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Stimulated Rayleigh-Brillouin gain spectra of pure gases are reported. Stimulated Rayleigh scattering is now clearly distinguishable from stimulated Brillouin scattering without the aid of induced absorption. As examples, spectral line shapes of Ar and SF6 at various pressures and the associated gain asymmetry are discussed. Potential applications of coherent Rayleigh-Brillouin spectroscopy are suggested.
An adiabatic quantal theory of spectral line shapes in collision-induced absorption and emission is presented which incorporates the induced translation-rotation and translation-vibration spectra. The generalization to account for the anisotropy of the scattering potential is given. Calculations are carried out of the collision-induced absorption spectra of He in collisions with H2 with ab initio electric dipole functions and realistic potentials. The anisotropy of the interaction potential is small and is not included in the calculations. The predicted spectra are in satisfactory agreement with experimental data though some deviations occur which may be significant. The rotational line shapes have exponential wings and are not Lorentzian. The connection between the quantal and classical theories is written out explicitly for the isotropic overlap induction.
A description is presented of coherent Raman spectroscopic studies of N2, CO, and NO molecules. It is pointed out that the Q-branch Raman spectra of these simple diatomics are characterized by lines which overlap with increasing pressure as a result of collisional line broadening. Attention is given to Q-branch vibrational spectra and their determination, the spectral line shape of isolated lines, the line overlap regime, fitting laws, and the isotropic Raman spectrum of NO. It is found that the room temperature spectra of the considered molecules at low pressure (approximately 0.2 atm) may be treated as a sum of isolated lines. It is possible to extract J-dependent pressure-broadening coefficients. With increasing pressure, collisional narrowing occurs and the description of the spectrum must include the effects of interference among neighboring lines.
On the basis of a spectral line shape computation and radiative transfer calculations, it is shown that the unexplained, diminutive structures seen in the Voyager IRIS Jovian spectra near the hydrogen S0(0) and S0(1) rotational frequencies are due to bound-free transitions involving hydrogen dimers. The absorption intensities of these transitions, as well as of the collision-induced background, are given. These dimer structures may possibly prove to be useful for determining the helium/hydrogen ratio and the para-hydrogen fraction in the atmospheres of the outer planets.
The Airborne Imaging Spectrometer (AIS) was flown over granitic, volcanic, and calc-silicate terrain around the Mary Kathleen Uranium Mine in Queensland, in a test of its mineralocial mapping capabilities. An analysis strategy and restoration and enhancement techniques were developed to process the 128 band AIS data. A preliminary analysis of one of three AIS flight lines shows that the data contains considerable spectral variation but that it is also contaminated by second-order leakage of radiation from the near-infrared region. This makes the recognition of expected spectral absorption shapes very difficult. The effect appears worst in terrains containing considerable vegetation. Techniques that try to predict this supplementary radiation coupled with the log residual analytical technique show that expected mineral absorption spectra can be derived. The techniques suggest that with additional refinement correction procedures, the Australian AIS data may be revised. Application of the log residual analysis method has proved very successful on the cuprite, Nevada data set, and for highlighting the alunite, linite, and SiOH mineralogy.
High resolution (lambda/delta lambda approx. = 3 x 10 to the 5th power) near-infrared observations of H2O emission from Comet Halley were acquired at the time of maximum post-perihelion geocentric Doppler shift. The observed widths and absolute positions of the H2O line profiles reveal characteristics of the molecular velocity field in the coma. These results support H2O outflow from a Sun-lit hemisphere or the entire nucleus, but not from a single, narrow jet emanating from the nucleus. The measured pre- and post-perihelion outflow velocities were 0.9 + or - 0.2 and 1.4 + or - 0.2 km/s, respectively. Temporal variations in the kinematic properties of the outflow were inferred from changes in the spectral line shapes. These results are consistent with the release of H2O into the coma from multiple jets.
High-resolution observations of H2O in comet Halley are presented. The positions and widths of the H2O emission line profiles are indicative of the coma's velocity field characteristics. Spectral line shape changes are used to infer temporal variations in the kinematic properties of the outflow. The results suggest that H2O is released into the coma by way of multiple jets.
Ion implanted (100) cadmium telluride was studied using the contactless technique of photoreflectance. The implantations were performed using 50- to 400-keV boron ions to a maximum dosage of 1.5 x 10(16)/sq cm, and the annealing was accomplished at 500 C under vacuum. The spectral measurements were made at 77 K near the E(0) and E(1) critical points; all the spectra were computer-fitted to Aspnes' theory. The spectral line shapes from the ion damaged, partially recovered and undamaged, or fully recovered regions could be identified, and the respective volume fraction of each phase was estimated.
The influence of the optical Stark effect on spectral line shapes in four-wave-mixing Raman spectroscopy (FWMRS) and stimulated Raman spectroscopy (SRS) is investigated experimentally and theoretically. Using an experimental setup capable of rapid alternation between the simultaneous measurement of coherent Stokes Raman spectroscopy and inverse Raman spectroscopy at low and high intensities, together with a sophisticated frequency reference scheme, it was possible to perform a rather direct comparison between Stark-broadened and non-Stark-broadened spectra of both classes of Raman spectroscopies. The results demonstrate that SRS spectra show more Stark shift and broadening than their FWMRS counterparts. A discrepancy with theoretical results is pointed out, and an attempt is made to explain it.
Atomic absorption spectroscopy was utilized to measure the ground state atomic hydrogen number density in the plasma produced in a low power hydrogen arcjet. A microwave driven hydrogen plasma was used as the source of radiation resonant with the vacuum ultraviolet Lyman alpha transition. The suitability of this radiation source is discussed. The optical depth of this transition prevented measurements at locations where the ground state atomic hydrogen number density was larger than 3 x 10 exp 19/cu m. These results indicate that other single-photon optical diagnostic techniques are equally ineffective in locations of higher hydrogen number density unless the spectral line shape of the atomic hydrogen absorbers is known.
An extreme ultraviolet imaging spectrograph was used to obtain coronal observations with high spectral and spatial resolution. The imaging properties of the instrument enable measurements of spectral line shapes and positions in discrete spatial elements of a region, so that the dynamic characteristics of the coronal plasma, as well as the distribution of emission measure with temperature and well known density diagnostics, can be studied for specific features. The instrumentation is described and several results of a sounding rocket flight on 5 May 1989, when the corona over NOAA Region 5464 including emission over the umbra of the region's largest sunspot and the pre-impulsive phase emission of a small flare was recorded, are summarized.
Two FTIR spectrometers were employed in the late winters 1990 and 1991 in Esrange, North Sweden, and in Ny Aalesund, Spitsbergen to detect zenith column amounts of several trace gases. Time series of column amounts of the trace gases O3, N2O, CH4, HNO3, NO2, CHl, and HF have been derived from the measured spectra. Additionally, some information on the vertical distribution of HCl could be obtained by analyzing the spectral line shapes. The results are interpreted in terms of dynamical and chemical processes.
The gamma-ray spectrum simulation program BSIMUL was designed to allow the operator to follow the path of a gamma-ray through a detector, shield and collimator whose dimensions are entered by the operator. It can also be used to simulate spectra that would be generated by a detector. Several improvements have been made to the program within the last few months. The detector, shield and collimator dimensions can now be entered through an interactive menu whose options are discussed below. In addition, spectra containing more than one gamma-ray energy can now be generated with the menu - for isotopes listed in the program. Adding isotopes to the main routine is also quite easy. Subroutines have been added to enable the operator to specify the material and dimensions of a collimator. This report details the progress made in simulating gamma-ray spectra for a variety of user-specified detector designs. In addition, a short discussion of work done in the related areas of pulse shape analysis and the spectral analysis is included. The pulse shape analysis and spectral analysis work is being performed pursuant to the requirements of contract F-94-C-0006, for the Advanced Research Projects Agency and the U.S. Air Force.
We describe a refined calculation of high-energy emission from rotation-powered pulsars based on the outer gap model of Cheng, Ho, & Ruderman (1986 a, b). In this calculation, vacuum gaps form in regions near the speed-of-light cylinder of the pulsar magnetosphere along the boundary between the closed and open field line zones. We have improved upon previous efforts to model the spectra from these pulsars (e.g., Cheng et al. 1986b; Ho 1989) by following the variation in particle production and radiation properties with position in the outer gap. Curvature, synchotron, and inverse-Compton scattering fluxes vary significantly over the gap, and their interactions via photon-photon pair production build up the radiating charge populations at varying rates. We have also incorporated an approximate treatment of the transport particle and photon fluxes between gap emission zones. These effects, along with improved computations of the particle and photon distribution, provide very important modifications of the model gamma-ray flux. In paticular, we attempt to make specific predictions of pulse profile shapes and spectral variations as a function of pulse phase and suggest further extensions to the model which may provide accurate computations of the observed high-energy emissions.
Filtered Rayleigh Scattering (FRS) is a diagnostic technique which measures velocity, temperature, and pressure by determining Doppler shift, total intensity, and spectral line shape of laser induced Rayleigh-Brillouin scattering. In the work reported here, this is accomplished by using a narrow line width, injection seeded Nd-YAG laser sheet to induce Rayleigh-Brillouin scattering from a gas flow. This light is passed through an optical notch filter, and transmitted light is imaged onto an intensified charge coupled display (CCD) camera. By monitoring the grayscale value at a particular pixel while the laser frequency is tuned, the convolution between the Rayleigh-Brillouin scattering profile and the filter transmission profile is attained. Since the filter profile can be independently measured, it can be deconvolved from the measuring signal, yielding the Rayleigh-Brillouin scattering profile. From this profile, flow velocity, temperature, and pressure are determined. In this paper the construction and characterization of the optical notch filter and a newly developed frequency apparatus are discussed.
Earth science research and application requirements for multispectral data have often been driven by currently available remote sensing technology. Few parametric studies exist that specify data required for certain applications. Consequently, data requirements are often defined based on the best data available or on what has worked successfully in the past. Since properties such as spatial resolution, swath width, spectral bands, signal-to-noise ratio (SNR), data quantization and band-to-band registration drive sensor platform and spacecraft system architecture and cost, analysis of these criteria is important to optimize system design objectively. Remote sensing data requirements are also linked to calibration and characterization methods. Parameters such as spatial resolution, radiometric accuracy and geopositional accuracy affect the complexity and cost of calibration methods. However, few studies have quantified the true accuracies required for specific problems. As calibration methods and standards are proposed, it is important that they be tied to well-known data requirements. The Application Research Toolbox (ART) developed at the John C. Stennis Space Center provides a simulation-based method for multispectral data requirements development. The ART produces simulated datasets from hyperspectral data through band synthesis. Parameters such as spectral band shape and width, SNR, data quantization, spatial resolution and band-to-band registration can be varied to create many different simulated data products. Simulated data utility can then be assessed for different applications so that requirements can be better understood.
Earth science research and application requirements for multispectral data have often been driven by currently available remote sensing technology. Few parametric studies exist that specify data required for certain applications. Consequently, data requirements are often defined based on the best data available or on what has worked successfully in the past. Since properites such as spatial resolution, swath width, spectral bands, signal-to-noise ratio (SNR), data quantization, and band-to-band registration drive sensor platform and spaceraft system architecture and cost, analysis of these criteria is important to objectively optimize system design. Remote sensing data requirements are also linked to calibration and characterization methods. Parameters such as spatial resolution, radiometric accuracy, and geopositional accuracy affect the complexity and cost of calibration methods. However, there are few studies that quantify the true accuracies required for specific problems. As calibration methods and standards are proposed, it is important that they be tied to well-known data requirements. The Application Research Toolbox (ART) developed at Stennis Space Center provides a simulation-based method for multispectral data requirements development. The ART produces simulated data sets from hyperspectral data through band synthesis. Parameters such as spectral band shape and width, SNR, data quantization, spatial resolution, and band-to-band registration can be varied to create many different simulated data products. Simulated data utility can then be assessed for different applications so that requirements can be better understood. This paper describes the ART and its applicability for rigorously deriving remote sensing data requirements.
We study the linear intersubband absorption spectra of a 15 nm InAs quantum well using the intersubband semiconductor Bloch equations with a three-subband model and a constant dephasing rate. We demonstrate the evolution of intersubband absorption spectral line shape as a function of temperature and electron density. Through a detailed examination of various contributions, such as the phase space filling effects, the Coulomb many-body effects and the non-parabolicity effect, we illuminate the underlying physics that shapes the spectra. Keywords: Intersubband transition, linear absorption, semiconductor heterostructure, InAs quantum well