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At least 631 records · Page 35

Compressor Station Differential Risk Assessment for Hydrogen and Natural Gas Blends

Blending hydrogen into existing natural gas pipelines is a current initiative for large-scale hydrogen deployment in the United States. Understanding changes in hazards and risk for fuel blends can help inform regulations. A differential risk assessment was conducted to understand how the safety profile of fires and unignited flammable plumes of leaking fuel would change based on blend composition. The area affected by harmful heat fluxes from jet fires was found to be larger for blends with more natural gas in them, while the distance affected by unignited flammable fuel concentrations was found to be larger for blends with more hydrogen in them. Component leak frequencies and ignition probabilities greatly impact both heat flux risk and the flammable plume risk. The collection of additional blend-specific industry data could help understand which assumptions are most valid to make when calculating risk.

08 HYDROGEN↗

MR13A-3183: Microbial and Geochemical Characterization of Groundwater: Implications for Underground Hydrogen Storage Leakage

Underground hydrogen storage (UHS) in geological formations is a key element of the clean energy transition as it enables the decarbonization of the transportation and industrial sectors by decoupling hydrogen production and storage. UHS has many benefits, including low cost, much wider availability, large storage capacity, well-established infrastructure, and increased safety because of geological sealing capabilities. However, the impact of hydrogen (H2) biogeochemical interactions in the presence of subsurface microorganisms is largely neglected from UHS perspectives. These interactions might affect the effectiveness of storage and can even cause H2 to leak into the shallow aquifers. Leakage of H2 into groundwater can change the geochemistry and induce several microbial-driven processes. Microorganisms, such as sulfate-reducers, are naturally abundant in groundwater and consume H2 to produce hydrogen sulfide (H2S), which can contaminate the freshwater drinking groundwater and cause damage to infrastructure. Hydrogen leakage can also trigger microbial reactions responsible for metal mobility, which can impact the water quality. However, the kinetics of these reactions and the temporal impact of hydrogen leakage in groundwater are still unknown. Therefore, a time series hydrogen-groundwater interaction experiment was conducted, and the changes in fluid chemistry and headspace gas composition will be analyzed along with DNA sequencing results to understand the extent and kinetics of biogeochemical reactions that occur if hydrogen leaks into groundwater. In the experiments, Ultra High Purity (UHP) hydrogen gas will be injected into glass vials with groundwater samples, for a designated time period. For each glass-sealed vial, 16S rRNA gene sequencing, IC, ICP-MS, and GC-TCD will be performed. The experiments provide insights into plausible impacts of hydrogen leakage into shallow drinking water aquifers.

Clark, Allison [West Virginia University (WVU)]↗

Technical Justifications for Outdoor Bulk Gaseous Hydrogen Storage Setback Distances

Setback distances define a prescribed distance between a potentially hazardous system and different types of other systems, people, buildings, or materials that may be exposed to that hazard. Riskinformed separation distances are not meant to completely eliminate risk, but rather to limit the risk to an acceptable level. A sensitivity study of risk suggested that a leak size of 3% of the pipe cross-sectional area would be a conservative but reasonable basis. Calculation of the setback distances for gaseous hydrogen was done in a deterministic manner, using a selected leak size and harm criteria for each group of exposures. Harm criteria have been updated to better reflect the exposure types under consideration, and to be consistent with setback distances for liquid hydrogen. The resulting setback distance values are primarily driven by radiative heat flux values for all exposure groups. For the typical pipe sizes, the setback distances slightly increase compared to the previous version of NFPA 2.

08 HYDROGEN↗

Quantum Enhanced Fiber Sensing for Oil and Gas Applications (Final Technical Report)

The major goal of the project was to develop a quantum sensing approach compatible with current infrastructure in the oil and gas industry that could provide a quantum enhancement, with a focus towards pipeline leak detection. The proposed approach to achieving this goal consisted of the use of quantum states of light to enhance the sensitivity of fiber optic sensors beyond the classical limit. To address the limitations of existing commercial leak detection, the project focused on the study of two technologies: distributed acoustic sensors (DAS) and fiber Bragg grating (FBG)-based sensors. The initial phase of the project centered around the identification and mitigation of dominant sources of classical noise to enable operation at the classical shot noise limit (SNL). The second phase focused on the use of quantum resources to obtain sensitivities beyond the classical SNL. The final phase sought to combine quantum noise reduction techniques with advanced dynamical classical noise cancelation approaches.

02 PETROLEUM↗

Assessing the release, transport, and retention of radioactive aerosols from hypothetical breaches in spent fuel storage canisters

Interim dry storage of spent nuclear fuel involves storing the fuel in welded stainless-steel canisters. Under certain conditions, the canisters could be subjected to environments that may promote stress corrosion cracking leading to a risk of breach and release of aerosol-sized particulate from the interior of the canister to the external environment through the crack. Research is currently under way by several laboratories to better understand the formation and propagation of stress corrosion cracks, however little work has been done to quantitatively assess the potential aerosol release. The purpose of the present work is to introduce a reliable generic numerical model for prediction of aerosol transport, deposition, and plugging in leak paths similar to stress corrosion cracks, while accounting for potential plugging from particle deposition. The model is dynamic (changing leak path geometry due to plugging) and it relies on the numerical solution of the aerosol transport equation in one dimension using finite differences. The model’s capabilities were also incorporated into a Graphical User Interface (GUI) that was developed to enhance user accessibility. Model validation efforts presented in this paper compare the model’s predictions with recent experimental data from Sandia National Laboratories (SNL) and results available in literature. We expect this model to improve the accuracy of consequence assessments and reduce the uncertainty of radiological consequence estimations in the remote event of a through-wall breach in dry cask storage systems.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Methane Quantification Performance of the Quantitative Optical Gas Imaging (QOGI) System Using Single-Blind Controlled Release Assessment

Quantitative optical gas imaging (QOGI) system can rapidly quantify leaks detected by optical gas imaging (OGI) cameras across the oil and gas supply chain. A comprehensive evaluation of the QOGI system’s quantification capability is needed for the successful adoption of the technology. This study conducted single-blind experiments to examine the quantification performance of the FLIR QL320 QOGI system under near-field conditions at a pseudo-realistic, outdoor, controlled testing facility that mimics upstream and midstream natural gas operations. The study completed 357 individual measurements across 26 controlled releases and 71 camera positions for release rates between 0.1 kg Ch 4 /h and 2.9 kg Ch 4 /h of compressed natural gas (which accounts for more than 90% of typical component-level leaks in several production facilities). The majority (75%) of measurements were within a quantification factor of 3 (quantification error of –67% to 200%) with individual errors between –90% and 831%, which reduced to –79% to +297% when the mean of estimates of the same controlled release from multiple camera positions was considered. Performance improved with increasing release rate, using clear sky as plume background, and at wind speeds ≤1 mph relative to other measurement conditions.

42 ENGINEERING↗

Orphaned oil and gas well methane emission rates quantified using Gaussian plume inversions of ambient observations

Abstract. Annually, ∼ 3.6 million abandoned oil and gas wells in the US emit a combined ∼ 2.6 Tg methane (CH4), adversely affecting climate and regional air quality. However, these estimates depend on emission factors derived from measuring subpopulations of wells that vary by orders of magnitude due to very limited field sampling and poorly characterized distributions. Currently, US protocols to remediate orphaned wells lacks standardized quantification methods needed to both prioritize plugging and account for emission reductions. Therefore, sensitive, reliable, affordable, and scalable CH4 flux quantification methods are needed. We report the use of a simple Gaussian plume method where the dispersion parameters are constrained by in situ ground measurements of CH4 concentration at four locations 7.5–49 m downwind of the orphan well as well as local winds to estimate the leak rate from an orphan well. We derive a flux of 10.53 ± 1.16 kg CH4 h−1 during a venting procedure in April 2023 that agrees with the directly measured volumetric flow rate of 9.00 ± 0.25 kg CH4 h−1. This is 71 % greater than the 5.3 kg CH4 h−1 flux measured 7 months prior. Additionally, we discovered a secondary leak through the surface casing inferred as 0.43–0.67 kg CH4 h−1 both by our ground Gaussian analysis and by transecting the plume with an uncrewed aerial system (UAS). We show that in situ determination of the dispersion parameters used in our Gaussian inversions allows us to measure methane emissions to 15 % accuracy, significantly reducing errors when compared to the standard practice of assuming stability class. Our results help develop simpler methods and protocols for robust orphan well emission quantification that can be used for reporting.

Follansbee, Emily↗

Gas flowmeter

Mass flowmeter measures rates of flow of all common gases from purges and collected leaks at leak ports. Without dependence on gravity, it measures rates between 5 and 650 cc/min with pressures ranging from 0.001 to 10 to the minus thirteenth torr at temperatures between 70 and 500 degrees K.

Morris, T. F.↗

Airbreathing nuclear propulsion: A new look

Nuclear-powered air-cushion vehicles using lightweight aircraft-type nuclear powerplants show promise of carrying transoceanic cargo at cost-per-metric-ton-kilometer (cost-per-ton-n mi) rates comparable to railroad rates. These rates are independent of the distance traveled. Cargo rates for nonstop distances of 4000 n mi are expected to be less than one-half those for similar fossil-fueled air-cushion vehicles. For 6000-n mi nonstop distances, the rates are expected to be less than one-sixth as much. There are no fundamental technical reasons why subsonic nuclear aircraft cannot be made to fly successfully if the gross weight is over 1 million lb. Public safety of airborne nuclear powerplants is receiving the greatest attention in low-level experimental and analytical investigations. Idealized model containment vessels which have been impacted on reinforced concrete showed no leaks after impact at velocities to 400 mph. The experiments indicate feasibility of impacting at speeds over 600 mph with no leaks.

Rom, F. E.↗

A solenoid failure detection system for cold gas attitude control jet valves

The development of a solenoid valve failure detection system is described. The technique requires the addition of a radioactive gas to the propellant of a cold gas jet attitude control system. Solenoid failure is detected with an avalanche radiation detector located in the jet nozzle which senses the radiation emitted by the leaking radioactive gas. Measurements of carbon monoxide leakage rates through a Mariner type solenoid valve are presented as a function of gas activity and detector configuration. A cylindrical avalanche detector with a factor of 40 improvement in leak sensitivity is proposed for flight systems because it allows the quantity of radioactive gas that must be added to the propellant to be reduced to a practical level.

Johnston, P. A.↗

Testing methods and techniques: Quality control and nondestructive testing: A complication

A variety of devices and techniques useful in nondestructive testing is described. Ranging in complexity from an automated ultrasonic testing system designed for complex laminated honeycomb structures, to a flexible leak detector probe, the items represent either potential savings in cost and time, or improvement in inspection quality over past techniques. Data cover weld and braze inspection, leak detection, and inspection of composite materials.

Source record↗

Examination of T-111 clad uranium nitride fuel pins irradiated up to 13,000 hours at a clad temperature of 990 C

The examination of 27 fuel pins irradiated for up to 13,000 hours at 990 C is described. The fuel pin clad was a tantalum alloy with uranium nitride as the nuclear fuel. Two nominal fuel pin diameters were tested with a maximum burnup of 2.34 atom percent. Twenty-two fuel pins were tested for fission gas leaks; thirteen pins leaked. Clad ductility tests indicated clad embrittlement. The embrittlement is attributed to hydrogen from an n,p reaction in the fuel. Fuel swelling was burnup dependent, and the amount of fission gas release was low, generally less than 0.5 percent. No incompatibilities between fuel, liner, and clad were in evidence.

Slaby, J. G.↗

Deployable pressurized cell structure for a micrometeoroid detector

This disclosure comprises a plurality of individual pressurized cells which are caused to leak in response to a micrometeoroid penetration, the leak being sensed by appropriate instrumentation. The plurality of cells may be rolled into a compact arrangement such that the volume of the micrometeoroid detector is small and therefore readily packed in a payload of a launch vehicle. Once the payload is placed in orbit, the rolled up cells can be released, pressurized and provide a relatively rigid, large surface area for detecting micrometeoroid penetration.

Kinard, W. H.↗

Study of multilayered insulation pipe penetration. Thermal acoustic oscillation

Tests were conducted to determine the net heat leak to a source of liquid nitrogen caused by a metal penetration through the blanket of multilayer insulation. The conditions under which the tests were conducted are described. A graph of the theoretical and experimental temperature distribution is developed for comparison. The variables involved in the computer program to process the data are defined. A study was conducted to develop analytical methods for predicting the effect and magnitudes of thermoacoustic oscillations on the penetration heat leak to cryogens. The oscillations develop as a result of large thermal gradients imposed on a compressible fluid. The predominant amplitudes and frequencies of the thermal acoustic oscillations were investigated.

Lovin, J. K.↗

Accelerations experienced during low-G flight of Black Brant VC (NAS 21.015) on 4 October 1974

This investigation was to determine whether a Black Brant VC (BBVC) sounding rocket equipped with the Goddard Space Flight Center (GSFC) rate control system (RCS) would produce g-levels which are satisfactory for space processing. Accelerations measured by the Marshall Space Flight Center (MSFC) low-g accelerometer system (LGAS) were compared with accelerations calculated from measured payload RCS gyro data during a low-g flight of BBVC NAS 21.015 at White Sands Missile Range, N.M., on October 4, 1974. Accelerations of up to 0.0002 g existed at the LGAS accelerometers from 70 through 420 sec (5.8 min), with the exception of a spike at 101 sec of 0.0004 g which occurred when the RCS was activated the second time. Accelerations of 0.0001 g existed from 140 through 400 sec (4.3 min). Accelerations of 0.0002 g along the roll axis up to 150 sec and of 0.0015 g in the lateral plane at about 135 sec are being investigated by GSFC. They may be associated with leaking thruster valves or a leak in one of the heat pipe experiments. The vehicle rate buildup each time after the RCS nulls out are also being investigated by GSFC. This rate caused most of the 0.0001 g acceleration experienced after 150 sec into the flight. Aerodynamic drag produced no significant accelerations after about 80 sec. The principal conclusion was that the BBVC with the GSFC RCS produces g-levels satisfactory for space processing.

Kissel, R.↗

Maximum likelihood failure detection techniques applied to the shuttle orbiter reaction control subsystem

A technique for on-board detection and identification of hard failures and leaks of the shuttle orbiter reaction control subsystem jets, during the orbital flight phase, is presented. The method uses gimbal angle and linear accelerometer measurements from the orbiter inertial measurement unit and requires no additional hardware. Extended Kalman filters with residual traps are employed for state estimation, and generalized likelihood ratio tests for jet failure identification. Rigid body simulation results indicate identification times of less than 2 seconds for hard jet failures and less than 70 seconds for jet leaks.

Deckert, J. C.↗

Borosilicate glass-to-Kovar tube bonding

Two-micron-diameter inlet leak, useful in mass spectrometry applications, minimizes gas sample distortion that occurs between sample and leak, is easily joined to spectrometer inlet system, and withstands unusual gas pressures and temperatures.

Harris, R. F.↗

Powder metallurgy processing of high strength turbine disk alloys

Using vacuum-atomized AF2-1DA and Mar-M432 powders, full-scale gas turbine engine disks were fabricated by hot isostatically pressing (HIP) billets which were then isothermally forged using the Pratt & Whitney Aircraft GATORIZING forging process. While a sound forging was produced in the AF2-1DA, a container leak had occurred in the Mar-M432 billet during HIP. This resulted in billet cracking during forging. In-process control procedures were developed to identify such leaks. The AF2-1DA forging was heat treated and metallographic and mechanical property evaluation was performed. Mechanical properties exceeded those of Astroloy, one of the highest temperature capability turbine disk alloys presently used.

Evans, D. J.↗