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NASA NTRS1992

An isotopic biogeochemical study of the Green River oil shale

Thirty-five different samples from three different sulfur cycles were examined in this stratigraphically oriented study of the Shell 22x-l well (U.S.G.S. C177 core) in the Piceance Basin, Colorado. Carbon isotopic compositions of constituents of Green River bitumens indicate mixing of three main components: products of primary photoautotrophs and their immediate consumers (delta approximately -30% vs PDB), products of methanotrophic bacteria (delta approximately -85%), and products of unknown bacteria (delta approximately -40%). For individual compounds synthesized by primary producers, delta-values ranged from -28 to -32%. 13C contents of individual primary products (beta-carotane, steranes, acyclic isoprenoids, tricyclic triterpenoids) were not closely correlated, suggesting diverse origins for these materials. 13C contents of numerous hopanoids were inversely related to sulfur abundance, indicating that they derived both from methanotrophs and from other bacteria, with abundances of methanotrophs depressed when sulfur was plentiful in the paleoenvironment. gamma-Cerane coeluted with 3 beta(CH3),17 alpha(H),21 beta(H)-hopane, but delta-values could be determined after deconvolution. gamma-Cerane (delta approximately -25%) probably derives from a eukaryotic heterotroph grazing on primary materials, the latter compound (delta approximately -90%) must derive from methanotrophic organisms. 13C contents of n-alkanes in bitumen differed markedly from those of paraffins generated pyrolytically. Isotopic and quantitative relationships suggest that alkanes released by pyrolysis derived from a resistant biopolymer of eukaryotic origin and that this was a dominant constituent of total organic carbon.

Non-NASA Center↗

NASA NTRS1994

Acquisition and processing of data for isotope-ratio-monitoring mass spectrometry

Methods are described for continuous monitoring of signals required for precise analyses of 13C, 18O, and 15N in gas streams containing varying quantities of CO2 and N2. The quantitative resolution (i.e. maximum performance in the absence of random errors) of these methods is adequate for determination of isotope ratios with an uncertainty of one part in 10(5); the precision actually obtained is often better than one part in 10(4). This report describes data-processing operations including definition of beginning and ending points of chromatographic peaks and quantitation of background levels, allowance for effects of chromatographic separation of isotopically substituted species, integration of signals related to specific masses, correction for effects of mass discrimination, recognition of drifts in mass spectrometer performance, and calculation of isotopic delta values. Characteristics of a system allowing off-line revision of parameters used in data reduction are described and an algorithm for identification of background levels in complex chromatograms is outlined. Effects of imperfect chromatographic resolution are demonstrated and discussed and an approach to deconvolution of signals from coeluting substances described.

NASA Discipline Exobiology↗

NASA NTRS1995

Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.

Non-NASA Center↗

NASA NTRS2001

Rapid flow-induced responses in endothelial cells

Endothelial cells alter their morphology, growth rate, and metabolism in response to fluid shear stress. To study rapid flow-induced responses in the 3D endothelial cell morphology and calcium distribution, coupled fluorescence microscopy with optical sectioning, digital imaging, and numerical deconvolution techniques have been utilized. Results demonstrate that within the first minutes of flow application nuclear calcium is increasing. In the same time frame whole cell height and nuclear height are reduced by about 1 microm. Whole cell height changes may facilitate reduction of shear stress gradients on the luminal surface, whereas nuclear structural changes may be important for modulating endothelial growth rate and metabolism. To study the role of the cytoskeleton in these responses, endothelial cells have been treated with specific disrupters (acrylamide, cytochalasin D, and colchicine) of each of the cytoskeleton elements (intermediate filaments, microfilaments, and microtubules, respectively). None of these compounds had any effect on the shear-induced calcium response. Cytochalasin D and acrylamide did not affect the shear-induced nuclear morphology changes. Colchicine, however, completely abrogated the response, indicating that microtubules may be implicated in force transmission from the plasma membrane to the nucleus. A pedagogical model based on tensegrity theory principles is presented that is consistent with the results on the 3D endothelial morphology.

Non-NASA Center↗

NASA NTRS2000

Neural network recognition of chemical class information in mobility spectra obtained at high temperatures

A minimal neural network was applied to a large library of high-temperature mobility spectra drawn from 16 chemical classes including 154 substances with 2000 spectra at various concentrations. A genetic algorithm was used to create a representative subset of points from the mobility spectrum as input to a cascade-type back-propagation network. This network demonstrated that significant information specific to chemical class was located in the spectral region near the reactant ions. This network failed to generalize the solution to unfamiliar compounds necessitating the use of complete spectra in network processing. An extended back-propagation network classified unfamiliar chemicals by functional group with a mean for average values of 0.83 without sulfides and 0.79 with sulfides. Further experiments confirmed that chemical class information was resident in the spectral region near the reactant ions. Deconvolution of spectra demonstrated the presence of ions, merged with the reactant ion peaks that originated from introduced samples. The ability of the neural network to generalize the solution to unfamiliar compounds suggests that these ions are distinct and class specific.

NASA Discipline Environmental Health↗

NASA NTRS2004

Physics of Galaxy Clusters and How it Affects Cosmological Tests

The main activities in 2004 were focused on completion of the new 400 square degrees ROSAT PSPC survey for distant galaxy clusters. We observed and reduced optical spectra for all X-ray candidates and now we have complete identification for a statistically complete sample of distant 283 clusters. The papers describing the cluster catalog and first science results are in preparation and will be submitted in early 2005. We also completed a project to measure temperature and density profiles at large radii using Chandra observations of a 11 well exposed low-redshift clusters. We were able to demonstrate that the density, temperature, and total mass profiles are self-similar at large radii. This analysis has led to significant improvements in determination of the cluster baryon fraction as well as cosmologically important scaling relations, such as Mtot-T. The paper describing these results is submitted to ApJ in November, 2004. We continued to study evolution of the cluster scaling relations at high redshifts using Chandra and XMM data. We developed code for image and spectral deconvolution of the XMM observations. This code was used to reconstruct the distribution of baryons and total mass from observations of distant clusters which suffer from the finite size of the XMM PSF. This study allowed us to derive a high-redshift relation between cluster temperature and mass and compare it with the local relation obtained. The paper describing the first results is submitted to the ApJ. However, the project is still on-going as more distant cluster observations enter XMh4 and Chandra public data archives. We continued our work on improving techniques for accurate measurements of the cluster mass function and obtaining cosmological constraints from such observations. We published (ApJ, 601, 610) a study in which we derived the baryon mass function for a complete sample of low-redshift clusters. These papers argued that it was an excellent proxy for the total mass function. The baryon mass function can be used to constrain the amplitude and slope of the density fluctuation power spectrum on cluster scales. This method does not use observational determinations of the total mass and thus bypasses major uncertainties in the traditional analyses based on the X-ray temperature function. We derived the measurements for the amplitude of density perturbations, sigma8 = 0.72 +/- 0.04 and the shape parameter Omega*h = 0.l3 +/- 0.07, in good agreement with a number of independent methods.

Oliversen, Ronald J.↗

NASA NTRS2004

Insights into Tropospheric Ozone from the INTEX Ozonesonde Network Study (IONS)

Ozone profile data from soundings integrate models, aircraft and other ground-based measurements for better interpretation of atmospheric chemistry and dynamics. A well-designed network of ozonesonde stations, with consistent sampling, can answer questions not possible with short campaigns or current satellite technology. The SHADOZ (Southern Hemisphere Additional Ozonesondes) project, for example, has led to these findings about tropical ozone: definition of the zonal tropospheric wave-one pattern in equatorial ozone, characterization of the "Atlantic ozone paradox" and establishment of a link between tropical Atlantic and Indian Ocean pollution. Building on the SHADOZ concept, a short-term ozone network was formed in July-August 2004 to coordinate ozonesonde launches during the ICARTT/INTEX/NEAQS (International Consortium on Atmospheric Research on Transport and Transformation)/Intercontinental Transport Experiment/New England Air Quality Study. In IONS (INTEX Ozonesonde Network Study), more than 250 soundings, with daily frequency at half the sites, were launched from eleven North American stations and an oceanographic ship in the Gulf of Maine. Although the goal was to examine pollution influences under stable high-pressure systems and transport associated with "warm conveyor belt" flows, the INTEX study region was dominated by a series of weak frontal system that mixed aged pollution with stratospheric ozone in the middle troposphere. Deconvoluting ozone sources provides new insights into ozone in the transition between mid-latitude and polar air.

Thompson, Anne M.↗

NASA NTRS2005

Lunar and Planetary Science XXXVI, Part 10

The Problem of Incomplete Mixing of Interstellar Components in the Solar Nebula: Very High Precision Isotopic Measurements with Isoprobes P and T. Finally: Presolar Graphite Grains Identified in Orgueil. Basaltic Ring Structures as an Analog for Ring Features in Athabasca Valles, Mars. Experimental Studies of the Water Sorption Properties of Mars-Relevant Porous Minerals and Sulfates. Silicon Isotope Ratio Variations in CAI Evaporation Residues Measured by Laser Ablation Multicollector ICPMS. Crater Count Chronology and Timing of Ridged Plains Emplacement at Schiaparelli Basin, Mars. Martian Valley Networks and Associated Fluvial Features as Seen by the Mars Express High Resolution Stereo Camera (HRSC). Fast-Turnoff Transient Electromagnetic (TEM) Field Study at the Mars Analog Site of Rio Tinto, Spain. Time Domain Electromagnetics for Mapping Mineralized and Deep Groundwater in Mars Analog Environments. Mineralogical and Seismological Models of the Lunar Mantle. Photometric Observations of Soils and Rocks at the Mars Exploration Rover Landing Sites. Thermal Infrared Spectral Deconvolution of Experimentally Shocked Basaltic Rocks Using Experimentally Shocked Plagioclase Endmembers.

Source record↗

NASA NTRS2005

A Survey of Singular Value Decomposition Methods and Performance Comparison of Some Available Serial Codes

This contractor report describes a performance comparison of available alternative complete Singular Value Decomposition (SVD) methods and implementations which are suitable for incorporation into point spread function deconvolution algorithms. The report also presents a survey of alternative algorithms, including partial SVD's special case SVD's, and others developed for concurrent processing systems.

Plassman, Gerald E.↗

NASA NTRS2005

Three-Dimensional Application of DAMAS Methodology for Aeroacoustic Noise Source Definition

At the 2004 AIAA/CEAS Aeroacoustic Conference, a breakthrough in acoustic microphone array technology was reported by the authors. A Deconvolution Approach for the Mapping of Acoustic Sources (DAMAS) was developed which decouples the array design and processing influence from the noise being measured, using a simple and robust algorithm. For several prior airframe noise studies, it was shown to permit an unambiguous and accurate determination of acoustic source position and strength. As a follow-on effort, this paper examines the technique for three-dimensional (3D) applications. First, the beamforming ability for arrays, of different size and design, to focus longitudinally and laterally is examined for a range of source positions and frequency. Advantage is found for larger array designs with higher density microphone distributions towards the center. After defining a 3D grid generalized with respect to the array s beamforming characteristics, DAMAS is employed in simulated and experimental noise test cases. It is found that spatial resolution is much less sharp in the longitudinal direction in front of the array compared to side-to-side lateral resolution. 3D DAMAS becomes useful for sufficiently large arrays at sufficiently high frequency. But, such can be a challenge to computational capabilities, with regard to the required expanse and number of grid points. Also, larger arrays can strain basic physical modeling assumptions that DAMAS and all traditional array methodologies use. An important experimental result is that turbulent shear layers can negatively impact attainable beamforming resolution. Still, the usefulness of 3D DAMAS is demonstrated by the measurement of landing gear noise source distributions in a difficult hard-wall wind tunnel environment.

Brooks, Thomas F.↗

NASA NTRS2005

Energy Spectra of H and He from the ATIC-2 Experiment

The Advanced Thin Ionization Calorimeter (ATIC) experiment measures the energy spectra of individual elements, from H to Fe, in the energy region from about 100 GeV to tens of TeV. The ATIC instrument was flown twice in long-duration balloon flights around the South Pole in 2000-2001 (ATIC-1) and 2002-2003 (ATIC-2). ATIC-2 gathered about 18 days of data at an altitude of 36 km. In this paper we discuss the separation of protons from helium and present preliminary energy spectrum of each component, including deconvolution of the measured energy deposit spectra. The results are compared to previous data and to different cosmic ray propagation models, including a diffusion model with weak re-acceleration.

Wefel, J. P.↗

NASA NTRS2005

Sub-pixel phase-measuring interferometry with interlace stitching

Measurement of mid spatial frequency figure error is critical to large precision optics for missions such as TPF-C. This presentation introduces a technique for increasing the spatial sampling resolution to meet these requirements using conventional video resolution phase-measuring interferometer. Technique involves sub-pixel data shifts, interlaced stitching and PSF deconvolution.

Mooney, James T.↗

NASA NTRS2006

Extension of DAMAS Phased Array Processing for Spatial Coherence Determination (DAMAS-C)

The present study reports a new development of the DAMAS microphone phased array processing methodology that allows the determination and separation of coherent and incoherent noise source distributions. In 2004, a Deconvolution Approach for the Mapping of Acoustic Sources (DAMAS) was developed which decoupled the array design and processing influence from the noise being measured, using a simple and robust algorithm. In 2005, three-dimensional applications of DAMAS were examined. DAMAS has been shown to render an unambiguous quantitative determination of acoustic source position and strength. However, an underlying premise of DAMAS, as well as that of classical array beamforming methodology, is that the noise regions under study are distributions of statistically independent sources. The present development, called DAMAS-C, extends the basic approach to include coherence definition between noise sources. The solutions incorporate cross-beamforming array measurements over the survey region. While the resulting inverse problem can be large and the iteration solution computationally demanding, it solves problems no other technique can approach. DAMAS-C is validated using noise source simulations and is applied to airframe flap noise test results.

Brooks, Thomas F.↗

NASA NTRS1996

(abstract) Radiometric Calibration of the Multi-angle Imaging Spectro-Radiometer

The EOS/MISR instrument has completed preflight calibration and characterization of its nine cameras. The radiometric calibration requirements includes absolute radiometric accuracy to 3 percent. To meet this challenging requirement MISR has employed detector based calibration methodology. The source, a 1.65 m integrating sphere, is spatially and spectrally featureless. Thus, when viewing scenes that are likewise homogeneous, the sensor incident radiance is easily retrieved to high accuracy. To enhance the radiance product for arbitrary scene types, however, MISR is planning to incorporate spectral out-of-band, point-spread function deconvolution, and pixel nonuniformity of response corrections. A summary of the preflight calibration is presented in this paper, as well as the error uncertainties for specific scene types with and without these processing corrections.

radiometric calibration EOS MISR↗

NASA NTRS1995

Evidence on Sizes and Fragmentation of the Nuclei of Comet Shoemaker-Levy 9 from Hubble Space Telescope Images

Central regions on the digital maps of 13 nuclear condensations of Comet Shoemaker-Levy 9, obtained with the Planetary Camera of the Hubble Space Telescope on January 24-25, March 28-30, and July 4, 1994, have been analyzed with the aim to identify the presence of distinct, major fragments in each condensation, to deconvolve their contributions to the signal that also includes the contribution from a surrounding cloud of dust (modeled as an extended source, using two different laws), to estimate the dimensions of the fragments and to study their temporal variations, and to determine the spatial distributions of the fragments as projected onto the plane of the sky. The deconvolution method applied is described and the results of the analysis are summarized, including the finding that sizable fragments die survive until the time of atmospheric entry. This result does not contradict evidence of the comet's continuing, apparently spontaneous fragmentation, which still went on long after the extremely close approach to Jupiter in July 1992 and which, because of the jovian tidal effects, may even have intensified in the final days before the crash on Jupiter. On plausible assumptions, the largest fragments are found to have had effect diameters of 4 km as late as March and event early July 1994. In most condensations, several sizable companions ( 1 km or more across) have been detected within 1000 km of the projected location of the brightest fragment and the surrounding dust cloud has been found to be centered on a point that is shifted in the general direction of the tail, probably due to effects of solar radiation pressure. Since the developed approach is based on certain premises and involves approximations, the results should be viewed as preliminary and the problem should be a subject of further investigation.

Comet Shoemaker-Levy 9↗

NASA NTRS1994

Dimensions and Fragmentation of the Nuclei of Comet Shoemaker-Levi 9

Central regions on the digital maps of 13 nuclear condensations of Comet Shoemaker-Levi 9, obtained with the Planetary Camera of the Hubble Space Telescope on January 27, March 30, and July 4, 1994, have been analyzed with the aim to identify the presence of distinct, major fragments in each condensation, to deconvolve their contributions to the signal that also includes the contribution from a surrounding cloud of dust (modeled as an extended source, using two different laws), to estimate the dimensions of the fragments and to study their temporal variations, and to determine the spatial distributions of the fragments as projected on to the plane of the sky. The deconvolution method applied is described and the results of the analysis are summarized, including the finding that sizable fragments did survive until the time of atmospheric entry. This result does not contradict evidence of the comet's continuing, apparently spontaneous fragmentation, which still went on long after the extremely close approach to Jupiter in July 1992 and which, because of the Jovian tidal effects, may have intensified in the final days before the crash on Jupiter. Since the developed approach is based on certain premises and involves approximations, the results should be viewed as preliminary and the problem should be the subject of further investigation.

Comet Shoemaker-Levi 9 Hubble Space Telescope come↗

NASA NTRS2007

Noise Spectra and Directivity For a Scale-Model Landing Gear

An extensive experimental study has been conducted to acquire detailed noise spectra and directivity data for a high-fidelity, 6.3%-scale, Boeing 777 main landing gear. The measurements were conducted in the NASA Langley Quiet Flow Facility using a 41-microphone directional array system positioned at a range of polar and azimuthal observer angles with respect to the model. DAMAS (Deconvolution Approach for the Mapping of Acoustic Sources) array processing as well as straightforward individual microphone processing were employed to compile unique flyover and sideline directivity databases for a range of freestream Mach numbers (0.11 - 0.17) covering typical approach conditions. Comprehensive corrections were applied to the test data to account for shear layer ray path and amplitude variations. This allowed proper beamforming at different measurement orientations, as well as directivity presentation in free-field emission coordinates. Four different configurations of the landing gear were tested: a baseline configuration with and without an attached side door, and a noise reduction concept "toboggan" truck fairing with and without side door. DAMAS noise source distributions were determined. Spectral analyses demonstrated that individual microphones could establish model spectra. This finding permitted the determination of unique, spatially-detailed directivity contours of spectral band levels over a hemispherical surface. Spectral scaling for the baseline model confirmed that the acoustic intensity scaled with the expected sixth-power of the Mach number. Finally, comparison of spectra and directivity between the baseline gear and the gear with an attached toboggan indicated that the toboggan fairing may be of some value in reducing gear noise over particular frequency ranges.

Humphreys, William M., Jr.↗

NASA NTRS2007

Aero-acoustics of Drag Generating Swirling Exhaust Flows

Aircraft on approach in high-drag and high-lift configuration create unsteady flow structures which inherently generate noise. For devices such as flaps, spoilers and the undercarriage there is a strong correlation between overall noise and drag such that, in the quest for quieter aircraft, one challenge is to generate drag at low noise levels. This paper presents a rigorous aero-acoustic assessment of a novel drag concept. The idea is that a swirling exhaust flow can yield a steady, and thus relatively quiet, streamwise vortex which is supported by a radial pressure gradient responsible for pressure drag. Flows with swirl are naturally limited by instabilities such as vortex breakdown. The paper presents a first aero-acoustic assessment of ram pressure driven swirling exhaust flows and their associated instabilities. The technical approach combines an in-depth aerodynamic analysis, plausibility arguments to qualitatively describe the nature of acoustic sources, and detailed, quantitative acoustic measurements using a medium aperture directional microphone array in combination with a previously established Deconvolution Approach for Mapping of Acoustic Sources (DAMAS). A model scale engine nacelle with stationary swirl vanes was designed and tested in the NASA Langley Quiet Flow Facility at a full-scale approach Mach number of 0.17. The analysis shows that the acoustic signature is comprised of quadrupole-type turbulent mixing noise of the swirling core flow and scattering noise from vane boundary layers and turbulent eddies of the burst vortex structure near sharp edges. The exposed edges are the nacelle and pylon trailing edge and the centerbody supporting the vanes. For the highest stable swirl angle setting a nacelle area based drag coefficient of 0.8 was achieved with a full-scale Overall Sound Pressure Level (OASPL) of about 40dBA at the ICAO approach certification point.

Shah, P. N.↗