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At least 631 records · Page 35

The application of connectionism to query planning/scheduling in intelligent user interfaces

In the mid nineties, the Earth Observing System (EOS) will generate an estimated 10 terabytes of data per day. This enormous amount of data will require the use of sophisticated technologies from real time distributed Artificial Intelligence (AI) and data management. Without regard to the overall problems in distributed AI, efficient models were developed for doing query planning and/or scheduling in intelligent user interfaces that reside in a network environment. Before intelligent query/planning can be done, a model for real time AI planning and/or scheduling must be developed. As Connectionist Models (CM) have shown promise in increasing run times, a connectionist approach to AI planning and/or scheduling is proposed. The solution involves merging a CM rule based system to a general spreading activation model for the generation and selection of plans. The system was implemented in the Rochester Connectionist Simulator and runs on a Sun 3/260.

Short, Nicholas, Jr.↗

1,10-Phenanthroline-Iron Complex-Derived Fe-N-C Electrocatalysts: Enhanced Oxygen Reduction Activity and Stability Through Synthesis Tuning

The development of electrocatalysts composed of earth-abundant elements is essential for advancing the commercial application of Proton Exchange Membrane Fuel Cells (PEMFC). Among these, single-atom electrocatalysts, such as Fe-N-C, show great promise for the oxygen reduction reaction (ORR). This study aims to improve the ORR activity and stability of Fe-N-C electrocatalysts by fine-tuning the straightforward 1,10-phenanthroline-iron complexation synthesis method. Key parameters, including iron-to-phenanthroline ratio, carbon powder surface area, and pyrolysis temperature were systematically varied to evaluate their influence on the resulting electrocatalysts. The findings of this study revealed that the electrocatalysts synthesized with 1,10-phenanthroline (Phen) and high-surface-area Black Pearls (BP) possessed much better ORR activity than electrocatalysts prepared by using Vulcan carbon (lower surface area). Interestingly, electrocatalysts prepared with BP, but with a non-bidentate nitrogen-containing ligand molecule, such as imidazole, showed a much poorer activity, as the resulting material predominantly consisted of inactive structures, such as encapsulated iron nanoparticles and iron oxide, as evidenced by HR-TEM, EXAFS, and XRD. Therefore, the results suggest that only the synergistic combination of the bidentate ligand phenanthroline (Phen) and the high-surface-area carbon support (BP) favored the formation of ORR-active Fe-N-C single-atom species upon pyrolysis. The study also unveiled a significant enhancement in electrocatalyst stability during accelerated durability tests (and air storage) as the pyrolysis temperature was increased from 700 to 1300 °C, albeit at the expense of ORR activity, likely resulting from the generation of iron particles. Pyrolysis at 1050 °C yielded the electrocatalyst with the most favorable balance of activity and stability in rotating disk measurements, while maintaining moderate durability under PEM fuel cell operation. The insights obtained in this study may guide the development of more active efficient and durable electrocatalysts, synthesized via a simple method using earth-abundant elements, for application in PEMFC cathodes.

30 DIRECT ENERGY CONVERSION↗

Mission Operations of the Mars Exploration Rovers

A document describes a system of processes involved in planning, commanding, and monitoring operations of the rovers Spirit and Opportunity of the Mars Exploration Rover mission. The system is designed to minimize command turnaround time, given that inherent uncertainties in terrain conditions and in successful completion of planned landed spacecraft motions preclude planning of some spacecraft activities until the results of prior activities are known by the ground-based operations team. The processes are partitioned into those (designated as tactical) that must be tied to the Martian clock and those (designated strategic) that can, without loss, be completed in a more leisurely fashion. The tactical processes include assessment of downlinked data, refinement and validation of activity plans, sequencing of commands, and integration and validation of sequences. Strategic processes include communications planning and generation of long-term activity plans. The primary benefit of this partition is to enable the tactical portion of the team to focus solely on tasks that contribute directly to meeting the deadlines for commanding the rover s each sol (1 sol = 1 Martian day) - achieving a turnaround time of 18 hours or less, while facilitating strategic team interactions with other organizations that do not work on a Mars time schedule.

Bass, Deborah↗

Deep Learning for Full Waveform Inversion of Elastic Active-Source Seismic Data to Estimate P-Wave Velocity Models

Seismic imaging methods are critical for Global Security and Energy & Homeland Security missions and activities that rely on subsurface characterization, but traditional methods remain computationally expensive and require significant labor hours and expertise to execute. Within the past few years, machine learning (ML), namely deep learning (DL), has been used to develop data-driven end-to-end full waveform inversion (FWI) methods to estimate 2D P-wave velocity (Vp) models in a fraction of the time as conventional FWI. These methods, however, are trained on simplistic acoustic wave seismic data and Vp models that are not realistic nor representative of real-world observations, leaving a large gap between the state-of-the-art and deployable, feasible, and practical DL FWI methods. Here, we generate a synthetic active-source, 3D, elastic wave seismic data set and a variety of Vp models with realistic geologic structure for training DL FWI methods. We evaluate six different methods that have performed well for acoustic DL FWI or medical imaging tasks using our more realistic dataset. We find that these six trained models do not match the performance of published acoustic end-to-end DL FWI methods, indicating more training data may be needed, physics may need to be incorporated to achieve good accuracy at the sacrifice of the end-to-end advantage, and/or novel methods need to be developed to enable end-to-end DL FWI methods to perform well for real-world seismic data.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Radicals as Exceptional Electron-Withdrawing Groups: Nucleophilic Aromatic Substitution of Halophenols Via Homolysis-Enabled Electronic Activation

While heteroatom-centered radicals are understood to be highly electrophilic, their ability to serve as transient electron-withdrawing groups and facilitate polar reactions at distal sites has not been extensively developed. Here, we report a new strategy for the electronic activation of halophenols, wherein generation of a phenoxyl radical via formal homolysis of the aryl O-H bond enables direct nucleophilic aromatic substitution of the halide with carboxylate nucleophiles under mild conditions. Pulse radiolysis and transient absorption studies reveal that the neutral oxygen radical (O • ) is indeed an extraor-dinarily strong electron-withdrawing group [σ p - (O • ) = 2.79 vs. σ p - (NO 2 ) = 1.27]. Additional mechanistic and computational studies indicate that the key phenoxyl intermediate serves as an open-shell electron-withdrawing group in these reactions, lowering the barrier for nucleophilic substitution by more than 20 kcal/mol relative to the closed-shell phenol form of the substrate. Finally, by using radicals as transient activating groups, this homolysis-enabled electronic activation strategy provides a powerful platform to expand the scope of nucleophile-electrophile couplings and enable previously challenging transformations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Small Scale Motions Observed by Aircraft in the Tropical Tropopause Layer - Convective and Non-Convective Environments

Indirect evidence indicates a role for vertical mixing in the Tropical Tropopause Layer (TTL). In particular, detailed model studies suggest that such vertical mixing may be required to explain the value of the water vapor minimum in the TTL. There have been previous observations during the STEP Tropical aircraft campaign (1987) of bursts of high frequency activity associated with convectively generated gravity waves in the tropical western Pacific. Higher frequency, higher quality measurements from NASA high altitude aircraft (ER-2, WB-57, and Global Hawk) have been made available in the last 20 years. These include measurements of vertical velocity and other meteorological parameters. Most recently, during the ATTREX Global Hawk aircraft mission (Airborne Tropical TRopopause EXperiment), there have been extensive measurements at all altitudes of the TTL in both convective (winter western Pacific) and less convective (winter eastern Pacific) regions. This presentation represents an initial analysis of high frequency small scale (a few km max) meteorological measurements from the ATTREX dataset. We obtain some basic information about the distribution and character of high frequency activity in vertical velocity in the TTL. In particular, we focus on relating the high frequency activity to nearby tropical convection and to vertical shears associated with gravity and inertia-gravity waves.

convection↗

The Psyche Planning Software Subsystem: Creating a Robust Toolset for a Discovery-class Mission

Psyche is a Discovery-class mission to the small metal-rich asteroid (16) Psyche, and is slated to launch in 2022. Psyche, like many missions, requires low-cost activity planning and sequence generation that serves as the backbone to overall uplink design. Such tools must be maintainable over long periods of operations, and powerful enough to solve complex issues that deep-space one-off missions encounter. In this paper we introduce cost-effective solutions that leverage inner- and open-source principles to meet a variety of common and novel use cases.The uplink process that was designed to meet these challenges is presented, as well as the data-flow through the high-level architecture of the planning software subsystem. The user-facing planning tools are described, particularly the Science Opportunity Analyzer, the Plan Editor, Psyche’s planning automation in the Blackbird framework, and Psyche Simulation Reports. All these applications are either new or have been substantially revamped to meet Psyche’s concept of operations. In particular, ensuring the entire toolchain can correctly process epoch-relative activities is discussed. Underlying the main applications are a common set of dependencies developed and maintained by a new cross-mission association of planning developers. In this way, Psyche can inherit well-tested functionality which saves effort and ensures its developers can focus on solving domain challenges. Quality control of the applications and libraries is ensured with a code-review and unit-test based novel ‘CM lite’ process. Collaboration with international industry and academia using the open-source modules is already occurring.The planning and scheduling software is designed to maximize operator awareness of the integrated plan at every step of the process and use common interfaces and file formats to easily transfer information. Design choices plus the team’s test-driven development process enables more expansive capabilities compared to the decentralized planning and sequence generation functions typical of Discovery-class orbiters without significant development cost increases. Benefits and drawbacks of Psyche’s approach are discussed, including comparison to other missions and tools where appropriate.

Ramanathan, Keshav↗

Overview of Upcoming Process Improvement Efforts at the Saltstone Facilities at the Savannah River Site - 20474

The Saltstone Facilities at the Savannah River Site (SRS) process and dispose of low activity salt solution waste generated by other liquid waste facilities. Today in the Liquid Waste System (LWS), approximately 125 million liters of salt waste remain to be processed. The Saltstone Production Facility (SPF) receives the decontaminated salt waste, which is mixed with dry feeds consisting of cement, fly ash and slag to produce the saltstone. The mixed slurry is pumped to the Saltstone Disposal Units (SDUs) for safe disposal in the Saltstone Disposal Facility (SDF). To support continuous Salt Waste Processing Facility (SWPF) operations at annual processing volumes many times higher than present, significant modifications are required to ensure that the SPF has the capacity to support the throughput of salt waste. These changes include several infrastructure upgrades that are being worked through the Enhanced Low Activity Waste Disposal (ELAWD) project. In addition to infrastructure upgrades, Savannah River Remediation (SRR), the Savannah River Site's Liquid Waste Contractor for the U.S. Department of Energy, has identified a flowsheet improvement opportunity of implementing a cement-free saltstone formulation to eliminate cement from the current three component formulation. This two-component formulation would simplify the procurement, transport, off-loading, and storage of the premix materials, and increase the storage capacity for the individual components. This flowsheet, when implemented, will reduce operational risk and improve throughput necessary to achieve disposal rates necessary for SWPF operations. Research has been completed to confirm the feasibility of this formulation, with the new cement-free flowsheet expected to be implemented in the next few years. Improvements have also been identified downstream of the SPF to increase SDU utilization. Specifically, a concentrated effort has taken place to raise the fill height in SDU 6 to the full disposal height, 13 meters, to maximize the usage of each SDU in support of the liquid waste disposal mission. This improvement has been made through additional thermal modeling and improved process understanding to create a SDU flammability model and control strategy more representative of facility operations. This work will allow for the completion of construction and operational readiness for SDU 7 while filling SDU 6 to ensure there is no lapse in available space once SWPF starts up. A summary of these improvements as they relate to increased throughput will be provided along with associated status. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Relation Between Polar Plumes and Fine Structure in the Solar Wind from Ulysses High-Latitude Observations

Ulysses observations showed that pressure balance structures (PBSs) are a common feature in the high-latitude and high-speed solar winds near the solar minimum. On the other hand, coronal plumes are common in polar coronal holes. PBSs are believed to be remnants of coronal plumes and to be related to network activity such as magnetic reconnection in the photosphere from previous studies. This suggests that information on the magnetic structure of PBSs would help to confirm the relation between PBSs and polar plumes We have investigated the magnetic structures of the PBSs by applying a minimum variance analysis to Ulysses/Magnetometer data and by examining the pitch-angle distribution of energetic electrons measured with Ulysses/SWOOPS. We have found that PBSs have relatively more tangential discontinuities rather than rotational from the minimum variance analysis. Further, most PBSs also show bi-directional electron flux or isotropic pitch-angle distribution or the distribution expected in association with current-sheet structures from the analysis of high-energy electron data. In this, we find further evidence that PBSs are generated due by network activity at the base of polar plumes and their magnetic structures are like current sheets or plasmoids.

Yamauchi, Yohei↗

Evaluation of Second Target Station Target Streaming for the Preliminary Design of the Target Assembly

This report documents the analysis of dose rate fields from a combination of two sources stemming from the target system of the Oak Ridge National Laboratory (ORNL) Spallation Neutron Source (SNS) Second Target Station (STS). This analysis supports the target drive components’ lifetime estimates and conventional facilities’ preliminary design. The two sources detailed in this report are the radiation generated by the proton beam incident on the target and the activated cooling water in the pipes at the top of the target assembly. The analysis considers the STS target system in operational configuration, with all shielding in place. The dose rate fields are calculated in the target drive room and through the target drive room ceiling. This report calculates the thickness necessary for the target drive room’s high-density concrete ceiling to meet the 0.25 mrem/hr dose limit requirement in the high bay directly above the target drive room. In addition to sizing the target drive room ceiling, this report includes details of the dose field surrounding the target drive assembly to estimate the deposited dose in the target drive assembly components resulting from both streaming and decay of activated water. Prompt neutrons and gammas generated by the proton beam incident on the target primarily stream along the gaps between the target assembly and core vessel shielding. Because the models and analysis detailed in this report are based on the STS preliminary design, future analysis is needed to support the STS final design.

43 PARTICLE ACCELERATORS↗

Electrodynamic Dust Shield Testing on the Materials on International Space Station Experiment 11

Dust is a major concern for lunar exploration. To combat the effects of dust, NASA, academia, and industry are developingsolutions to the dust problem. One potential technology solution for this problem is the Electrodynamic DustShield (EDS). Many years of research and development have gone into this technology. The Materials on InternationalSpace Station Experiment - 11 (MISSE-11) provides a long term space exposure platform for this technology to verifycompatibility of materials and manufacturing processes to the space environment. The MISSE-11 EDS experimentconsists of 12 EDS panels. These panels are made of glass, polyimide, or prototype spacesuit fabric. Some panels arecovered with a lotus leaf coating while others are covered with thermal paint. They are flown in the wake position ofthe ISS to simulate the lunar environment. Two panels are in an active configuration and are energized with a highvoltage power supply, which generates high-voltage pulses to activate the dust shields. Current and voltage data arerecovered from each of these trials to compare to baseline data. Also, each of the EDS panels are imaged on a monthlybasis to track any changes with time that may occur with the EDS variants. In this paper, we report preliminary dataand analysis from this spaceflight experiment.

Johansen, Michael R.↗

Tuning acidity in silica-overcoated oxides for hydroalkoxylation

Mixed oxides are ubiquitious solid acid catalysts for a number of transformations. Here, the chemistry of mixed oxide interfaces was experimentally probed by constructing model SiO 2 on MO x interfaces using a liquid-phase, stoichiometrically-controlled deposition of tetraethyl orthosilicate (TEOS). Catalytically active Brønsted sites were generated in four series of overcoated SiO 2 on metal oxide materials prepared by depositing TEOS onto Al 2 O 3 , anatase TiO 2 , Nb 2 O 5 , and ZrO 2 . Pyridine DRIFTS studies indicate that the acidity of deposited silanol groups was enhanced by interaction with the metal oxide surface, suggesting that pseudo-bridging silanol type structures were formed. Trimethylphosphine oxide (TMPO) 31 P NMR experiments showed that Brønsted acid strength varied in the overcoated materials, with increasing strength in the following order: SiO 2 /ZrO 2 < SiO 2 /TiO 2 < SiO 2 /Nb 2 O 5 < SiO 2 /Al 2 O 3 . This order correlated with the Lewis acidity and chemical hardness of the underlying metal oxides. The catalytic performance of the materials was evaluated in the liquid-phase hydroalkoxylation of dihydropyran with n-octanol, revealing that activity was highly dependent on SiO 2 loading, which impacted the density of acid sites, and scaled exponentially with Brønsted acid strength, determined by the core metal oxide identity. Brønsted acid strength appears to be the key driver of the materials’ activity, with the highest areal rate of 2.2 mmol / m 2 – h being measured over SiO 2 /Al 2 O 3 . Furthermore, this study shows that SiO 2 -overcoated materials are a systematically tunable class of catalysts that can be applied to acid catalyzed reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Preparation of Flight Operations and IWS Integration of the CELIAS Experiment on the SOHO Spacecraft

During this annual progress report time period, the following activities took place: (1) Generation of several versions of the CELIAS (STOF/SEM/CTOF/MTOF/DPU) commissioning timeline for the first 180 days after launch. These were written and submitted by A. Galvin after consultation (phone, fax, e-mail, meetings) with the CELIAS Instrument Manager and Lead-Co-I's. (2) Identification of several problems with the CELIAS portion of the Project Data Base (PDB). (3) Meetings with the Flight Operations Team regarding PDB, critical commands, etc. (4) Attend Science Operations Working Group (SOWG) Meetings (November 1994, February 1995, May 1995) and Flight Operations Review Meeting (July 1995). (5) Participate in Flight Operation Simulations SIM 1 (November 14-18, 1994), SIM 2 (May 1-4, 1995) and SIM3 (August 7-11, 1995). (6) Participate in the Ground System Compatibility Test Rehearsal (April 24- 28, 1995), GSCT #2 (May 30-June 14, 1995), GSCT #3 (September 12-22, 1995), and GSCT #4b (October 30-November 5, 1995). A small portion of the documentation for the above cited activities is appended.

Ipavich, Fred↗

Recent Progress of JT-60SA Project toward Plasma Operation

Superconducting tokamak JT-60SA plays an essential role in fusion research and development by supporting and complementing ITER project, providing directions to the DEMO design activity and fostering next generation scientists and engineers. Since the incident of the Equilibrium Field coil #1 during the Integrated Commissioning (IC) in March 2021, both EU and JA Implementing agencies (IAs) have examined how to ensure safety operation of JT-60SA by mitigating the risk of possible discharge occurrence inside the cryostat. Based on the experience of the Global Paschen tests, the IAs have established a strategy of risk mitigation measures, which is a combination of (i) reinforcement of insulation, (ii) avoiding unnecessary voltage application to the coil systems and (iii) immediate de-energization of the coils when deteriorated vacuum condition is detected. Thanks to the considerable efforts of the Integrated Project Team (IPT) members, the IC restarted in May 2023. After the confirmation of superconducting state of coil systems (TF, EF and CS), the coil energization test and the plasma operation (OP-1) starts. The first plasma was successfully achieved on 23 October 2023 with a limited value of applied voltage and current to the coils. The plasma configuration control will be also confirmed with low plasma current and low auxiliary heating power conditions. Based on the IO-F4E-QST collaboration, activities of JT-60SA have been shared with the IO and provided an important lesson learned for ITER assembly and commissioning, and will provide an outstanding contribution to fusion research at large. After OP-1, Maintenance & Enhancement phase 1 (M/E-1) starts from January 2024, in which in-vessel components are installed, and heating system and diagnostic system are extensively upgraded to allow high power heating experiment planned in OP-2. In order to make the best use of JT-60SA, newly organized JT-60SA experiment team will refine the research plan in the future high heating power operation phase.

Broader Approach activities↗

Active control of turbomachine discrete tones

This paper was directed at active control of discrete frequency noise generated by subsonic blade rows through cancellation of the blade row interaction generated propagating acoustic waves. First discrete frequency noise generated by a rotor and stator in a duct was analyzed to determine the propagating acoustic pressure waves. Then a mathematical model was developed to analyze and predict the active control of discrete frequency noise generated by subsonic blade rows through cancellation of the propagating acoustic waves, accomplished by utilizing oscillating airfoil surfaces to generate additional control propagating pressure waves. These control waves interact with the propagating acoustic waves, thereby, in principle, canceling the acoustic waves and thus, the far field discrete frequency tones. This model was then applied to a fan exit guide vane to investigate active airfoil surface techniques for control of the propagating acoustic waves, and thus the far field discrete frequency tones, generated by blade row interactions.

Fleeter, Sanford↗

Search for Heavy Neutral Leptons at the MINER$\nu$A detector

Heavy Neutral Leptons (HNL) are particles hypothesised to provide a mass generation mechanism for the active (observed) neutrino species, which are known to have nonzero mass from the definitive observation of neutrino oscillations. HNL are eigenstates of mass of the order $\mathcal{O}(0.1 − 1\,\,\mathrm{GeV}/c^{2})$, which mix into the active flavour eigenstates through the extended leptonic mixing matrix. Apart from neutrino mass, they could provide a natural dark matter candidate and a mechanism for matter-antimatter asymmetry in the early Universe, giving rise to today’s matter-dominated cosmos. Searches for HNL typically attempt to either confirm the existence of HNL through an excess in data that is most compatible with an HNL hypothesis, or by setting limits on the HNL parameter space $\left(M_{N4}, \left|U_{\alpha 4}\right|^{2}\right)$ in the case of statistically insignificant excess. Such searches are intensifying as part of a global research programme at both colliders and accelerator / atmospheric neutrino experiments. One such setting is the MINER$\nu$A experiment, located in the NuMI beamline at Fermilab. MINER$\nu$A has collected a large amount of data over seven years of operation to measure the cross-sections of neutrino-nucleus interactions necessary to drive systematic uncertainties down, in order for neutrino oscillation experiments to achieve sensitivity to CP violation in the neutrino sector. With the high-energy, high-intensity NuMI beam, and with good timing, position, and angular resolution leading to sensitivity to HNL decays, MINER$\nu$A is fertile ground for an HNL search, which is performed in this thesis. Specifically, a novel, experiment-agnostic and general simulation of HNL production and decay is presented and deployed; this simulation has been incorporated in the ubiquitous GENIE neutrino event generator for use with neutrino experiments in the future. The event selection and background characterisation is discussed in detail, including the primary background coming from charged-current coherent and diffractive pion production from neutrino-nucleus interactions, and constraints on the background using control regions from MINER$\nu$A data are derived. Finally, by means of a fake-data study given a background of $\mathcal{O}(500)$ events, the discovery potential and limit-setting capacity of MINER$\nu$A is demonstrated, and ways to improve this capacity are expounded upon.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Development of Closed-Loop Simulation Methods for a Next-Generation Terminal Area Automation System

A next-generation air traffic decision support tool, known as the Active Final Approach Spacing Tool (aFAST), will generate heading, speed and altitude commands to achieve more precise separation of aircraft in the terminal area. The techniques used to analyze the performance of earlier generation decision support tools are not adequate to analyze the performance of aFAST. This paper summarizes the development of a new and innovative fully closed-loop testing method for aFAST. This method, called trajectory feedback testing, closes each aircraft's control loop inside of the aFAST scheduling algorithm. Validation of trajectory feedback testing by examination of the variation of aircraft time-of-arrival predictions between schedule updates and the variation of aircraft excess separation distances between simulation runs is presented.

Robinson, John E., III↗

The Sunspot Record: 1826-1980

The International Sunspot Number is used as a measure of the level of solar activity in many important studies. This includes studies of the effects of solar activity on climate change and on the generation of radioisotopes used to infer levels of solar activity going back thousands of years. Any systematic errors in the historical record of the sunspot number can profoundly alter the conclusions of these studies. There is substantial evidence that the currently accepted International Sunspot Numbers have been subjected to changes in the way the numbers are calculated and to changes in the weights given to observations of various observers. In this talk I will focus on the time period from 1826 to 1980 which covers principal observers Schwabe, Wolf, Wolfer, Brunner, and Waldmeier. Previous investigations have indicated problems associated with Schwabe's observations (1826 to 1867), the first decades of the Greenwich observations (1874 to about 1910), and the introduction of a different counting method by Waldmeier (1946-1980). I will examine the evidence for these problems and the possible solutions that might be used to provide improved estimates of the sunspot numbers and their errors over this time interval.

Hathaway, David H.↗