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At least 631 records · Page 35

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NASA NTRS1977

Petrology of Apollo 15 black-and-white rocks 15445 and 15455 - Fragments of the Imbrium impact melt sheet

The paper describes two macroscopically similar black-and-white rocks, 15445 and 15455, which were collected from the rim of Spur Crater on the Apennine Front. The two Apollo 15 rocks are very similar in chemistry and clast population, but the matrix of 15455 is finer grained than that of 15445. The 15445 sample contains a lithic clast assemblage of plutonic/metamorphic spinel troctolite, troctolite, norite, and anorthosite, and its fine-grained vesicular black coherent matrix consists of a melt-bonded aggregate of small mineral clasts which are mainly olivine, plagioclase, and pink spinel. The two rocks are distinct from any other large samples from the Apollo 15 site. It is suggested that the rocks are samples of an impact melt sheet which forms a bedrock unit of the Apennine Front, and that this melt sheet did not form in a local small-scale event but was produced during the Imbrium impact event.

Ryder, G.↗

NASA NTRS1977

Impact conditions required for formation of melt by jetting in silicates

It is demonstrated that the process of jetting which occurs when particles collide at oblique angles may produce melt at much lower velocities than are required for melt production in head-on collisions. The minimum velocities of impact required for jetting in aluminum, bronzitite, dunite, and quartz are calculated by the method of shock polars. The analysis, which depends on stated assumptions about attained pressures and the occurrence of jetting, uses shock-velocity particle-velocity equations of state with three shock regimes. The treatment indicates that jetting should arise in bronzitite, dunite, and quartz at relative velocities as low as 1-2 km/sec. At such velocities material which passes near the stagnation point in the jet-forming region is subjected to sufficiently high pressures so that it is probably melted.

Kieffer, S. W.↗

NASA NTRS1975

Thermal regimes in impact melts and the petrology of the Apollo 17 Station 6 boulder

A progress report is presented on the petrologic study of the Station 6 boulder, taking into account the implications of its petrographic and geochemical studies to the understanding of the processes of formation and crystallization of impact melts. The interpretation of the data from the boulder suggests processes that appear reasonable for a petrogenetic model of impact events large enough to produce a layer of melt a kilometer or more wide and at most a few tens of meters thick. A summary of the model is presented. The primary difference between the new model and the previous models of Warner et al. (1973, 1974) and Simonds et al. (1973, 1974) is that melt and clasts are derived from distinctly different parts of the cratering regime. The cooling is modeled in two steps, first the rapid equilibration between clasts and matrix, and second, the much slower loss of heat to the surroundings.

Simonds, C. H.↗

NASA NTRS1980

Thermodynamic and melting properties of RDX at elevated pressures

The laboratory set up for determination of melting and thermodynamic properties of RDX using a diamond anvil cell apparatus capable of pressures exceeding 10 kbar and 250 C is described. The slope of the melting temperature versus applied pressure curve for RDX, as determined in the diamond cell, was found to equal 4.09 + or - 0.6 C (kbar). The density of liquid RDX at its melting point was calculated from this slope to be approximately 1.63 gm/cu cm. Practical and theoretical considerations in using the diamond anvil cell to generate thermodynamic data on RDX are discussed.

Carlson, D. W.↗

NASA NTRS1982

Segregation during directional melting and its implications on seeded crystal growth: A theoretical analysis

Directional melting of binary systems, as encountered during seeding in melt growth, is analyzed for concurrent compositional changes at the crystal-melt interface. It is shown that steady state conditions cannot normally be reached during seeding and that the growth interface temperature at the initial stages of seeded growth is a function of backmelt conditions. The theoretical treatment is numerically applied to Hg1-xCdXTe and Ga-doped Ge.

Bourret, E. D.↗

NASA NTRS1982

The partitioning of Zr and Nb between diopside and melts in the system diopside-albite-anorthite

The crystal/liquid distribution coefficient for Zr between diopside and melt is measured for six compositions and three temperatures in the diopside field of Di-Ab-An, and the distribution coefficient for Nb is measured for three of these compositions. Nb is found to be excluded from diopside, while D(Zr), which is defined as wt % ZrO2 in crystals/wt % ZrO2 in melt, is variable and ranging from 0.05 to 0.45. D(Zr) is positively correlated with the Al content of both the melt and the pyroxene, and is negatively correlated with temperature. Both D(Zr) and D(Nb) are independent of oxygen fugacity, which implies that neither Zr nor Nb suffer valence changes over a range of oxygen fugacities spanning lunar and terrestrial conditions.

Dunn, T.↗

NASA NTRS1984

Melt-Level Sensing in Silicon-Web Groowth

Laser beam reflected from silicon-melt surface onto position detector to monitor melt level during web growth. Silicon web production increased by synchronizing silicon melt replenishment with web growth rate.

Duncan, C. S.↗

NASA NTRS1982

Sulfide saturation of basalt and andesite melts at high pressures and temperatures

When the sulfur content of an Fe-bearing magma exceeds the saturation limit for the bulk composition, an immiscible iron sulfide melt fraction separates. For an understanding of the geochemistry of sulfur-bearing magmatic systems, more information is needed regarding the solubility of metal sulfide in silicate melt at its source and the solubility changes as a function of changing intensive and extensive variables. In the present investigation, the sulfur saturation surface is determined for the pressure range from 12.5 to 30 kbar and the temperature range from 1300 to 1460 C for three silicate melt compositions representing a range of SiO2 and FeO compositions.

Wendlandt, R. F.↗

NASA NTRS1985

Improved Melt-Level Control System

Laser feedback control automatically maintains silicon melt levels. During long-term growth of dendritic-web silicon, silicon melt level controlled and held nearly constant using laser feedback system to sense level of melt and control silicon-pellet feed rate.

Meier, D. L.↗

NASA NTRS1983

Dissipative melting as a mechanism for core formation

Cosmochemical studies strongly favor a near-homogeneous accretion of the earth. These studies also show that core segregation probably occurred within the first 100,000 years of earth history. Mechanisms of core formation have received relatively little attention. The principal purpose of this paper is to examine dissipative melting as a possible mechanism for core segregation. For a large iron body migrating through the mantle, the potential energy lost by the body is dissipated by frictional heating. If the body has a radius greater than about 30 km, the frictional heating is sufficient to melt a path through which the body can fall. If the iron body is liquid (as expected) with a low viscosity, it would penetrate the mantle as a diapir. The problem of an immiscible liquid body melting its way through a solid is solved, and a family of diapir shapes is obtained. It is found that dissipative heating may be a viable mechanism for core segregation if sufficiently large bodies of liquid iron can form.

Turcotte, D. L.↗

NASA NTRS1984

Rapid solidification via melt spinning - Equipment and techniques

One of the simpler methods available to accomplish rapid solidification processing is free jet melt spinning. With only a modest expenditure of time, effort, and capital, an apparatus suitable for preliminary experimentation can be assembled. Wheel and crucible materials, process atmospheres, crucible design, heating methods, and process parameters and their relationship to melt composition are described. Practical solutions to processing problems, based on 'hands-on' experience, are offered. Alloys with melting points up to 3000 F have been rapidly solidified using the techniques described.

Jech, R. W.↗

NASA NTRS1984

Ring torque on Janus and the melting of Enceladus

The absence of craters noted on Voyager 2 images of Encedalus indicates geologically recent resurfacing, probably due to internal melting; heating mechanism calculations, however, yield heating rates too small to cause melting. If Janus, whose orbital mean motion is currently decreasing as Janus' orbit evolves outward due to resonant torques from Saturn's rings, were ever to become locked into a stable 2:1 orbital commensurability with Encedalus, the resulting angular momentum transfer could have sufficiently enhanced the eccentricity of Encedalus' orbit for the ensuing tidal heating to have melted Encedalus' interior. However, the predicted rapid time scale for ring evolution due to resonant torques from Saturn's inner moons remains a major problem.

Lissauer, J. J.↗

NASA NTRS1984

An electromotive force series in a borosilicate glass-forming melt

An electromotive force series for redox couples was defined as a function of oxygen fugacity in a borosilicate melt at 1150 C. The resulting order of relative reduction potentials can be used to estimate the amounts of redox species in glass during processing. The electromotive force series in this melt is comparable to those in other silicate glass-forming melts and in aqueous systems but differs in detail because of interaction of the solvents with individual redox couples.

Schreiber, H. D.↗

NASA NTRS1984

Hot melt adhesive attachment pad

A hot melt adhesive attachment pad for releasably securing distinct elements together is described which is particularly useful in the construction industry or a spatial vacuum environment. The attachment pad consists primarily of a cloth selectively impregnated with a charge of hot melt adhesive, a thermo-foil heater, and a thermo-cooler. These components are securely mounted in a mounting assembly. In operation, the operator activates the heating cycle transforming the hot melt adhesive to a substantially liquid state, positions the pad against the attachment surface, and activates the cooling cycle solidifying the adhesive and forming a strong, releasable bond.

Fox, R. L.↗

NASA NTRS1985

Crystal Melts Under Reduced Gravity

To date, fluid motion due to thermocapillary convection and centrifugal buoyancy has been studied theoretically and numerically, by adapting specialized programs for rotating viscous fluids. It has been shown that by rotating the crystal melt, thermocapillary flow can be confined to a thin layer at the melt-gas interface even when the interfacial velocity is large enough for non-linear effects to be important. Theoretical analysis of the basic processes proceeds, but a much larger effort is now being devoted to the numerical simulation of the actual motion in a rotating crystal melt. A numerical program is under development for the study of the fully nonlinear problem. Although the flow is viewed, to start, as one of rapid rotation (in order that certain boundary layer simplifications can be invoked), a more general approach will allow consideration of the situations and conditions of real practical interest.

Greenspan, H. P.↗

NASA NTRS1985

Containerless Processing of Undercooled Melts

The physical mechanisms controlling liquid undercooling were studied for application to solidification processing methods. The undercooling potential of containerless processing was assessed on droplet samples of high melting temperature metals drop tube and drop tower facilities and in a laboratory-scale apparatus. New insight into nucleation and crystal growth will be obtained in undercooled liquids of high melting temperature iron and nickel-base systems. The processing parameters include melt superheat, droplet size and particle statistics and droplet surface coating. The solidification behavior is determined by thermal analysis and by structural and metallographic characterization.

Perepezko, J. H.↗

NASA NTRS1985

Concentrations and behavior of oxygen and oxide ion in melts of composition CaO.MgO.xSiO2

The behavior of oxygen and oxide ion in silicate melts was investigated through their electrochemical reactions at a platinum electrode. Values are given for the diffusion coefficient for molecular oxygen in diopside melt and the activation energy of diffusion. It is shown that molecular oxygen dissociates prior to undergoing reduction and that oxide ion reacts quickly with silicate polymers when it is produced. The concentration of oxide ion is kept low by a buffering effect of the silicate, the exact level being dependent on the silicate composition. Data on the kinetics of reaction of the dissociation of molecular oxygen and on the buffering reactions are provided. It is demonstrated that the data on oxygen in these silicate melts are consistent with those for solid buffers.

Semkow, K. W.↗

NASA NTRS1986

Dynamic crystallization of chondrule melts of porphyritic and radial pyroxene composition

Dynamic crystallization experiments in which heterogeneous nucleation is an important variable have been completed on four melts of chondrule composition. Compositions were chosen to best represent chondrules with porphyritic pyroxene and radial pyroxene textures. Experimental results show that heterogeneous nucleation is essential for the formation of porphyritic textures. Without preexisting nuclei, too much supercooling is established before crystallization is initiated and the textures are more likely to be dendritic or radial. In the near total absence of nuclei, radial textures can form at cooling rates as slow as 5 C/hr in this study. By varying the heterogeneous nucleation conditions and having a melt in which the appropriate phases are stable or metastable, analogs to most of the recognized chondrule textures can be produced in a single melt composition.

Lofgren, G.↗