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At least 631 records · Page 35

Slope-aspect color shading for parametric surfaces

The invention is a method for generating an image of a parametric surface, such as the compass direction toward which each surface element of terrain faces, commonly called the slope-aspect azimuth of the surface element. The method maximizes color contrast to permit easy discrimination of the magnitude, ranges, intervals or classes of a surface parameter while making it easy for the user to visualize the form of the surface, such as a landscape. The four pole colors of the opponent process color theory are utilized to represent intervals or classes at 90 degree angles. The color perceived as having maximum measured luminance is selected to portray the color having an azimuth of an assumed light source and the color showing minimum measured luminance portrays the diametrically opposite azimuth. The 90 degree intermediate azimuths are portrayed by unique colors of intermediate measured luminance, such as red and green. Colors between these four pole colors are used which are perceived as mixtures or combinations of their bounding colors and are arranged progressively between their bounding colors to have perceived proportional mixtures of the bounding colors which are proportional to the interval's angular distance from its bounding colors.

Moellering, Harold J.↗

Filling-In of Broad Far-Red Solar Lines by Terrestrial Fluorescence and Atmospheric Raman Scattering as Detected by SCIAMACHY Satellite Measurements

Global mapping of terrestrial vegetation fluorescence from space has recently been accomplished with high spectral resolution measurements from the Japanese Greenhouse gases Observing SATellite (GOSAT). These data are of interest because they can potentially provide global information on the functional status of vegetation including light use efficiency and global primary productivity that can be used for global carbon cycle modeling. Quantifying the impact of fluorescence on the O2-A band is important as this band is used for cloud- and aerosol-characterization for other trace-gas retrievals including CO2. Here, we demonstrate that fluorescence information can be derived from space using potentially lower-cost hyperspectral instrumentation, i.e., more than an order of magnitude less spectral resolution than GOSAT, with a relatively simple algorithm. As a demonstration, we use the filling-in of one of the few wide and deep solar Fraunhofer lines in the red and far-red chlorophylla fluorescence bands, the calcium II line near 866 nm, to retrieve fluorescence with the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) satellite instrument. Although the signal from vegetation fluorescence is extremely weak at 866 nm, our results suggest that useful information may be obtained after adjustments are made to the observed spectra to correct for instrumental artifacts. We compare fluorescence from SCIAMACHY with that retrieved at 758 and 770 nm from similarly-corrected GOSAT data as well with the Enhanced Vegetation Index (EVI) from the MODerate-resolution Imaging Spectroradiometer (MODIS). We also show that filling-in occurs at 866 nm over barren areas, possibly originating from luminescent minerals in rock and soil.

Joiner, J.↗

Visible-Light-Initiated Free-Radical Polymerization by Homomolecular Triplet-Triplet Annihilation

Polymerization reactions initiated by ultraviolet light are ubiquitous in scores of industrial applications but would markedly benefit from visible-light activation to overcome stability, energy consumption, light penetration, and sample geometry limitations. The current work leverages visible-light-driven homomolecular triplet-triplet annihilation (TTA) in zinc(II) meso-tetraphenylporphyrin (ZnTPP) to initiate facile free-radical polymerization in trimethylolpropane triacrylate (TMPTA) and methyl acrylate (MA) monomers through ultrafast electron transfer quenching. Selective Q-band (S 1 ) excitation of ZnTPP in the green or yellow sensitizes TTA occurring between two 3 ZnTPP* energized chromophores, ultimately generating the highly reducing S 2 excited state on one ZnTPP molecule (E red = –2.13 V versus saturated calomel electrode, SCE). Subsequently, this S 2 state engages in electron transfer with TMPTA or MA, thereby initiating the radical polymerization process. Bimolecular electron transfer was confirmed through optically gated fluorescence upconversion. In conclusion, FT-IR and EPR spin-trapping experiments verified visible-light-initiated polymerization leading to the formation of well-defined macro- and microscopic objects.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Action painting under spectroscopic light: Excited-state exchange interactions behind the vibrant blue in Jackson Pollock’s Number 1A, 1948

Number 1A, 1948 by Jackson Pollock is a quintessential example of his action painting technique where ropes of color, drips of black, and pools of white coalesce into the layered dynamism that defines his style. While past work has identified the red and yellow pigments that form part of his core palette, the vibrant blue in the painting has remained unassigned. In this study resonance Raman spectroscopy is used to assign the blue in the painting as manganese blue. This assignment offers critical context for the conservation of his works. Importantly, assignment of this pigment enables spectroscopic investigation of the electronic structure origin of the pure hue of manganese blue and the chemical phenomena that produce its color. To probe these phenomena, resonance Raman data are coupled to magnetic circular dichroism spectroscopy and density functional theory calculations to assign and analyze the two electronic transitions that create the blue color. This study reveals these bands are split by excited-state exchange interactions; the gap between them contains the reflected light that gives manganese blue its appearance. This sheds light on distinct advantages of molecular inorganic pigments: their ability to leverage ligand field effects in charge transfer states to create multiple intense visible absorption features and the ability to fine-tune pigment color through host lattice electrostatics.

DFT↗

Exploring Plasmonic Photocatalysis via Single-Molecule Reaction Imaging

Plasmonic photocatalysis has emerged as a new frontier in heterogeneous catalysis due to its promise in harvesting light to drive reactions. Yet many mechanistic aspects remain to be unambiguously defined. Using single-molecule fluorescence imaging, Li et al. studied a fluorogenic and plasmon-enhanced reaction, amplex red oxidation, on single Au nanorods at subturnover resolution and under operando conditions. Both the rate-determining step and its activation energy were identified from the multiple elemental reactions. Here, the results provide insights into the mechanism of plasmonic photocatalysis that may help the rational design of heterogeneous catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hydroporphyrin-Doped Near-Infrared-Emitting Polymer Dots for Cellular Fluorescence Imaging

We report Near-infrared (NIR) fluorescent semiconductor polymer dots (Pdots) have shown great potential for fluorescence imaging due to their exceptional chemical and photophysical properties. This paper describes the synthesis of NIR emitting Pdots with great control and tunability of emission peak wavelength. The Pdots were prepared by doping poly [(9,9-dioctylfluorenyl-2,7-diyl)-altco-(1,4-benzo-(2,1’,3)-thiadiazole)] (PFBT), a semiconducting polymer commonly used as a host polymer in luminescent Pdots, with a series of chlorins and bacteriochlorins with varying functional groups. Chlorins and bacteriochlorins are ideal dopants due to their high hydrophobicity, which precludes their use as molecular probes in aqueous biological media but on the other hand prevents their leakage when doped into Pdots. Additionally, chlorins and bacteriochlorins have narrow deep-red to NIR emission bands and the wide array of synthetic modifications available for modifying their molecular structure enables tuning their emission predictably and systematically. Transmission electron microscopy (TEM) and dynamic light scattering (DLS) measurements show the chlorin and bacteriochlorin-doped Pdots to be nearly spherical with an average diameter of 46±12 nm. Efficient energy transfer between PFBT and the doped chlorins or bacteriochlorins decreases the PFBT donor emission to near baseline level and increases the emission of the doped dyes that serve as acceptors. The chlorin and bacteriochlorindoped Pdots show narrow emission bands ranging from 640 nm to 820 nm depending on the doped dye. The paper demonstrates the utility of the systematic chlorin and bacteriochlorin synthesis approach by preparing Pdots of varying emission peak wavelength, utilizing them to visualize multiple targets using wide field fluorescence microscopy, binding them to secondary antibodies, and determining the binding of secondary antibody-conjugated Pdots to primary antibody-labeled receptors in plant cells. Additionally, the chlorin and bacteriochlorin doped Pdots show a blinking behavior that could enable their use in super resolution imaging methods like STORM.

13C-NMR↗

Mars - Topographic control of clouds, 1907-1973

Mariner 9 high-resolution photos and topographic information were used to make a topographic analysis of 'blue' and 'red' cloud positions reported over a 66-year period. A sample of 77 'blue' cloud sites lay preferentially at the highest Martian elevations; 60% centered precisely on the seven major volcanic mountain peaks (unknown when the clouds were observed); another 16% lay on substantial slopes or contacts between cratered terrain and lower plains. The median altitude of blue cloud sites was 2.1 km above the global topographic median. These results agree with other evidence that most earth-detected blue clouds are orographic uplift clouds, composed of condensates. Over half of 131 sporadic yelowish or red clouds were associated with blue clouds or volcanoes, and thus probably did not represent dust storm phenomena. Of 88 'possible dust clouds', about two-thirds occur at borders between light and dark areas, in the light regions. These sites may have thin veneers of dust, and current depositional or denudational activity. Median altitude of 'possible dust cloud' sites was 0.5 km below the global topographic median.

Hartmann, W. K.↗

Three-color CCD photometry of the distant cluster of galaxies Cl 0024 + 1654

Photometry of 265 galaxies in rich cluster Cl 0024 + 1654 (z = 0.39), based on CCD imaging in three filters, is presented. The luminosity of this system ranks it among the richest known clusters, and it has a blue mass-to-light ratio of about 210. The color-magnitude diagram has a prominent E/S0 sequence. There are essentially no blue cluster members brighter than r equals about 19.3, and only very red galaxies inhabit the central 30 arcsec of the cluster. The blue cluster members have sizes and surface brightnesses similar to spiral galaxies in nearby clusters.

Schneider, D. P.↗

Deimos: A featureless asteroid-like spectrum

High quality CCD spectra were obtained of Deimos from 0.5 to 1.0 micron at a spectral resolution of 15A at the time of the 1988 Mars opposition. The data acquisition and reduction methods allowed the quantitative prevention of scattered light from Mars contaminating the spectra. Solar analog stars BS560, BS2007, and BS8931 were observed the same night to allow removal of telluric absorptions. The ratio spectrum of Deimos has a red slope, increasing in reflectance by a factor of approx. 50 pct. over the one octave wavelength interval observed. Other than this slope, the spectrum is remarkably featureless. The absence of absorption bands in the spectrum of Deimos is in marked contrast with the spectra of Martian surface materials. No trace of the Fe(2+) charge transfer absorption band around 1 micron is observed, which rules out the presence of significant quantities of minerals such as the pyroxenes or olivine at the surface of Deimos. The featureless red spectrum of Deimos appears to be consistent with a surface composition of fine grained carbonaceous chondrite type material. An analysis is presented of the spectrum of Deimos which makes use of the Hapke scattering surface model.

Grundy, W. M.↗

Earthshine as an Illumination Source at the Moon

Earthshine is the dominant source of natural illumination on the surface of the Moon during lunar night, and at some locations within permanently shadowed regions (PSRs) near the poles that never receive direct sunlight. As such, earthshine has the potential to enable the scientific investigation and exploration of conditions in areas of the Moon that are either temporarily or permanently hidden from the Sun. Earthshine has also been used to refer to Earthlight reflected from the lunar surface, but in this study we use it to refer specifically to Earthlight incident at the Moon. Under certain circumstances, the heat flux from earthshine could also influence the transport and cold-trapping of volatiles present in the very coldest areas within PSRs. In this study, Earth's spectral irradiance, as it would appear at the Moon in the solar reflectance band (0.3–3.0 µm) and at thermal emission wavelengths (3–50 µm), is examined with a suite of model image cubes and whole-disk spectra created using the Virtual Planetary Laboratory (VPL) three-dimensional (latitude, longitude and altitude) modeling capability. At the Moon, the broadband, hemispherical irradiance from Earth at full-phase is approximately 0.15 W m−2 with comparable contributions from solar reflectance and thermal emission; for context, this about 0.01% that of solar irradiance and has an equivalent temperature of around 40 K. Over the simulated timeframe, spanning two lunations, Earth's thermal irradiance shows very little net change (less than a few mW m−2 resulting from cloud variability and the south-to-north motion of the sub-observer latitude on Earth). In the solar band, Earth's diurnally averaged light curve at phase angles g ≤ 60° is well-fit using a Henyey–Greenstein integral phase function. At wavelengths longward of about 0.7 µm, near the well-known vegetation “red edge”, Earth's reflected solar radiance shows significant diurnal modulation as a result of the broad maximum in projected landmass at terrestrial longitudes between 60°W and 0°, as well as from the distribution of clouds. A simple formulation with adjustable coefficients is presented, condensed from the VPL model grid, for estimating Earth's hemispherical irradiance at the Moon as a function of wavelength, phase angle and sub-observer coordinates (terrestrial latitude and longitude). Uncertainties in any one prediction are estimated to be 10–12% at 0.3 µm, rising to >25% near 2.5 µm as a result of the increasing relative brightness and unpredictable influence of clouds. Although coefficient values are derived from a suite of spring equinox models, the approximation appears to be valid for all seasons, to within the stated uncertainties. It is demonstrated that earthshine is sufficiently bright to serve as a natural illumination source for optical measurements on a robotic lander/rover, allowing the identification of water ice mixed with regolith at the percent-level of fractional area.

Surface↗

Searching for quasar candidates with periodic variations from the Zwicky Transient Facility: results and implications

ABSTRACT We conduct a systematic search for quasars with periodic variations from the archival photometric data of the Zwicky Transient Facility by cross-matching with the quasar catalogues of the Sloan Digital Sky Survey and Véron-Cetty and Véron. We first select out 184 primitive periodic candidates using the generalized Lomb–Scargle periodogram and autocorrelation function and then estimate their statistical significance of periodicity based on two red-noise models, i.e. damped random walk (DRW) and single power-law (SPL) models. As such, we finally identify 106 (DRW) and 86 (SPL) candidates with the most significant periodic variations out of 143 700 quasars. We further compare DRW and SPL models using Bayes factors, which indicate a relative preference of the SPL model for our primitive sample. We thus adopt the candidates identified with SPL as the final sample and summarize its basic properties. We extend the light curves of the selected candidates by supplying other archival survey data to verify their periodicity. However, only three candidates (with 6–8 cycles of periods) meet the selection criteria. This result clearly implies that, instead of being strictly periodic, the variability must be quasi-periodic or caused by stochastic red-noise. This exerts a challenge to the existing search approaches and calls for developing new effective methods.

Chen, Yong-Jie (ORCID:0000000342807673)↗

Phytochrome-mediated responses: Implications for controlled environment research facilities

Light is undoubtedly the most important environmental variable for plant growth and development; plants not only use radiant energy in photosynthesis, they also respond to the quantity, quality, direction and timing of incident radiation through photomorphogenic response that can have huge effects on the rate of growth and the pattern of development. It is surprising, therefore, that the manufacturers and suppliers of controlled environment facilities have been singularly uninventive in the design of the lighting assemblies they provide. The consumer has one choice only - a lighting assembly that provides irradiance levels usually only a fraction of sunlight, and a control system that is limited to regulating the timing of the on-off switch. The reasons for these limitations are partly technological, but in the main they result from ignorance on the part of both the consumer and the manufacturer. A specific and powerful example of this ignorance relates to the importance of the so-called far-red wavelengths (FR = 700-800 nm). Because the human eye can hardly detect wavelengths above 700 nm, and photosynthesis also cuts off at about 700 nm, the majority of plant and crop physiologists are still almost completely unaware that FR radiation can have massive effects on growth rate and development. In consequence, most growth cabinets have light sources based on fluorescent tubes, and provide very little FR apart from that emitted by a token number of small incandescent bulbs. Larger growth facilities often use broader spectrum light sources, but growth facilities that provide the capability to vary the FR incident upon the plants are about as abundant as seals in the Sahara. This article sets the background of the significance of FR radiation in the natural environment and its importance for plant growth and development in the hope that it might inform intelligently those concerned with improving the design of plant growth facilities.

Smith, Harry↗

Constraints on Solar Wind Plasma Properties Derived from Coordinated Coronal Observations

The goal of the proposed research is to increase the understanding of coronal plasma phenomena by making use of different observational approaches and combine the observations with the necessary theoretical considerations. We continued to study the formation of spectral lines in the corona/transition region under different non-equilibrium conditions. In addition to Mg and Ne we have also studied some cases involving Si ions and spectral lines. Due to the fact that the sun was at the maximum phase of the solar cycle, we spent some time on observing coronal mass ejections. Observations of the H I Lyman-alpha spectral line and the line pair 0 VI 1031.91 AA and 1037.61 AA were carried out with the UVCS instrument in the northern polar region of the sun at position angle 270 deg. The region was monitored at about 2 RS for about 5 hours on March 04, and for about 8 hours on March 05. During that time interval a major Coronal Mass Ejection developed in the northern hemisphere. Density, velocity and temperature maps of the ejected plasma have been obtained from the UVCS data. This event was also seen in the white light Large Angle and Spectrometric Coronagraph Experiment (LASCO) images, and its evolution at lower heights can be followed in Extreme Ultraviolet Imaging Telescope (EIT). The LASCO images are essential in providing the larger scale context for this event which is unique in the sense that it developed almost due North and had very little interactions with adjacent regions. The combination of UVCS velocity maps and LASCO images which were reduced using advanced image processing techniques, show very clearly how the mass ejection evolved from the solar surface to several solar radii, the twisting of the flux ropes, which are seen in UVCS as blue and red shifted velocities. First results were presented at the AGU Meeting in Boston. To study the quieter side of the coronal plasma, we carried out an experiment during the past eclipse, in June 01. We measured the corona in several iron spectral lines, and polarized white light. The results from that experiment look promising so far.

Esser, Ruth↗

Amplified Spontaneous Emission from Electron–Hole Quantum Droplets in Colloidal CdSe Nanoplatelets

Two-dimensional cadmium selenide nanoplatelets (NPLs) exhibit large absorption cross sections and homogeneously broadened band-edge transitions that offer utility in wide-ranging optoelectronic applications. Here, we examine the temperature-dependence of amplified spontaneous emission (ASE) in 4- and 5-monolayer thick NPLs and show that the threshold for close-packed (neat) films decreases with decreasing temperature by a factor of 2-10 relative to ambient temperature owing to extrinsic (trapping) and intrinsic (phonon-derived line width) factors. Interestingly, for pump intensities that exceed the ASE threshold, we find development of intense emission to lower energy in particular provided that the film temperature is <= 200 K. For NPLs diluted in an inert polymer, both biexcitonic ASE and low-energy emission are suppressed, suggesting that described neat-film observables rely upon high chromophore density and rapid, collective processes. Transient emission spectra reveal ultrafast red-shifting with the time of the lower energy emission. Taken together, these findings indicate a previously unreported process of amplified stimulated emission from polyexciton states that is consistent with quantum droplets and constitutes a form of exciton condensate. For studied samples, quantum droplets form provided that roughly 17 meV or less of thermal energy is available, which we hypothesize relates to polyexciton binding energy. Polyexciton ASE can produce pump-fluence-tunable red-shifted ASE even 120 meV lower in energy than biexciton ASE. Finally, our findings convey the importance of biexciton and polyexciton populations in nanoplatelets and show that quantum droplets can exhibit light amplification at significantly lower photon energies than biexcitonic ASE.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Diazirine-based photo-crosslinkers for defect free fabrication of solution processed organic light-emitting diodes

The fabrication of solution deposited OLEDs is fraught with difficulties, largely due to the interlayer mixing and surface erosion during sequential deposition of the layers. We demonstrate that these problems can be circumvented by using photopolymerizable diazirine-based cross-linker capable of converting soluble organic materials into highly cross-linked insoluble networks. 3-Trifluoromethyl(aryl)diazirines photolyze readily upon the 10–15 min exposure of 365 nm UV irradiation to generate carbenes, which react with polymers or small molecules via C–H bond insertion producing highly cross-linked materials. This photo-generated cross-linking does not require any catalyst, initiator or short-wavelength UV light and is performed at room temperature, releasing molecular nitrogen as the only byproduct. To show the cross-linked polymer layers do not display inter-layer mixing, we deposited red-emitting regioregular poly(3-hexylthiophene-2,5-diyl) (P3HT) over cross-linked (10% cross-linker) blue emitting dioctyl polyfluorene (PFO) layer. The overlaid layers showed clear and well-defined boundary with no interlayer mixing. The surface morphology of the solution deposited layers was investigated by AFM to show that the cross-linked layers exhibited significant decrease in surface roughness. This is also shown on the example of the hole transporting material 4,4'-bis[N-(1-naphthyl)-N-phenylamino]-biphenyl (NPB) which displayed roughness average to decrease from 6.4 nm to 1.0 nm. The effect of decreased surface roughness on the performance of phosphorescent OLEDs was investigated by fabricating devices with configuration of ITO/PEDOT:PSS/NPB:(0%/5%/10%) cross-linker/MCP:6% Ir(mppy) 3 /TPBI/CsF/Al. Furthermore, following the diazirine-mediated cross-linking, the OLEDs displayed a decrease in turn-on voltage from 3.8 V to 3.0 V along with a six-fold enhancement of external quantum efficiency (EQE max ) from 1.1% to 6.8% and maximum luminous efficiency increase from 3.8 cd A -1 to 22.9 cd A -1 . These results demonstrate that the simple diazirine mediated photo-cross-linking using mild conditions compatible with organic layers is a promising strategy for improving the performance of the solution-processed OLEDs.

36 MATERIALS SCIENCE↗

Luminescence petrography of lunar samples

Light-colored metaclastic rock fragments, mainly anorthositic breccias, are dominant in the lithic clasts of rock 14321 and constitute about 25% of the Apollo 14 soils. Concentration of anorthositic breccias is less in the Apollo 15 soils, but is higher in the Front samples. The Rille edge soils are rich in basalt fragments. The Apollo 15 soils are also rich in green glasses. True anorthosites in the Hadley region were found only at the St. George Crater site. Varying degrees of metamorphism were found in the anorthositic fragments, and luminescence zonations give independent evidence of metamorphism. Compositional zoning verifies the interpretation of luminescence. Rock 14321 gives evidence of modest annealing, but the light metaclastic fragments were metamorphosed before incorporation into the rock. Reaction rimming on plagioclase results in mosaicism and preferentially affects grains. The spectral analysis of luminescence in plagioclase shows that a red-infrared emission band is present in a small fraction of plagioclase grains. Samples from trench bottoms and from beneath a large boulder were compared with surface samples. Large variations in soil composition indicate marked layering in the Apollo 15 soils.

Source record↗

Colour dependence of zodiacal light models

Colour models of the zodiacal light in the ecliptic have been calculated for both dielectric and metallic particles in the sub-micron and micron size range. Two colour ratios were computed, a blue ratio and a red ratio. The models with a size distribution proportional to s to the -2.5 power ds (where s is the particle radius) generally show a colour close to the solar colour and almost independent of elongation. Especially in the blue colour ratio there is generally no significant dependence on the lower cutoff size (0.1-1 micron). The main feature of absorbing particles is a reddening at small elongations. The models for size distributions proportional to s to the -4 power ds show larger departures from solar colour and more variation with model parameters. Colour measurements, including red and near infra-red, therefore are useful to distinguish between flat and steep size spectra and to verify the presence of slightly absorbing particles.

Giese, R. H.↗

The variable stars of NGC 1866

A search has been conducted for new variables in the LMC cluster NGC 1866 using new multiepoch CCD photometry. Eight previously unknown Cepheid variables, most near the cluster core, are found. Of the new variables reported by Storm et al. (188), only six of 10 appear to be Cepheids and one of these is not a member. Periods and mean magnitudes and colors for sufficiently uncrowded variables are reported, as is one red giant variable of long period and one Cepheid which is a single-lined spectroscopic binary with a velocity semiamplitude greater than or equal to 10.5 km/s. The variation of light-curve amplitude with position in the instability strip is reported along with an apparently nonvariable star, which is a radial velocity member, in the strip. A true distance modulus of 18.57 + or - 0.01 mag is obtained for the cluster.

Welch, Douglas L.↗