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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

Airborne Lidar Measurements of Atmospheric Pressure Made Using the Oxygen A-Band

We report on airborne measurements of atmospheric pressure using a fiber-laser based lidar operating in the oxygen A-band near 765 nm and the integrated path differential absorption measurement technique. Our lidar uses fiber optic technology and non-linear optics to generate tunable laser radiation at 765 nm, which overlaps an absorption line pair in the Oxygen A-band. We use a pulsed time resolved technique, which rapidly steps the laser wavelength across the absorption line pair, a 20 cm telescope and photon counting detector to measure Oxygen concentrations.

Riris, Haris↗
NASA NTRS2001

Real-time measurements of endogenous CO production from vascular cells using an ultrasensitive laser sensor

Carbon monoxide (CO) has been implicated as a biological messenger molecule analogous to nitric oxide. A compact gas sensor based on a midinfrared laser absorption spectroscopy was developed for direct and real-time measurement of trace levels (in approximate pmol) of CO release by vascular cells. The midinfrared light is generated by difference frequency mixing of two nearinfrared lasers in a nonlinear optical crystal. A strong infrared absorption line of CO (4.61 microm) is chosen for convenient CO detection without interference from other gas species. The generation of CO from cultured vascular smooth muscle cells was detected every 20 s without any chemical modification to the CO. The sensitivity of the sensor reached 6.9 pmol CO. CO synthesis was measured from untreated control cells (0.25 nmol per 10(7) cells/h), sodium nitroprusside-treated cells (0.29 nmol per 10(7) cells/h), and hemin-treated cells (0.49 nmol per 10(7) cells/h). The sensor also detected decreases in CO production after the addition of the heme oxygenase (HO) inhibitor tin protoporphyrin-IX (from 0.49 to 0.02 nmol per 10(7) cells/h) and increases after the administration of the HO substrate hemin (from 0.27 to 0.64 nmol per 10(7) cells/h). These results demonstrate that midinfrared laser absorption spectroscopy is a useful technique for the noninvasive and real-time detection of trace levels of CO from biological tissues.

Non-NASA Center↗
NASA NTRS2019

Discovery of Highly Blueshifted Broad Balmer and Metastable Helium Absorption Lines in a Tidal Disruption Event

We report the discovery of nonstellar hydrogen Balmer and metastable helium absorption lines accompanying a transient, high-velocity (0.05c) broad absorption line (BAL) system in the optical spectra of the tidal disruption event (TDE) AT2018zr (z = 0.071). In the Hubble Space Telescope UV spectra, absorption of high- and low-ionization lines is also present at this velocity, making AT2018zr resemble a low-ionization BALQSO. We conclude that these transient absorption features are more likely to arise in fast outflows produced by the TDE than absorbed by the unbound debris. In accordance with the outflow picture, we are able to reproduce the flat-topped Hα emission in a spherically expanding medium without invoking the typical prescription of an elliptical disk. We also report the appearance of narrow (∼1000 kms−1) N III λ4640, He II λ4686, Hα, and Hβ emission in the latetime optical spectra of AT2018zr, which may be a result of UV continuum hardening at late times, as observed by Swift. Including AT2018zr, we find a high association rate (three out of four) of BALs in the UV spectra of TDEs. This suggests that outflows may be ubiquitous among TDEs and less sensitive to viewing angle effects compared to QSO outflows.

T Hung↗
NASA NTRS1992

Thermal control paints on LDEF: Results of sub-experiment 802-18

Several thermal control paints were flown on the LDEF, including the white paints Chemglaze A276, S13GLo, and YB-71, and the black paint D-111. The effects of low earth orbit, which includes UV radiation and atomic oxygen, varied significantly with each paint and its location on LDEF. This paper will examine the performance of these paints as determined by changes in their optical and physical properties, including solar absorptance, surface chemical changes, and changes in surface morphology. It will also provide a correlation of these optical and physical property changes to the physical phenomena that occurred in these materials during the LDEF mission.

Jaggers, Christopher H.↗
NASA NTRS2019

Discovery of Highly Blueshifted Broad Balmer and Metastable Helium Absorption Lines in a Tidal Disruption Event

We report the discovery of nonstellar hydrogen Balmer and metastable helium absorption lines accompanying a transient, high-velocity (0.05c) broad absorption line (BAL) system in the optical spectra of the tidal disruption event (TDE) AT2018zr (z = 0.071). In the Hubble Space Telescope UV spectra, absorption of high- and low-ionization lines is also present at this velocity, making AT2018zr resemble a low-ionization BALQSO. We conclude that these transient absorption features are more likely to arise in fast outflows produced by the TDE than absorbed by the unbound debris. In accordance with the outflow picture, we are able to reproduce the flat-topped Hα emission in a spherically expanding medium without invoking the typical prescription of an elliptical disk. We also report the appearance of narrow (~1000 kms(exp −1)) N III λ4640, He II λ4686, Hα, and Hβ emission in the late-time optical spectra of AT2018zr, which may be a result of UV continuum hardening at late times, as observed by Swift. Including AT2018zr, we find a high association rate (three out of four) of BALs in the UV spectra of TDEs. This suggests that outflows may be ubiquitous among TDEs and less sensitive to viewing angle effects compared to QSO outflows.

Hung, T.↗
NASA NTRS2017

Effect of Ram and Zenith Exposure on the Optical Properties of Polymers in Space

The temperature of spacecraft is influenced by the solar absorptance and thermal emittance of the external spacecraft materials. Optical and thermal properties can degrade over time in the harsh low Earth orbital (LEO) space environment where spacecraft external materials are exposed to various forms of radiation, thermal cycling, and atomic oxygen. Therefore, it is important to test the durability of spacecraft materials in the space environment. One objective of the Polymers and Zenith Polymers Experiments was to determine the effect of LEO space exposure on the optical properties of various spacecraft polymers. These experiments were flown as part of the Materials International Space Station Experiment 7 (MISSE 7) mission on the exterior of the International Space Station (ISS) for 1.5 years. Samples were flown in ram, wake or zenith directions, receiving varying amounts of atomic oxygen and solar radiation exposure. Total and diffuse reflectance and transmittance of flight and corresponding control samples were obtained post-flight using a Cary 5000 UV-Vis-NIR Spectrophotometer. Integrated air mass zero solar absorptance (s) of the flight and control samples were computed from the total transmittance and reflectance, and compared. The optical data are compared with similar polymers exposed to space for four years as part of MISSE 2, and with atomic oxygen erosion data, to help understand the degradation of these polymers in the space environment. Results show that prolonged space exposure increases the solar absorptance of some materials. Knowing which polymers remain stable will benefit future spacecraft design.

Yuanchun Li↗
NASA NTRS1994

A weak diffuse interstellar band in the far-ultraviolet spectrum of zeta Ophiuchi?

Goddard High Resolution Spectrograph (GHRS) observations at 3.5 km/s resolution reveal several new weak unidentified interstellar absorption lines in the ultraviolet spectrum of zeta Ophiuchi. The unidentified line at 1369.13 A has the appearance and characteristics of a weak diffuse interstellar band (DIB). The line has a smooth profile similar to many optical diffuse interstellar bands (i.e., a shallow asymmetric profile), it is clearly broader than identified interstellar lines near it in wavelength, and its full width at half maximum in ergs is comparable to the widths of the weak optical DIBs. The asymmetric profile cannot be attributed to blended absorption from diffuse clouds at different velocities; at this resolution the two principal cloud complexes on the sight line at heliocentric velocities of -27 and -15 km/s are clearly separated. We compare this unidentified absorption feature to identified interstellar atomic and molecular absorption lines and optical DIBs observed on the zeta Oph and xi Per sight lines, and we conclude that it is reasonable to suggest that this absorption feature might be a DIB. This is not a unique interpretation however; the unidentified line could alternatively be due to gas in the zeta Oph H II region or a blend of unknown neutral atomic or molecular absorption lines.

Tripp, Todd M.↗
NASA NTRS1979

Spectra of Fe-Ti silicate glasses - Implications to remote-sensing of planetary surfaces

Optical spectra of synthetic Fe-Ti silicate glasses and the temperature variations of the spectral features were investigated. The spectra are assigned to absorptions due to crystal field (CF) transitions in Ti(3+), Fe(2+) in octahedral coordination, and Fe(2+) in tetrahedral coordination, and to metal-metal and oxygen-metal charge transfer (CT) transitions which contribute to the near ultraviolet absorption edge. Temperature variations of the optical bands have been studied to explore implications for remote sensing. Caution is urged in the use of the absorption edge as a measure of TiO2 concentrations on planetary surfaces and in regolith samples.

Nolet, D. A.↗
NASA NTRS2007

Temperature Evolution in Excitonic Absorptions of Cd(0.96)Zn(0.04) Materials

We report cryogenic optical properties of Cd(0.96)Zn(0.04)Te wafers that are used as substrate seed layers in HgCdTe focal-plane array detectors. These studies are motivated by the fact that the substrate optical properties influence the overall detector performance. The studies consist of measuring the sample frequency dependent transmittance (T) and reflectance (R) above and below the optical band-gap in the UV/Visible and infrared frequency ranges, and with temperature variation of the sample from 5 to 300 K. These measurements show that the optical gap near 1.49 eV at 300 K increases to 1.62 eV at 5 K. Finally, we observe sharp absorption peaks near this gap energy at low temperatures. The close proximity of these peaks to the optical transition threshold suggests that they originate from the creation of bound electron-hole pairs or excitons. The decay of these excitonic absorptions may contribute to a photoluminescence and transient background response of these back-illuminated HgCdTe CCD detectors.

Quijada, Manuel A.↗
NASA NTRS2014

Optical Multi-Gas Monitor Technology Demonstration on the International Space Station

There are a variety of both portable and fixed gas monitors onboard the International Space Station (ISS). Devices range from rack-mounted mass spectrometers to hand-held electrochemical sensors. An optical Multi-Gas Monitor has been developed as an ISS Technology Demonstration to evaluate long-term continuous measurement of 4 gases. Based on tunable diode laser spectroscopy, this technology offers unprecedented selectivity, concentration range, precision, and calibration stability. The monitor utilizes the combination of high performance laser absorption spectroscopy with a rugged optical path length enhancement cell that is nearly impossible to misalign. The enhancement cell serves simultaneously as the measurement sampling cell for multiple laser channels operating within a common measurement volume. Four laser diode based detection channels allow quantitative determination of ISS cabin concentrations of water vapor (humidity), carbon dioxide, ammonia and oxygen. Each channel utilizes a separate vertical cavity surface emitting laser (VCSEL) at a different wavelength. In addition to measuring major air constituents in their relevant ranges, the multiple gas monitor provides real time quantitative gaseous ammonia measurements between 5 and 20,000 parts-per-million (ppm). A small ventilation fan draws air with no pumps or valves into the enclosure in which analysis occurs. Power draw is only about 3 W from USB sources when installed in Nanoracks or when connected to 28V source from any EXPRESS rack interface. Internal battery power can run the sensor for over 20 hours during portable operation. The sensor is controlled digitally with an FPGA/microcontroller architecture that stores data internally while displaying running average measurements on an LCD screen and interfacing with the rack or laptop via USB. Design, construction and certification of the Multi-Gas Monitor were a joint effort between Vista Photonics, Nanoracks and NASA-Johnson Space Center (JSC). Vista Photonics developed the core technology and built the sensor. Nanoracks designed, constructed the enclosure, interfaces, and battery power management circuitry, integrated all subsystems into the enclosure, and then managed the certification tests, documentation and manifesting. The unit was calibrated in the JSC Toxicology Laboratory. The Multi-Gas Monitor is manifested to fly as a technology demonstration to the ISS in November 2013 and will operate for at least 6 months with data sent to the ground for evaluation. The primary goal is to demonstrate long term interference free operation in the real spacecraft environment.

Pilgrim, Jeffrey S.↗
NASA NTRS2001

Remote Sensing of Non-Aerosol (anomalous) Absorption in Cloud Free Atmosphere

The interaction of sunlight with atmospheric gases, aerosols and clouds is fundamental to the understanding of climate and its variation. Several studies questioned our understanding of atmospheric absorption of sunlight in cloudy or in cloud free atmospheres. Uncertainty in instruments' accuracy and in the analysis methods makes this problem difficult to resolve. Here we use several years of measurements of sky and sun spectral brightness by selected instruments of the Aerosol Robotic Network (AERONET), that have known and high measurement accuracy. The measurements taken in several locations around the world show that in the atmospheric windows 0.44, 0.06, 0.86 and 1.02 microns the only significant absorbers in cloud free atmosphere is aerosol and ozone. This conclusions is reached using a method developed to distinguish between absorption associated with the presence of aerosol and absorption that is not related to the presence of aerosol. Non-aerosol absorption, defined as spectrally independent or smoothly variable, was found to have an optical thickness smaller than 0.002 corresponding to absorption of sunlight less than 1W/sq m, or essentially zero.

Kaufman, Yoram J.↗
NASA NTRS1984

1E 0104.2 + 3153 - A broad absorption-line QSO viewed through a giant elliptical galaxy

The optical identification of the X-ray source 1E 0104.2 + 3153 is complicated by the close projection of a broad absorption-line (BAL) QSO (z = 2.027) 10 arcsec from a giant elliptical galaxy (z = 0.111) at the center of a compact group of galaxies. At only 1.2 de Vaucouleur radii (16 kpc for H sub 0 = 100 km/s Mpc) this QSO-galaxy projection is the closest yet discovered. Based upon current observations, the source of the X-ray emission cannot be conclusively determined. Present in the BAL QSO spectrum are extremely strong Ca II H and K absorption lines due to the intervening galaxy, the first optical detection of the cold interstellar medium in an elliptical galaxy. The strength of these lines (EW = 2 and 1 A) requires observation through several interstellar clouds in the line of sight to the QSO. By its proximity to the central regions of the elliptical galaxy and the relative distances of the galaxy and QSO, this QSO is a particularly good candidate for observing dramatic transient gravitational lensing phenomena due to halo stars in the foreground galaxy.

Stocke, J. T.↗
NASA NTRS1972

Soft X-rays from Cygnus X-2 and from Cygnus X-1 /in eclipse/.

Observations of Cygnus X-1 (probably in eclipse) and Cygnus X-2 on Oct. 23, 1971, show quite low absorption in their spectrum, and yet they are thought to be in a double or multiple star system from the optical data. The lack of intrinsic absorption in their spectra may be taken to mean that they lie sufficiently far from their primaries for a reduction to virtually zero of their interaction with the atmosphere of the primaries.

Stevens, J. C.↗
NASA NTRS1983

Analysis of 12-700 micron reflectance spectra of three optical black samples

Normal incidence, specular reflectance spectra of three samples of optical black coatings have been measured in 10 filter passbands at effective wavelengths between 12 and 700 microns. Strong absorption, due to amorphous silicate material in the coatings, is found in the 15-50 micron region of each spectrum. Reflecting-layer model calculations are fitted by a nonlinear least-squares routine to the spectra at wavelengths beyond the absorption band to determine far-infrared optical parameters. It is found that, with a similar wavelength dependence, the absorption coefficient of a new black coating (ECP 2200) made by the Minnesota Mining and Manufacturing Company (3M) is less than 1/10 that of the discontinued coating, 3M Black Velvet Nextel. It is also shown that the extinction effect of a very rough substrate is negligible compared with the effects of increased upper surface roughness and coating thickness attendant upon fully covering a very rough substrate.

Smith, S. M.↗
NASA NTRS2006

A Fast Infrared Radiative Transfer Model for Overlapping Clouds

A fast infrared radiative transfer model (FIRTM2) appropriate for application to both single-layered and overlapping cloud situations is developed for simulating the outgoing infrared spectral radiance at the top of the atmosphere (TOA). In FIRTM2 a pre-computed library of cloud reflectance and transmittance values is employed to account for one or two cloud layers, whereas the background atmospheric optical thickness due to gaseous absorption can be computed from a clear-sky radiative transfer model. FIRTM2 is applicable to three atmospheric conditions: 1) clear-sky, 2) single-layered ice or water cloud, and 3) two simultaneous cloud layers in a column (e.g., ice cloud overlying water cloud). Moreover, FIRTM2 outputs the derivatives (i.e., Jacobians) of the TOA brightness temperature with respect to cloud optical thickness and effective particle size. Sensitivity analyses have been carried out to assess the performance of FIRTM2 for two spectral regions, namely the longwave (LW) band (587.3 - 1179.5/cm) and the short-to-medium wave (SMW) band (1180.1 - 2228.9/cm). The assessment is carried out in terms of brightness temperature differences (BTD) between FIRTM2 and the well-known discrete ordinates radiative transfer model (DISORT), henceforth referred to as BTD (F-D). The BTD (F-D) values for single-layered clouds are generally less than 0.8 K. For the case of two cloud layers (specifically ice cloud over water cloud), the BTD(F-D) values are also generally less than 0.8 K except for the SMW band for the case of a very high altitude (>15 km) cloud comprised of small ice particles. Note that for clear-sky atmospheres, FIRTM2 reduces to the clear-sky radiative transfer model that is incorporated into FIRTM2, and the errors in this case are essentially those of the clear-sky radiative transfer model.

Niu, Jianguo↗
NASA NTRS1973

ERTS-1 Virgin Islands experiment 589: Determine boundaries of ERTS and aircraft data within which useful water quality information can be obtained

The author has identified the following significant results. The boundaries of application of ERTS-1 and aircraft data are established for St. Thomas harbor within which useful water quality information can be obtained. In situ physical, chemical, and biological water quality and benthic data were collected. Moored current meters were employed. Optical measurements of solar irradiance, color test panel radiance and water absorption were taken. Procedures for correlating in situ optical, biological, and chemical data with underflight aircraft I2S data and ERTS-1 MSS scanner data are presented. Comparison of bulk and precision CCT computer printout data for this application is made, and a simple method for geometrically locating bulk data individual pixels based on land-water interface is described. ERTS spacecraft data and I2S aircraft imagery are correlated with optical in situ measurements of the harbor water, with the aircraft green photographic and ERTS-1 MSS-4 bands being the most useful. The biological pigments correlate inversely with the optical data for inshore areas and directly further seaward. Automated computer data processing facilitated analysis.

Coulbourn, W. C.↗
NASA NTRS1987

Nonlinear absorption in AlGaAs/GaAs multiple quantum well structures grown by metalorganic chemical vapor deposition

This paper reports the study of growth conditions for achieving the sharp exciton resonances and low-intensity saturation of these resonances in AlGaAs-GaAs multiple quantum well structures grown by metalorganic chemical vapor deposition. Low growth temperature is necessary to observe this sharp resonance feature at room temperature. The optimal growth conditions are a tradeoff between the high temperatures required for high quality AlGaAs and low temperatures required for high-purity GaAs. A strong optical saturation of the excitonic absorption has been observed. A saturation density as low as 250 W/sq cm is reported.

Lee, H. C.↗
NASA NTRS2007

Weathering of Thermal Control Coatings

Spacecraft radiators reject heat to their surroundings. Radiators can be deployable or mounted on the body of the spacecraft. NASA's Crew Exploration Vehicle is to use body mounted radiators. Coatings play an important role in heat rejection. The coatings provide the radiator surface with the desired optical properties of low solar absorptance and high infrared emittance. These specialized surfaces are applied to the radiator panel in a number of ways, including conventional spraying, plasma spraying, or as an applique. Not specifically designed for a weathering environment, little is known about the durability of conventional paints, coatings, and appliques upon exposure to weathering and subsequent exposure to solar wind and ultraviolet radiation exposure. In addition to maintaining their desired optical properties, the coatings must also continue to adhere to the underlying radiator panel. This is a challenge, as new composite radiator panels are being considered as replacements for the aluminum panels used previously. Various thermal control paints, coatings, and appliques were applied to aluminum and isocyanate ester composite coupons and were exposed for 30 days at the Atmospheric Exposure Site of the Kennedy Space Center s Beach Corrosion Facility for the purpose of identifying their durability to weathering. Selected coupons were subsequently exposed to simulated solar wind and vacuum ultraviolet radiation to identify the effect of a simulated space environment on the as-weathered surfaces. Optical properties and adhesion testing were used to document the durability of the paints and coatings. The purpose of this paper is to present the results of the weathering testing and to summarize the durability of several thermal control paints, coatings, and appliques to weathering and postweathering environments.

Jaworske, Donald A.↗