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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Rotational relaxation measurements in ozone - Temperature and collision partner effects

Time-resolved infrared double resonance experiments have been conducted on ozone mixtures in order to determine rotational relaxation rates. A pulsed CO2 laser pumps a nu(3)-ground state transition, while a diode laser is tuned to a hot band transition so that the relaxation process in nu(3) = 1 may be observed. Nitrogen, oxygen, rare gas, and self-relaxation rates have been measured, and the temperature dependence of these rates has been investigated over the 200-300 K range.

Flannery, C. C.↗
NASA NTRS1992

Infrared absorption-coefficient data on SF6 applicable to atmospheric remote sensing

Spectral absorption coefficients, k(nu)/cm per atm, of SF6 have been measured in the central Q-branches of the nu(3)-fundamental at 947/cm at various temperature-pressure combinations representing tangent heights in solar-occultation experiments or layers in the atmosphere. The data obtained with the Doppler-limited spectral resolution (about 0.0001/cm) of a tunable-diode laser spectrometer are useful in the atmospheric remote sensing of this trace gas.

Varanasi, P.↗
NASA NTRS1992

Odd oxygen formation in the laser irradiation of O2 at 248 nm - Evidence for reactions of O2 in the Herzberg states with ground state O2

Two O3 formation processes (initiation and autocatalytic) are studied in pure O2 and in O2+N2 and O2+Ar mixtures at pressures between 200 and 1600 torr and at temperatures between 298 and 370 K. Evidence is presented that the initiation process produces O3 through chemical reactions between ground state O2 and excited O2 in the Herzberg states, which are produced by the photoabsorption of O2 at 248 nm. For the autocatalytic process, the results are consistent with the proposal that the O3 formation is accelerated by photodissociating vibrationally excited O2(nu), produced in the photolysis of O3 following its initial formation. It is argued that the O2 Herzberg states and O2(nu) may play important roles in the odd oxygen chemistry in the middle atmosphere. It is estimated that the O2(A3Sigma-u(+))+O2 reaction may yield up to about 6 percent of the total odd oxygen production rate near 50 km.

Shi, Jichun↗
NASA NTRS1992

Noise in Josepson effect mixers and the RSJ model

Josephson effect mixers have previously been observed to display 'excess' noise both in experiments with point contacts and in numerical simulations using the resistively shunted junction (RSJ) model. This excess noise causes the mixer noise temperature to be a factor of typically 20-100 times the physical temperature of the device. Previously, this excess was ascribed to conversion from unwanted sidebands of the local oscillator and Josephson frequencies and their harmonics. Our numerical modeling of the RSJ equations has led to a new understanding of the excess noise, which is simply due to the intrinsic Josephson oscillations of the device. In addition, we have extended the modeling to include the previously ignored case of finite device capacitance (i.e. RSJ capacitance parameter beta(sub c) does not equal 0, which is more realistic for lithographically defined Josephson such as shunted tunnel junctions or SNS bridges. For some cases, this yields an improvement of a factor of two in noise temperature from the zero capacitance models. We will discuss the device parameters which optimize the mixer performance for frequencies approaching the characteristic frequency of the device, which is given by the Josephson frequency at the I(sub c)R(sub n) voltage (nu = 2eI(sub c)R(sub n)/h). These modeling results predict good conversion efficiency and a noise temperature within a factor of a few of the physical temperature. Experiments are in progress to determine the accuracy of this modeling using a waveguide mixer at 100 GHz with optimized, resistively shunted Nb tunnel junctions. If the modeling results are valid, they are particularly encouraging for mixers in the submillimeter regime, given the possibility of obtaining non-hysteretic Josephson devices with I(sub c)R(sub n) products in excess of a millivolt, using for instance, high-T(sub c) SNS bridges. We discuss the modifications to the classical RSJ model which are necessary in the quantum regime (h nu greater than kT), and conclude the Josephson mixers may attain noise temperatures less than ten times the quantum limit at high frequencies.

Schoelkopf, R.↗
NASA NTRS1992

An investigation of the isotropy of epoxy polymers

Measurements of the engineering constants E, G, and nu are routinely made for polymeric materials. If these materials are isotropic, these measurements should satisfy the relationship G = E/2(1 nu). However, many past measurements have indicated that this relationship is not satisfied. This raises questions about the assumptions of material isotropy and the applicability of Hooke's law. The methods used to measure these engineering constants for a number of different polymers are first described. Then, new results obtained in the current investigation are presented, indicating that the elastic constants do in fact satisfy the isotropic relationship for strains up to 0.5 percent. However, it is shown that at strain levels above this level, the relationship between stress and strain is nonlinear.

Odom, Edwin M.↗
NASA NTRS1991

The role of valence-band excitation in laser ablation of KCl

We present recent measurements of excited-atom and ion emission from KCl surfaces illuminated by vacuum-ultraviolet synchrotron radiation (h-nu = 8-28 eV) and ultraviolet laser light (h-nu = 4 eV). At low intensities characteristic of the synchrotron experiments, excited atoms are desorbed by simple valence-band excitation process involving the metallization of the KCl surface. At the higher intensities typical of laser desorption and ablation, we observe a strong decrease in K emission as a function of the number of laser shots, but an essentially constant yield of Cl. K(+) and Cl(-) emission at high intensities show similar behavior. The energetics of these desorption phenomena can be treated in a bond-orbital model which shows that creation of a single valence hole is sufficient to excite an ion to an anti-bonding state.

Haglund, Richard F., Jr.↗
NASA NTRS1993

The spectrum and variability of radio emission from AE Aquarii

The first detections of the magnetic cataclysmic variable AE Aquarii at millimeter wavelengths are reported. AE Aqr was detected at wavelengths of 3.4 and 1.25 mm. These data are used to show that the time-averaged spectrum is generally well fitted by a power law S(nu) varies as nu exp alpha, where alpha is approximately equal to 0.35-0.60, and that the power law extends to millimeter wavelengths, i.e., the spectral turnover is at a frequency higher than 240 GHz. It is suggested that the spectrum is consistent with that expected from a superposition of flarelike events where the frequency distribution of the initial flux density is a power law f (S0) varies as S0 exp -epsilon, with index epsilon approximately equal to 1.8. Within the context of this model, the high turnover frequency of the radio spectrum implies magnetic field strengths in excess of 250 G in the source.

Abada-Simon, Meil↗
NASA NTRS1993

Circularly polarized radio emission from the T Tauri star Hubble 4

Multiwavelength VLA observations of the weak-lined T Tauri star (WTTS) Hubble 4, which is located in the nearby (about 140 pc) Taurus-Auriga star-forming region, are reported. The emission is characterized by a nearly flat spectral energy distribution with a spectral index of 0 (S sub nu varies as nu exp alpha). Right circular polarization was detected at both 3.6 and 6 cm at levels of 19 +/- 5 percent and 18 +/- 3 percent, respectively, with an upper limit of not more than 15 percent (3 sigma) at 20 cm. The star was in a state of low radio activity, with flux densities of 1.3-1.7 mJy and a radio luminosity of 10 exp 16.5 ergs/Hz s. The unambiguous detection of circularly polarized radio emission from Hubble 4 provides direct evidence for the existence of ordered magnetic fields in this WTTS.

Skinner, Stephen L.↗
NASA NTRS1993

Infrared spectroscopic measurements relevant to atmospheric remote sensing

SF6 is a synthetic chemical which is used in many industrial applications and as a meteorological tracer. This paper describes determinations of spectral absorption coefficients k-nu of SF6 measured in the central Q-branches of the nu(3)-fundamental at 947/cm at various temperature-pressure combinations representing tangent heights in solar-occultation experiments or layers in the atmosphere. Spectral data were also obtained for C2H4 and NH3 fundamental bands. Measurements were made with the Doppler-limited spectral resolution of a tunable diode laser spectrometer with a cryogenically cooled absorption cell, described by Varanasi and Chudamani (1992).

Varanasi, Prasad↗
NASA NTRS1956

Review of experimental investigations of liquid-metal heat transfer

Experimental data of various investigators of liquid-metal heat-transfer characteristics were reevaluated using as consistent assumptions and methods as possible and then compared with each other and with theoretical results. The reevaluated data for both local fully developed and average Nusselt numbers in the turbulent flow region were found still to have considerable spread, with the bulk of the data being lower than predicted by existing analysis. An equation based on empirical grounds which represents most of the fully developed heat-transfer data is nu = 0.625 pe(0.4) where nu represents the Nusselt number and pe the Peclet number. The theoretical prediction of the heat transfer in the entrance region was found to give lower values, in most cases, than those found in the experimental work.

Lubarsky, Bernard↗
NASA NTRS1994

Radio and optical emission: Spectral shapes and breaks in GRB

Relativistic blast wave models of Gamma Ray Bursts (GRB) predict the spectrum of the emitted synchrotron radiation. The electrons in the shocked region are heated to a Wien distribution whose 'temperature' is 1/3 of the mean electron energy. This energy determines a characteristic (break) frequency of synchrotron radiation. At much lower frequencies, a spectrum F(sub nu) varies as nu(sup 1/3) is predicted independently of the details of the emitting region. This is consistent with the observed soft x ray emission of GRB. It implies low visible and radio intensities, unless there are collective emission processes.

Katz, J. I.↗
NASA NTRS1994

Scaling, elasticity, and CLPT

The first few viewgraphs describe the general solution properties of linear elasticity theory which are given by the following two statements: (1) for stress B.C. on S(sub sigma) and zero displacement B.C. on S(sub u) the altered displacements u(sub i)(*) and the actual stresses tau(sub ij) are elastically dependent on Poisson's ratio nu alone: thus the actual displacements are given by u(sub i) = mu(exp -1)u(sub i)(*); and (2) for zero stress B.C. on S(sub sigma) and displacement B.C. on S(sub u) the actual displacements u(sub i) and the altered stresses tau(sub ij)(*) are elastically dependent on Poisson's ratio nu alone: thus the actual stresses are given by tau(sub ij) = E tau(sub ij)(*). The remaining viewgraphs describe the minimum parameter formulation of the general classical laminate theory plate problem as follows: The general CLT plate problem is expressed as a 3 x 3 system of differential equations in the displacements u, v, and w. The eighteen (six each) A(sub ij), B(sub ij), and D(sub ij) system coefficients are ply-weighted sums of the transformed reduced stiffnesses (bar-Q(sub ij))(sub k); the (bar-Q(sub ij))(sub k) in turn depend on six reduced stiffnesses (Q(sub ij))(sub k) and the material and geometry properties of the k(sup th) layer. This paper develops a method for redefining the system coefficients, the displacement components (u,v,w), and the position components (x,y) such that a minimum parameter formulation is possible. The pivotal steps in this method are (1) the reduction of (bar-Q(sub ij))(sub k) dependencies to just two constants Q(*) = (Q(12) + 2Q(66))/(Q(11)Q(22))(exp 1/2) and F(*) - (Q(22)/Q(11))(exp 1/2) in terms of ply-independent reference values Q(sub ij); (2) the reduction of the remaining portions of the A, B, and D coefficients to nondimensional ply-weighted sums (with 0 to 1 ranges) that are independent of Q(*) and F(*); and (3) the introduction of simple coordinate stretchings for u, v, w and x,y such that the process is neatly completed.

Brunelle, Eugene J.↗
NASA NTRS1995

Algebraic theory of molecules

An algebraic formulation of quantum mechanics is presented. In this formulation, operators of interest are expanded onto elements of an algebra, G. For bound state problems in nu dimensions the algebra G is taken to be U(nu + 1). Applications to the structure of molecules are presented.

Iachello, Franco↗
NASA NTRS1994

Second-order closure PBL model with new third-order moments: Comparison with LES data

This paper contains two parts. In the first part, a new set of diagnostic equations is derived for the third-order moments for a buoyancy-driven flow, by exact inversion of the prognostic equations for the third-order moment equations in the stationary case. The third-order moments exhibit a universal structure: they all are a linear combination of the derivatives of all the second-order moments, bar-w(exp 2), bar-w theta, bar-theta(exp 2), and bar-q(exp 2). Each term of the sum contains a turbulent diffusivity D(sub t), which also exhibits a universal structure of the form D(sub t) = a nu(sub t) + b bar-w theta. Since the sign of the convective flux changes depending on stable or unstable stratification, D(sub t) varies according to the type of stratification. Here nu(sub t) approximately equal to wl (l is a mixing length and w is an rms velocity) represents the 'mechanical' part, while the 'buoyancy' part is represented by the convective flux bar-w theta. The quantities a and b are functions of the variable N(sub tau)(exp 2), where N(exp 2) = g alpha derivative of Theta with respect to z and tau is the turbulence time scale. The new expressions for the third-order moments generalize those of Zeman and Lumley, which were subsequently adopted by Sun and Ogura, Chen and Cotton, and Finger and Schmidt in their treatments of the convective boundary layer. In the second part, the new expressions for the third-order moments are used to solve the ensemble average equations describing a purely convective boundary laye r heated from below at a constant rate. The computed second- and third-order moments are then compared with the corresponding Large Eddy Simulation (LES) results, most of which are obtained by running a new LES code, and part of which are taken from published results. The ensemble average results compare favorably with the LES data.

Canuto, V. M.↗
NASA NTRS1994

Is H20 present on Io? The detection of a new strong band near 3590/cm (2.79 micrometer)

A strong absorption band at 3590 +/- 20/cm (2.790 +/- 0.015 microns) has been discovered in the spectrum of Io using the Kuiper Airborne Observatory (KAO). The 2 nu(sub 1) + nu(sub 3) comination mode of solid SO2 falls at this position. Since SO2 is abundant on Io it must contribute to the new band. However, a band due to H2O was predicted near this frequency in Io's spectrum based on laboratory experiments of H2O:SO2 mixed Io ice analogs which were used to assign the two weak, variable features at 3370 and 3170/cm (2.97 and 3.15 microns) to trace amounts of H2O frozen in solid SO2 on Io. The new band probably originates from both SO2 and H2O. Unfortunately, the spectral resolution of the data is insufficient to settle the issue of whether there are two resolvable components.

Salama, F.↗
NASA NTRS1994

The hidden nuclear spectrum of the luminous IRAS source FSC 10214+4724

Optical spectropolarimetry of the luminous IRAS source FSC 10214+4724 (z=2.286) reveals that the strong (approximately 17%) linear polarization detected by Lawrence et al. is shared by both the narrow ultraviolet (UV) emission lines and the underlying continuum. This observation and the brightness of the source rule out synchrotron emission and dichroic extinction by dust as the polarizing mechanism, leaving scattering as the only plausible cause of the polarized emission. The narrowness of the lines requires that the scatterers be dust grains or cool (below 1.6 x 10(exp 4) K) electrons. We can recover the spectrum that is incident on the scattering medium provided we make some reasonable assumptions regarding the source geometry. The scattered UV spectrum has a power-law index alpha of -1.2 plus or minus 0.6 (F(sub nu) varies as nu(sup alpha)), steeper than would be expected from a young burst of star formation but similar to that of many active galactic nucleus (AGNs).

Jannuzi, Buell T.↗
NASA NTRS1994

Coherent-phase or random-phase acceleration of electron beams in solar flares

Time structures of electron beam signatures at radio wavelengths are investigated to probe correlated versus random behavior in solar flares. In particular we address the issue whether acceleration and injection of electron beams is coherently modulated by a single source, or whether the injection is driven by a stochastic (possibly spatially fragmented) process. We analyze a total of approximately = 6000 type III bursts observed by Ikarus (Zurich) in the frequency range of 100-500 MHz, during 359 solar flares with simultaneous greater than or = 25 keV hard X-ray emission, in the years 1890-1983. In 155 flares we find a total of 260 continuous type III groups, with an average number of 13 +/- 9 bursts per group, a mean duration of D = 12 +/- 14 s, a mean period of P = 2.0 +/- 1.2 s, with the highest burst rate at a frequency of nu = 310 +/- 120 MHz. Pulse periods have been measured between 0.5 and 10 s, and can be described by an exponential distribution, i.e., N(P) varies as e (exp -P/1.0s). The period shows a frequency dependence of P(nu)=46(exp-0.6)(sub MHz)s for different flares, but is invariant during a particular flare. We measure the mean period P and its standard deviation sigma (sub p) in each type III group, and quantify the degree of periodicity (or phase-coherence) by the dimensionless parameter sigma (sub p)P. The representative sample of 260 type III burst groups shows a mean periodicity of sigma (sub p/P) = 0.37 +/- 0.12, while Monte Carlo simulations of an equivalent set of truly random time series show a distinctly different value of sigma (sub p)P = 0.93 +/- 0.26. This result indicates that the injection of electron beams is coherently modulated by a particle acceleration source which is either compact or has a global organization on a timescale of seconds, in contrast to an incoherent acceleration source, which is stochastic either in time or space. We discuss the constraints on the size of the acceleration region resulting from electron beam propagation delays and from Alfvenic synchronization during a pulse period. We discuss two periodic preocesses in flares, which potentially control quasi-periodic particle acceleration: (1) MHD oscillations, and (2) current sheets with oscillatory dynamics.

Aschwanden, Markus J.↗