Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “potential yield”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Novel nitrogen-based organosulfur electrodes for advanced intermediate temperature batteries

Advanced secondary batteries operating at intermediate temperatures (100 to 200 C) have attracted considerable interest due to their inherent advantages (reduced corrosion and safety risks) over higher temperature systems. Current work in this laboratory has involved research on a class of intermediate temperature Na/beta double prime- alumina/RSSR batteries conceptually similar to Na/S cells, but operating within a temperature range of 100 to 150 C, and having an organosulfur rather than inorganic sulfur positive electrode. The organosulfur electrodes are based on the reversible, two electron eduction of organodisulfides to the corresponding thiolate anions, RSSR + 2 electrons yield 2RS(-), where R is an organic moiety. Among the advantages of such a generic redox couple for battery research is the ability to tailor the physical, chemical, and electrochemical properties of the RSSR molecule through choice of the organic moiety. The viscosity, liquidus range, dielectric constant, equivalent weight, and redox potential can in fact be verified in a largely predictable manner. The current work concerns the use of multiple nitrogen organosulfur molecules, chosen for application in Na/RSSR cells for their expected oxidizing character. In fact, a Na/RSSR cell containing one of these materials, the sodium salt of 5-mercapto 1-methyltetrazole, yielded the highest open circuit voltage obtained yet in the laboratory; 3.0 volts in the charged state and 2.6 volts at 100 percent discharge. Accordingly, the cycling behavior of a series of multiple nitrogen organodisulfides as well as polymeric organodisulfides are presented in this manuscript.

Visco, S. J.↗
NASA NTRS2015

Taurus Littrow Pyroclastic Deposit: High-Yield Feedstock for Lunar Oxygen

Future human habitation of the Moon will likely require the use of locally derived materials because of the high cost of transportation from Earth. Oxygen, extracted from oxides and silicates, is a potentially abundant lunar resource vital for life support and spacecraft propulsion. The anticipated costs of supplying all oxygen needs for a lunar base from Earth are high enough to warrant serious study of oxygen production from local resources.

Allen, Carlton C.↗
NASA NTRS1974

A finite-element analysis for steady and oscillatory supersonic flows around complex configurations

The problem of small perturbation potential supersonic flow around complex configurations is considered. This problem requires the solution of an integral equation relating the values of the potential on the surface of the body to the values of the normal derivative, which is known from the small perturbation boundary conditions. The surface of the body is divided into small (hyperboloidal quadrilateral) surface elements, sigma sub i, which are described in terms of the Cartesian components of the four corner points. The values of the potential (and its normal derivative) within each element is assumed to be constant and equal to its value at the centroid of the element, and this yields a set of linear algebraic equations. The coefficients of the equation are given by source and doublet integrals over the surface elements, sigma sub i. The results obtained using the above formulation are compared with existing analytical and experimental results.

Morino, L.↗
NASA NTRS1980

HCMM and LANDSAT imagery for geological mapping in northwest Queensland

The author has identified the following significant results. Photographic prints made from negatives of day-visible and day-IR cover of selected areas were compared with enhanced color composites generated from LANDSAT computer compatible tapes and films. For geological mapping purposes, HCMM imagery is of limited value. While large scale features like the Mikadoodi anticlinorium, contrasting lithological units, and major structures may be distinguished on day-visible and day-IR cover, the spectral bands are too broad and the resolution too coarse even for regional mapping purposes. The imagery appears to be most useful for drainage studies. Where drainage is seasonal, sequential imagery permits monitoring of broad scale water movement while the day-IR imagery yields valuable information on former channels. In plains areas subject to periodic change of stream courses, comparable IR cover at a larger scale would offer considerable potential for reconstruction of former drainage patterns essential for the correct interpretation of geochemical data relative to mineral exploration.

Cole, M. M.↗
NASA NTRS1985

Composite Loads Spectra for Select Space Propulsion Structural Components

Rocket engine technology continues to demand higher performance with lighter weight components that have man-rated reliability requirements. These requirements have yielded higher operating pressures, temperatures, and transient effects as well as markedly increased mechanical vibration and flow-related loads. The difficulty in installation, cost, and potential for destroying an engine severely limited the required instrumentation and measurements to adequately define loads of key components such as turbine blades. Also, accurate analytical methodologies for defining internal flow-related loads are just emerging for problems typically found in rocket engines. The difficulty of obtained measured data and verified analysis methodologies has led to the probabilistic load definition approach.

Newell, J. F.↗
NASA NTRS1985

A computer program for determining the electrophoretic mobility of cells in a rectangular chamber during asymmetric electroosmotic flow

In the field of cell electrophoresis, computer programs have been used for the estimation of zeta potential and surface charge density of specific charged chemical species from electrophoretic mobility data. The union of computer and microscope cell electrophoresis in the laboratory has yielded several satisfying results. The method organizes and error checks these data and stores them on permanent file for future reference or reanalysis. This computer analysis, accomplished in two steps by two main programs and a major subroutine, provides a quick, useful and realistic presentation of mobility data in histogram form, and is appropriate for any microelectrophoretic work using rectangular chambers. Computer program 1 is the first step of two in the analysis of mobility data. Program 2 consists of the main program, POLY2, which fits a least squares parabola to the apparent mobility data generated by Program 1, and the subroutine EXTRA which determines actual cell mobilities using the regression curve equation.

Source record↗
NASA NTRS1987

Theoretical determination of the radiative lifetime of the A 2Sigma(+) state of OH

The present theoretical potentials and transition moment-based computation of the radiative lifetime of the A 2Sigma(+)(v-prime = 0, N-prime = 1) state of OH yields a value of 673 ns, in excellent agreement with two of the experimental values obtained through laser excitation fluorescence. The theoretical radiative lifetimes, which are expected to be lower bounds and accurate to 2 percent, are accurate enough to preclude both the slightly lower value determined by Hanle effect studies and the higher values obtained by the high frequency deflection technique.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1992

New Synthesis Of Poly(1,3,4-Oxadiazoles)

Synthesis via aromatic nucleophilic displacement yields new high-molecular-weight polymers. Polymers exhibited good mechanical and thermal properties. Synthetic route provided high-molecular-weight POX of new chemical structure, potentially more economical. Availability of large variety of activated aromatic dihalides, facilitates variation of chemical structures. Exhibit properties making them useful as films. Also useful in coatings, adhesives, moldings, and composites.

Connell, John W.↗
NASA NTRS1993

Large eddy simulation and direct numerical simulation of high speed turbulent reacting flows

The objective of this research is to make use of Large Eddy Simulation (LES) and Direct Numerical Simulation (DNS) for the computational analyses of high speed reacting flows. Our efforts in the first phase of this research conducted within the past three years have been directed in several issues pertaining to intricate physics of turbulent reacting flows. In our previous 5 semi-annual reports submitted to NASA LaRC, as well as several technical papers in archival journals, the results of our investigations have been fully described. In this progress report which is different in format as compared to our previous documents, we focus only on the issue of LES. The reason for doing so is that LES is the primary issue of interest to our Technical Monitor and that our other findings were needed to support the activities conducted under this prime issue. The outcomes of our related investigations, nevertheless, are included in the appendices accompanying this report. The relevance of the materials in these appendices are, therefore, discussed only briefly within the body of the report. Here, results are presented of a priori and a posterior analyses for validity assessments of assumed Probability Density Function (PDF) methods as potential subgrid scale (SGS) closures for LES of turbulent reacting flows. Simple non-premixed reacting systems involving an isothermal reaction of the type A + B yields Products under both chemical equilibrium and non-equilibrium conditions are considered. A priori analyses are conducted of a homogeneous box flow, and a spatially developing planar mixing layer to investigate the performance of the Pearson Family of PDF's as SGS models. A posteriori analyses are conducted of the mixing layer using a hybrid one-equation Smagorinsky/PDF SGS closure. The Smagorinsky closure augmented by the solution of the subgrid turbulent kinetic energy (TKE) equation is employed to account for hydrodynamic fluctuations, and the PDF is employed for modeling the effects of scalar fluctuations. The implementation of the model requires the knowledge of the local values of the first two SGS moments. These are provided by additional modeled transport equations. In both a priori and a posteriori analyses, the predicted results are appraised by comparison with subgrid averaged results generated by DNS. Based on these results, the paths to be followed in future investigations are identified.

Adumitroaie, V.↗
NASA NTRS1993

Estimation of crown closure from AVIRIS data using regression analysis

Crown closure is one of the input parameters used for forest growth and yield modelling. Preliminary work by Staenz et al. indicates that imaging spectrometer data acquired with sensors such as the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) have some potential for estimating crown closure on a stand level. The objectives of this paper are: (1) to establish a relationship between AVIRIS data and the crown closure derived from aerial photography of a forested test site within the Interior Douglas Fir biogeoclimatic zone in British Columbia, Canada; (2) to investigate the impact of atmospheric effects and the forest background on the correlation between AVIRIS data and crown closure estimates; and (3) to improve this relationship using multiple regression analysis.

Staenz, K.↗
NASA NTRS1990

Gravitropism of cucumber hypocotyls: biophysical mechanism of altered growth

The biophysical basis for the changes in cell elongation rate during gravitropism was examined in aetiolated cucumber (Cucumis sativus L.) hypocotyls. Bulk osmotic pressures on the two sides of the stem and in the epidermal cells were not altered during the early time course of gravitropism. By the pressure-probe technique, a small increase in turgor (0.3 bar, 30 kPa) was detected on the upper (inhibited) side, whereas there was a negligible decrease in turgor on the lower (stimulated) side. These small changes in turgor and water potential appeared to be indirect, passive consequences of the altered growth and the small resistance for water movement from the xylem, and indicated that the change in growth was principally due to changes in wall properties. The results indicate that the hydraulic conductance of the water-transport pathway was large (.25 h-1 bar-1) and the water potential difference supporting cell expansion was no greater than 0.3 bar (30 kPa). From pressure-block experiments, it appeared that upon gravitropic stimulation (1) the yield threshold of the lower half of the stem did not decrease and (2) the wall on the upper side of the stem was not made more rigid by a cross-linking process. Mechanical measurements of the stress/strain properties of the walls showed that the initial development of gravitropism did not involve an alteration of the mechanical behaviour of the isolated walls. Thus, gravitropism in cucumber hypocotyls occurs principally by an alteration of the wall relaxation process, without a necessary change in wall mechanical properties.

Non-NASA Center↗
NASA NTRS2004

Laboratory Infrared Spectra of Polycyclic Aromatic Nitrogen Heterocycles: Quinoline, and Phenanthridine in Solid Argon and H2O

Polycyclic aromatic hydrocarbons (PAHs) are common throughout the universe. Their detection and identification are based on telescopic infrared (IR) spectra compared with laboratory data. Polycyclic Aromatic Nitrogen Heterocycles (PANHs) are heterocyclic aromatics i.e., PAHs with carbon atoms replaced by a nitrogen atom. These molecules should be present in the interstellar medium, but have received relatively little attention. We present mid-IR spectra of two PANHs, quinoline (C9H7N), and phenanthridine (C13H9N) isolated in solid argon and frozen in solid H2O at 12 K, conditions yielding data directly comparable to astronomical observations. In contrast to simple PAHs, that do not interact strongly with solid H2O, the nitrogen atoms in PANHs are potentially capable of hydrogen bonding with H2O. Whereas the IR spectrum of phenanthridine in H2O is similar to that of the same compound isolated in an argon matrix, quinoline absorptions shift up to 16 cm(sup -1) (0.072 mm) between argon and H2O. Thus, astronomers will not always be able to rely on IR band positions of matrix isolated PANHs to correctly interpret the absorptions of PANHs frozen in H2O ice grains. Furthermore, our data suggest that relative band areas also vary, so determining column densities to better than a factor of 3 will require knowledge of the matrix in which the PANH is embedded and laboratory studies of relevant samples.

Bernstein, M. P.↗
NASA NTRS2008

Radiative Susceptibility of Cloudy Atmospheres to Droplet Number Perturbations: 2. Global analysis from MODIS

Global distributions of albedo susceptibility for areas covered by liquid clouds are presented for 4 months in 2005. The susceptibility estimates are based on expanded definitions presented in a companion paper and include relative cloud droplet number concentration (CDNC) changes, perturbations in cloud droplet asymmetry parameter and single-scattering albedo, atmospheric/surface effects, and incorporation of the full solar spectrum. The cloud properties (optical thickness and effective radius) used as input in the susceptibility calculations come from MODIS Terra and Aqua Collection 5 gridded data. Geographical distributions of susceptibility corresponding to absolute ( absolute cloud susceptibility ) and relative ( relative cloud susceptibility ) CDNC changes are markedly different indicating that the detailed nature of the cloud microphysical perturbation is important for determining the radiative forcing associated with the first indirect aerosol effect. However, both types of susceptibility exhibit common characteristics such as significant reductions when perturbations in single-scattering properties are omitted, significant increases when atmospheric absorption and surface albedo effects are ignored, and the tendency to decrease with latitude, to be higher over ocean than over land, and to be statistically similar between the morning and afternoon MODIS overpasses. The satellite-based susceptibility analysis helps elucidate the role of present-day cloud and land surface properties in indirect aerosol forcing responses. Our realistic yet moderate CDNC perturbations yield forcings on the order of 1-2 W/sq m for cloud optical property distributions and land surface spectral albedos observed by MODIS. Since susceptibilities can potentially be computed from model fields, these results have practical application in assessing the reasonableness of model-generated estimates of the aerosol indirect radiative forcing.

Oreopoulos, Lazaros↗
NASA NTRS2008

Requirements for an Advanced Low Earth Orbit (LEO) Sounder (ALS) for Improved Regional Weather Prediction and Monitoring of Greenhouse Gases

Hyperspectral infrared atmospheric sounders (e.g., the Atmospheric Infrared Sounder (AIRS) on Aqua and the Infrared Atmospheric Sounding Interferometer (IASI) on Met Op) provide highly accurate temperature and water vapor profiles in the lower to upper troposphere. These systems are vital operational components of our National Weather Prediction system and the AIRS has demonstrated over 6 hrs of forecast improvement on the 5 day operational forecast. Despite the success in the mid troposphere to lower stratosphere, a reduction in sensitivity and accuracy has been seen in these systems in the boundary layer over land. In this paper we demonstrate the potential improvement associated with higher spatial resolution (1 km vs currently 13.5 km) on the accuracy of boundary layer products with an added consequence of higher yield of cloud free scenes. This latter feature is related to the number of samples that can be assimilated and has also shown to have a significant impact on improving forecast accuracy. We also present a set of frequencies and resolutions that will improve vertical resolution of temperature and water vapor and trace gas species throughout the atmosphere. Development of an Advanced Low Earth Orbit (LEO) Sounder (ALS) with these improvements will improve weather forecast at the regional scale and of tropical storms and hurricanes. Improvements are also expected in the accuracy of the water vapor and cloud properties products, enhancing process studies and providing a better match to the resolution of future climate models. The improvements of technology required for the ALS are consistent with the current state of technology as demonstrated in NASA Instrument Incubator Program and NOAA's Hyperspectral Environmental Suite (HES) formulation phase development programs.

temperature↗
NASA NTRS2016

Integrating Satellite and Surface Sensor Networks for Irrigation Management Applications in California

Satellite mapping of evapotranspiration (ET) from irrigated agricultural lands can provide agricultural producers and water managers with information that can be used to optimize agricultural water use, especially in regions with limited water supplies. The timely delivery of information on agricultural crop water requirements has the potential to make irrigation scheduling more practical, convenient, and accurate. We present a system for irrigation scheduling and management support in California and describe lessons learned from the development and implementation of the system. The Satellite Irrigation Management Support (SIMS) framework integrates satellite data with information from agricultural weather networks to map crop canopy development, basal crop coefficients (Kcb), and basal crop evapotranspiration (ETcb) at the scale of individual fields. Information is distributed to agricultural producers and water managers via a web-based irrigation management decision support system and web data services. SIMS also provides an application programming interface (API) that facilitates integration with other irrigation decision support tools, estimation of total crop evapotranspiration (ETc) and calculation of on-farm water use efficiency metrics. Accuracy assessments conducted in commercial fields for more than a dozen crop types to date have shown that SIMS seasonal ETcb estimates are within 10 mean absolute error (MAE) for well-watered crops and within 15 across all crop types studied, and closely track daily ETc and running totals of ETc measured in each field. Use of a soil water balance model to correct for soil evaporation and crop water stress reduces this error to less than 8 MAE across all crop types studied to date relative to field measurements of ETc. Results from irrigation trials conducted by the project for four vegetable crops have also demonstrated the potential for use of ET-based irrigation management strategies to reduce total applied water by 20-40 relative to grower standard practices while maintaining crop yields and quality.

Nemani, Ramakrishna R.↗
NASA NTRS2021

Satellite Remote Sensing Observations of Trans-Atlantic Dust Transport and Deposition: A Multi-Sensor Analysis

We analyze the decade-long (2007-2016) record of aerosol measurements from four distinctive sensors, namely CALIOP, MODIS, MISR, and IASI, to quantify the trans-Atlantic dust transport and deposition. These satellite sensors use different techniques to characterize particle size and shape properties; and we have developed sensor-specific methods (broadly categorized into size-based and shape-based method) to derive dust optical depth (DOD). The size-based DOD from MODIS and IASI generally agrees better with AERONET-derived DOD than the shape-based DOD from CALIOP and MISR does. Overall, the shape-based DOD is smaller than the size-based DOD by about 25%, which is consistent with distinctive ways of accounting for coarse-spherical particles of dust-pollution internal mixture. While such dust-pollution mixtures are counted as dust in the size-based DOD, they are excluded in the shape-based DOD. DOD is not a good proxy for dust deposition. Instead, the dust deposition depends strongly on the gradient of DOD on a monthly basis and can be derived by calculating the meridional and zonal dust mass flux based on the three-dimensional distributions of dust. Among the remote sensing measurements, difference in dust deposition is smaller than that of DOD, suggesting that different satellites characterize the DOD gradient more consistently than DOD itself. Satellite measurements of dust deposition and DOD also provide an accurate estimate of the dust loss frequency (LF) that measures how efficient the dust is removed from the atmosphere. We found that these remote sensing measurements yield similar LF values of 0.078 –0.102 d-1, which however is factors of 2-5 smaller than model simulations. This analysis provides valuable insights into potential deficiencies in models’ emission and transport/removal processes and hence helps guide model improvement.

remote sensing↗
NASA NTRS2021

On the Loading Rate Dependence of Environment-assisted Cracking in Sensitized AA5456-H116 Exposed to Marine Environments

The influence of the applied loading rate (dK/dt) on the environment-assisted cracking (EAC) behavior of sensitized AA5456-H116 in 0.6 M NaCl at applied potentials ranging from −800 to −900 mV_SCE is assessed via a rising-K testing framework. The applied potential strongly affects the dK/dt-dependence of EAC with results suggesting a minimal influence for potentials more positive than −830 mVSCE and a stronger dK/dt-dependence for potentials more negative than −830 mV_SCE. Crack growth rates measured using rising versus static K testing are compared, which demonstrates that rising K methods consistently yield conservative EAC metrics with increased efficiency.

Al-Mg↗
NASA NTRSDate not supplied

Simultaneous Orthogonal Imaging for Cold Flow Characterization of Additively Manufactured Injector Elements

Additively manufactured (AM) injectors have the potential to improve characteristic velocity (C*) performance beyond the 90-97% of theoretical C* performance seen by traditionally manufactured (TM) combustion device injectors. Maximized C* performance yields high overall combustion efficiency in all types of combustion devices, particularly liquid rocket engines (LREs) and rotating detonation rocket engines (RDREs). A high degree of propellant atomization and mixedness is required to achieve maximum C* performance and therefore high overall combustion efficiency. This study focused on measuring and comparing the performance of different novel AM injector elements over a broad range of operating conditions under high pressure, cold flow. As part of this work, a high pressure, cold flow experimental spray facility was designed to measure each element’s injector spray patterns under pressures ranging from 50 to 1000 psig and stiffness ratios from 0.5 to 2.0. Preliminary results are presented from orthogonal, simultaneous imaging comparing atomization and spray geometry between quad, trio, pentad, slotted, and triplet impingers in gas-liquid flow.

Ari D Goldman↗