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At least 631 records · Page 35

Optical Evaluation of Digital Micromirror Devices (DMDs) with UV-Grade Fused Silica, Sapphire, and Magnesium Fluoride Windows and Longterm Reflectance of Bare Devices

Digital micromirror devices (DMDs) are commercial micro-electromechanical systems, consisting of millions of mirrors which can be individually addressed and tilted into one of two states (+/-12deg). These devices were developed to create binary patterns in video projectors, in the visible range. Commercially available DMDs are hermetically sealed and extremely reliable. Recently, DMDs have been identified as an alternative to microshutter arrays for space-based multi-object spectrometers (MOS). Specifically, the MOS at the heart of the proposed Galactic Evolution Spectroscopic Explorer (GESE) uses the DMD as a reprogrammable slit mask. Unfortunately, the protective borosilicate windows limit the use of DMDs in the UV and IR regimes, where the glass has insufficient throughput. In this work, we present our efforts to replace standard DMD windows with custom windows made from UV-grade fused silica, low-absorption optical sapphire (LAOS) and magnesium fluoride (MgF2). We present transmission measurements of the antireflection coated windows and the reflectance of bare (window removed) DMDs. Furthermore, we investigated the long-term stability of the DMD reflectance and experiments for coating DMD active area with a layer of pure aluminum (Al) to boost reflectance performance in the UV spectral range (200−400 nm).

reflectance↗

A 30+ Year AVHRR Land Surface Reflectance Climate Data Record and Its Application to Wheat Yield Monitoring

The Advanced Very High Resolution Radiometer (AVHRR) sensor provides a unique global remote sensing dataset that ranges from the 1980's to the present. Over the years, several efforts have been made on the calibration of the different instruments to establish a consistent land surface reflectance time-series and to augment the AVHRR data record with data from other sensors such as the Moderate Resolution Imaging Spectroradiometer (MODIS). In this paper, we present a summary of all the corrections applied to the AVHRR Surface Reflectance and NDVI Version 4 Product, developed in the framework of the National Oceanic and Atmospheric Administration (NOAA) Climate Data Record (CDR) program. These corrections result from assessment of the geo-location, improvement of the cloud masking and calibration monitoring. Additionally, we evaluate the performance of the surface reflectance over the AERONET sites by a cross-comparison with MODIS, which is an already validated product, and evaluation of a downstream Leaf Area Index (LAI) product. We demonstrate the utility of this long time-series by estimating the winter wheat yield over the USA. The methods developed by [1] and [2] are applied to both the MODIS and AVHRR data. Comparison of the results from both sensors during the MODIS-era shows the consistency of the dataset with similar errors of 10%. When applying the methods to AVHRR historical data from the 1980's, the results have errors equivalent to those derived from MODIS.

AVHRR↗

Synoptic Ozone, Cloud Reflectivity, and Erythemal Irradiance from Sunrise to Sunset for the Whole Earth as Viewed by the DSCOVR Spacecraft from the Earth-Sun Lagrange 1 Orbit

EPIC (Earth Polychromatic Imaging Camera) on board the DSCOVR (Deep Space Climate Observatory) spacecraft is the first earth science instrument located near the earth-sun gravitational plus centrifugal force balance point, Lagrange 1. EPIC measures earth-reflected radiances in 10 wavelength channels ranging from 317.5 to 779.5 nm. Of these channels, four are in the UV range 317.5, 325, 340, and 388 nm, which are used to retrieve O3, 388 nm scene reflectivity (LER: Lambert equivalent reflectivity), SO2, and aerosol properties. These new synoptic quantities are retrieved for the entire sunlit globe from sunrise to sunset multiple times per day as the earth rotates in EPIC's field of view. Retrieved ozone amounts agree with ground-based measurements and satellite data to within 3 %. The ozone amounts and LER are combined to derive the erythemal irradiance for the earth's entire sunlit surface at a nadir resolution of 1818 km2 using a computationally efficient approximation to a radiative transfer calculation of irradiance. The results show very high summertime values of the UV index (UVI) in the Andes and Himalayas (greater than 18), and high values of UVI near the Equator at equinox.

Cloud reflectivity↗

GEO-LEO Reflective Band Inter-Comparison with BRDF and Atmospheric Scattering Corrections

The inter-comparison of the reflective solar bands (RSB) between the instruments onboard a geostationary orbit satellite and a low Earth orbit satellite is very helpful in assessing their calibration consistency. Himawari-8 was launched 7 October 2014 and GOES-R was launched on 19 November 2016. Unlike previous GOES instruments, the Advanced Himawari Imager (AHI) on Himawari-8 and the Advanced Baseline Imager (ABI) on GOES-R have onboard calibrators for the RSB. Independent assessment of calibration is nonetheless important to enhance their product quality. MODIS (Moderate Resolution Imaging Spectroradiometer) and VIIRS (Visible Infrared Imaging Radiometer Suite) can provide good references for sensor calibration. In this work, the inter-comparison between AHI and VIIRS is performed over a pseudo-invariant target. The use of stable and uniform calibration sites provides comparison with accurate adjustment for band spectral difference, reduction of impact from pixel mismatching, and consistency of BRDF (Bidirectional Reflectance Distribution Function) and atmospheric correction. The site used is the Strzelecki Desert in Australia. Due to the difference in solar and view angles, two corrections must be applied in order to compare the measurements. The first is the atmospheric scattering correction applied to the top of atmosphere reflectance measurements. The second correction is applied to correct the BRDF effect. The atmospheric correction is performed using a vector version of the Second Simulation of a Satellite Signal in the Solar Spectrum (6SV) model and the BRDF correction is performed using a semi-empirical model. Our results show that AHI band 1 (0.47 microns) has a good agreement with VIIRS band M3 within 0.15 percent. AHI band 5 (1.61 microns) shows the largest difference (5.09 percent) with VIIRS band M10, while AHI band 5 shows the least difference (1.87 percent) in comparison with VIIRS band I3. The methods developed in this work can also be directly applied to assess GOES-16/ABI (Geostationary Operational Environment Satellite16 / Advanced Baseline Imager) calibration consistency, a topic we will address in the future.

The inter-comparison of the reflective solar bands↗

Uncertainty Analysis of the GeoNEX Top-of-Atmospheric Reflectance Products Generated from the Third-Generation Geostationary Satellite Sensors

The GeoNEX (Geostationary-NASA Earth eXchange) Level-1G products consist of top-of-atmosphere (TOA) bi-directional reflectance factor (BRF) and brightness temperature generated with data streams from the latest geostationary (GEO) sensors including GOES-16/17 ABI, Himawari-8/9 AHI, and GK-2A AMI on a global tiled common grid (60oN-60o and 180oW-180oE) in geographic coordinates. With their 16 spectral bands, 0.01o/0.02o nadir spatial resolution, and 10-minute temporal resolutions, these products provide exciting opportunity to monitor Earth surface processes. However, the unique Sun-Target-Satellite geometry of geostationary sensors demands special attention in analyzing/interpreting these datasets. In this study we present a systematic analysis on the relationship between the radiometric uncertainties of the GeoNEX TOA reflectance and the corresponding solar/satellite zenith angles. We show that the signal-to-noise ratio (SNR) of the BRF are positively proportional to the square roots of the cosine of solar illuminating zenith angles. That is, the BRF data are noisier earlier in the morning or later in the afternoon than in the mid of the day. The cosine of satellite viewing zenith angles do not directly influence the SNR of the TOA BRF. However, they positively regulate the relative importance of the surface component in the TOA BRF. This means that variations in surface reflectance are more difficult to detect for pixels with larger view zenith angles, even when the SNR of the TOA BRF is the same. We are developing metrics to specify such illumination-view geometry related uncertainties in the GeoNEX L1G TOA BRF products so that this key information can be easily accessed by the user community.

Geostationary satellite↗

Surface Polarized Reflectance Analysis For Aerosol Remote Sensing

We study the Earth surface polarized reflectance using data collected by a space-based lidar. Accurate modelling of the surface reflectance supports retrieval algorithm development for the current and future Earth Science missions. Strong polarization of the laser light from Cloud-Aerosol Transport System (CATS) instrument, operated in 2015-2017, and nighttime measurements yield higher signal-to-noise ratio for polarization compared to the previous analysis of reflected, initially unpolarized, solar light.

Earth surface polarized reflectance↗

Evaluation of the Surface Reflectance Long-Term Data Record from AVHRR over Multiple Land Surface Types

In this work, we evaluate the performance of the AVHRR surface reflectance LTDR V4 using Landsat-5 Thematic Mapper (TM5) Collection-1 surface reflectance data over 440 globally distributed sites, which give a representative set of land surface types and climate conditions. Surface reflectance anisotropy effects were normalized using the VJB method, and spectral response differences were accounted for with spectral band adjustment factors (SBAFs) computed as a function of the Normalized Difference Vegetation Index (NDVI) from a set of over 100,000 hyperspectral spectra from Hyperion. The performance of the AVHRR record is reported in terms of the accuracy, precision, and uncertainty, as compared to the specifications of the reference product. Results show that the AVHRR record performance is close to the 0.071ρ+0.0071 specification defined in the original TM5 product evaluation.

LTDR↗

Characterization of Bidirectional Transmissive and Reflective Properties of Black Silicon

This paper describes the initial work of characterizing the transmissive and reflective properties of black silicon diffusers. The diffusers were fabricated from a 100 mm diameter black silicon sample at NASA’s Goddard Space Flight Center (GSFC). The directional hemispherical reflectance from 250 nm to 2500 nm and BRDF/BTDF measurements at 632.8 nm, 1064 nm, and 1550 nm were measured using the GSFC Diffuser Calibration Laboratory’s (DCL) spectrophotometer and optical scatterometer. The diffusers exhibit a low level of specular reflection up to ~1100 nm with no evidence of retroscatter. The measurements are traceable to those made at the National Institute of Standards and Technology (NIST).

Bidirectional Reflectance Distribution Function↗

MODIS Reflective Solar Bands Calibration Improvements for Collection 7

Calibration of Terra and Aqua MODIS reflective solar bands (RSB) has evolved significantly since the launch of the first MODIS instrument on the Terra satellite more than 21 years ago. In NASA’s current Collection 6 and 6.1 Level 1B products (C6/C6.1 L1B), the RSB calibration algorithm continues to rely primarily on the onboard solar diffuser to calibrate the instrument gain. Lunar observations are used to track on-orbit changes in the response versus scan angle (RVS), and data from pseudo-invariant desert sites are used to apply adjustments to the gain and RVS calibration for select bands. The resulting reflectance products have in general shown a very stable performance. In recent years, some performance degradation has been noted for a few bands and algorithm changes have been tested to further improve the calibration accuracy for the upcoming Collection 7 (C7) L1B reprocess. In this paper, we present the MODIS RSB calibration improvements that will be included in C7. Major improvements include: applying polarization correction to the desert data before using it to generateRVS for Terra bands 8, 9, 3, and 10; using ocean scene data and an interband calibration approach to correct for long-term drift of Terra bands 11 and 12; applying an updated crosstalk correction to Terra SWIR bands over the entire mission; and using data from deep convective clouds in Terra SWIR band calibration, including the addition of time-dependent RVS for bands 5 and 26. All other minor calibration changes are also covered. Overall, the reflectance differences at nadir between C6.1 and C7 are within a few percent, though the differences increase in some cases at large scan angles. The Terra visible (3, 8-12) and SWIR bands (5-7, 26) have the most significant improvements. For all other Terra bands and all Aqua bands, the C7-C6.1 differences are mostly within 1%

MODIS↗

Assessment of MODIS and VIIRS Calibration Consistency for Reflective Solar Bands Using Vicarious Approaches

The Moderate-Resolution Imaging Spectroradiometer (MODIS) is the key instrument of the NASA’s Earth Observing System (EOS) Terra and Aqua missions, launched in December 1999 and May 2002, respectively. The Visible Infrared Imaging Radiometer Suite (VIIRS) expands the MODIS legacy, launched onboard the Suomi National Polar-orbiting Partnership (SNPP) satellite in October 2011 and NOAA20 satellite in November 2017, respectively. The MODIS and VIIRS sensors have a similar design with spectrally matched reflective solar spectral bands (RSB). Their on-board calibration components include a solar diffuser and a solar diffuser stability monitor for RSB, a V-grooved blackbody for the thermal emissive bands (TEB), and a space view as a background reference. This study evaluates the calibration consistency of the Terra and Aqua MODIS RSB based on the current Collection 6.1 L1B data products generated by the NASA MODAPS, which have used consistent calibration coefficient look up tables (LUT) for the entire data-record. In the case of SNPP and NOAA20 VIIRS, the latest L1B data produced by NASA Land SIPS are used. Several independent vicarious approaches are used to examine the stability and consistency of the at-sensor reflectance among MODIS and VIIRS instruments. Vicarious approaches include observations from simultaneous nadir overpasses (SNO), the Libya-4 desert and Dome C snow sites, as well as deep convective clouds (DCC). Impact of existing band spectral difference on the reflectance is corrected using hyperspectral observations provided by Europe Space Agency’s SCIAMACHY sensor. Results of this study provide comprehensive assessments of calibration performance, radiometric agreement and associated uncertainties.

MODIS↗

Determining the Primary Sources of Uncertainty in Retrieval of Marine Remote Sensing Reflectance From Satellite Ocean Color Sensors

Uncertainties in the retrieval of the remote sensing reflectance, R_rs, from Ocean Color (OC) satellite sensors have a strong impact on the performance of algorithms for the estimation of chlorophyll-a, mineral concentrations, and inherent optical properties (IOPs). The uncertainties are highest in the blue bands. The total radiance measured at the top of the atmosphere captures the instantaneous state of the atmosphere-ocean system: the in-water conditions, sky and Sun glint reflected from the wind-roughened ocean surface, as well as light scattered from molecules and aerosols in the atmosphere. Each of these components has associated uncertainties, and when combined with the additional uncertainties from the instrument noise and the atmospheric correction process, they contribute to the total uncertainty budget for the retrieved R_rs. We analyzed the contribution of each component uncertainties to the total R_rs uncertainties in SNPP-VIIRS level 2 products, taking advantage of the spectral differences between the components. We examined multiple scenes in the open ocean and coastal waters at spatial resolutions ranging from 2250 to 5250 m by comparing the retrieved R_rs to in situ measurements made at several AERONET-OC sites and at the MOBY site. It was shown that uncertainties associated with the molecular (Rayleigh) scattering play the most significant role, while the contributions of other components are usually smaller. Uncertainties in Rayleigh scattering are primarily attributed to the variability of Rayleigh optical thickness (ROT) with a standard deviation of approximately 1.5% of ROT, which can largely explain the frequency of negative R_rs retrievals as observed using the current standard atmospheric correction process employed by NASA. Variability of the sky light reflected from the ocean surface in some conditions also contributed to uncertainties in the blue; water variability proportional to R_rs had a very pronounced peak in the green at coastal sites.

remote sensing reflectance↗

Methods for Analytic Reflected Light Flux modelling in Observing Human Made Space Vehicles

During the Artemis I mission, the Orion Optical Navigation (OpNav) camera was used in a flight test to capture images of the Interim Cryogenic Propulsion Stage (ICPS) at long range. Novel methods in reflectance modelling were developed to estimate the reflected light flux as a function of range to inform the camera settings used to obtain the images. Postflight analysis was performed with the obtained images and telemetry. Techniques were developed using specialized star identification and attitude determination software to localize ICPS and positively identify it. The images were then used to verify the preflight reflected light flux as a function of range prediction and provide insight into the vehicle’s attitude dynamics.

Reflectance↗

Iridescence from Total Internal Reflection at 3D Microscale Interfaces: Mechanistic Insights and Spectral Analysis

An experimental investigation and the optical modeling of the structural coloration produced from total internal reflection interference within 3D microstructures are described. Ray-tracing simulations coupled with color visualization and spectral analysis techniques are used to model, examine, and rationalize the iridescence generated for a range of microgeometries, including hemicylinders and truncated hemispheres, under varying illumination conditions. An approach to deconstruct the observed iridescence and complex far-field spectral features into its elementary components and systematically link them to ray trajectories that emanate from the illuminated microstructures is demonstrated. The results are compared with experiments, wherein microstructures are fabricated with methods such as chemical etching, multiphoton lithography, and grayscale lithography. Microstructure arrays patterned on surfaces with varying orientation and size lead to unique color-traveling optical effects and highlight opportunities for how total internal reflection interference can be used to create customizable reflective iridescence. The findings herein provide a robust conceptual framework for rationalizing this multibounce interference mechanism and establish approaches for characterizing and tailoring the optical and iridescent properties of microstructured surfaces.

36 MATERIALS SCIENCE↗

The Page curve for reflected entropy

We study the reflected entropy $S_{R}$ in the West Coast Model, a toy model of black hole evaporation consisting of JT gravity coupled to end-of-the-world branes. We demonstrate the validity of the holographic duality relating it to the entanglement wedge cross section away from phase transitions. Further, we analyze the important non-perturbative effects that smooth out the discontinuity in the phase transition. By performing the gravitational path integral, we obtain the reflected entanglement spectrum analytically. The spectrum takes a simple form consisting of superselection sectors, which we interpret as a direct sum of geometries, a disconnected one and a connected one involving a closed universe. We find that area fluctuations of $\textit{O}$$\sqrt{G_N}$ spread out the $S_{R}$ phase transition in the canonical ensemble, analogous to the entanglement entropy phase transition. We also consider a Renyi generalization of the reflected entropy and show that the location of the phase transition varies as a function of the Renyi parameter.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Molecular dynamics simulations of reflection and sputtering behavior of boron under deuterium ion irradiation

Boronization is a commonly used method of wall conditioning in fusion reactors. The application of boron films to the plasma-facing materials results in enhanced plasma performance due to the reduction of intrinsic impurities. This is primarily driven by a reduction in oxygen content that is chemically trapped in the boron film. The reactive nature of these boron films also raises questions concerning interactions with hydrogen isotopes. In this work, boron-deuterium interactions were studied using molecular dynamics (MD). Reactive force field potentials were used to model the chemical interactions between B and D. An amorphous boron substrate was irradiated by D atoms at varying incident energies, 10 eV < E i < 150 eV and angles, 0° < α < 85°. The reflection probability was calculated and compared to results from the commonly-used binary collision approximation (BCA) method. This comparison found that the BCA underestimated the reflection probability at E i < 35 eV and α > 45 ∘ . The source of this discrepancy was found to be the surface binding energy model. The BCA calculation with an isotropic surface binding energy model was more closely aligned to the MD result. This, in combination with a correction function based on the MD results allows for corrections to the reflection probability of deuterium impinging on boron surfaces. The sputtering of the substrate material was also studied. While this study did not contain sufficient events to quantitatively describe the sputtering behavior, some qualitative results emerged: namely, chemical sputtering of B and D-containing molecules (BD, BD 2 , BD 3 ) at low ( < 20 eV) incident deuterium energies. This result suggests that chemical sputtering could be a significant factor in limiting boron coating lifetime when exposed to lower ion energies, such as those in detached plasmas. The results show that chemical interactions should be taken into account when modeling the interactions between D ions and B surfaces.

Boron↗

Validation of the two-region Rossi-alpha model for reflected assemblies

Nuclear criticality safety, nonproliferation and safeguards, emergency response, and stockpile stewardship utilize estimates of the k eff multiplication factor. The value of k eff cannot be directly measured, but it can be inferred from the prompt neutron period. One modality of measuring the prompt neutron period is the Rossi-alpha method, which is predicated on fitting a histogram of detection time differences due to the nonrandom temporal distribution of same-fission-chain neutrons. Recent works have developed the motivation and theory to expand traditional one-region point kinetic models resulting in one-exponential histogram fits to two-region models that result in two-exponential fits. This paper validates the new two-region model using organic scintillator measurements of copper-reflected weapons-grade plutonium (0:83 ≤ k eff ≤ 0:94) and high-density- polyethylene-reflected highly enriched uranium (0:73 ≤ k eff ≤ 0:95). Furthermore, the results show that more thermal systems have shorter prompt neutron periods in the core region due to increased induced-fission probabilities for moderated neutrons. Here, a new parameter introduced by the two- region model is also shown to be correlated to the amount of reflection, and may be used to infer assembly properties such as type and amount of reflector.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Reflections on the anomalous ANITA events: the Antarctic subsurface as a possible explanation

The Antarctic Impulsive Transient Antenna (ANITA) balloon experiment was designed to detect radio signals initiated by high-energy neutrinos and cosmic ray (CR) air showers. These signals are typically discriminated by the polarization and phase inversions of the radio signal. The reflected signal from CRs suffer phase inversion compared to a direct ‘tau neutrino’ event. In this paper, we study subsurface reflection, which can occur without phase inversion, in the context of the two anomalous up-going events reported by ANITA. It is found that subsurface layers and firn density inversions may plausibly account for the events, while ice fabric layers and wind ablation crusts could also play a role. This hypothesis can be tested with radar surveying of the Antarctic region in the vicinity of the anomalous ANITA events. Future experiments should not use phase inversion as a sole criterion to discriminate between down-going and up-going events, unless the subsurface reflection properties are well understood.

54 ENVIRONMENTAL SCIENCES↗

In Situ Attenuated Total Reflectance Infrared Spectroelectrochemistry (ATR-IR-SEC) for the Characterization of Molecular Redox Processes on Surface-Proximal Doped Silicon ATR Crystal Working Electrodes

In situ mid-infrared spectroscopy is a powerful technique for understanding the mechanism of CO 2 reduction (CO 2 R) catalysts because it enables the direct detection of catalytic intermediates and products. Moreover, spectroelectrochemistry (SEC), the coupling of spectroscopy with electrochemistry, allows spectroscopic changes to be correlated with applied potentials to reveal potential-dependent intermediates that are often relevant to photoelectrochemical reactions. Hybrid photoelectrodes, comprised of a narrow bandgap semiconductor, like silicon (Si), with a covalently-linked molecular catalyst, are a promising platform for sunlight-driven catalysis, but characterization of the catalytic mechanism(s) is challenging under photoelectrochemical conditions, particularly when the catalyst is present in monolayer or less concentrations. Here, we have developed a new strategy to use multiple-reflection attenuated total reflectance IR spectroscopy (ATR-IR) coupled with electrochemistry to characterize catalysts directly integrated with a semiconductor surface under applied potential. We show that by surface-proximal n-type or p-type doping of the top ~100-200 nm of the crystal surface, Si ATR crystals can be used simultaneously as the internal reflection element and semiconductor working electrode for ATR-IR-SEC measurements. The surface-proximal doping strategy yields a quasi-equipotential surface with excellent infrared transparency that would have been compromised by free carrier absorption if the crystal was uniformly doped. This approach permits the catalytically-active functionalized surface to be directly probed without modification and overcomes signal-to-noise limitations of other strategies that use separately deposited working electrodes on Si ATR crystals. Proof-of-concept ATR-IR-SEC spectra were collected during the reduction and oxidation of monolayers of Re- and Ru-based transition metal carbonyl complexes, respectively, verifying the viability of the technique to probe redox processes associated with CO 2 R catalysts on Si electrode surfaces with high sensitivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗