Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Volcano”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 631 records · Page 35
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Total Volcanic Stratospheric Aerosol Optical Depths and Implications for Global Climate Change

Understanding the cooling effect of recent volcanoes is of particular interest in the context of the post-2000 slowing of the rate of global warming. Satellite observations of aerosol optical depth above 15 km have demonstrated that small-magnitude volcanic eruptions substantially perturb incoming solar radiation. Here we use lidar, Aerosol Robotic Network, and balloon-borne observations to provide evidence that currently available satellite databases neglect substantial amounts of volcanic aerosol between the tropopause and 15 km at middle to high latitudes and therefore underestimate total radiative forcing resulting from the recent eruptions. Incorporating these estimates into a simple climate model, we determine the global volcanic aerosol forcing since 2000 to be 0.19 +/- 0.09W/sq m. This translates into an estimated global cooling of 0.05 to 0.12 C. We conclude that recent volcanic events are responsible for more post-2000 cooling than is implied by satellite databases that neglect volcanic aerosol effects below 15 km.

aerosols↗
NASA NTRS1995

(abstract) SIR-C/X-SAR: A Multifaceted Radar

The Spaceborne Imaging Radar-C/X-band Synthetic Aperture Radar (SAR-C/X-SAR) was a joint US/German/Italian project, with flights aboard the shuttle Endeavor in April and October 1994. SIR-C/X-SAR is the first spaceborne multifrequency, multipolarization radar. The SIR-C and the X-SAR were designed to operate in conjunction with each other, collecting data over common sites. Scientists around the world are using the data in conjunction with ground measurements to conduct experiments relating to Earth's ecology, geology, hydrology, and oceanography. In addition, the data are the most comprehensive set yet available for engineering characterization of spaceborne SAR capabilities relative to various radar phenomenology and methodology. Preliminary results show changes between missions in vegetation, ice, snow, flooding, and volcano activity.

imaging↗
NASA NTRS2021

Tracking aerosols and SO2 clouds from the Raikoke eruption: 3D view from satellite observations

The 21 June 2019 eruption of the Raikoke volcano (Kuril Islands, Russia; 48° N, 153° E) produced significant amounts of volcanic aerosols (sulfate and ash) and sulfur dioxide (SO2) gas that penetrated into the lower stratosphere. The dispersed SO2 and sulfate aerosols in the stratosphere were still detectable by multiple satellite sensors for many months after the eruption. For this study of SO2 and aerosol clouds we use data obtained from two of the Ozone Mapping and Profiler Suite sensors on the Suomi National Polar-orbiting Partnership satellite: total column SO2 from the Nadir Mapper and aerosol extinction profiles from the Limb Profiler as well as other satellite data sets. We evaluated the limb viewing geometry effect (the “arch effect”) in the retrieval of the LP standard aerosol extinction product at 674 nm. It was shown that the amount of SO2 decreases with a characteristic period of 8–18 d and the peak of stratospheric aerosol optical depth recorded at a wavelength of 674 nm lags the initial peak of SO2 mass by 1.5 months. Using satellite observations and a trajectory model, we examined the dynamics of an unusual atmospheric feature that was observed, a stratospheric coherent circular cloud of SO2 and aerosol from 18 July to 22 September 2019.

Eruption of the Raikoke volcano↗
NASA NTRS2022

Volcanic Eruption of Cumbre Vieja, La Palma, Spain: A First Insight to the Particulate Matter Injected in the Troposphere

The volcanic eruption of Cumbre Vieja (La Palma Island, Spain), started on 19 September, 2021, and was declared terminated on 25 December, 2021. A complete set of aerosol measurements were deployed around the volcano within the first month of the eruptive activity. This paper describes the results of the observations made at Tazacorte on the west bank of the island where a polarized micro pulse lidar was deployed. The two and a half months analyzed (16 October – 31 December) reveal that the peak height of the lowermost and strongest volcanic plume did not exceed 3 km (mean of 1.43±0.45 km over the whole period) and was highly variable. It steadily increased until week 11 after the eruption start (and 3 weeks before its end) and started decreasing afterwards. The ash mass concentration has been assessed with a method based on the polarization capability of the instrument. Considering the limitation of current remote sensing techniques to detect large to giant particles, the ash mass concentration on one of the days with the highest ash load is estimated to have peaked in the range 800-3200 μg m(exp -3) in the lowermost layer below 2.5 km.

Cumbre Vieja↗
NASA NTRS2022

Stratospheric Circulation Changes Associated with the Hunga Tonga-Hunga Ha'apai Eruption

The 15 January 2022 eruption of the Hunga Tonga-Hunga Ha'apai underwater volcano (20.5°S, 175.4°W) injected a record amount of water directly into the stratosphere. This study attempts to quantify this impact on the temperature, as well as the subsequent changes to the stratospheric circulation, during the months following the eruption based on reanalysis fields. The extreme nature of the temperature, wind, and circulation changes are tracked through comparisons of the first six months of 2022 with the previous 42 years. Examination of the data assimilation process shows that at 20 hPa the thermal observations are forcing significant cooling, compensating for the absence of the excess stratospheric moisture in the model used for the reanalysis. In response to this cooling the atmosphere adjusts by creating strong westerly winds above the temperature anomaly and large changes to the downward and poleward mean meridional circulation.

Volcano↗
NASA NTRS2022

Out of the blue: volcanic SO e2 emissions during the 2021–2022 eruptions of Hunga Tonga – Hunga Ha'apai (Tonga)

Most volcanism on Earth is submarine, but volcanic gas emissions by submarine eruptions are rarely observed and hence largely unquantified. On January 15, 2022 a submarine eruption of Hunga Tonga-Hunga Ha'apai (HTHH) volcano (Tonga) generated an explosion of historic magnitude, and was preceded by ≈1 month of Surtseyan eruptive activity and two precursory explosive eruptions. We present an analysis of ultraviolet (UV) satellite measurements of volcanic sulfur dioxide (SO 2 ) between December 2021 and the climactic January 15, 2022 eruption, comprising an unprecedented record of Surtseyan eruptive emissions. UV measurements from the Ozone Monitoring Instrument (OMI) on NASA’s Aura satellite, the Ozone Mapping and Profiler Suite (OMPS) on Suomi-NPP, the Tropospheric Monitoring Instrument (TROPOMI) on ESA’s Sentinel-5P, and the Earth Polychromatic Imaging Camera (EPIC) aboard the Deep Space Climate Observatory (DSCOVR) are combined to yield a consistent multi-sensor record of eruptive degassing. We estimate SO 2 emissions during the eruption’s key phases: the initial December 19, 2021 eruption (≈0.01 Tg SO 2 ); continuous SO 2 emissions from December 20, 2021 – early January 2022 (≈0.12 Tg SO 2 ); the January 13, 2022 stratospheric eruption (0.06 Tg SO 2 ); and the paroxysmal January 15, 2022 eruption (≈0.4-0.5 Tg SO 2 ); yielding a total SO 2 emission of ≈0.60.7 Tg SO 2 for the eruptive episode. We interpret the vigorous SO 2 emissions observed prior to the January 2022 eruptions, which were significantly higher than measured in the 2009 and 2014 HTHH eruptions, as strong evidence for a rejuvenated magmatic system. High cadence DSCOVR/EPIC SO 2 imagery permits the first UV-based analysis of umbrella cloud spreading and volume flux in the January 13, 2022 eruption, and also tracks early dispersion of the stratospheric SO 2 cloud injected on January 15. The ≈0.4-0.5 Tg SO 2 discharged by the paroxysmal January 15, 2022 HTHH eruption is low relative to other eruptions of similar magnitude, and a review of other submarine eruptions in the satellite era indicates that modest SO 2 yields may be characteristic of submarine volcanism, with the emissions and atmospheric impacts likely dominated by water vapor. The origin of the low SO 2 loading awaits further investigation but scrubbing of SO 2 in the water-rich eruption plumes and rapid conversion to sulfate aerosol are plausible, given the exceptional water emission by the January 15, 2022 HTHH eruption.

Volcanoes↗
NASA NTRSDate not supplied

Projecting the Lasting Fate of the Hunga Tonga-Hunga Ha’apai Eruption on the Stratosphere through Connecting Measurements to Models

On 15th Jan. 2022 the submarine volcano Hunga Tonga-Hunga Ha’apai (HTHH) injected approximately 0.5 Tg of sulfur dioxide into the stratosphere, but more significantly added 150-170 Tg of water vapor to the stratospheric background (over a 10% perturbation) in a matter of several hours. The sulfur dioxide rapidly converted to sulfate aerosol and along with water vapor, was transported around the Southern Hemisphere sub-tropics into midlatitudes with some transport into the Northern Hemisphere. With a much longer lifetime than sulfate aerosol, measurable water vapor anomalies are likely to persist for the remainder of the decade. Satellite measurements from limb and nadir viewing observing instruments provide the information needed to reasonably initialize the HTHH eruption in the Goddard Earth Observing System (GEOS) model using the “replay” framework coupled to the Global Modeling Initiative (GMI) stratosphere-troposphere chemical mechanism for the recent past and continue the simulations into the future with the free running chemistry climate model (CCM). Using a number of model ensemble members together with the satellite observations, we are beginning to quantify how the HTHH eruption is perturbing stratospheric composition and climate and projecting the influences to come as the enhanced water vapor continues to spread globally with only very slow removal mechanisms. We will also discuss some of the future measurement needs to understand how the atmosphere is responding to events like the HTHH eruption, large wildfires, and a changing climate.

volcano↗
NASA NTRS2023

A New Multi-Method Assessment of Stratospheric Sulfur Load From the Okmok II Caldera-Forming Eruption of 43 BCE

The 43 BCE eruption of Okmok Volcano has been proposed to have had a significant climate cooling impact in the Northern Hemisphere. In this study, we quantify the climate cooling potential of the Okmok II eruption by measuring sulfur concentration in melt inclusions (up to 1,606 ppm) and matrix glasses and estimate a total of 62 ± 16 Tg S released. The proportion reaching the stratosphere (2.5%–25%, i.e., 1.5–15.5 Tg S) was constrained by physical modeling of the caldera-collapse eruption. Using the NASA Goddard Institute for Space Studies E2.2 climate model we found a linear response between cooling and stratospheric sulfur load (0.05–0.08°C/Tg S). Thus, the 1–2°C of cooling derived from proxy records would require 16–32 Tg sulfur injection. This study underscores the importance of combining approaches to estimate stratospheric S load. For Okmok II, we find all methods are consistent with a range of 15–16 Tg S.

volcano-climate interaction↗
NASA NTRSDate not supplied

Projecting the Lasting Fate of the Hunga Tonga-Hunga Ha’apai Eruption on the Stratosphere through Connecting Measurements to Models

On 15th Jan. 2022 the submarine volcano Hunga Tonga-Hunga Ha’apai (HTHH) injected approximately 0.5 Tg of sulfur dioxide into the stratosphere, but more significantly added 150-170 Tg of water vapor to the stratospheric background (over a 10% perturbation) in a matter of several hours. The sulfur dioxide rapidly converted to sulfate aerosol and along with water vapor, was transported around the Southern Hemisphere sub-tropics into midlatitudes with some transport into the Northern Hemisphere. With a much longer lifetime than sulfate aerosol, measurable water vapor mass anomalies have persisted with only small losses over the past almost 2 years and are likely to continue above background for the remainder of the decade. Satellite measurements from limb and nadir viewing observing instruments provide the information needed to reasonably initialize the HTHH eruption in the Goddard Earth Observing System (GEOS) model using the “replay” framework coupled to the Global Modeling Initiative (GMI) stratosphere-troposphere chemical mechanism for the recent past and continue the simulations into the future with the free running chemistry climate model (CCM). Using a number of model ensemble members together with the satellite observations, we quantify how the HTHH eruption is perturbing stratospheric composition and climate and projecting the influences to come as the enhanced water vapor continues in the stratosphere with only very slow removal mechanisms. HTHH eruption provides a useful test of chemistry climate models and an opportunity for observation-based process understanding, which we will highlight.

Hunga Tonga-Hunga Ha’apai↗
NASA NTRSDate not supplied

Observing and Projecting the Lasting Fate of the Hunga Eruption on Atmospheric Water Vapor and Hydroxyl Radical

On 15th Jan. 2022 the submarine Hunga volcano erupted injecting approximately 0.5 Tg of sulfur dioxide into the stratosphere, but more significantly added 150-170 Tg of water vapor to the stratospheric background (over a 10% perturbation) in a matter of several hours. The sulfur dioxide rapidly converted to sulfate aerosol and along with water vapor, was transported around the Southern Hemisphere sub-tropics into midlatitudes and beyond with some transport into the Northern Hemisphere. With a much longer lifetime than sulfate aerosol, measurable water vapor mass anomalies have persisted with only small losses over more than 2 years since the eruption and are likely to continue above background for the remainder of the decade. Satellite measurements from limb and nadir viewing observing instruments provide the information needed to reasonably initialize the Hunga eruption in the Goddard Earth Observing System (GEOS) model using the “replay” framework coupled to the Global Modeling Initiative (GMI) stratosphere-troposphere chemical mechanism for the recent past and have continued the simulations into the future with the free running chemistry climate model (CCM). Using a number of model ensemble members together with the satellite observations, we quantify how the Hunga eruption is perturbing atmospheric composition and climate and projecting the influences to come as the enhanced water vapor continues in the stratosphere with only very slow removal mechanisms. Modeling suggests that the water rich eruption enhanced stratospheric hydroxyl radiacal (OH) and is supported by the speed of the observed conversion of SO2 into sulfate aerosol. These simulations also suggest a significant reduction in tropospheric OH over the mid-high latitude Southern Hemisphere, which has implications for numerous species that are impacted by this radical. The Hunga eruption provides a useful test of chemistry climate models and an opportunity for observation-based process understanding and in making new connections.

Hunga volcano↗
NASA NTRS2024

Simulating the Volcanic Sulfate Aerosols From the 1991 Eruption of Cerro Hudson and Their Impact on the 1991 Ozone Hole

The Chilean volcano Cerro Hudson erupted between August 8th and 15th, 1991, injecting between 1.7 and 2.9 Tg of SO2 into the upper troposphere and lower stratosphere. We simulate this injection using the GEOS Earth system model with detailed sulfur chemistry and sectional aerosol microphysics, focusing on the resulting aerosols and their contribution to the 1991 Antarctic Austral Springtime ozone hole. The simulations show a column ozone deficit (12 DU) in the Southern Hemisphere vortex collar region. The majority of this effect is between 10 and 20 km and due to heterogeneous chemistry. The model shows a 26% decrease in ozone from background levels at these altitudes, compared with in-situ observations of a 50% decrease. Above 20 km, the dynamical response to the eruption also causes lower ozone values, a novel modeling result. This experiment highlights potential interactions between proposed solar radiation management geoengineering aerosols and volcanic eruptions.

aerosols↗
DOE OSTI2024

Design and Synthesis of PtPdNiCoMn High‐Entropy Alloy Electrocatalyst for Enhanced Alkaline Hydrogen Evolution Reaction: A Theoretically Supported Predictive Design Approach

Electrocatalytic hydrogen generation requires a multifunctional electrocatalyst with abundant active sites to drive multielectron transfer reactions. High entropy alloys (HEA) are five or more-elements with high configurational entropy are considered unique materials for next-generation electrocatalysts. Here, in this work, based on new screening guidelines for catalyst selections that combine density-functional theory calculated Gibbs formation-enthalpy with bond length and electronegativity variance, a novel HEA electrocatalyst consisting of five elements, namely, Pt, Pd, Ni, Co, and Mn has been designed. By simple room temperature electrodeposition, the designed catalyst is prepared and its hydrogen evolution reaction (HER) is explored and validated through experimental and theoretical approaches. The HEA demonstrated a superior HER activity with an overpotential of 22.6 mV at -10 mA cm -2 which outperforms Pt/C commercial catalyst. No evident degradation of the material is detected even after 100 hours of continuous operation under high current density. Moreover, the HEA has shown exceptional performance in harsh electrolyte conditions such as in simulated seawater and actual seawater. Remarkably, the density-functional theory calculated Gibbs formation-enthalpy is small (≈0 eV) compared to Pt/C placing the new HEA near the apex of Trasatti's model of Volcano plot, which is also suggestive of superior HER activity.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Theory Guided Fine‐Tune of Strain Effects in Pt Ternary Alloy via Rare Earth Templating: Achieving High Performance PEMFCs Catalysts

The sluggish kinetics and insufficient durability of platinum-based catalysts remain crucial barriers limiting proton-exchange-membrane fuel cells (PEMFCs) deployment. Here, we report a theory-guided synthesis combined with rare-earth templating to realize a previously inaccessible Pt 5 Co-like phase with tailored atomic-scale strain. Guided by density functional theory (DFT) calculations, we identified that a Pt 5 Co-like sublayer can induce a unique mild compressive strain (−1.24%) to the Pt(111) shell and an optimal *OH binding energy shift (ΔE ≈ 0.11 eV). This shift positions the alloy catalyst near the apex of the oxygen reduction reaction activity volcano. This prediction guided the synthesis of ternary alloy Pt 5 (Ce)Co@Pt multilayer nanoparticles, featuring a Ce-stabilized core, a Pt 5 Co-like sublayer, and a Pt-rich shell. This catalyst demonstrates both exceptionally high activity and durability, achieving a mass activity of 2.6 A∙mg Pt −1 in rotating disk electrode testing. In fuel cell membrane electrode assembly tests, Pt 5 (Ce)Co@Pt achieves a current density of 1.9 A∙cm −2 at 0.7 V under heavy-duty vehicle conditions. Remarkably, it maintains 1.2 A∙cm −2 after 1 80 000 AST cycles, doubling the U.S. DOE 2025 target. This work demonstrates a rational design strategy that DFT-guided strain engineering integrates with rare-earth templating to advance Pt-based catalysts for fuel cell applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2025

Crossing the Oxo‐Peroxo Wall for Selective Electrochemical Epoxidation

Electrochemical oxidation in water requires the formation of reactive oxygen species to be able to oxidize unsaturated hydrocarbons to epoxides, aldehydes, and ketones. These reactions, broadly classified as alternative oxidation reactions (AOR), directly compete with the prevalent oxygen evolution reaction (OER). In molecular catalysis, the Oxo-Wall dictates a transition from a stable oxo intermediate (OER active) to a meta-stable metal-oxo (OER inactive) generally occurs. In this work on heterogeneous catalysis, the same Oxo-Wall applies, however, a meta-stable oxo preferentially coordinates with lattice oxygen to form a more stable surface peroxo intermediate. A universal free energy onset of this process is identified at 3.39 eV under electrochemical activation in water and show that it is completely decoupled from the OER oxo species. Such decoupling gives rise to a new region of oxygen reactivity relevant for AOR where a selective oxidation of the unsaturated C-C bonds is predicted to occur instead of OER. A distinct AOR overpotential volcano is constructed and identify recently reported electrocatalysts, including palladium-platinum for propylene epoxidation and silver-nickel for ethylene epoxidation, along with others such as TiO 2 and CuO. Broader implications and limitations of electrochemical AOR are discussed, highlighting their potential to enable electrochemically enhanced thermal catalysis.

Electrocatalysis↗
DOE OSTI2021

Twinning Enhances Efficiencies of Metallic Catalysts toward Electrolytic Water Splitting

Twinning is demonstrated to be an effective way of enhancing efficiencies of metallic catalysts toward electrolytic water splitting. Dendritic Cu possessing dense coherent nanotwin (NT) boundaries (NTCu-5nm) is successfully prepared with an organic-assisted electrodeposition at high pulse current densities. NT boundaries significantly improve electrocatalytic efficiencies and stability of NTCu-5nm over nanocrystalline Cu (NCCu), reducing overpotentials at 10 mA cm -2 for the oxygen evolution reaction (OER) from 378 to 281 mV and from 235 to 88 mV for the hydrogen evolution reaction (HER), with a small chronoamperometric decay of 5% after 100 h continuous overall water splitting at an ultrahigh initial current density of 500 mA cm -2 , largely outperforming the large chronoamperometric decay of 27% for only 1 h operation of the NCCu//NCCu couple. The defective twin boundaries enable formation of active Cu III O 2 - at low overpotentials, thus enhancing OER performance. Furthermore, the synergistic geometric and electronic effects induced by the twin boundaries result in shifts in Gibbs free energies of hydrogen adsorption (ΔG H ) toward the apex of a volcano plot of exchange current density versus ΔG H , leading to the remarkable improvement in HER activity.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

Mapping the Binary Covalent Alloy Space to Pursue Superior Nitrogen Reduction Reaction Catalysts

The electrochemical nitrogen reduction reaction (NRR) has the potential to decarbonize industrial ammonia production. However, NRR has poor activity and selectivity versus the competing hydrogen evolution reaction for catalysts that adhere to scaling relations. Overcoming the limitations imposed by scaling relations requires more complex catalyst materials, however, evaluating materials beyond simple metal systems is a large combinatorial problem that requires an improved understanding of the electrocatalyst surface to rationally guide the discovery of superior catalysts. The study uses grand canonical density functional theory to uncover NRR trends on a large and disparate set of binary covalent alloys (BCA) with variable compositions and active-site geometries. The studied BCAs generally follow scaling relations, albeit with larger variance and several systems that significantly break scaling. BCAs with early- to mid-transition metals tend to lie near the volcano peak and activate the N 2 triple bond via a side-on binding configuration. Trends in the BCA space cannot be readily predicted using simple electronic descriptors, which is ascribed to the large geometric variability of the BCA surfaces. Furthermore, it is anticipated that these findings will provide a foundation for the rational design of superior NRR electrocatalysts with increasing material complexity.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Could the chemical industry mitigate rapid global cooling from a catastrophic volcanic eruption?

Abstract Estimates based on historical data place the probability of a catastrophic volcanic eruption in the next 100 years at around one in six. Large volcanic eruptions can lead to significant global cooling for 2–4 years, with potentially devastating impacts on global agriculture. In principle, the negative impacts of volcano‐induced cooling could be reduced by deliberate emission of short‐lived chemicals with high greenhouse gas intensity into the atmosphere. This article examines the physical feasibility of this concept for a wide range of short‐lived climate pollutants, using the global chemical industry for context. Deliberate emission of any known chemical species would require gigatons of material, which would have to be produced and stored far in advance of the volcanic event. The cost of this undertaking would be immense. In addition to these daunting logistical challenges, a range of other uncertainties and complications associated with this concept are discussed.

Sholl, David S. [University of Tennessee‐Oak Ridge↗