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At least 631 records · Page 35

Airborne Wind Profiling Algorithms for the Pulsed 2-Micron Coherent Doppler Lidar at NASA Langley Research Center

Two versions of airborne wind profiling algorithms for the pulsed 2-micron coherent Doppler lidar system at NASA Langley Research Center in Virginia are presented. Each algorithm utilizes different number of line-of-sight (LOS) lidar returns while compensating the adverse effects of different coordinate systems between the aircraft and the Earth. One of the two algorithms APOLO (Airborne Wind Profiling Algorithm for Doppler Wind Lidar) estimates wind products using two LOSs. The other algorithm utilizes five LOSs. The airborne lidar data were acquired during the NASA's Genesis and Rapid Intensification Processes (GRIP) campaign in 2010. The wind profile products from the two algorithms are compared with the dropsonde data to validate their results.

Beyon, Jeffrey Y.↗

Global and Regional Radiative Forcing from 20 Reductions in BC, OC and SO4 an HTAP2 Multi-Model Study

In the Hemispheric Transport of Air Pollution Phase 2 (HTAP2) exercise, a range of global atmospheric general circulation and chemical transport models performed coordinated perturbation experiments with 20% reductions in emissions of anthropogenic aerosols, or aerosol precursors, in a number of source regions. Here, we compare the resulting changes in the atmospheric load and vertically resolved profiles of black carbon (BC), organic aerosols (OA) and sulfate (SO4/ from 10 models that include treatment of aerosols. We use a set of temporally, horizontally and vertically resolved profiles of aerosol forcing efficiency (AFE) to estimate the impact of emission changes in six major source regions on global radiative forcing (RF) pertaining to the direct aerosol effect, finding values between. 51.9 and 210.8mW/sq m/Tg for BC, between -2.4 and -17.9mW/sq m/Tg for OA and between -3.6 and -10.3W/sq m/Tg for SO4. In most cases, the local influence dominates, but results show that mitigations in south and east Asia have substantial impacts on the radiative budget in all investigated receptor regions, especially for BC. In Russia and the Middle East, more than 80 % of the forcing for BC and OA is due to extra-regional emission reductions. Similarly, for North America, BC emissions control in east Asia is found to be more important than domestic mitigations, which is consistent with previous findings. Comparing fully resolved RF calculations to RF estimates based on vertically averaged AFE profiles allows us to quantify the importance of vertical resolution to RF estimates. We find that locally in the source regions, a 20% emission reduction strengthens the radiative forcing associated with SO4 by 25% when including the vertical dimension, as the AFE for SO4 is strongest near the surface. Conversely, the local RF from BC weakens by 37% since BC AFE is low close to the ground. The fraction of BC direct effect forcing attributable to intercontinental transport, on the other hand, is enhanced by one-third when accounting for the vertical aspect, because long-range transport primarily leads to aerosol changes at high altitudes, where the BC AFE is strong. While the surface temperature response may vary with the altitude of aerosol change, the analysis in the present study is not extended to estimates of temperature or precipitation changes.

profiles of aerosol forcing efficiency (AFE)↗

Toward Realistic Dynamics of Rotating Orbital Debris, and Implications for Lightcurve Interpretation

Optical observations of rotating space debris near GEO contain important information on size, shape, composition, and rotational states, but these aspects are difficult to extract due to data limitations and the high number of degrees of freedom in the modeling process. For tri-axial rigid debris objects created by satellite fragmentations, the most likely initial rotation state has a large component of initial angular velocity directed along the intermediate axis of inertia, leading to large angular reorientations of the body on the timescale of the rotation period. This lends some support to the simplest possible interpretation of light curves -- that they represent sets of random orientations of the objects of study. However, effects of internal friction and solar radiation are likely to cause significant modification of rotation states within a time as short as a few orbital periods. In order to examine the rotational dynamics of debris objects under the influences of these effects, a set of seven first-order coupled equations of motion were assembled in state form: three are Euler equations describing the rates of change of the components of angular velocity in the body frame, and four describe the rates of change of the components of the unit quaternion. Quaternions are a four-dimensional extension of complex numbers that form a seamless, singularity-free representation of body orientation on S3. The Euler equations contain explicit terms describing torque from solar radiation in terms of spherical harmonics, and terms representing effects of a prescribed rate of internal friction. Numerical integrations of these equations of motion are being performed, and results will be presented. Initial tests show that internal friction without solar radiation torque leads to rotation about the maximum principal axis of inertia, as required, and solar radiation torque is expected to lead to spin-up of objects. Because the axis of maximum rotational inertia tends to be roughly coincident with the normal to the largest projected cross-sectional area, internal friction is expected to lead to reduced variation of light curve amplitudes at a given phase angle, but a large dependence of the same on phase angle. At a given phase angle, databases are generated which contain reflected intensities for comprehensive sets of equally-likely orientations, represented as unit quaternions. When projected onto three dimensions (S2) and color-coded by intensity, the set is depicted as points within a solid, semi-transparent unit sphere, within which all possible reflected intensities for an object at a given phase angle may be inspected simultaneously. Rotational sequences are represented by trajectories through the sphere. Databases are generated for each of a set of phase angles separately, forming a comprehensive dataset of reflected intensities spanning all object orientations and solar phase angles. Symmetries in the problem suggest that preferred rotation states are likely, defined relative to the object-sun direction in inertial space and relative to the maximum principal axis of inertia in the body coordinate system. Such rotation states may greatly simplify the problem of light curve interpretation by reducing the number of degrees of freedom in the problem.

Ojakangas, Gregory W.↗

Numerical solution of the Navier-Stokes equations for super-sonic flows with strong shocks

The numerical solution of the full Navier-Stokes Equations for viscous flows with high Mach numbers and a strong detached bow shock was obtained. Two dimensional flows around a circular cylinder, and a circular cylinder with an aft-body in the form of a fairing, were considered. The solution of the compressible N.S. equations was accomplished by the method of finite differences. An implicit scheme of solution, the S.O.R., was used with the optimum acceleration parameters determined by trial and error. The tensor notation was used in writing the N-S Equations transformed into general curvilinear coordinates. The equations for the generation of the coordinate system were solved, followed by the solution of the N.S. equations, at the end of a set of given number of time steps. "Wiggles", constituted the one major problem that needed to be overcome. These oscillations give rise to quantities such as negative temperatures, which ultimately caused the computational program to break down. Certain dissipative finite-difference schemes damped these oscillations.

Devarayalu, K.↗

Effect of outer-cylinder rotation on the radially heated Taylor–Couette flow

A Taylor–Couette setup with radial heating is considered where a Boussinesq fluid is sheared in the annular region between two concentric, independently rotating cylinders maintained at different temperatures. Linear stability analysis is performed to determine the Taylor number for the onset of instability. Two radius ratios corresponding to wide and thin gaps with several rotation rate ratios are considered. The rotation of the outer cylinder is found to have a general stabilizing effect on the stability threshold as compared to pure inner-cylinder rotation, with a few exceptions. The radial heating sets up an axial flow which breaks the reflection symmetry of isothermal Taylor–Couette flow in the axial coordinate. This symmetry breaking separates linear stability thresholds, and we find the fastest growing modes with both positive and negative azimuthal numbers for different parameters. Another important finding of the current study is the discovery of unstable modes in the Rayleigh-stable regime. Furthermore, closed disconnected neutral curves (CDNCs) are observed for both wide and thin gaps which can separate from or merge into open neutral–stability curves. Alternatively, CDNCs can also morph into open neutral stability curves as the rotation rate ratio is changed. CDNCs are observed to be sensitive to changes in control parameters, and their appearance/disappearance is shown to induce discontinuous jumps in the critical Taylor number. Finally, for both wide and thin gaps, the fastest-growing modes found in the pure corotation case are shown to have their origins in the instability islands at smaller values of rotation rate ratios.

97 MATHEMATICS AND COMPUTING↗

Transition Prediction in Hypersonic Boundary Layers Using Receptivity and Freestream Spectra

Boundary-layer transition in hypersonic flows over a straight cone can be predicted using measured freestream spectra, receptivity, and threshold values for the wall pressure fluctuations at the transition onset points. Simulations are performed for hypersonic boundary-layer flows over a 7-degree half-angle straight cone with varying bluntness at a freestream Mach number of 10. The steady and the unsteady flow fields are obtained by solving the two-dimensional Navier-Stokes equations in axisymmetric coordinates using a 5th-order accurate weighted essentially non-oscillatory (WENO) scheme for space discretization and using a third-order total-variation-diminishing (TVD) Runge-Kutta scheme for time integration. The calculated N-factors at the transition onset location increase gradually with increasing unit Reynolds numbers for flow over a sharp cone and remain almost the same for flow over a blunt cone. The receptivity coefficient increases slightly with increasing unit Reynolds numbers. They are on the order of 4 for a sharp cone and are on the order of 1 for a blunt cone. The location of transition onset predicted from the simulation including the freestream spectrum, receptivity, and the linear and the weakly nonlinear evolutions yields a solution close to the measured onset location for the sharp cone. The simulations over-predict transition onset by about twenty percent for the blunt cone.

Balakumar, P.↗

Distributed directory of named data elements in coordination namespace

An approach is described that provides a distributed directory structure within a storage of an information handling system (a local node). A request is received with the request corresponding to a shared virtual address. The shared virtual address that is shared amongst a number of nodes that includes the local node and some remote nodes. A Global Address Space Directory (GASD) is retrieved that corresponds to a global virtual address space. The GASD is stored in a Coordination Namespace that is stored in a memory that is distributed amongst the nodes. A mapping that is included in the GASD is used to determine the node where the shared virtual address currently resides. The shared virtual address is then accessed from the node where it currently resides.

Johns, Charles Ray↗

Chondrites, S asteroids, and space weathering: Thumping noises from the coffin?

Most of the spectral characteristics of ordinary chondrites and S-asteroids in the visible and infrared can be reduced to three numerical values. These values represent the depth of the absorption band resulting from octahedrally coordinated Fe(sup 2+), the reflectance at 0.56 microns and the slope of the continuum (as measured according to convention). By plotting these three characteristics, it is possible to immediately compare the spectral characteristics of large numbers of ordinary chondrites and S-asteroids. Commonality of spectral characteristics between these populations can thus be evaluated on the basis of overlap in position on three two-coordinate systems: albedo vs. band depth, band depth vs. slope, and slope vs. albedo. In order to establish identity, members of the two populations must overlap on all three of these independent parameter spaces. In this coordinate system, spectra of 23 ordinary chondrites (representing all metamorphic grades), and 39 S-asteroids were compared. It was found that there was no overlap between the two populations in terms of the slope vs. band depth parameters, nor were most chondrites identical to the S-asteroids with respect to the other criteria. However, the controversial question remains: Where are the parent bodies of the chondrites? Perhaps an even more critical question is: Where are our samples of the S-asteroids? Considering the geography of the asteroid belt and the theory that early solar-system electromagnetic induction heating differentiated protoasteroids in the inner portion of the main belt, it was suggested that although S-asteroids and ordinary chondrites have very similar mineralogy, the S-asteroids are mixtures of metallic nickel iron and silicates which resulted from magmatism induced by electromagnetic heating whereas chondrites were only slightly metamorphosed nebular condensates. In this scenario chondrites would have been derived from a population of bodies with thermal lag times so short that they were not subjected to melting during the phase of the electromagnetic induction heating event but only to various degrees of pervasive metamorphism. Furthermore, these objects would then have been too small to be observed and systematically included in the library of asteroidal spectra. It was also suggested that the parametric distribution of S-asteroid spectra could be reproduced by mixing various proportions of NiFe meteorite and achondritic materials. This has also been demonstrated in the laboratory.

Fanale, F. P.↗

Water-Rock Interactions in Outer Solar System Bodies: Evidence from the Coordinated Analysis of Interplanetary Dust

NASA has an ongoing program of collecting interplanetary dust particles (IDPs) in the stratosphere using high altitude research aircraft. The collected IDPs are derived from asteroids and comets and here we report studies of a subset of hydrated IDPs rich in carbonaceous matter that are proposed to have a cometary origin. Our studies are aimed at understanding the evolution of oxygen reservoirs in the Solar System and their interaction with cometary minerals and organic matter. The small size (<20 μm) and fragility of these IDPs present a number of analytical challenges. We have pioneered techniques for performing chemical, mineralogical, isotopic, and spectroscopic measurements on the same sample in a carefully coordinated sequence. Coordinated analyses of nanogram-size samples is made possible by several delicate sample preparation techniques. To avoid organic contamination, we embed IDPs in elemental sulfur and use ultramicrotomy to partly section the particles (the first few micrometers). Multiple thin sections (50-70 nm thick) are placed on different substrates depending on the analysis technique. We use a JEOL 2500SE scanning, transmission electron microscope (STEM) to determine the mineralogy, microstructure, and elemental compositions of constituent minerals in the thin sections through a combination of high resolution imaging, electron diffraction, quantitative energy-dispersive x-ray mapping, and electron energy-loss spectroscopy. Following the STEM analyses, we use a NanoSIMS 50L for high spatial resolution isotopic measurements of H, C, N, and O to search for presolar grains and to understand the origin of the indigenous organic matter. The isotopic analyses are performed on the same sections analyzed in the STEM in order to correlate isotopic properties with the elemental and mineralogical data. We reserve other thin sections for non-destructive analyses utilizing synchrotron-based techniques including Fourier-transform infrared (FTIR) micro-spectroscopy and X-ray absorption near-edge structure (XANES) analyses, especially for functional group analysis of organic matter in the particles. The remainder of the IDP is extracted from the sulfur bead that was used for microtomy and is pressed into Au foil for quantitative analysis (including light elements) using a JEOL 8530F field emission electron probe microanalyzer (EPMA). After the EPMA measurements, high precision oxygen isotopic analyses are obtained using Cameca IMS1270/1290 instruments at UCLA. The hydrated IDPs in this study are dominated by saponitic clays, with minor magnetite, carbonate and abundant organic matter. The remarkable oxygen isotopic compositions, high carbon contents, and the abundance of isotopically anomalous organic matter, together suggest that the high carbon, hydrated IDPs are derived from primitive sources not yet represented in meteorite collections such as outer main belt P- and D-type asteroids or comets.

Keller, Lindsay P.↗

Heterobimetallic multi-site concerted proton electron transfer (MS-CPET) promotes coordination-induced O–H bond weakening

Coordination-induced bond weakening of X–H bonds (X = O, N, C) has been observed in a number of low-valent transition metal compounds. However, the impact of an appended electron reservoir on the bond dissociation free energy of the O–H bond (BDFE O–H ) of a substrate bound to a d 0 metal is poorly understood. To gain insight into the ability of separated deprotonation and oxidation sites to decrease the BDFE O–H during proton-coupled electron transfer (PCET) reactions, a bimetallic system in which the sites of proton and electron loss are two distinct metal sites is described. Herein, the interconversion of tris(phosphinoamide) Zr/Co complexes HO–Zr(MesNP i Pr 2 ) 3 CoCN t Bu and O$≡$Zr(MesNP i Pr 2 ) 3 CoCN t Bu via hydrogen atom addition/abstraction was studied. Since the Zr center remains in the d 0 Zr IV state throughout these transformations, the electron transfer process is mediated by the appended redox-active Co 0/I center. A series of open-circuit potential (OCP) measurements on the HO–Zr(MesNP i Pr 2 ) 3 CoCN t Bu and O$≡$Zr(MesNP i Pr 2 ) 3 CoCN t Bu complexes was performed, from which the BDFE O–H was found to be 64 ± 1 kcal mol −1 . The BDFE O–H value was further verified through a series of stoichiometric H atom transfer reactions, stoichiometric protonation/deprotonation reactions, and computational studies.

Chemistry↗

Molecular structure determination: Equilibrium structure of pyrimidine (m-C 4 H 4 N 2 ) from rotational spectroscopy (reSE) and high-level ab initio calculation (re) agree within the uncertainty of experimental measurement

The pure rotational spectrum of pyrimidine (m-C 4 H 4 N 2 ), the meta-substituted dinitrogen analog of benzene, has been studied in the millimeter-wave region from 235 GHz to 360 GHz. The rotational spectrum of the ground vibrational state has been assigned and fit to yield accurate rotational and distortion constants. Over 1700 distinct transitions were identified for the normal isotopologue in its ground vibrational state and least-squares fit to a partial sextic S-reduced Hamiltonian. Transitions for all four singly substituted 13 C and 15 N isotopologues were observed at natural abundance and were likewise fit. Deuterium-enriched samples of pyrimidine were synthesized, giving access to all eleven possible deuterium-substituted isotopologues, ten of which were previously unreported. Experimental values of rotational constants and computed values of vibration–rotation interaction constants and electron-mass corrections were used to determine semi-experimental equilibrium structures (r e SE ) of pyrimidine. The r e SE structure obtained using coupled-cluster with single, double, and perturbative triple excitations [CCSD(T)] corrections shows exceptional agreement with the re structure computed at the CCSD(T)/cc-pCV5Z level (≤0.0002 Å in bond distance and ≤0.03° in bond angle). Of the various computational methods examined, CCSD(T)/cc-pCV5Z is the only method for which the computed value of each geometric parameter lies within the statistical experimental uncertainty (2σ) of the corresponding semi-experimental coordinate. The exceptionally high accuracy and precision of the structure determination is a consequence of the large number of isotopologues measured, the precision and extent of the experimental frequency measurements, and the sophisticated theoretical treatment of the effects of vibration–rotation coupling and electron mass. Taken together, these demanding experimental and computational studies establish the capabilities of modern structural analysis for a prototypical monocyclic aromatic compound.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Numerical solutions of the Navier-Stokes equations for the supersonic laminar flow over a two-dimensional compression corner

Numerical solutions have been obtained for the supersonic, laminar flow over a two-dimensional compression corner. These solutions were obtained as steady-state solutions to the unsteady Navier-Stokes equations using the finite difference method of Brailovskaya, which has second-order accuracy in the spatial coordinates. Good agreement was obtained between the computed results and wall pressure distributions measured experimentally for Mach numbers of 4 and 6.06, and respective Reynolds numbers, based on free-stream conditions and the distance from the leading edge to the corner. In those calculations, as well as in others, sufficient resolution was obtained to show the streamline pattern in the separation bubble. Upstream boundary conditions to the compression corner flow were provided by numerically solving the unsteady Navier-Stokes equations for the flat plate flow field, beginning at the leading edge. The compression corner flow field was enclosed by a computational boundary with the unknown boundary conditions supplied by extrapolation from internally computed points.

Carter, J. E.↗

Calculation of unsteady transonic aerodynamics for oscillating wings with thickness.

An analytical approach is presented to account for some of the nonlinear characteristics of the transonic flow equation for finite thickness wings undergoing harmonic oscillation at sonic flight speed in an inviscid, shock-free fluid. The thickness effect is accounted for in the analysis through use of the steady local Mach number distribution over the wing at its mean position by employing the local linearization concept and a coordinate transformation. Computed results are compared with that of the linearized theory and experiments. Application to a flutter problem is shown.

Ruo, S. Y.↗

Calculation of unsteady transonic aerodynamics for oscillating wings with thickness

An analytical approach is presented to account for some of the nonlinear characteristics of the transonic flow equation for finite thickness wings undergoing harmonic oscillation at sonic flight speed in an inviscid, shock-free fluid. The thickness effect is accounted for in the analysis through use of the steady local Mach number distribution over the wing at its mean position by employing the local linearization concept and a coordinate transformation. Computed results are compared with that of the linearized theory and experiments. Based on the local linearization concept, an alternate formulation avoiding the limitations of the coordinate transformation method is presented.

Ruo, S. Y.↗

Zero-G experiments in two-phase fluids flow regimes

The two-phase flows studied were liquid and gas mixtures in a straight flow channel of circular cross-section. Boundaries between flow regimes have been defined for normogravity on coordinates of gas quality and total mass velocity; and, when combined with boundary expressions having a Froude number term, an analytical model was derived predicting boundary shifts with changes in gravity level. Experiments with air and water were performed, first in the normogravity environment of a ground laboratory and then in 'zero gravity' aboard a KC-135 aircraft flying parabolic trajectories. Data reduction confirmed regime boundary shifts in the direction predicted, although the magnitude was a little less than predicted. Pressure drop measurements showed significant increases for the low gravity condition.

Heppner, D. B.↗

Improved data display for milling machine

Axis position and sequence number indicator system is designed to work in conjunction with numerical tape controller. Visual display of coordinate-axis position to nearest 0.0001 inch and sequential blocks of input data up to maximum of 999 are provided.

Surrency, W. M.↗

Calculation of a simulated 3-D high speed inlet using the Navier-Stokes equations

A hybrid numerical algorithm, developed to solve the full three-dimensional Navier-Stokes equations, is applied to the computation of the flowfield in a simulated three-dimensional high speed aircraft inlet at a Mach number of 2.5 and Reynolds number of 1.4 x 10 to the 7th based on inlet length. The numerical algorithm incorporates a coordinate transformation in order to handle general flow geometries, and utilizes the algebraic turbulent eddy viscosity model of Baldwin and Lomax. The hybrid algorithm has been vectorized on the CDC CYBER 203 computer using the SL/1 vector programming language developed at NASA Langley. The computed results are compared with experimental measurements of the ramp and cowl static pressures, and boundary layer pitot profiles. The results are also compared with a previous two-dimensional Navier-Stokes computation of the same configuration. The agreement with the experimental data is generally good; however, additional improvements in turbulence modeling are needed.

Knight, D. D.↗