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At least 631 records · Page 35

Revealing the Configuration and Conformation of Surface Organometallic Catalysts with DNP-Enhanced NMR

Although single-site, supported organometallic catalysts were designed with homogeneity in mind, little is strictly known about their atomic-level structure and uniformity. This is in large part due to the inability of conventional characterization tools to provide structural information with adequate resolution and range for this purpose. In this work, we show that dynamic nuclear polarization (DNP)-enhanced solid-state nuclear magnetic resonance (NMR) enables the measurement of distances between the surface and individual carbons, making it possible to orient complexes and molecules on surfaces. We use this approach to determine the orientation and configuration of naturally 13 C-abundant acetate and supported organoiridium(III) pincer complex, both supported on γ-Al 2 O 3 . By combining solid-state NMR and extended X-ray absorption fine structure spectroscopy (EXAFS) experiments with periodic density functional theory (DFT) calculations, we are able to determine the three-dimensional arrangement of ligands around the metal center and thereby identify the structure of the supported complex at a resolution reminiscent of that associated with single-crystal diffractometry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Illuminating the North Korean nuclear explosion test in 2017 using remote infrasound observations

North Korea conducted its sixth underground nuclear explosion test (mb 6.3) on 2017 September 3. The underground explosion produced substantial low-frequency atmospheric waves, which were detected by infrasound arrays located up to a distance of 566 km. These infrasound waves are formed by the conversion of seismic energy to acoustic energy across the lithosphere–atmosphere interface. While infrasound records at regional distances produce estimates of ground motion amplitude over spatially extended regions covering about 26 500 km 2 , 3-D full seismo-acoustic simulations within the lithosphere and atmosphere provide quantitative information about seismo-acoustic energy partitioning. Our results demonstrate the capability of remote infrasound observations combined with 3-D propagation modelling to further develop discrimination methods for underground sources. These results contribute to enhance the confidence of source identification and characterization in nuclear test monitoring research, which is essential for the enforcement of the Comprehensive Nuclear-Test-Ban Treaty.

58 GEOSCIENCES↗

Investigations of correlation and coherence in turbulence from a large-eddy simulation

Abstract. Microscale flow descriptions are often given in terms of mean quantities, turbulent kinetic energy, and/or stresses. Those metrics, while valuable, give limited information about turbulent eddies and coherent turbulent structures. This work investigates the structure of an atmospheric boundary layer using coherence and correlation in space and time with a range of separation distances. We calculate spatial correlations over entire planes of velocity fluctuations, from which we can evaluate the correlation along different directions at different spacings. Similarly, coherence of the three velocity components over separations in the three directions is also investigated. We apply these analyses to a mesoscale–microscale coupled scenario with time-varying conditions and examine nuances in spatial correlations that are often overlooked. Through these analyses and results, this work highlights important differences observed in terms of coherence when comparing large-eddy simulation data to simpler models and suggests ways to improve these simpler models. We note that such differences are important for disciplines like wind energy structural dynamic analysis, in which blade loading and fatigue depend strongly on the structure of the turbulence. We emphasize the additional wealth of data that can be provided by typical atmospheric boundary layer large-eddy simulation when correlation and coherence analysis is included, and we also state the limitations of large-eddy simulation data, which inherently truncate the smaller scales of turbulence.

17 WIND ENERGY↗

The Voyager 2 mission to Neptune

Voyager 2 and its twin, Voyager 1, were launched in 1977. Both spacecraft investigated Jupiter's and Saturn's systems. Voyager 2 continued on to fly past Utranus in 1986 and Neptune in 1989, while Voyager 1 headed out of the solar system. The mission at Neptune presented many engineering and scientific challenges. Neptune is about 30 Astronomical Units (AU) from the sun and earth, resulting in extremely low lights levels (nearly 1000 times lower than at earth) and in communication distances of nearly 4.5 billion kilometers. To compensate for the long communication distances, several new techniques were developed. As at Uranus, an onboard backup computer compressed the imaging data. In addition, the data return was further improved by electronically arraying and expanding several receiving antennas. As a result, the data rates from Neptune were about the same as they were from Saturn, even though the distance was three times greater. Several changes were made in the onboard software to optimize Voyager's operations at the very low light levels at Neptune. Finally, to obtain the maximum information from the Neptune encounter, a trajectory was selected which passed within just 5000 kilometers of Neptune's atmosphere, but which also posed several possible environmental hazards.

Haynes, Norman R.↗

Headphone localization of speech stimuli

Recently, three dimensional acoustic display systems have been developed that synthesize virtual sound sources over headphones based on filtering by Head-Related Transfer Functions (HRTFs), the direction-dependent spectral changes caused primarily by the outer ears. Here, 11 inexperienced subjects judged the apparent spatial location of headphone-presented speech stimuli filtered with non-individualized HRTFs. About half of the subjects 'pulled' their judgements toward either the median or the lateral-vertical planes, and estimates were almost always elevated. Individual differences were pronounced for the distance judgements; 15 to 46 percent of stimuli were heard inside the head with the shortest estimates near the median plane. The results infer that most listeners can obtain useful azimuth information from speech stimuli filtered by nonindividualized RTFs. Measurements of localization error and reversal rates are comparable with a previous study that used broadband noise stimuli.

Begault, Durand R.↗

Headphone localization of speech

Three-dimensional acoustic display systems have recently been developed that synthesize virtual sound sources over headphones based on filtering by head-related transfer functions (HRTFs), the direction-dependent spectral changes caused primarily by the pinnae. In this study, 11 inexperienced subjects judged the apparent spatial location of headphone-presented speech stimuli filtered with nonindividualized HRTFs. About half of the subjects 'pulled' their judgments toward either the median or the lateral-vertical planes, and estimates were almost always elevated. Individual differences were pronounced for the distance judgments; 15 to 46 percent of stimuli were heard inside the head, with the shortest estimates near the median plane. The results suggest that most listeners can obtain useful azimuth information from speech stimuli filtered by nonindividualized HRTFs. Measurements of localization error and reversal rates are comparable with a previous study that used broadband noise stimuli.

Begault, Durand R.↗

About the Compatibility of DORIS and VLBI Observations

We investigated the compatibility of the DORIS and VLBI observations at Badary Observatory. The DORIS beacon stands at 100-m distance from the main radio telescope dish and transmits signals on two frequencies: 2036.25 MHz and 401.25 MHz. The latter frequency is modulated to send messages containing an ID number, timing information, data from the meteorological sensors, and engineering data (e.g., power). Both frequencies affect the S/X band radio telescope receivers. The parameters of the DORIS signals were measured at the outputs of the S/X band intermediate frequency amplifier. It was found that: (1) The level of RFI, produced by the DORIS beacon, practically corresponds to the level of the system (antenna plus receiver) noise signal and does not overload the S/X band receivers. (2) The DORIS 401.25 MHz signal is out of the frequency bands recorded during standard VLBI sessions. As a result, RFI from DORIS does not affect VLBI observations. This conclusion was confirmed after data correlations of actual VLBI observations that were conducted with the DORIS beacon turned on/off.

Il'in, Gennady↗

Islands far outside the horizon

Information located in an entanglement island in semiclassical gravity can be nonperturbatively reconstructed from distant radiation, implying a radical breakdown of effective field theory. We show that this occurs well outside of the black hole stretched horizon. We compute the island associated to large-angular momentum Hawking modes of a four-dimensional Schwarzschild black hole. These modes typically fall back into the black hole but can be extracted to infinity by relativistic strings or, more abstractly, by asymptotic boundary operators constructed using the timelike tube theorem. Remarkably, we find that their island can protrude a distance of order $\sqrt{\ell_p{r}_{\textrm{hor}}}$ outside the horizon. This is parametrically larger than the Planck scale ℓ p and is comparable to the Bohr radius for supermassive black holes. Therefore, in principle, a distant observer can determine experimentally whether the black hole information paradox is resolved by complementarity, or by a firewall.

AdS-CFT correspondence↗

On the Use of Smart Meter Data to Estimate the Voltage Magnitude on the Primary Side of Distribution Service Transformers

This paper develops a novel method to estimate the voltage magnitude on the primary side of distribution service transformers. The proposed method relies exclusively on smart meters, and therefore it is fully data-driven. This is an important feature because electric utilities have detailed models of only the primary network - that is, the network between the distribution substation and the primary side of service transformers that are installed closer to end-customer sites. The network that connects the secondary side of service transformers to end-customer sites, referred to as the secondary network, is simply represented by a lumped load. For each secondary network, the proposed method uses data acquired from only 2 smart meters: the closest and the farthest-in the sense of electrical distance - from the service transformer. As a reference to this feature, the proposed method is named SM2Vp. To our knowledge, this is the first time a method is shown to provide actionable information for realtime operation and control of power distribution grids using only two smart meters per secondary network. This is important because utilities have experienced barriers in managing and using large data sets for real-time operation and control. SM2Vp is primarily intended to provide pseudo-measurements for distribution system state estimation, but it can also be used directly for voltage control schemes. The performance of SM2Vp is demonstrated by numerical simulations carried out on three secondary network synthetic models and by using field data provided by a utility partner serving customers in southwestern California. A maximum relative error of approximately 3.9% or less is observed for the primary voltage magnitude estimates in all numerical experiments.

distribution service transformer↗

Communications and tracking

Many phases of communications theory and practice could not be touched upon in this presentation. It is hoped that these objectives have been obtained: to show how, in a general way, it is possible to get back enough information to Justify a space vehicle; to show how the path of this vehicle may be followed from the ground, and to state some of the obstacles to communications over very long distances.

P A Gainer↗

Optical communication in free space

Two classes of laser communication systems for handling very high data rates across inter-satellite distances are considered that provide for high antenna gains, wide modulation bandwidths, and optical receiver sensitivities. System design considerations are based upon the carbon dioxide laser modulation to accommodate digital or analog information, and the neodymium doped YAG laser pulse for digital modulation.

Plotkin, H. H.↗

Simulator method and apparatus for practicing the mating of an observer-controlled object with a target

A servo controlled target replica, and a surface bearing a computer generated line drawing of an object are individually viewed by separate television cameras allowing a two-dimensional composite of the target replica and the object to be displayed on a monitor simulating what an observer would see through a window in a spacecraft. The target replica is coded along one self coordinate axis in such a way that the distance of an elemental area on the target along the axis is capable of being remotely readout by a television camera. A third television camera responsive to the code reads out this information by which the Z-coordinate, relative to the observer, can be calculated, on-line with the scan, for the contents of each picture element of the scene televised by the target camera.

Polstorff, W. K.↗

Wide-Angle, Wide-Band Camera for Remote Imaging

Improved ultraviolet-to-infrared camera design combines high resolution and relatively wide field of view in remote-imaging system. Although design intended for satellite-borne system to give information on such Earth features as vegetation, pollution, and land formation mineral deposits, optical principle also useful in ground-based or airborne high-resolution television for imaging objects at great distances.

Atcheson, P. D.↗

Laser diode array and transmission optics

Information on laser diode array and transmission optics is given in viewgraph form. Information is given on coherent combining of laser diode arrays, amplification through a laser diode array, the far field pattern of a laser diode transmitter, and beam diameter at receiver vs. transmission distance.

Kwon, Jin H.↗

South-North and radial traverses through the interplanetary dust cloud

Identical in situ dust detectors are flown on board the Galileo and Ulysses spacecraft. They record impacts of micrometeoroids in the ecliptic plane at heliocentric distances from 0.7 to 5.4 AU and in a plane almost perpendicular to the ecliptic from -79 deg to +79 deg ecliptic latitude. The combination of both Ulysses and Galileo measurements yield information about the radial and latitudinal distributions of micron and sub-micron sized dust in the solar system. Two types of dust particles were found to dominate the dust flux in interplanetary space: (1) Interplanetary micrometeoroids covering a wide mass range from 10(exp -16) to 10(exp -6) gr are mostly recorded inside 3 AU, and at latitudes below 30 deg; and (2) Interstellar grains with masses between 10(exp -14) and 10(exp -12) gr have been positively identified outside 3 AU near the ecliptic plane and outside 1.8 AU at high ecliptic latitudes (> 50 deg). Interstellar grains move on hyperbolic trajectories through the planetary system and constitute the dominant dust flux (1.5 x 10(exp -4)/ sq m sec) in the outer solar system and at high ecliptic latitudes. In order to compare and analyze the Galileo and Ulysses data sets, a new model is developed based on Divine's (1993) "Five populations of interplanetary meteoroids" model. By using this model, which takes into account the measured velocities and the effect of radiation pressure on small particles, we define four populations of meteoroids on elliptical orbits plus one population on hyperbolic orbits that all can fit the micrometeoroid flux observed by Galileo and Ulysses.

Gruen, E.↗

Crew Activity Analyzer

The crew activity analyzer (CAA) is a system of electronic hardware and software for automatically identifying patterns of group activity among crew members working together in an office, cockpit, workshop, laboratory, or other enclosed space. The CAA synchronously records multiple streams of data from digital video cameras, wireless microphones, and position sensors, then plays back and processes the data to identify activity patterns specified by human analysts. The processing greatly reduces the amount of time that the analysts must spend in examining large amounts of data, enabling the analysts to concentrate on subsets of data that represent activities of interest. The CAA has potential for use in a variety of governmental and commercial applications, including planning for crews for future long space flights, designing facilities wherein humans must work in proximity for long times, improving crew training and measuring crew performance in military settings, human-factors and safety assessment, development of team procedures, and behavioral and ethnographic research. The data-acquisition hardware of the CAA (see figure) includes two video cameras: an overhead one aimed upward at a paraboloidal mirror on the ceiling and one mounted on a wall aimed in a downward slant toward the crew area. As many as four wireless microphones can be worn by crew members. The audio signals received from the microphones are digitized, then compressed in preparation for storage. Approximate locations of as many as four crew members are measured by use of a Cricket indoor location system. [The Cricket indoor location system includes ultrasonic/radio beacon and listener units. A Cricket beacon (in this case, worn by a crew member) simultaneously transmits a pulse of ultrasound and a radio signal that contains identifying information. Each Cricket listener unit measures the difference between the times of reception of the ultrasound and radio signals from an identified beacon. Assuming essentially instantaneous propagation of the radio signal, the distance between that beacon and the listener unit is estimated from this time difference and the speed of sound in air.] In this system, six Cricket listener units are mounted in various positions on the ceiling, and as many as four Cricket beacons are attached to crew members. The three-dimensional position of each Cricket beacon can be estimated from the time-difference readings of that beacon from at least three Cricket listener units

Murray, James↗

Estimating Shock Spectra: Extensions beyond GEVS

Shock response spectra (SRS) are the standard description of some vibration environments on spacecraft for equipment qualification. For shock events produced by pyrotechnic devices, SRS can have significant frequency content as high as 10 kHz. It is difficult to construct and analyze finite element models that can resolve dynamic behavior at such high frequencies. GEVS provides simple, empirically based methods for approximating the SRS for a wide variety of shock events. It begins with a base SRS according to the type of pyrotechnic device, and then provides attenuation relations to adjust this SRS according to distance from the shock source, the type of structural frame and the properties of any structural joints between the source and equipment. In our paper we extend GEVS to include more detailed information about the spacecraft structure. To retain the general framework of GEVS, we begin with a base SRS and adjust this SRS using attenuation relations. We use modal and traveling wave concepts to derive the attenuation relations for simple canonical structures. Then we show how these concepts can be used to analyze more complex structures using finite element mode shapes to explicitly calculate the attenuation factors. Since the low- to mid-frequency finite element modal information is extrapolated to obtain the low- to high-frequency attenuation relations, the resulting attenuated SRS is formulated as an upper bound rather than as mean predicted values. We illustrate the extended GEVS approach by analyzing the impact response of composite tubes and the shock response of the STEREO spacecraft.

Igusa, Takeru↗

Medical System Concept of Operations for Mars Exploration Mission-11: Exploration Medical Capability (ExMC) Element - Human Research Program

NASA’s exploration missions to Mars will have durations of 2-3 years and will take humans farther away from Earth than ever before. This will result in a paradigm shift for mission planning, spacecraft design, human systems integration, and in-flight medical care. Constraints on real-time communication, resupply, and medical evacuation are major architectural drivers. These constraints require medical system development to be tightly integrated with mission and vehicle design to provide crew autonomy and enable mission success. This concept of operations provides a common vision of medical care for developing a medical system for Mars exploration missions. It documents an overview of the stakeholder needs and goals of a medical system and provides examples of the types of activities the system will be used for during the mission. Development of the concept of operations considers mission variables such as distance from Earth, duration of mission, time to definitive medical care, communication protocols between crewmembers and ground support, personnel capabilities and skill sets, medical hardware and software, and medical data management. The information provided in this document informs the ExMC Systems Engineering effort to define the functions to be provided by the medical system. In addition, this concept of operations will inform the subsequent systems engineering process of developing technical requirements, system architectures, interfaces, and verification and validation approaches for the medical system. This document supports the closure of ExMC Gap Med01: We do not have a concept of operations for medical care during exploration missions, corresponding to the ExMC-managed human system risk: Risk of Adverse Health Outcomes & Decrements in Performance due to Inflight Medical Conditions. This document is applicable to the ExMC Element Systems Engineering process and may be used for collaboration within the Human Research Program.

Urbina, Michelle↗