be achieved at least environmental impact. This work provides high level guidance on the potential of secondary sources by characterizing quality (concentrations of different rare earths) and quantity (mass of rare earths in global scale wastes and byproducts). This significant first step helps clarify directions for policy and research and development investments.
42 ENGINEERING↗
Study plasma interactions in the auroral ionosphere
Analyzed data from rocket flight, 29.007UE is presented. In a discrete electron arc the measured upward moving electrons are well accounted for by secondaries produced in collisional scattering of the measured downcoming electrons. No collective mechanisms need to invoke. The low energy downcoming electrons are accounted for by thermal plasma accelerated through a potential drop of a few kV that specularly reflects upward-moving lower energy electrons. No low altitude collective effects need to invoke in the arc. Simultaneous measurements of electric field by double probes on 29.007 and the Chatanika Radar allow one to infer that there are upward drifting ions above the discrete electron arc, and there is a westward neutral wind in the discrete arc. Two rocket payloads were built to investigate plasma effects in the pulsating aurora.
Anderson, H. R.↗
Structure and magnetism in epitaxial Fe 1 + x VSb nanocomposite films
The combination of ferromagnetism and semiconducting behavior offers an avenue for realizing novel spintronics and spin-enhanced thermoelectrics. Here we demonstrate the synthesis of doped and nanocomposite half-Heusler Fe 1+x VSb films by molecular beam epitaxy. For dilute excess Fe (x < 0.1), we observe a decrease in the Hall electron concentration and no secondary phases in x-ray diffraction. Magnetotransport measurements suggest weak ferromagnetism that onsets at a temperature of T c ≈ 5 K. For higher Fe content (x > 0.1), ferromagnetic Fe nanostructures precipitate from the semiconducting FeVSb matrix. The Fe/FeVSb interfaces are epitaxial, as observed by transmission electron microscopy and x-ray diffraction. Further, magnetotransport measurements suggest proximity-induced magnetism in the FeVSb from the Fe/FeVSb interfaces, or superparamagnetically coupled Fe-rich clusters, at an onset temperature of T c ≈ 20 K.
36 MATERIALS SCIENCE↗
Chemical and structural characterization of particulate fallout isolated from air-filters
We report particulate nuclear fallout is the radioactive byproduct of a nuclear event formed by the mixture of proximate environmental materials with vaporized bomb debris. The fallout debris can be transported into the atmosphere during cloud rise, raining out locally and dispersing globally constituting a radiation hazard and contributing to the distribution of anthropogenic radionuclides in the environment. Questions remain on how entrainment of environmental material in the fireball affects fallout formation processes and radionuclide incorporation and distribution during cooling. To inform the characterization of fallout including the development of fallout size distributions and how radionuclides are incorporated into fallout debris where entrainment plays a role, we analyzed an archived historic US air-filter collected by aircraft in the aftermath of ground interacting nuclear tests. Particulate fallout collected on the filter was isolated and analyzed using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and NanoSIMS (Secondary Ion Mass Spectrometry) to determine chemistry, structure, morphology, and size of the particles. Results demonstrate that the particles isolated from the filter have spherical shape, display complex internal structures, and are mainly composed of Fe and Si oxides. In these spherical particles, Pu is preferentially associated with Fe-rich composition. The characterization of fallout particulate samples can provide information on nucleation and particle growth from the vapor phase to improve modeling and simulation of fallout hazards.
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
Suppressor plate eliminates undesired arcing during electron beam welding
Suppressor grid eliminates undesired arcing during electron beam welding in one of two ways. A grid at ground potential collects secondary emission of ions and electrons produced by the beam as it strikes the workpiece, or a negatively energized grid repels the plasma arc back to the workpiece. This eliminates ground screens used to cover view ports.
Hanchey, K. K.↗
Magnetic Field Amplification by a Nonlinear Electron Streaming Instability
Magnetic field amplification by relativistic streaming plasma instabilities is central to a wide variety of high-energy astrophysical environments as well as to laboratory scenarios associated with intense lasers and electron beams. We report on a new secondary nonlinear instability which arises for relativistic dilute electron beams after the saturation of the linear Weibel instability. This instability grows due to the transverse magnetic pressure associated with the beam current filaments, which cannot be quickly neutralized due to the inertia of background ions. We show that it can amplify the magnetic field strength and spatial scale by orders of magnitude, leading to large-scale plasma cavities with strong magnetic field and to very efficient conversion of the beam kinetic energy into magnetic energy. The instability growth rate, saturation level, and scale length are derived analytically and shown to be in good agreement with fully-kinetic simulations.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Toward Tunable Magnetic Dirac Semimetals: Mn Doping of Cd 3 As 2
Magnetic impurities provide a route toward increasing functionality in electronic materials, often enabling new device concepts and architectures. In the case of topological semimetals, dilute magnetic doping presents a particularly attractive approach for inducing a Dirac to Weyl phase change via time reversal symmetry breaking. However, efforts to realize changes in the electronic structure have been limited by challenges in incorporating magnetic impurities into crystals with sufficiently high electron mobilities to detect them via transport or spectroscopic techniques. Here, we demonstrate incorporation of Mn into Cd 3 As 2 Dirac semimetal thin films grown by molecular beam epitaxy (MBE). Using As-rich growth conditions and [001] oriented thin films, Mn compositions of >10% are achieved. Films contain uniform distributions of Mn with no evidence of secondary phases and exhibit electron mobilities greater than 10 000–30 000 cm 2 /Vs up to 5% Mn. An evolution in the magnetization behavior along with the emergence of a second quantum oscillation frequency at low Mn concentrations provide preliminary evidence of Mn-induced changes in the electronic structure that are consistent with a Weyl phase. This work demonstrates the potential of magnetically doping topological semimetal thin films and a pathway for synthesizing them.
36 MATERIALS SCIENCE↗
Organometallic chemical vapor deposition and characterization of ZnGeP2/GaP multiple heterostructures on GaP substrates
The growth of ZnGeP2/GaP double and multiple heterostructures on GaP substrates by organometallic chemical vapor deposition is reported. These epitaxial films were deposited at a temperature of 580 C using dimethylzinc, trimethylgallium, germane, and phosphine as source gases. With appropriate deposition conditions, mirror smooth epitaxial GaP/ZnGeP2 multiple heterostructures were obtained on (001) GaP substrates. Transmission electron microscopy (TEM) and secondary ion mass spectroscopy (SIMS) studies of the films showed that the interfaces are sharp and smooth. Etching study of the films showed dislocation density on the order of 5x10(exp 4)cm(sup -2). The growth rates of the GaP layers depend linearly on the flow rates of trimethylgallium. While the GaP layers crystallize in zinc-blende structure, the ZnGeP2 layers crystallize in the chalcopyrite structure as determined by (010) electron diffraction pattern. This is the first time that multiple heterostructures combining these two crystal structures were made.
Xing, G. C.↗
Measurement of G-phase volume fraction and number density in duplex stainless steels using transmission electron microscopy
Duplex stainless steels (DSS) have a high toughness and strength due the presence of both austenitic and ferritic phases. These alloys have had limited use in power production applications due to thermal embrittlement caused by spinodal decomposition and development of G-phase precipitates in the ferrite. Lean grade DSS alloys (e.g., 2101, 2003) may offer improved thermal stability due to the reduction of Cr- and Ni-equivalent elements when compared to standard grade compositions (e.g., 2205, 2209). The abundance of the G-phase was measured in five duplex stainless steels, three wrought alloys (2101, 2003, 2205) and their matching filler metals (2101-w, 2209-w), after aging at 427 °C for 1000 h and 10,000 h. The G-phase volume fraction, number density, size, and precipitate spacing were found using quantitative analysis of transmission electron microscopy dark field images and the composition of G-phase precipitates on other clusters were characterized with atom probe tomography (APT). In the welded alloys, the G-phase was found to develop rapidly, relative to the wrought material. A positive correlation was found between the nickel equivalent composition of the alloy and the G-phase volume fraction. The alloys 2205, 2209, and 2101-w, which are higher in Cr and Ni, all showed significant G-phase precipitation, further strengthening the hypothesis that lean grade DSS alloys are more thermally stable against precipitation in the ferrite. Electron diffraction showed a secondary phase present in the 2101 wrought alloy at 10,000 h, but it was not crystallographically consistent with the G-phase; APT showed the presence of nanoclusters rich in both nickel and copper for this alloy. In conclusion, no secondary phases or clusters were found in 2003 after 10,000 h of aging, so it may be a candidate alloy for applications that require long-life times at high operating temperatures.
36 MATERIALS SCIENCE↗
Crystal Growth and Phase Formation of High-Entropy Rare-Earth Aluminum Perovskites
In this work, we demonstrate for the first time the crystal growth of high-entropy rare-earth (RE) aluminum perovskites (REAlO 3 ) using the micro-pulling-down method to inform future exploration of functional crystals. To determine how composition affects phase formation, we formulate equiatomic compositions containing five REs from the following list: Lu, Yb, Tm, Er, Y, Ho, Dy, Tb, Gd, Eu, Sm, Nd, Pr, Ce, La. To test whether combinations of REs with similar ionic radii may favor a single phase, compositions containing REs with consecutive or nonconsecutive ionic radius values were formulated. Powder and single-crystal X-ray diffraction indicate that crystals containing only REs with similar ionic radii that form orthorhombic single-RE REAlO 3 are a single phase. Crystals containing REs with dissimilar ionic radii or mixtures of REs that form orthorhombic, rhombohedral, and tetragonal single-RE REAlO 3 are a mixture of phases. The elemental distribution in single-phase crystals analyzed via electron probe microanalysis confirms no evidence of preferential incorporation of any of the constituent REs. The distribution and composition of secondary phases were analyzed via scanning electron microscopy and energy dispersive spectroscopy; secondary phases were seen as a small region in the center of the crystals with branching features closer to the outer surface.
36 MATERIALS SCIENCE↗
Measurements on the shuttle of the LET spectra of galactic cosmic radiation and comparison with the radiation transport model
A new class of tissue-equivalent proportional counters has been flown on two space shuttle flights. These detectors and their associated electronics cover a lineal energy range from 0.4 to 1250 keV/microns with a multichannel analyzer resolution of 0.1 keV/microns from 0.4 to 20 keV/microns and 5 keV/microns from 20 to 1250 keV/microns. These detectors provide the most complete dynamic range and highest resolution of any technique currently in use. On one mission, one detector was mounted in the Shuttle payload bay and another older model in the mid-deck, thus providing information on the depth dependence of the lineal energy spectrum. A detailed comparison of the observed lineal energy and calculated LET spectra for galactic cosmic radiation shows that, although the radiation transport models provide a rather accurate description of the dose (+/- 15%) and equivalent dose (+/- 15%), the calculations significantly underestimate the frequency of events below about 100 keV/microns. This difference cannot be explained by the inclusion of the contribution of splash protons. The contribution of the secondary pions, kaons and electrons produced in the Shuttle shielding, if included in the radiation transport model, may explain these differences. There are also significant differences between the model predictions and observations above 140 keV/microns, particularly for 28.5 degrees inclination orbit.
NASA Discipline Radiation Health↗
Electron Calorimeter Experiment
Boron loaded scintillators are suitable for measuring secondary neutrons produced by high-energy particles: protons & electrons Neutron flux can be used to discriminate hadron and electro-magnetic particles Combined effectiveness of all e/p discriminators techniques employedTBD Only moderate improvement in detection efficiency for B-10 concentrations >few% in thick moderators Bottom scintillator might serve as cascade penetration counter (TBC)
Adams, James H.↗
Exploring the relationship between deposition method, microstructure, and performance of Nb/Si-based superconducting coplanar waveguide resonators
Superconducting quantum circuits (SQC) are one of the most promising hardware platforms for quantum computing, yet their performance is currently limited by the presence of various structural defects inside the circuit's structure. Despite impressive progress in the past decade, a precise understanding of the origin of these defects from various fabrication processes and their impact on coherence is still lacking. Here, in this study, we performed a comprehensive investigation on the microstructure, superconductivity, and resonator quality factor of Nb films deposited by high-power impulse magnetron sputtering (HiPIMS) and direct current (DC) magnetron sputtering. A suite of characterization techniques, including electron microscopy with spectroscopy, secondary ion mass spectrometry, magneto-optical microscopy, and pump-probe reflectivity spectroscopy is used. We reveal that niobium (Nb) resonators fabricated using HiPIMS exhibit a smaller average grain size, thicker surface oxide with larger thickness variations (rougher surface), and a thicker amorphous Nb/Si interface layer compared to samples deposited by DC sputtering. We identified that the amorphous Nb oxides (mainly located at the Nb surface and along the grain boundaries) and Nb-Si amorphous layers (at the Nb/Si interface) are major and potential sources of two-level system (TLS), while off-stochiometric oxides and suboxides of Nb close to the surface, crystalline defects (i.e., dislocations at grain boundary, point defects introduced during deposition) are main contributors of non-TLS sources. Our findings clarify the relationship between different defects and coherence loss mechanisms, highlighting the importance of material microstructure control on performance optimization in SQC.
36 MATERIALS SCIENCE↗
Electron excitation of a Jovian Aurora
Because Jupiter possesses a magnetic field, auroral activity is very likely. The auroral emissions due to electron precipitation are estimated for a model atmosphere with and without helium. The incident primary electrons, which are characterized by representative spectra, are degraded in energy by applying the continuous slow down approximation. All secondaries, tertiaries, and higher generation electrons are assumed to be absorbed locally. A compilation of excitation, dissociation, and ionization cross section data for H, H2, and He are used to model all aspects of the energy deposition process. Volume emission rates are calculated from the total direct excitation rates, and appropriate corrections for cascading are applied. Helium emissions are relatively small because the majority of electrons are absorbed above the region of maximum He concentration.
Heaps, M. G.↗
Method for energy dither of a particle beam
A method for applying an energy dither to a charged particle beam in order to vary the wavelength of the charged particle beam. Bunches of charged particle beams are accelerated by cavities that are operated at a harmonic of the bunch repetition rate. One or more secondary radiofrequency accelerator cavities are added near the wiggler after the primary beam transport to apply a fluctuation between individual bunches with a pseudo-random distribution. The secondary radiofrequency accelerator cavities provide fine variations of the beam energy about a nominal operating point. Operating a free electron laser (FEL) with a 1% change in the electron beam energy via the secondary cavity will result in a 2% wavelength variation of the FEL output.
42 ENGINEERING↗
Analysis of furnace contamination on superconducting radio frequency niobium using secondary-ion mass spectrometry
Detection of surface contamination on niobium materials used in superconducting radio frequency (SRF) applications is difficult due to quantitative sensitivity and near-atomic depth resolution needed. Inspection of samples known to have experienced surface contamination was found to have inconsistent nitride coverage after high-temperature nitrogen gas exposure (“doping”). Here we compare contaminating species found on samples treated in several different vacuum furnaces, both “exposed” directly in the chamber and “protected” by containment shielding from evaporative sources with “furnace caps.” Typically, furnace caps are used to impede contamination from reaching the interior surface of cavities during the high-temperature vacuum bake that immediately precedes exposure to nitrogen gas. Although, to date, little is known about the effectiveness of these caps, SIMS results showed that they were effective in limiting contamination arising from the furnace environment. Inspection of sample surfaces by SEM showed a lack of nitrides present on contaminated specimens. TEM with energy dispersive spectroscopy performed on these samples revealed that a carbon-rich layer now existed, indicating that a relatively high contaminant load prevents the nucleation and growth of surface nitrides, while thus inhibiting interstitial nitrogen uptake. Except in extreme cases, subsequent removal of the top several micrometers of the surface via electropolishing appears to effectively eliminate any strong influence on the subsequent SRF cavity performance. With the absence of furnace cleaning, carbon contamination was found to be nearly 10× higher for protected nitrogen-doped and electropolished samples, with minimal metallic contamination detected for both processes. SIMS analysis was also performed to compare the cleanliness of samples fully prepared by such nitrogen “doping” with those prepared by a related process, involving the dissolution of niobium surface oxide and diffusion of oxygen into the surface. This oxygen doping or alloying process offers attractive advantages.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗