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Tl2InSn crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Tl2InSn ribbons oriented in the (1, 0, 0) direction. Tl is bonded in a linear geometry to one In and one Sn atom. The Tl–In bond length is 2.93 Å. The Tl–Sn bond length is 2.75 Å. In is bonded in a linear geometry to two equivalent Tl atoms. Sn is bonded in a linear geometry to two equivalent Tl atoms.
NaHgTl2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NaHgTl2 ribbons oriented in the (1, 0, 0) direction. Na is bonded in a linear geometry to two equivalent Tl atoms. Both Na–Tl bond lengths are 3.18 Å. Hg is bonded in a linear geometry to two equivalent Tl atoms. Both Hg–Tl bond lengths are 2.94 Å. Tl is bonded in a linear geometry to one Na and one Hg atom.
ErEuTl2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Er is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Er–Tl bond lengths are 3.36 Å. Eu is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Eu–Tl bond lengths are 3.36 Å. Tl is bonded in a body-centered cubic geometry to four equivalent Er and four equivalent Eu atoms.
TlSO4 crystallizes in the trigonal R32 space group. The structure is two-dimensional and consists of three thallium molecules and three Tl(SO4)2 sheets oriented in the (0, 0, 1) direction. In each Tl(SO4)2 sheet, Tl is bonded to six equivalent O atoms to form distorted TlO6 pentagonal pyramids that share corners with six equivalent SO4 tetrahedra. All Tl–O bond lengths are 2.29 Å. S is bonded to four O atoms to form SO4 tetrahedra that share corners with three equivalent TlO6 pentagonal pyramids. There is one shorter (1.47 Å) and three longer (1.50 Å) S–O bond length. There are two inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one S atom. In the second O site, O is bonded in a distorted bent 120 degrees geometry to one Tl and one S atom.
NaTl2Sn crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NaTl2Sn ribbons oriented in the (1, 0, 0) direction. Na is bonded in a linear geometry to two equivalent Tl atoms. Both Na–Tl bond lengths are 3.11 Å. Tl is bonded in a linear geometry to one Na and one Sn atom. The Tl–Sn bond length is 2.78 Å. Sn is bonded in a linear geometry to two equivalent Tl atoms.
Na2HgTl crystallizes in the cubic F-43m space group. The structure is three-dimensional. there are two inequivalent Na sites. In the first Na site, Na is bonded to four equivalent Tl atoms to form distorted corner-sharing NaTl4 tetrahedra. All Na–Tl bond lengths are 3.28 Å. In the second Na site, Na is bonded to four equivalent Hg atoms to form distorted corner-sharing NaHg4 tetrahedra. All Na–Hg bond lengths are 3.28 Å. Hg is bonded in a body-centered cubic geometry to four equivalent Na and four equivalent Tl atoms. All Hg–Tl bond lengths are 3.28 Å. Tl is bonded in a body-centered cubic geometry to four equivalent Na and four equivalent Hg atoms.
CdTl2In crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two CdTl2In ribbons oriented in the (1, 0, 0) direction. Cd is bonded in a linear geometry to two equivalent Tl atoms. Both Cd–Tl bond lengths are 3.09 Å. Tl is bonded in a linear geometry to one Cd and one In atom. The Tl–In bond length is 2.95 Å. In is bonded in a linear geometry to two equivalent Tl atoms.
K5Ta(TlAs2)2 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are three inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 4-coordinate geometry to one Tl1+ and three As3- atoms. The K–Tl bond length is 3.48 Å. There are one shorter (3.64 Å) and two longer (3.76 Å) K–As bond lengths. In the second K1+ site, K1+ is bonded in a 5-coordinate geometry to two equivalent Tl1+ and three As3- atoms. There are one shorter (3.57 Å) and one longer (3.66 Å) K–Tl bond lengths. There are a spread of K–As bond distances ranging from 3.42–3.53 Å. In the third K1+ site, K1+ is bonded in a 7-coordinate geometry to two equivalent Tl1+ and five As3- atoms. There are one shorter (3.64 Å) and one longer (3.73 Å) K–Tl bond lengths. There are a spread of K–As bond distances ranging from 3.30–3.70 Å. Ta5+ is bonded in a tetrahedral geometry to four As3- atoms. There are a spread of Ta–As bond distances ranging from 2.50–2.53 Å. There are two inequivalent Tl1+ sites. In the first Tl1+ site, Tl1+ is bonded in a 7-coordinate geometry to five K1+ and two As3- atoms. There are one shorter (2.79 Å) and one longer (2.96 Å) Tl–As bond lengths. In the second Tl1+ site, Tl1+ is bonded in a 2-coordinate geometry to four equivalent K1+ and two equivalent As3- atoms. Both Tl–As bond lengths are 2.87 Å. There are three inequivalent As3- sites. In the first As3- site, As3- is bonded in a 1-coordinate geometry to five K1+, one Ta5+, and one Tl1+ atom. In the second As3- site, As3- is bonded in a 6-coordinate geometry to six K1+, one Ta5+, and one Tl1+ atom. In the third As3- site, As3- is bonded in a 1-coordinate geometry to four K1+, one Ta5+, and one Tl1+ atom.
SmNdTl2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Sm is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Sm–Tl bond lengths are 3.37 Å. Nd is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Nd–Tl bond lengths are 3.37 Å. Tl is bonded in a body-centered cubic geometry to four equivalent Sm and four equivalent Nd atoms.
Nd6Fe13Tl crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Nd sites. In the first Nd site, Nd is bonded in a 5-coordinate geometry to twelve Fe and one Tl atom. There are a spread of Nd–Fe bond distances ranging from 3.04–3.27 Å. The Nd–Tl bond length is 3.40 Å. In the second Nd site, Nd is bonded in a 6-coordinate geometry to four Fe and two equivalent Tl atoms. There are a spread of Nd–Fe bond distances ranging from 2.97–3.34 Å. Both Nd–Tl bond lengths are 3.39 Å. There are four inequivalent Fe sites. In the first Fe site, Fe is bonded in a 12-coordinate geometry to three Nd and nine Fe atoms. There are a spread of Fe–Fe bond distances ranging from 2.46–2.75 Å. In the second Fe site, Fe is bonded to five Nd and seven Fe atoms to form a mixture of distorted face and corner-sharing FeNd5Fe7 cuboctahedra. There are a spread of Fe–Fe bond distances ranging from 2.55–2.65 Å. In the third Fe site, Fe is bonded to twelve Fe atoms to form a mixture of face and corner-sharing FeFe12 cuboctahedra. All Fe–Fe bond lengths are 2.40 Å. In the fourth Fe site, Fe is bonded to two equivalent Nd and ten Fe atoms to form a mixture of face and corner-sharing FeNd2Fe10 cuboctahedra. There are two shorter (2.52 Å) and one longer (2.56 Å) Fe–Fe bond lengths. Tl is bonded in a distorted q6 geometry to ten Nd atoms.
TlB5O12 crystallizes in the monoclinic P2_1/c space group. The structure is one-dimensional and consists of four TlB5O12 ribbons oriented in the (1, 0, 0) direction. Tl is bonded in a 2-coordinate geometry to three O atoms. There are two shorter (2.06 Å) and one longer (2.54 Å) Tl–O bond lengths. There are five inequivalent B sites. In the first B site, B is bonded in a tetrahedral geometry to four O atoms. There are a spread of B–O bond distances ranging from 1.46–1.52 Å. In the second B site, B is bonded in a trigonal planar geometry to three O atoms. There are a spread of B–O bond distances ranging from 1.35–1.43 Å. In the third B site, B is bonded in a trigonal planar geometry to three O atoms. There are a spread of B–O bond distances ranging from 1.36–1.40 Å. In the fourth B site, B is bonded in a trigonal planar geometry to three O atoms. There are a spread of B–O bond distances ranging from 1.35–1.42 Å. In the fifth B site, B is bonded in a trigonal planar geometry to three O atoms. There are a spread of B–O bond distances ranging from 1.33–1.46 Å. There are twelve inequivalent O sites. In the first O site, O is bonded in a bent 120 degrees geometry to two B atoms. In the second O site, O is bonded in a single-bond geometry to one O atom. The O–O bond length is 1.33 Å. In the third O site, O is bonded in a single-bond geometry to one Tl atom. In the fourth O site, O is bonded in a bent 120 degrees geometry to two B atoms. In the fifth O site, O is bonded in a bent 120 degrees geometry to two B atoms. In the sixth O site, O is bonded in a bent 120 degrees geometry to two B atoms. In the seventh O site, O is bonded in a bent 120 degrees geometry to two B atoms. In the eighth O site, O is bonded in a water-like geometry to one Tl and one B atom. In the ninth O site, O is bonded in a single-bond geometry to one B atom. In the tenth O site, O is bonded in a water-like geometry to one Tl and one B atom. In the eleventh O site, O is bonded in a bent 120 degrees geometry to two B atoms. In the twelfth O site, O is bonded in a distorted single-bond geometry to one B and one O atom.
HoNdTl2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ho is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Ho–Tl bond lengths are 3.33 Å. Nd is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Nd–Tl bond lengths are 3.33 Å. Tl is bonded in a body-centered cubic geometry to four equivalent Ho and four equivalent Nd atoms.
MgPmTl2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Mg is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Mg–Tl bond lengths are 3.27 Å. Pm is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Pm–Tl bond lengths are 3.27 Å. Tl is bonded in a body-centered cubic geometry to four equivalent Mg and four equivalent Pm atoms.
Rh3Tl is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent Rh sites. In the first Rh site, Rh is bonded to eight Rh and four equivalent Tl atoms to form distorted RhTl4Rh8 cuboctahedra that share corners with four equivalent TlRh12 cuboctahedra, corners with fourteen RhTl4Rh8 cuboctahedra, edges with six equivalent TlRh12 cuboctahedra, edges with twelve RhTl4Rh8 cuboctahedra, faces with four equivalent TlRh12 cuboctahedra, and faces with sixteen RhTl4Rh8 cuboctahedra. There are a spread of Rh–Rh bond distances ranging from 2.75–2.96 Å. There are two shorter (2.85 Å) and two longer (2.86 Å) Rh–Tl bond lengths. In the second Rh site, Rh is bonded to eight equivalent Rh and four equivalent Tl atoms to form distorted RhTl4Rh8 cuboctahedra that share corners with four equivalent TlRh12 cuboctahedra, corners with fourteen RhTl4Rh8 cuboctahedra, edges with six equivalent TlRh12 cuboctahedra, edges with twelve equivalent RhTl4Rh8 cuboctahedra, faces with four equivalent TlRh12 cuboctahedra, and faces with sixteen RhTl4Rh8 cuboctahedra. There are two shorter (2.85 Å) and two longer (2.86 Å) Rh–Tl bond lengths. Tl is bonded to twelve Rh atoms to form TlRh12 cuboctahedra that share corners with six equivalent TlRh12 cuboctahedra, corners with twelve equivalent RhTl4Rh8 cuboctahedra, edges with eighteen RhTl4Rh8 cuboctahedra, faces with eight equivalent TlRh12 cuboctahedra, and faces with twelve RhTl4Rh8 cuboctahedra.
CaLaTl2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two CaLaTl2 ribbons oriented in the (1, 0, 0) direction. Ca is bonded in a linear geometry to two equivalent Tl atoms. Both Ca–Tl bond lengths are 3.17 Å. La is bonded in a linear geometry to two equivalent Tl atoms. Both La–Tl bond lengths are 3.14 Å. Tl is bonded in a linear geometry to one Ca and one La atom.
CaTl2Pb crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two CaTl2Pb ribbons oriented in the (1, 0, 0) direction. Ca is bonded in a linear geometry to two equivalent Tl atoms. Both Ca–Tl bond lengths are 3.32 Å. Tl is bonded in a linear geometry to one Ca and one Pb atom. The Tl–Pb bond length is 2.92 Å. Pb is bonded in a linear geometry to two equivalent Tl atoms.
Li2YbTl is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Li is bonded in a body-centered cubic geometry to four equivalent Yb and four equivalent Tl atoms. All Li–Yb bond lengths are 3.06 Å. All Li–Tl bond lengths are 3.06 Å. Yb is bonded in a distorted body-centered cubic geometry to eight equivalent Li and six equivalent Tl atoms. All Yb–Tl bond lengths are 3.53 Å. Tl is bonded in a body-centered cubic geometry to eight equivalent Li and six equivalent Yb atoms.
TmYTl2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Tm is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Tm–Tl bond lengths are 3.27 Å. Y is bonded in a body-centered cubic geometry to eight equivalent Tl atoms. All Y–Tl bond lengths are 3.27 Å. Tl is bonded in a body-centered cubic geometry to four equivalent Tm and four equivalent Y atoms.