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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Coherent magnetic nanoinclusions induce charge localization in half-Heusler alloys leading to high- T c ferromagnetism and enhanced thermoelectric performance

Performance improvement traditionally realized through a combination of power factor optimization via electronic doping and lattice thermal conductivity reduction using nanostructuring have reached their optimal limits in many leading thermoelectric materials, making further enhancement in the thermoelectric figure of merit extremely challenging. Here, a novel approach to electronic transport engineering using coherent magnetic nanoinclusions is demonstrated. It was found that the incorporation of coherent magnetic full-Heusler (FH) nanoinclusions (Ti(Ni 4/3 Fe 2/3 )Sn) into a half-Heusler (HH) matrix (Ti 0.25 Zr 0.25 Hf 0.5 NiSn 0.975 Sb 0.025 ) with optimal doping level and lattice thermal conductivity leads to high Curie temperature ferromagnetism (T c ~ 650 K) along with a large reduction in the effective carrier density within the HH matrix. It is believed that the embedded magnetic FH nanoinclusions interact with the spin of itinerant carriers, leading to charge localization and the formation of overlapping bound magnetic polarons (BMPs). This gives rise to significant enhancements of both carrier mobility and thermopower, which minimizes the reduction in the overall power factor, simultaneously with a large drop in the total thermal conductivity owing to the reduction of the electronic contribution to the thermal conductivity. Here, whe implementation of the magnetic nanoinclusions strategy in a variety of state-of-the-art thermoelectric materials could pave the way towards even larger figures of merit.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Steric effects in light-induced solvent proton abstraction

The significance of solvent structural factors in the excited-state proton transfer (ESPT) reactions of Schiff bases with alcohols is reported here. In this work, we use the super photobase FR0-SB and a series of primary, secondary, and tertiary alcohol solvents to illustrate the steric issues associated with solvent to photobase proton transfer. Steady-state and time-resolved fluorescence data show that ESPT occurs readily for primary alcohols, with a probability proportional to the relative –OH concentration. For secondary alcohols, ESPT is greatly diminished, consistent with the barrier heights obtained using quantum chemistry calculations. ESPT is not observed in the tertiary alcohol. We explain ESPT using a model involving an intermediate hydrogen-bonded complex where the proton is “shared” by the Schiff base and the alcohol. The formation of this complex depends on the ability of the alcohol solvent to achieve spatial proximity to and alignment with the FR0-SB* imine lone pair stabilized by the solvent environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Demonstration of neutron radiation-induced nucleation of supercooled water

In this study, we present direct evidence for neutrons causing nucleation of supercooled water. Highly purified water (20 nm filtration) is cooled to well below freezing (as low as −20 °C) with a radioactive calibration source of neutrons/gamma-rays either present or removed during each of many control cooling runs for the same volume of water. When it is primarily neutrons irradiating the sample bulk, the non-equilibrium freezing point (also known as the “supercooling point”) is, on average, +0.7 °C warmer than the control equivalent, with a statistical significance of greater than 5 Sigma, with systematic uncertainty included. This effect is not observed with water in the presence of gamma-rays instead of neutrons. While these neutrons should have theoretically had sufficient energy to mount the energy barrier, corroborating our results, their raising of supercooling temperature has never been reported experimentally to the best of our knowledge. The potential to use deeply supercooled solutions, not only water, as metastable detectors for radiation and perhaps dark matter or neutrino physics presents now a new avenue for exploration.

Szydagis, Matthew↗
DOE OSTI2013

Nanoparticle size and morphology control using ultrafast laser induced forward transfer of Ni thin films

We have developed a nanoparticle (NP) printing technique using Ni thin film lift-off from glass substrates after ultrafast irradiation in air. Unique interactions of ultrafast laser pulses with thin films allow for control over NP faceting and size distributions. Control is achieved by changing the laser fluence, film thickness, and film-substrate distance. We demonstrate 20 nm Ni film removal from substrates and rapid NP printing, with size distributions centered at a 6 nm diameter. When the Ni film thickness is lowered to 10 nm, NPs are printed with distributions peaked at a 2 nm diameter.

36 MATERIALS SCIENCE↗