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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 631 records · Page 35

Technical, economic, and load-following capabilities assessment of grid-connected geothermal and geothermal-solar hybrid systems

The technical and economic performance as well as the load-following capabilities of grid-connected geothermal hybrid systems were assessed in this work. The analyzed geothermal hybrid configuration is composed of a binary geothermal plant integrated with a concentrating solar-thermal system and underground thermal energy storage (UTES) through a primary heat exchanger. Physics-based models for the hybrid system for plant generation capacities of 1, 25, and 50 MW were developed from validated models for each subsystem. Also, an economic model was developed that accounts for different hybrid system capabilities, solar field sizes, and thermal storage duration. The advantage of the geothermal hybrid system was assessed by comparing the performance with the baseline benchmark geothermal plant with a similar configuration and generation capacity. It was found that hybridizing geothermal plants with concentrating solar and thermal energy storage not only improves the thermal efficiency by up to 8 percentage points when additional heat from the solar-UTES loop rises the evaporator temperatures from 70 to 125 °C, but also enhances the load-following capability for the geothermal plant, which can meet a typical residential load profile with a power rate of change 0.25 kW/s with an absolute error under 13 kW for a 1 MW plant. Other benefits of hybridization include resource preservation and a potential LCOE reduction of up to 56% for a 50 MW geothermal hybrid plant having a 50% solar share, a 1.4 solar multiple, and 24-h storage capacity. The results presented in this work demonstrate that hybridizing geothermal systems transforms them into a flexible and cost-effective solution for addressing the dynamic requirements of modern electric grids.

15 GEOTHERMAL ENERGY↗

A High Temperature Gas Reactor Integrated Energy System Using Energy Storage as a Buffer for Hydrogen Production

Analysis of an integrated energy system producing hydrogen in a high temperature steam electrolysis system via steam provided by a sensible heat thermal energy storage system charged by a high temperature gas reactor. Preliminary results over a continuous discharge cycle and single charging cycle shows minimal reactor impact despite 25% electrical power load change. Hydrogen production is held constant with steam provided by the thermal energy storage system.

08 HYDROGEN↗

2023 Real-time Optimization Workflow Status Update

Nuclear integrated energy systems are composed of a diverse set of energy generation sources and exist in dynamic and competitive electricity markets. With the inclusion of thermal energy storage, nuclear power systems can store heat for future use through various processes, such as water desalination or hydrogen generation. This heat storage can be managed in such a way as to economically optimize its usage. By combining real-time price data from the day-ahead and real-time markets with predictive and intelligent models, the charging and discharging of the thermal energy storage may be determined and optimized. This research details an approach through models and systems for the real-time optimization (RTO) of capacity allocation. Virtual models of the energy system and its physics phenomenon and component interactions provide intelligence to verification and prediction of operations. An optimization framework can use data generated from both a set of physical assets as well as the virtual models to predict future performance and create optimization and control workflows. Data warehouse technologies can be used to combine data across models, optimization workflows, market price data, and sensor data to intuitively store various types of data and provide integrations to physical control systems as well as user visualizations. Put together, these components can create a system for the RTO of nuclear integrated energy systems. Various virtual models and bench-scale physical demonstrations have been successfully performed and verified using this system. Larger scale testbeds that include thermal energy storage systems have been identified as future opportunities. A gap analysis that details the steps necessary to reach a physical demonstration at this scale is provided, along with conclusions on the current effort and future work.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Thermal conductivity measurement using modulated photothermal radiometry for nitrate and chloride molten salts

Molten salts are being used or explored for thermal energy storage and conversion systems in concentrating solar power and nuclear power plants. Thermal conductivity of molten salts is an important thermophysical property dictating the performance and cost of these systems, but its accurate measurement has been challenging, as evidenced by wide scattering of existing data in literature. The corrosive and conducting nature of these fluids also leads to time consuming sample preparation processes of many contact-based measurements. Here, in this work, we report the measurement of thermal conductivity of molten salts using a modulated photothermal radiometry (MPR) technique, which is a laser-based, non-contact, frequency-domain method adopted for molten salts for the first time. By unitizing the advantages of front side sensing of frequency-domain measurements and the vertical holder orientation, the technique can minimize the natural convection and salt creeping effects, thus yielding accurate molten salt thermal conductivity . The MPR technique is first calibrated using standard molten materials including paraffin wax and sulfur. It is then applied on measuring pure nitrate salts (NaNO 3 and KNO 3 ), solar salt (NaNO 3 –KNO 3 mixture), and chloride salt (NaCl–KCl–MgCl 2 ). The measurement results are compared with data from literature, especially those obtained from laser flash analysis (LFA). Our results demonstrate that the MPR is a convenient and reliable technique of measuring thermal conductivity of molten salts. Accurate thermal conductivity data of molten salts will be valuable in developing the next-generation high-temperature thermal energy storage and conversion systems.

14 SOLAR ENERGY↗

Using concentrating-solar-power plants as economic carbon-free capacity resources

Deep decarbonization of electricity systems raises concerns about the need for generating capacity that can maintain reliable energy supply. Given this concern, we explore the ability of concentrating-solar-power plants with thermal energy storage to provide a carbon-free source of such capacity. We develop an approach to assessing the capacity contribution of concentrating-solar-power plants that considers future systems. Such considerations are important, because of potential differences in net-load patterns compared to today (e.g., due to higher renewable-energy penetrations). Using historical data spanning an 18-year period, we demonstrate that concentrating-solar-power plants with thermal energy storage can provide this necessary capacity with little impact on their financial viability. We examine the impact of myopic decisions and imperfect foresight of future system conditions on the operation of concentrating-solar-power plants and the resultant impact on their capacity contributions. We find that imperfect foresight can have limited impacts on such a use of concentrating-solar-power plants, so long as proper forecasting techniques are developed and used. Overall, our work shows that concentrating-solar-power plants with thermal energy storage may have a role to play in delivering reliable electricity supply in a decarbonized energy system.

14 SOLAR ENERGY↗

Thermal Storage Performance of a Dual-Purpose Underground Thermal Battery for Shaping the Electric Demand of Buildings

A dual-purpose underground thermal battery (DPUTB) integrates a ground heat exchanger with underground thermal energy storage. It can be installed in shallow boreholes (less than 6 m deep) and thus is less expensive than the conventional ground heat exchangers. The thermal energy storage can be used to shave or shift the electric load for meeting the thermal demands of a building. The charging and discharging performance of a lab-scale DPUTB were tested. The test results show that the DPUTB can be fully charged within 4 h and can provide 34 W cooling continuously for 2.5 h with a supply water temperature below 14°C. A small amount of phase-change material significantly increased the thermal storage capacity.

Wang, Lingshi↗

Thermal energy grid storage: Liquid containment and pumping above 2000 °C

As the cost of renewable energy falls below fossil fuels, the key barrier to widespread sustainable electricity has become availability on demand. Energy storage can enable dispatchable renewables, but only with drastic cost reductions compared to current battery technologies. One electricity storage concept that could enable these cost reductions stores electricity as sensible heat in an extremely hot liquid (>2000°C) and uses multi-junction photovoltaics (MPV) as a heat engine to convert it back to electricity on demand hours, or days, later. Furthermore, this paper reports the first containment of silicon in a multipart graphite tank above 2000°C, using material grades that are affordable for energy storage at GWh scales. Low cost molded graphite with particle sizes as large as 10 μm successfully contained metallurgical grade silicon, even with as much as twothirds iron by mass for up to 10 hours and temperatures as high as 2300°C, in tanks as large as two gallons.

24 POWER TRANSMISSION AND DISTRIBUTION↗

High-temperature Pumping of Silicon for Thermal Energy Grid Storage

As the cost of renewable energy falls below fossil fuels, the key barrier to widespread sustainable electricity has become availability on demand. Energy storage can enable dispatchable renewables, but only with drastic cost reductions compared to current batteries. One electricity storage concept that could enable these cost reductions stores electricity as sensible heat in an extremely hot liquid (>2000 °C) and uses multi-junction photovoltaics (MPV) as a heat engine to convert it back to electricity on demand, hours or days later. This paper follows previously reported technoeconomics and liquid containment, examining equipment that would be needed to exchange heat between resistive heaters, a molten silicon storage tank above 2000 °C, and a heat engine. Herein, we report on a pump that was designed and tested to circulate the liquid silicon between these three regions and the effect of spatial thermal cycling was simulated in models and experiments. While the pump successfully circulated silicon between 1800-2080 °C for ten hours, circulation with a temperature gradient caused it and other non-isothermal experiments to dissolve significantly due to the temperature dependent solubility of not only carbon, but also silicon carbide which otherwise protected the graphite infrastructure. Furthermore, methods to reduce dissolution and an alternative embodiment are presented.

24 POWER TRANSMISSION AND DISTRIBUTION↗

SSTAC/ARTS review of the draft Integrated Technology Plan (ITP). Volume 3: Space power and thermal management

Viewgraphs of briefings from the SSTAC/ARTS review of the draft integrated technology plan on thermal power and thermal management are presented. Topics covered include: space energy conversion research and technology; space photovoltaic energy conversion; chemical energy conversion and storage; thermal energy conversion; power management; thermal management; space nuclear power; high capacity power; surface power and thermal management; space platforms power and thermal management; and project SELENE.

Source record↗

Heat storage in alloy transformations

The feasibility of using metal alloys as thermal energy storage media was investigated. The elements selected as candidate media were limited to aluminum, copper, magnesium, silicon, zinc, calcium, and phosphorus on the basis of low cost and latent heat of transformation. Several new eutectic alloys and ternary intermetallic phases were determined. A new method employing X-ray absorption techniques was developed to determine the coefficients of thermal expansion of both the solid and liquid phases and the volume change during phase transformation. The method and apparatus are discussed and the experimental results are presented for aluminum and two aluminum-eutectic alloys. Candidate materials were evaluated to determine suitable materials for containment of the metal alloys. Graphite was used to contain the alloys during the volume change measurements. Silicon carbide was identified as a promising containment material and surface-coated iron alloys were also evaluated. System considerations that are pertinent if alloy eutectics are used as thermal energy storage media are discussed. Potential applications to solar receivers and industrial furnaces are illustrated schematically.

Birchenall, C. E.↗

Making Small-Volume Heat Pump Water Heaters Larger: A Design Framework for Integrated Phase Change Material Heat Exchangers

Those that use electricity for water heating, the majority use resistive elements rather than heat pump water heaters (HPWHs), the latter of which use 60-70% less energy than the former. One major barrier to wider HPWH adoption is the added equipment required, which prevents current 50-80-gallon tanks on the market from fitting into smaller utility closets sized for 30-40 gallons, such as those found in manufactured housing. Additionally, these smaller HPWHs tend to underperform relative to their larger counterparts. One solution that addresses both space and performance concerns is thermal energy storage, and in particular, phase change materials (PCMs). PCMs have been studied extensively in building envelope and HVAC systems, but remain a nascent technology in residential water heating. While water itself has a uniquely high energy storage capacity, PCMs have an even higher energy storage density, thus providing the potential to elevate the performance of 40-gallon HPWHs to that of 50-gallon or larger tanks. This research is part of a larger project that seeks to utilize thermal energy storage to enable decarbonized water heating in low-income communities. In this study, we outline the design process used to produce novel PCM heat exchangers for use in small-volume HPWH tanks, including the identification of design constraints and performance targets relevant to real-world applications. In order to ensure optimal PCM utilization and tank storage capacity, we focus here on co-maximizing surface area and PCM volume in the heat exchangers; therefore, this research targets triply periodic minimal surface (TPMS) lattices. TPMS lattices boast enhanced heat transfer capabilities compared to traditional heat exchanger geometries and offer highly tailorable designs; thus, they pair well with the growing field of additive manufacturing, or 3D printing. Starting with a suite of TPMS lattices, we demonstrate a systematic approach for narrowing down feasible designs that comply with identified constraints while meeting PCM performance objectives.

25 ENERGY STORAGE↗

The heat transfer coefficient associated with a moving packed bed of silica particles flowing through parallel plates

Concentrating Solar Power (CSP) with thermal energy storage has the potential to be a renewable energy technology with long duration, inexpensive energy storage. Higher temperature operation increases the conversion efficiency and reduces the cost of energy storage. Several emerging CSP designs utilize particles as the solar receiver due to their high temperature stability and low cost. In some designs, the particles are also used as the thermal energy storage (TES) media. In either configuration, an energy transfer is required between the hot particles and the working fluid in the power cycle in a Particle-to-Fluid Heat Exchanger (PtFHX). Understanding the heat transfer between a moving packed bed and a stationary surface is critical to the successful design of a PtFHX. In this paper, a test facility is described in which a moving packed bed of silica sand with particle size 100–600 μm is introduced into the channel formed by two parallel plates, one of which is heated. The effective static thermal conductivity of the particles used for the test are separately measured over the entire range of test temperatures. The inlet and outlet bulk temperatures of the particle flow are measured as are the surface temperatures at several axial locations along the centerline of the plate. The result is the measurement of heat transfer coefficient as a function of temperature for several velocities. The uncertainty of the measurements is presented and the results are compared to model results found in the literature.

14 SOLAR ENERGY↗

Thermal Charging Rate of Composite Wax-Expanded Graphite Phase Change Materials

Phase change materials (PCMs) are valuable for their ability to store heat nearly isothermally around their phase transition temperature. PCMs are at the core of latent heat thermal energy storage (LHTES) systems, which provide the ability to buffer high thermal loads or decouple the time when heating or cooling is needed from when it is produced. Thermal charging and discharging of LHTES systems often employ a constant temperature source, and the rate at which heat can be exchanged is dependent on the thermophysical properties of the PCM. For graphite composite PCMs, the high thermal conductivity of the graphite enables an increased heat transfer rate through the material, but its presence displaces PCM which reduces the effective volumetric latent heat of the composite relative to the pure PCM. This results in a tradeoff between thermal power and volumetric energy storage capacity. The thermal charging rate is the average thermal energy stored in the material for some elapsed time. In this study, composite PCMs of compressed expanded natural graphite (CENG) and n-Octadecane are studied. Samples with varying CENG mass fractions were synthesized and the thermal charging rate was measured under a constant temperature boundary condition. For evaluation of the expanded graphite-PCM composite, one boundary of the material was exposed to a 50°C constant temperature plate, above the 27.5°C melting temperature of the PCM. The melting front progression [mm-s-1] and the thermal charging rate [W-cm-2] of the PCM were determined, and the results were compared with analytical predictions for the 1-D semi-infinite phase change. For CENG addition up to 5.75% mass fraction, a 450% thermal conductivity increase was observed with a 5% decrease in volumetric energy density as compared to pure octadecane. The average thermal charging rate was increased by over 430% for the melt to penetrate a depth of 22 mm. The experimental results matched analytical predictions, indicating that higher CENG fractions can be evaluated using analytical approaches.

Hirschey, Jason↗

Energy storage and thermal control system design status

The Space Station Freedom electric power system (EPS) will initially rely on photovoltaics for power generation and Ni/H2 batteries for electrical energy storage. The current design for and the development status of two major subsystems in the PV Power Module is discussed. The energy storage subsystem comprised of high capacity Ni/H2 batteries and the single-phase thermal control system that rejects the excess heat generated by the batteries and other components associated with power generation and storage is described.

Simons, Stephen N.↗

Energy storage and thermal control system design status

The Space Station Freedom electric power system (EPS) will initially rely on photovoltaics for power generation and Ni/H2 batteries for electrical energy storage. The current design for the development status of two major subsystems in the PV Power Module is discussed. The energy storage subsystem comprised of high capacity Ni/H2 batteries and the single-phase thermal control system that rejects the excess heat generated by the batteries and other components associated with power generation andstorage is described.

Simons, Stephen N.↗

Market Brief: Customer-sited Distributed Energy Resources

This market brief summarizes key takeaways from interviews with vendors and service providers in one or more areas of the DER market: DER controls, battery storage, solar photovoltaic, thermal energy storage, combined heat and power, flexible building loads, and electric vehicle charging. Back-up generators used only in emergencies are not in the scope of this market brief.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Thermal performance of phase change materials with anisotropic carbon fiber inserts

In thermal energy storage systems, phase change materials (PCMs) are widely used for thermal energy management. Most PCMs have low thermal conductivities, which limits the heat transfer rate within PCM and thus makes the phase-changing process very slow. However, thermal conductivities of PCMs can be altered by inserting targeted additives. We hypothesize that the size and shape of these additive inserts play a key role in thermal management efficiency. To this end, the impacts of carbon fiber (CF) inserts on the phase change behavior and consequent heat transfer efficiencies of inorganic and organic PCMs were investigated using experiments and simulations. Long, anisotropic CFs with high thermal conductivities formed continuous fast heat flux tunnels inside PCMs to enhance the heat transfer. Such CFs could extend the phase change fronts from the limited container-shaped interface to the larger surface of numerous CF inserts inside the PCM. These special CF inserts work with a new heat transfer mechanism, different from conventional small additives or long isotropic CF inserts. The thermal energy release rate increased by 2.5 times with 1 wt.% anisotropic CF inserts in inorganic PCM. However, CF inserts in liquid organic PCM hindered the natural convection and compromised the improved heat conduction. In conclusion, the lab-scale multiphysics simulations support these experimental observations and indicate that CF inserts have potential to enhance heat transfer in inorganic PCMs, but they are less effective in organic PCMs.

25 ENERGY STORAGE↗

Concentrating solar thermal power in the U.S.: lessons from setbacks at Ivanpah, light for the future

Concentrating solar thermal power (CSP) exhibits promise as a source of firm electricity. The proposed termination of Ivanpah’s power purchase agreement hinders confidence in the country’s CSP future. This work highlights how the lack of thermal energy storage (TES) undermined the first-of-a-kind plant’s economics as California’s grid transformed. Then, possible futures of the Ivanpah facility are analyzed; results show retrofitting with state-of-the-art TES systems could provide better returns.

14 SOLAR ENERGY↗