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NASA NTRS1987

Chemical abundances in molecular clouds

At present approximately 70 interstellar molecules are known. The paper discusses methods for determining chemical abundances in interstellar clouds and presents results for the best studied regions, which include the 'spiral arm' clouds seen towards distant continuum sources, quiescent dark and giant clouds, and the gas in regions of active star formation. For many simple molecules, abundances are rather uniform over a range of densities and temperatures in quiescent clouds, in accord with gas phase, ion-molecule chemical models. Some striking chemical differences do exist both within and among clouds, however, particularly in star-forming regions.

Irvine, W. M.↗
NASA NTRS1987

Elemental abundance analyses with coadded Dominion Astrophysical Observatory spectrograms. II - The mercury-manganese stars 53 Tauri, Mu Leporis and Kappa Cancri

Elemental abundance analyses based on the coaddition of at least 10 2.4 A/mm Ila-O Dominion Astrophysical Observatory spectrograms have been performed for three mercury-manganese stars, 53 Tauri, Mu Leporis, and Kappa Cancri. These fine analyses show a greater degree of internal consistency than previous studies based on lower signal-to-noise data. Lines as weak as of order 3 mA are employed in these studies, and lines of atomic species not previously identified have been discovered. The status of 53 Tau as an anomalous member of this class is confirmed in that it lacks a Hg II 3984 A line even at the 2 mA level. Further, its surface gravity indicates it is less evolved than Mu Lep and Chi Cnc. Violations of the odd-even effect in the photospheric abundances of all three stars suggest that nonnuclear processes have operated in their atmospheres. Some of the values are substantially changed from their presumably initial solar values.

Adelman, Saul J.↗
NASA NTRS1987

Cosmic-ray elemental abundances from 1 to 10 GeV per amu for boron through nickel

The relative abundances of cosmic-ray nuclei in the charge range boron through nickel over the energy range 1-10 GeV per amu were measured with a balloon-borne detector. The instrument consists of a scintillation and Cerenkov counter telescope with a multiwire proportional chamber hodoscope and has been flown in four high-altitude balloon flights. Good charge resolution (sigma = 0.2 charge units at iron) and high statistical accuracy have been achieved. These data are used to derive the energy dependence of the leakage path length using the leaky box model of propagation and confinement in the galaxy. This energy dependence is found to be best fit by lambda = E(tot) exp -n, where n = 0.49 + or - 0.06 over 1-10 GeV per amu. Relative abundances at the source are consistent with an energy-independent composition.

Dwyer, Robert↗
NASA NTRS1988

Chemical constraints on the water and total oxygen abundances in the deep atmosphere of Jupiter

The mechanisms responsible for the observed H2O/H2 mixing ratio (HMR) in the Jovian troposphere are analyzed, with a focus on the relationship between HMR and O2 abundance and the abundance of the nonequilibrium trace gases CO and SiH4. The results of computations using a Jupiter atmosphere model consistent with recent observations (Bjoraker et al., 1986) are presented graphically and discussed in detail. It is found that the observed mixing ratios of CO (about 10 to the -9th) and SiH4 (upper limit 2-4 x 10 to the -9th) preclude O2 depletion and the presence of significant global H2O. The low observed HMRs (0.00003 at 6 bar) are tentatively attributed to local condensation in cloud-forming regions.

Fegley, Bruce, Jr.↗
NASA NTRS1987

The helium abundance of Uranus from Voyager measurements

Voyager radio-occultation and IR spectroscopy measurements are combined to infer an He mole fraction in the upper troposphere of Uranus of 0.152 + or - 0.033; the corresponding mass fraction is Y = 0.262 + or - 0.048. This value is in agreement with recent estimates of the solar He abundance, suggesting that He differentiation has not occurred on Uranus. Comparisons with values previously obtained for Jupiter and Saturn imply that migration of He toward the core began long ago on Saturn and may also have recently begun on Jupiter. The protosolar He abundance inferred from the Uranus measurements and from recent solar evolutionary models is used along with an assumed primordial He mass fraction of 0.23-0.24 to estimate a 3-4-percent enrichment of He in the interstellar medium between the big bang and the origin of the solar system. The result is in agreement with galactic chemical evolution models which include a substantial decrease in D during the evolutionary process.

Conrath, B.↗
NASA NTRS1988

Insensitivity of solar p-mode frequencies to changes in the helium abundance

P-mode oscillation spectra (l = 0-4; n = 12-30) were calculated for three solar models with helium mass fractions Y = 0.230, 0.235, and 0.240. The solar models were tuned to have the Sun's radius and luminosity by adjusting both the age and the ratio of the mixing length to pressure scale height parameter. The models were identically constrained in all other respects. A 4 percent change in the mass fraction of helium produces less than a 0.1 percent change in the frequencies of the low degree p-modes. This result implies that it will be very difficult to determine the helium abundance of the sun directly from the p-mode oscillation spectrum since the frequencies of the modes are relatively insensitive to changes in the helium abundance.

Guenther, D. B.↗
NASA NTRS1988

Abundances in Comet Halley at the time of the spacecraft encounters

Spectrophotometric observations of Comet Halley obtained in March 1986 at the time of the spacecraft encounters with the comet are described, and the column densities derived from the integrated emission band fluxes are presented. The scale lengths are determined from the spatial profiles of the observed species. Production rates are derived and the parent identities and abundance ratios of the studied species are discussed. The data indicate that the abundance of the primordial condensate NH3 comprises about 0.2 percent of the total volatile fraction of the comet nucleus. The ratio of production rates Q(NH2)/Q(H2O) = 0.003 indicates that Q(NH3)/Q(H2O) is roughly 0.3 percent, which is nearly 10 times lower than the value determined from Giotto ion mass spectrometer data. The production rate Q(CH)/Q(H2O) of 0.007 and the CH spatial profile indicate that CH cannot derive entirely from direct photodissociation of CH4.

Wyckoff, Susan↗
NASA NTRS1988

Effect of solar proton events in 1978 and 1979 on the odd nitrogen abundance in the middle atmosphere

Daily average solar proton flux data for 1978 and 1979 are used in a proton energy degradation scheme to derive ion pair production rates and atomic nitrogen production rates. The latter are computed in a form suitable for inclusion in an atmopheric, two-dimensional, time-dependent photochemical model. Odd nitrogen distributions are computed from the model, including atomic nitrogen production from solar protons, and are compared with baseline distributions. The comparisons show that the average effect of the solar protons in 1978 and 1979 was to cause changes in odd nitrogen only above 10 mbar and at latitudes only above about 50 deg in both hemispheres. The influence of the solar proton-produced odd nitrogen on the local abundance of odd nitrogen depends primarily on the background odd nitrogen abundance as well as the altitude and season.

Jackman, Charles H.↗
NASA NTRS1988

Galactic interstellar abundance surveys with IUE. III - Silicon, manganese, iron, sulfur, and zinc

This paper continues a survey of intestellar densities, abundances, and cloud structure in the Galaxy using the IUE satellite. A statistical data set of 223 O3-B2.5 stars is constructed, including 53 stars in the Galactic halo. It is found that S II lines in B stars, of luminosity classes IV and V, have possible contamination from stellar S II, particular for stars with v sin i less than 200 km/s. The mean logarithmic depletions are -1.00, -1.19. -0.63, and -0.23 (Si, Mn,Fe,S, Zn). Depletions of Si, Mn, and Fe correlate with the mean hydrogen density n-bar along the line of sight, with a turnover for n-bar greater than 1/cm. Sulfur depletions correlate with n-bar along the line of sight. The slight Zn depletion correlation also appears to be statistically insignificant. No correlation of depletion is found with the physical density derived from H2 rotational states in 21 lines of sight. Depletion variations in the disk are consistent with a Galactic abundance gradient or with enhanced mean depletions in the anticenter region.

Van Steenberg, Michael E.↗
NASA NTRS1988

The abundances of carbon and nitrogen in I Zw 18

The first measurements of the semiforbidden C III 1909 A and forbidden N II 6583 A emission lines in I Zw 18 are reported. These data are combined with previously published spectrophotometry in order to derive the carbon and nitrogen abundances in I Zw 18 with the aid of a nebular model. The CNO abundances in I Zw 18 are found to exceed those found in the Magellanic Clouds and other well-observed oxygen-poor irregular galaxies and are more similar to those in the sun and nearby Galactic H II regions. It is argued that I Zw 18 may be older and more chemically evolved than previously believed, and that its extremely low O/H results from escape of O-rich supernova ejecta from the Galaxy or from dilution by accretion of primordial gas. Alternatively, I Zw 18 may have formed from a preenriched intergalactic medium. Spectroscopic diagnostics for composite photoionization models to fit the spectrum of I Zw 18 are discussed.

Dufour, Reginald J.↗
NASA NTRS1988

Chemical abundance of comets

Observations of NH2, (OI) and molecular ion spectra in comets represent virtually all of the volatile fraction of a comet nucleus. Their study leads to the N2, NH3, H2O, CO2, CO content of the nucleus, and thus to important constraints on models of comet formation and chemical processing in the primitive solar nebula. The observations of Comet Halley provide the opportunity for the first comprehensive determination of the abundances in a comet nucleus. The carbon isotope abundance ratio 12 C/13 C = 65 plus or minus 8 has been determined for Comet Halley from resolved rotational line structure in the CN B-X (0,0) band. The ratio is approximately 30 pct lower than the solar system value, 89, indicating either an enhancement of 13CN or a depletion of 12CN in the comet. Scenarios consistent with the observed carbon isotope ratio are: (1) formation of the comet at the periphery of the solar nebula in a fractionation-enriched 13CN region, or hidden from 12CN enrichment sources, and (2) capture of an interestellar comet. Long-slit charge coupled device (CCD) spectra obtained at the time of the spacecraft encounter of Comet Halley have also been analyzed. Scale lengths, production rates and column densities of CH, CN, C2 and NH2 were determined.

Wyckoff, Susan↗
NASA NTRS1988

ISM chemical abundances in two intermediate-velocity clouds in the line of sight to SN 1987A

The earliest IUE high-resolution spectra of SN 1987A have been studied and reveal the presence of several clouds in the line of sight to the LMC. In particular, there are two clouds with radial velocities of about 130 km/s and about 180 km/s. These clouds' velocities are between those of Galactic clouds at 0-80 km/s and those of LMC gas at about 270 km/s. Chemical-abundance determinations may help to determine the origin and location of these clouds. Curve-of-growth analysis and 21-cm observations show that they may be underabundant in heavy elements by about a factor of 2 as compared to solar abundances. No depletion indicative of grain formation can be seen.

Morgan, Siobahn↗
NASA NTRS1988

Solar-system abundances and processes of nucleosynthesis

The origin of the elements is studied. The average elemental composition of the solar system is examined and used to infer the primordial solar system abundances of the individual nuclides. Patterns in these nuclide abundances are used as clues to their origin. The possible cosmic significance of the patterns are considered. The astrophysical settings for nucleosynthesis and the chemical evolution of the Galaxy and information based on observed isotopic anomalies in meteorites are taken into account.

Woolum, Dorothy S.↗
NASA NTRS1989

The effect of density variations on elemental abundance ratios in gaseous nebulae

Using numerical analysis it is demonstrated that when there are changes in gas density within a nebulae various empirical methods for determining the electron density can give different results. Eleven different species are considered which have line pair ratios that are well-known electron density (Ne) diagnostic tools. In the presence of varying density, there is a progression in inferred values of Ne from N+ (122/204 microns) at the lowest to C(2+) (1906/1909 A) at the highest. For many of the 11 species there is a fixed order in the inferred density, while for others the order can change somewhat for different mixes of densities. When there are nonconstant density conditions, it is shown that systematic biases may occur in the empirical determination of chemical abundance ratios. Tabular material is presented that delineates the maximum bias that can occur in the determination of a particular abundance ratio in a two-component model.

Rubin, R. H.↗
NASA NTRS1989

NH2 fluorescence efficiencies and the NH3 abundance in Comet Halley

If NH3 is the dominant source of the NH2 observed in comet spectra, then the NH3 abundance can in principle be accurately determined. Fluorescence efficiencies for the (0, v-prime/2/, O) to (0, 0, 0) progression of NH2 bands are calculated for NH2 bands likely to be observed in the 4500-8200-A region of comets. The results differ from previous determinations of the NH2 band fluorescence efficiencies by factors in the range 1.4-5.9, leading t6o significant changes in previously reported NH2 production rates in comets. A recalculation of the NH3/H2O abundance ratio in Comet Halley gives about (0.5 + or - 0.2) percent in better agreement with the Giotto ion-mass-spectrometer results of Allen et al (1987).

Tegler, Stephen↗
NASA NTRS1989

Element abundances at high redshift

Abundances of Si(+), S(+), Cr(+), Mn(+), Fe(_), and Zn(+) are considered for two absorption-line systems in the spectrum of the QSO PKS 0528 - 250. Zinc and sulfur are underabundant, relative to H, by a factor of 10 compared to their solar and Galactic interstellar abundances. The silicon-, chromium-, iron-, and nickel-to-hydrogen ratios are less than the solar values and comparable to the local interstellar ratios. A straightforward interpretation is that nucleosynthesis in these high-redshift systems has led to only about one-tenth as much heavy production as in the gas clouds around the sun, and that the amount of the observed underabundances attributable to grain depletion is small. The dust-to-gas ratio in these clouds is less than 8 percent of the Galactic value.

Meyer, David M.↗
NASA NTRS1990

Probing the possibility of a C-12/C-13 galactic abundance gradient

High S/N (equal to or greater than 500) observations of interstellar CH+ with the 3.0 m telescope were performed at Lick Observatory and with the 4.0 m telescope at CTIO, of the reddened, early-type stars HD 183143, HD 24432, and HD 157038 in an effort to probe the existence of a C-12/C-13 abundance gradient in our Galaxy. Previous very high quality optical observations of interstellar CH+ toward five stars within 1 kpc of the Sun have yielded a precise weighted mean C-12/C-13 isotope ratio of 43 plus or minus 4 (1 sigma) (Hawkins, Jura, and Meyer 1985; Hawkins and Jura 1987). The isotope ratios derived toward four lines of sight in the local ISM are uniform within 12 percent. The similarity among these carbon isotope ratios determined in diffuse clouds possessing different physical conditions precludes the possibility that the CH+ molecule is suffering from isotope selective effects in these regions. The precise C-12/C-13 derivable from high quality observations of (12)CH+ and (13)CH+ provide the unique opportunity to probe the homogeneity of the ISM in a large scale and the history of nucleosynthesis in our Galaxy. Since CH+ seems to be the most sensitive probe of C-12/C-13 in the diffuse ISM, observations toward more distant stars located up to 2.5 kpc from the Sun are the best way to study the possibility of a Galactic (C-12/C-13) abundance gradient. The researcher obtained 4232 angstrom data toward all three of the stars mentioned above, 3957 angstrom data toward HD 183143 and HD 157038, and 3745 angstrom data toward HD 157038. Because of the poorer quality of the HD 24432 spectrum, and its weaker CH+ absorption lines, the satellite (13)CH+ line was not detected, and thus only a lower limit on the C-12/C-13 ratio toward this star was obtained. The results obtained from careful reduction and analysis of the data toward these stars in the Northern and Southern Hemispheres are presented.

Hawkins, Isabel↗
NASA NTRS1990

The Ar/Ca abundance ratio in solar flares

An Ar/Ca abundance ratio of at least 0.56 is derived using the X-ray spectra of solar flares recorded by the SOLFLEX spectrometers on the P78-1 spacecraft. The method involves determining the contribution of the Ar XVII 1s2 1S0-1s4p 1P1 line to a blended feature at 3.2005 A. This contribution is determined by considering the relationship of the other component of the blended feature, namely the Ca XVIII 1s2 2s 2S(1/2)-1s2p2s 2P(3/2) line, to the dielectronic satellite lines of Ca XVII that fall between 3.215 and 3.24 A. It is demonstrated that a broad-wavelength coverage solar X-ray spectrometer experiment is necessary for precise abundance measurements.

Doschek, George A.↗