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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Effect of gravity on the stability and structure of lean hydrogen-air flames

Detailed, time-dependent, 2D numerical simulations with full hydrogen-oxygen chemistry are used to investigate the effects of gravity on the stability and structure of laminar flames in lean, premixed hydrogen-air mixtures. The calculations show that the effects of gravity becomes more important as the lean flammability limit is approached. In a 12 percent hydrogen-air mixture, gravity plays only a secondary role in determining the multidimensional structure of the flame with the stability and structure of the flame controlled primarily by the thermo-diffusive instability mechanism. However, in leaner hydrogen-air mixtures gravity becomes more important. Upward-propagating flames are highly curved and evolve into a bubble rising upwards in the tube. Downward-propagating flames are flat or even oscillate between structures with concave and convex curvatures. The zero-gravity flame shows only cellular structures. Cellular structures which are present in zero gravity can be suppressed by the effect of buoyancy for mixtures leaner than 11 percent hydrogen. These observations are explained on the basis of an interaction between the processes leading to buoyancy-induced Rayleigh-Taylor instability and the thermo-diffusive instability.

Patnaik, G.↗
NASA NTRS1985

Calculation of charge-state ratios for satellite Tor I

The diffusion of ions in a satellite plasma torus is presently modeled in terms of a one-dimensional random walk in which the particle source is at 0, the particle sink is at an N value that is an integer greater than 2, and the scale size of the diffusion cell is unity. The probability distribution function of the number of steps to exit for an ion is obtained and used in a model which incorporates ionization by electron impact to derive steady state expressions for the ratio of doubly to singly ionized ions, as well as the total number of ions in the torus. The results thus obtained are applied to the torus of the Jovian satellite Io, in order to predict mean residence times for sulfur and oxygen ions.

Summers, D.↗
NASA NTRS1988

Modelling ignition characteristics of rich H2/O2 mixture in a monolithic catalytic reactor

Ignition of rich hydrogen-oxygen mixture in a monolithic catalytic reactor is studied using a transient combustion model. The model assumes a quasi-steady gas phase and a thermally-thin substrate. The ignition time lag is due to the thermal inertia of the substrate. One-step global chemical reaction is assumed both on the surface and in the gas phase. An effectiveness factor is introduced to account for the transition from a kinetically-limited catalytic surface reaction to a diffusion-limit one during ignition. Results presented include a catalytic ignition boundary, ignition delay time and the transient response in the catalytic bed.

Tien, Ta-Ching↗
NASA NTRS1989

Three-Man Solid Electrolyte Carbon Dioxide Electrolysis Breadboard

The development of the Three-Man (2.2 lb CO2/man-day) Solid Electrolyte CO2 Electrolysis Breadboard consisted of a Phase 1 and 2 effort. The Phase 1 effort constituted fabrication of three electrolysis cell types and performing parametric testing, off-design testing, and cell life testing. The Phase 2 consisted of the preliminary design, incorporation of palladium (Pd) tubes for hydrogen separation from the electrolyzer cathode feed gases, design support testing, final design, fabrication, and performance testing of the breadboard system. The results of performance tests demonstrated that CO2 electrolysis in an oxygen reclamation system for long duration space-based habitats is feasible. Closure of the oxygen system loop, therefore, can be achieved by CO2 electrolysis. In a two step process the metabolic CO2 and H2O vapor are electrolyzed into O2, H2, and CO. The CO can subsequently be disproportionated into carbon and CO2 in a carbon deposition reactor and the CO2 in turn be recycled and electrolyzed for total O2 recovery. The development effort demonstrated electrolyzer system can be designed and built to operate safely and reliably and the incorporation of Pd tubes for hydrogen diffusion can be integrated safely with predictable performance.

Isenberg, Arnold O.↗
NASA NTRS2007

First Terrestrial Soft X-Ray Auroral Observation by the Chandra X-Ray Observatory

Northern auroral regions of Earth were imaged with energetic photons in the 0.1-10keV range using the High-Resolution Camera (HRC-I) aboard the Chandra X-ray Observatory at 10 epochs (each approx.20 min duration) between mid- December 2003 and mid-April 2004. These observations aimed at searching for Earth's soft (< 2 keV) X-ray aurora in a comparative study with Jupiter's X-ray aurora, where a pulsating X-ray "hot-spot" has been previously observed by Chandra. The first Chandra soft X-ray observations of Earth's aurora show that it is highly variable 0ntense arcs, multiple arcs, diffuse patches, at times absent). In at least one of the observations an isolated blob of emission is observed near the expected cusp location. A fortuitous overflight of DMSP satellite F13 provided SSJ/4 energetic particle measurements above a bright arc seen by Chandra on 24 January 2004, 20:01-20:22 UT. A model of the emissions expected strongly suggests that the observed soft X-ray signal is bremsstrahlung and characteristic K-shell line emissions of nitrogen and oxygen in the atmosphere produced by electrons.

Bhardwaj, Anil↗
NASA NTRS2016

Electromagnetic Basis of Metabolism and Heredity

Living organisms control their cellular biological clocks to maintain functional oscillation of the redox cycle, also called the "metabolic cycle" or "respiratory cycle". Organization of cellular processes requires parallel processing on a synchronized time-base. These clocks coordinate the timing of all biochemical processes in the cell, including energy production, DNA replication, and RNA transcription. When this universal time keeping function is perturbed by exogenous induction of reactive oxygen species (ROS), the rate of metabolism changes. This causes oxidative stress, aging and mutations. Therefore, good temporal coordination of the redox cycle not only actively prevents chemical conflict between the reductive and oxidative partial reactions; it also maintains genome integrity and lifespan. Moreover, this universal biochemical rhythm can be disrupted by ROS induction in vivo. This in turn can be achieved by blocking the electron transport chain either endogenously or exogenously by various metabolites, e.g. hydrogen sulfide (H2S), highly diffusible drugs, and carbon monoxide (CO). Alternatively, the electron transport in vivo can be attenuated via a coherent or interfering transfer of energy from exogenous ultralow frequency (ULF) and extremely low frequency (ELF) electromagnetic (EM) fields, suggesting that-on Earth-such ambient fields are an omnipresent (and probably crucially important) factor for the time-setting basis of universal biochemical reactions in living cells. Our work demonstrated previously un-described evidence for quantum effects in biology by electromagnetic coupling below thermal noise at the universal electron transport chain (ETC) in vivo.

Electromagnetic↗
NASA NTRSDate not supplied

Ice Growth Model and Lunar Tanker for Polar Water Extraction

In-Situ Resource Utilization (ISRU) is a major component of sustainable and cost-effective missions to the Moon and beyond. Ever since it has been identified in the Permanently Shadowed Regions (PSRs) of the Moon, water has become a resource of interest for it’s wide range of uses such as life support and hydrogen and oxygen rocket propellant. It is ice-bound in the regolith, so separation typically involves heating to sublimation temperatures and capturing at very low pressure. One option is to then store it in ice form and transport it out of the PSR and into a sunlit ridge. From here, processes such as electrolysis can be performed. An understanding of frost growth dynamics under rarefied conditions is necessary for successful water production, though. An analytical model was developed using a Diffusion-Limited Aggregation (DLA) approach to evaluate bulk thermal conductivity changes of frost under varying conditions. This model will be evaluated using a one-dimensional frost growth experiment on a horizontal, flat plate under vacuum and cryogenic conditions. The tests will measure frost growth rate and bulk density, and the thermal conductivity of the ice layer as a function of thickness for different plate temperatures. The test data will then be used to validate and improve the analytical model.

Lunar water↗
NASA NTRS1990

Electron temperature and concentration in a thermal atomic oxygen source

A thermal atomic oxygen source for materials screening was built for NASA by Boeing Aerospace. The objective here was to use a microwave interferometer and Langmuir probe to characterize the electron concentration in this thermal atomic oxygen source. Typical operating conditions in the thermal atomic oxygen source were found to produce electron concentrations that were well below the detection threshold of the interferometer (10(exp 8) cm (sup -3)). The researchers calibrated (with the interferometer) the Langmuir probe at an artificially high plasma density and then used the circular and the square Langmuir probes to measure the low electron concentrations that exist during materials exposure tests. Electron concentration was measured as a function of power and position. The electrons were lost to the walls through ambipolar diffusion, and their concentration was accurately described by an equation. The electron concentration was proportional to power squared and decayed exponentially with distance.

Pedrow, Patrick Dennis↗
NASA NTRS1993

Influence of test configuration on the combustion characteristics of polymers as ignition sources

The experimental evaluation of polymers as ignition sources for metals was accomplished at the NASA White Sands Test Facility (WSTF) using a standard promoted combustion test. These tests involve the transient burning of materials in high-pressure oxygen environments. They have provided data from which design decisions can be made; data include video recordings of ignition and non-ignition for specific combinations of metals and polymers. Other tests provide the measured compositions of combustion products for polymers at select burn times and an empirical basis for estimating burn rates. With the current test configuration, the detailed analysis of test results requires modeling a three-dimensional, transient convection process involving fluid motion, thermal conduction and convection, the diffusion of chemical species, and the erosion of sample surface. At the high pressure extremes, it even requires the analysis of turbulent, transient convection where the physics of the problem are not well known and the computation requirements are not practical at this time. An alternative test configuration that can be analyzed with a relatively-simple convection model was developed during the summer period. The principal change constitutes replacing a large-diameter polymer disk at the end of the metal test rod with coaxial polymer cylinders that have a diameter nearer to that of the metal rod. The experimental objective is to assess the importance of test geometries on the promotion of metal ignition by testing with different lengths of the polymer and, with an extended effort, to analyze the surface combustion in the redesigned promoted combustion tests through analytical modeling of the process. The analysis shall use the results of cone-calorimeter tests of the polymer material to model primary chemical reactions and, with proper design of the promoted combustion test, modeling of the convection process could be conveniently limited to a quasi-steady boundary layer analysis where the economical solution of parabolic equations is involved. The products for the summer period are: (1) a conceptual-level redesign of the test apparatus, and (2) the development and use of an approximate integral boundary layer analysis to demonstrate the influence of geometry changes prior to testing. A computer code STAN5, an accurate numerical boundary layer model whose earlier versions were developed for the NASA Lewis Research Center by the Fellow, also was installed and validated on the WSTF and New Mexico State University computer systems as a starting point in the development of a more detailed fluid mechanics and combustion model.

Julien, Howard L.↗
NASA NTRS1972

Conceptual design study of a six-man solid electrolyte system for oxygen reclamation

A six-man solid electrolyte oxygen regeneration system (SEORS) that will produce 12.5 lbs/day of oxygen has been designed. The SEORS will simultaneously electrolyze both carbon dioxide and water vapor and be suitable for coupling with a carbon dioxide concentration system of either molecular sieve, solid amine or hydrogen depolarized electrochemical type. The total system will occupy approximately 19 cu ft (34.5 in. x .26 in. x 36 in. high) and will weigh approximately 500 pounds. It is estimated that the total electrical power required will be 1783 watts. The system consists of three major components; electrolyzer, hydrogen diffuser, and carbon deposition reactor. There are 108 electrolysis stacks of 12 cells each in the electrolyzer. Only 2/3 of the 108 stacks will be operated at a time; the remainder will be held in reserve. The design calls for 96 palladium membranes for hydrogen removal to give 60 percent redundancy. Four carbon deposition reactors are employed. The iron catalyst tube in each reactor weighs 7.1 lb and 100 percent redundancy is allowed.

Morris, J. P.↗
NASA NTRS1990

High-resolution X-ray spectroscopy of four active galaxies - Probing the intercloud medium

The focal plane crystal spectrometer (FPCS) on the Einstein Observatory has been used to perform a high-resolution spectroscopic search for oxygen X-ray line emission from four active galaxies: Fairall 9, Mrk 421, Mrk 501, and PKS 0548 - 322. Specifically, O VIII Ly-alpha and Ly-beta, whose unredshifted energies are 653 and 775 eV, respectively, were sought. No narrow-line emission was detected within the energy bands searched. Upper limits are calculated on the line flux from these sources of 30 eV equivalent width and use a photoionization model to place corresponding upper limits on the densities of diffuse gas surrounding the active nuclei. The upper limits on gas density range from about 0.02-50/cu cm and probe various radial distances from the central source. This is the first time high-resolution X-ray spectroscopy has been used to place constraints on the intercloud medium in active galaxies.

Lum, Kenneth S. K.↗
NASA NTRS1985

Ion partitioning in the hot Io torus - The influence of S2 outgassing

An alternative time-independent model of the ion partitioning in the hot Io torus is proposed which introduces the ratio of sulfur to oxygen in the neutral source as a free parameter. Measurements of the ion abundances in the torus plasma are presented and discussed, noting some ambiguities and identifying the features that are well established. Physical processes important to the understanding of the ion partitioning calculation are reviewed. The results of the model are discussed in the context of observational constraints, and spectroscopic constraints are discussed. It is concluded that a bimodal source model, together with a small percentage of hot electrons and a relatively short diffusion time scale, can account for the principal observational features without invoking significant time variability. In particular, the O III deficiency observed in 1981 can be obtained in a model that produces other aspects of the torus ion partitioning measured during the Voyager 1 encounter.

Moreno, M. A.↗
NASA NTRS1989

Near-Limit Flame Spread over a Thin Solid Fuel in Microgravity

Diffusion flame spread over a thin solid fuel in quiescent and slowly moving atmospheres is studied in microgravity. The flame behavior is observed to depend strongly on the magnitude of the relative velocity between the flame and the atmosphere. In particular, a low velocity quenching limit is found to exist in low oxgen environments. Using both the microgravity results and previously published data at high opposed-flow velocities, the flame spread behavior is examined over a wide velocity range. A flammability map using molar oxygen percentages and characteristic relative velocities as coordinates is constructed. Trends of flame spread rate are determined and mechanisms for flame extinction are discussed.

Olson, Sandra L.↗
NASA NTRS1999

Stability of Enclosed Laminar Flames Studied in Microgravity

In practical combustion systems, the flame is often anchored at the inlet where the fuel is injected into an air duct. This type of system is found in powerplant combustors, gas turbine combustors, and the jet engine afterburner. Despite its successful use, this configuration is vulnerable to adverse flow conditions that can cause the flame to literally lift off from the inlet or even blowout. Poor flame stability is, of course, unwanted, especially where safety has a high priority. Our understanding of the mechanisms that control flame stability is incomplete in part because the interaction of buoyant (i.e., gravity-induced) convection makes it difficult to interpret normal-gravity results. However, a comparison of normal-gravity and microgravity results can provide a clear indication of the influence of forced and buoyant flows on flame stability. Therefore, a joint microgravity study on the stability of Enclosed Laminar Flames (ELF) was carried out by researchers at The University of Iowa and the NASA Lewis Research Center. The microgravity tests were conducted in the Microgravity Glovebox (MGBX), during the STS-87 space shuttle mission in late 1997, using hardware designed and produced at Lewis. The primary objective of the ELF investigation was to determine the mechanisms controlling the stability of round, laminar, gas-jet diffusion flames in a coflow air duct. The study specifically focused on the effect of buoyancy on the flame characteristics and velocities at the lift-off, reattachment, and blowout of the flame. When the fuel or air velocity is increased to a critical value, the flame base abruptly jumps downstream, and the flame is said to have reached its lift-off condition. Flow conditions are such that the flame cannot be maintained at the burner rim despite the presence of both fuel and oxygen. When the velocity is further increased, the flame eventually extinguishes at its blowout condition. In contrast, if the velocity is reduced, the flame base eventually returns to anchor at the burner rim, at a velocity lower than that of lift-off, indicating a hysteresis effect.

Stocker, Dennis P.↗
NASA NTRS2002

Membrane Separation Processes at Low Temperatures

The primary focus of Kennedy Space Center's gas separation activities has been for carbon dioxide, nitrogen, and argon used in oxygen production technologies for Martian in-situ resource utilization (ISRU) projects. Recently, these studies were expanded to include oxygen for regenerative life support systems. Since commercial membrane systems have been developed for separation of carbon dioxide, nitrogen, and oxygen, initially the studies focused on these membrane systems, but at lower operating temperatures and pressures. Current investigations art examining immobilized liquids and solid sorbents that have the potential for higher selectivity and lower operating temperatures. The gas separation studies reported here use hollow fiber membranes to separate carbon dioxide, nitrogen, and argon in the temperature range from 230 to 300 K. Four commercial membrane materials were used to obtain data at low feed and permeate pressures. These data were used with a commercial solution-diffusion modeling tool to design a system to prepare a buffer gas from the byproduct of a process to capture Martian carbon dioxide. The system was designed to operate, at 230 K with a production rate 0.1 sLpm; Feed composition 30% CO2, 44% N2, and 26% Ar; Feed pressure 104 kPa (780); and Permeate pressure 1 kPa (6 torr); Product concentration 600 ppm CO2. This new system was compared with a similar system designed to operate at ambient temperatures (298 K). The systems described above, along with data, test apparatus, and models are presented.

Parrish, Clyde↗
NASA NTRS1992

Species and temperature measurement in H2/O2 rocket flow fields by means of Raman scattering diagnostics

Validation of Computational Fluid Dynamics (CFD) codes developed for prediction and evaluation of rocket performance is hampered by a lack of experimental data. Non-intrusive laser based diagnostics are needed to provide spatially and temporally resolved gas dynamic and fluid dynamic measurements. This paper reports the first non-intrusive temperature and species measurements in the plume of a 110 N gaseous hydrogen/oxygen thruster at and below ambient pressures, obtained with spontaneous Raman spectroscopy. Measurements at 10 mm downstream of the exit plane are compared with predictions from a numerical solution of the axisymmetric Navier-Stokes and species transport equations with chemical kinetics, which fully model the combustor-nozzle-plume flowfield. The experimentally determined oxygen number density at the centerline at 10 mm downstream of the exit plane is four times that predicted by the model. The experimental number density data fall between those numerically predicted for the exit and 10 mm downstream planes in both magnitude and radial gradient. The predicted temperature levels are within 10 to 15 percent of measured values. Some of the discrepancies between experimental data and predictions result from not modeling the three dimensional core flow injection mixing process, facility back pressure effects, and possible diffuser-thruster interactions.

Degroot, Wim A.↗
NASA NTRS1993

Near-ambient solid polymer fuel cell

Fuel cells are extremely attractive for extraterrestrial and terrestrial applications because of their high energy conversion efficiency without noise or environmental pollution. Among the various fuel cell systems the advanced polymer electrolyte membrane fuel cells based on sulfonated fluoropolymers (e.g., Nafion) are particularly attractive because they are fairly rugged, solid state, quite conductive, of good chemical and thermal stability and show good oxygen reduction kinetics due to the low specific adsorption of the electrolyte on the platinum catalyst. The objective of this program is to develop a solid polymer fuel cell which can efficiently operate at near ambient temperatures without ancillary components for humidification and/or pressurization of the fuel or oxidant gases. During the Phase 1 effort we fabricated novel integral electrode-membrane structures where the dispersed platinum catalyst is precipitated within the Nafion ionomer. This resulted in electrode-membrane units without interfacial barriers permitting unhindered water diffusion from cathode to anode. The integral electrode-membrane structures were tested as fuel cells operating on H2 and O2 or air at 1 to 2 atm and 10 to 50 C without gas humidification. We demonstrated that cells with completely dry membranes could be self started at room temperature and subsequently operated on dry gas for extended time. Typical room temperature low pressure operation with unoptimized electrodes yielded 100 mA/cm(exp 2) at 0.5V and maximum currents over 300 mA/cm(exp 2) with low platinum loadings. Our results clearly demonstrate that operation of proton exchange membrane fuel cells at ambient conditions is feasible. Optimization of the electrode-membrane structure is necessary to assess the full performance potential but we expect significant gains in weight and volume power density for the system. The reduced complexity will make fuel cells also attractive for smaller and portable power supplies and as replacement for batteries.

Holleck, G. L.↗
NASA NTRS1982

O-18 tracer studies of Al2O3 scale formation on NiCrAl alloys

Diffusion processes in Al2O3 scales formed on NiCrAl + Zr alloys were studied by the proton activation technique employing the O-18 isotope as a tracer. The O-18 profiles identified a zone of oxide penetration beneath the external scale. Both this subscale formation and the outer Al2O3 scale thickness were shown by this technique to increase with Zr content in the alloy. Estimated kp's from scale thicknesses were in agreement with gravimetric measurements for various Zr levels. Alternate exposures in O-16 and O-18 revealed that oxygen inward transport was the primary growth mechanism. A qualitative analysis of these O-18 profiles indicated that the oxygen transport was primarily via short-circuit paths, such as grain boundaries.

Reddy, K. P. R.↗